CN106116423B - A kind of preparation method of biomass energy-storage thermal-insulating tile - Google Patents
A kind of preparation method of biomass energy-storage thermal-insulating tile Download PDFInfo
- Publication number
- CN106116423B CN106116423B CN201610477192.4A CN201610477192A CN106116423B CN 106116423 B CN106116423 B CN 106116423B CN 201610477192 A CN201610477192 A CN 201610477192A CN 106116423 B CN106116423 B CN 106116423B
- Authority
- CN
- China
- Prior art keywords
- energy
- parts
- energy storage
- expanded perlite
- obtained above
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000004146 energy storage Methods 0.000 title claims abstract description 66
- 239000002028 Biomass Substances 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000010451 perlite Substances 0.000 claims abstract description 28
- 235000019362 perlite Nutrition 0.000 claims abstract description 28
- 230000008859 change Effects 0.000 claims abstract description 18
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 17
- 239000000194 fatty acid Substances 0.000 claims abstract description 17
- 229930195729 fatty acid Natural products 0.000 claims abstract description 17
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 17
- 239000000839 emulsion Substances 0.000 claims abstract description 14
- 239000000945 filler Substances 0.000 claims abstract description 14
- 238000007127 saponification reaction Methods 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims abstract description 13
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 17
- 239000002002 slurry Substances 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000003925 fat Substances 0.000 claims description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 235000012216 bentonite Nutrition 0.000 claims description 12
- 238000001914 filtration Methods 0.000 claims description 12
- 239000011521 glass Substances 0.000 claims description 12
- 239000003643 water by type Substances 0.000 claims description 8
- 239000006210 lotion Substances 0.000 claims description 7
- 238000006722 reduction reaction Methods 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 7
- 239000000440 bentonite Substances 0.000 claims description 6
- 229910000278 bentonite Inorganic materials 0.000 claims description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 6
- 238000001354 calcination Methods 0.000 claims description 6
- 239000004568 cement Substances 0.000 claims description 6
- 238000005253 cladding Methods 0.000 claims description 6
- 150000002193 fatty amides Chemical class 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 238000003837 high-temperature calcination Methods 0.000 claims description 6
- 239000005457 ice water Substances 0.000 claims description 6
- 238000002347 injection Methods 0.000 claims description 6
- 239000007924 injection Substances 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 6
- 238000001179 sorption measurement Methods 0.000 claims description 6
- 230000002269 spontaneous effect Effects 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 5
- 229960000583 acetic acid Drugs 0.000 claims description 5
- 229910052796 boron Inorganic materials 0.000 claims description 5
- 230000010355 oscillation Effects 0.000 claims description 5
- 239000010453 quartz Substances 0.000 claims description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 4
- OVYTZAASVAZITK-UHFFFAOYSA-M sodium;ethanol;hydroxide Chemical compound [OH-].[Na+].CCO OVYTZAASVAZITK-UHFFFAOYSA-M 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 238000013019 agitation Methods 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 11
- 239000007791 liquid phase Substances 0.000 abstract description 7
- 239000002994 raw material Substances 0.000 abstract description 7
- 239000002253 acid Substances 0.000 abstract description 5
- 239000012782 phase change material Substances 0.000 abstract description 5
- 238000004378 air conditioning Methods 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 125000001931 aliphatic group Chemical group 0.000 abstract description 2
- 239000012075 bio-oil Substances 0.000 abstract description 2
- 238000000748 compression moulding Methods 0.000 abstract description 2
- 239000004035 construction material Substances 0.000 abstract description 2
- 230000007547 defect Effects 0.000 abstract description 2
- 230000007812 deficiency Effects 0.000 abstract description 2
- 238000007598 dipping method Methods 0.000 abstract description 2
- 238000004945 emulsification Methods 0.000 abstract description 2
- 230000009467 reduction Effects 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000011232 storage material Substances 0.000 description 23
- 239000012071 phase Substances 0.000 description 12
- 230000009466 transformation Effects 0.000 description 9
- 239000007788 liquid Substances 0.000 description 8
- 230000007704 transition Effects 0.000 description 6
- 238000009413 insulation Methods 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical class [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 4
- 238000003760 magnetic stirring Methods 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 238000009423 ventilation Methods 0.000 description 4
- 230000001476 alcoholic effect Effects 0.000 description 3
- 238000003763 carbonization Methods 0.000 description 3
- 238000002242 deionisation method Methods 0.000 description 3
- 239000012074 organic phase Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229910052580 B4C Inorganic materials 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 description 1
- -1 boron carbides Chemical class 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000036561 sun exposure Effects 0.000 description 1
- 238000004781 supercooling Methods 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/14—Minerals of vulcanic origin
- C04B14/18—Perlite
- C04B14/185—Perlite expanded
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/1018—Coating or impregnating with organic materials
- C04B20/1022—Non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/1018—Coating or impregnating with organic materials
- C04B20/1022—Non-macromolecular compounds
- C04B20/1025—Fats; Fatty oils; Ester type waxes; Higher fatty acids; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/1055—Coating or impregnating with inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/12—Multiple coating or impregnating
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Civil Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Building Environments (AREA)
Abstract
The present invention relates to a kind of preparation methods of biomass energy-storage thermal-insulating tile, belong to construction material preparation field.This method is using leaf fat as raw material, compound lard fatty acid mixed is made in the buck saponification after tanning, acid adding reduction, by emulsification pretreatment after itself and lauryl alcohol mixing, energy storage filler is made with emulsion dipping expanded perlite, is aided with after other raw material compression mouldings up to biomass energy-storage thermal-insulating tile.The organic solid-liquid phase change material of aliphatic acid is made by raw material of bio oil in the present invention, it is loaded with expanded perlite, it solves fatty acid solid-liquid phase change material and is easy leakage when in use, oxygenolysis and the defect of volatilization easily occur under high temperature, and the heat of sunlight is absorbed using phase-change material, solid-liquid phase change occurs, automatically adjusts environment temperature, it compensates for again and brings the deficiency that mass energy consumes using air-conditioning, be a kind of new product of environmental protection and energy saving.
Description
Technical field
The present invention relates to a kind of preparation methods of biomass energy-storage thermal-insulating tile, belong to construction material preparation field.
Background technology
Tile, which is human occupancy, must use basic building block, and effect is rain-proof and heat-insulated, it can through exposing to the sun and rain and for many years
It is not bad.And plain tiles just seem less desirable on heat insulation, especially summer directly receives burning sun exposure, Indoor Temperature
Degree differed for ten several years up to the room temperature of more than 40 degree and lower layer.Thus, the resident for living in top layer day and night will be by high temperature in summer
It scorches.To winter since roofing is thin, poor thermal insulation property, thus tested again by severe cold, so it is desirable in roof room
Face can add the device of sunshading and thermal insulating.
Phase-change accumulation energy is the important technology of a kind of the raising efficiency of energy utilization and environmental protection of rising in recent years, be can be used for
Solve the mismatch contradiction between thermal energy supply and demand.When ambient temperature is excessively high, phase change material melts, and absorbs extraneous heat and works as
When external environment is too low, phase change material solidification, outwardly heat release, to reach control ambient temperature and energy-efficient purpose.
Currently used phase-changing energy storage material includes mainly inorganic and organic phase change material two major classes.Most inorganic phases
Change energy-storage material has the shortcomings that corrosivity to building structure and has supercooling and phase separation in phase transition process, limits in this way
Its application.Organic phase change energy storage material is non-corrosive, the shortcomings that in phase transition process almost without being subcooled and being separated, and
Chemical property is stablized, but common paraffin class organic phase change material is obtained through non-renewable mineral oil, and fatty
Acids solid-liquid phase change material has natural reproducible, can be extracted from biology, but is easy leakage when in use, under high temperature easily
Oxygenolysis and volatilization etc. occurs.
Invention content
Present invention mainly solves the technical issues of：Single for current plain tiles functionality, heat insulation is undesirable, protects
Warm poor performance causes Summer Indoor temperature excessively high, and winter temperature is again low, and adjusts room temperature using air-conditioning and consume mass energy,
The present situation for not meeting energy-saving and environment-friendly modern life theory provides a kind of preparation method of biomass energy-storage thermal-insulating tile.It should
Method is using leaf fat as raw material, the buck saponification after tanning, and lard fatty acid mixed is made in acid adding reduction, it is mixed with lauryl alcohol
Emulsification pretreatment after conjunction is made energy storage filler with emulsion dipping expanded perlite, is aided with after other raw material compression mouldings up to raw
Substance energy-storage thermal-insulating tile.The organic solid-liquid phase change material of aliphatic acid is made by raw material of bio oil in the present invention, is entrained in tile slurry
Thermal insulation tile is made in material, loads phase-change material with expanded perlite, solves fatty acid solid-liquid phase change material and hold when in use
It easily reveals, oxygenolysis and the defect of volatilization easily occurs under high temperature, and the sun is absorbed using phase-change material in tile is entrained in
The heat of light occurs solid-liquid phase change, heat storage is got up, avoids heat through tile and improves indoor temperature, has arrived at night
Temperature reduce, and can by daytime store heat discharge, avoid indoor temperature at night too low, to reach control environment temperature and
Energy-efficient purpose, and compensate for and bring the deficiency that mass energy consumes using air-conditioning, it is a kind of new product of environmental protection and energy saving.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
（1）It weighs 1~2kg leaf fats and is cut into the fritter that grain size is 2~3cm by knife, put it into iron pan and be added 200
~300mL deionized waters, first big fire change into small fire after enduring to boiling water, continue 40~60min of tanning, and the filtering removal dregs of fat obtain
Lard；
（2）It measures the above-mentioned boiled lards of 400~500mL to move into glass, is by volume 1:5 add into lard
Enter a concentration of 0.3mol/L sodium hydroxides ethanol solution, and glass moved into 65~75 DEG C of water-bath, is placed on magnetic force
On blender, 1~2h is stirred to react with 400~500r/min rotating speeds and obtains saponification liquor；
（3）A concentration of 0.5mol/L vinegar acid for adjusting pH is added into above-mentioned saponification liquor again to 3~4, stirs reduction reaction 30
It moves into 4~6 DEG C of ice-water baths and stands overnight after~40min, isolated upper layer lard fatty acid mixed, with 30~40 DEG C of warm water
Washing to leacheate is in neutrality；
（4）It is 2 by volume:1 will be fitted into after lard fatty acid mixed obtained above and lauryl alcohol mixing in beaker, add
Both enter the fatty amide polyoxyethylene ether of gross mass 10~15%, move into ultrasonic disperse instrument, at 35~45 DEG C with 200~
300W power ultrasonics disperse 30~40min, and energy storage emulsion is made, spare；
（5）It weighs 40~50g perlite ores to be put into Muffle furnace, 15~20min of preheating and calcining at 300~400 DEG C,
The ore in sand form after preheating is moved into tube type resistance furnace again, instant heating continues 10~15min of high-temperature calcination to 1000~1100 DEG C,
Obtain expanded perlite；
（6）Expanded perlite obtained above is immersed in the spare energy storage emulsion of 3~5 times of its volume, is shaken with whirlpool
It swings instrument and steeped overnight is vibrated with 30~40W power vortexs, the expanded perlite of adsorption energy-storing lotion is obtained by filtration, and rapidly by it
Vacuum tank is moved into, pours into and fills in the tray that grain size is 3~5 μm of Ultra-fine Bentonites, one layer of Ultra-fine Bentonite of cladding is rolled, is put into
Baking oven dry 2~3h at 105~110 DEG C, obtains energy storage filler；
（7）Meter weighs 50~60 parts of cement, 10~20 parts of quartz fibres, 10~15 parts of Ludox, 3~5 in parts by weight
Part boron carbide and 30~40 parts of energy storage fillers obtained above and 200~300 parts of deionized waters, are packed into Horizontal type mixer together
In, 3~5h of batch mixing obtains slurry；
（8）In the tile mould that slurry obtained above injection bottom is carried to 300 mesh screens, and extremely to mould pressurizing
100~140kPa pressurizes, 40~60min makes the moisture in slurry extrude, after placing it in the drying of spontaneous curing at room temperature 3~5 days
Form removal is to get biomass energy-storage thermal-insulating tile.
The principle of the present invention：Using energy storage material absorb solar radiant heat and cross-ventilation heat transfer and temperature rise, when up to
To energy storage material fusing point when, energy storage material is undergone phase transition, and becomes liquid from solid-state, while absorbing thermal energy and having been stored
Come, when temperature reduces, the temperature of energy storage material declines therewith, when temperature drops to the transformation temperature of energy storage material, generates inverse
Phase transformation is changed into solid-state by liquid, and the heat of storage is released, to play the role of controlling environment temperature.
The beneficial effects of the invention are as follows：
（1）Energy-storage thermal-insulating tile produced by the present invention is raw material using renewable substance, derives from a wealth of sources, meets sustainable development
The theory of exhibition；
（2）Energy-storage thermal-insulating tile heat-proof quality produced by the present invention is splendid, top layer indoor temperature and lower layer's indoor temperature temperature
Only 2~3 DEG C of difference, has good heat insulation；
（3）Energy-storage thermal-insulating tile produced by the present invention can control environment temperature by phase transformation, automatically adjust indoor temperature,
Energy consumption caused by reducing air-conditioning temperature adjustment meets energy-saving and environment-friendly modern life theory.
Specific implementation mode
It weighs 1~2kg leaf fats and is cut into the fritter that grain size is 2~3cm by knife, put it into iron pan and it is added 200~
300mL deionized waters, first big fire change into small fire after enduring to boiling water, continue 40~60min of tanning, and the filtering removal dregs of fat obtain pig
Oil；It measures the above-mentioned boiled lards of 400~500mL to move into glass, is by volume 1:5 be added into lard it is a concentration of
0.3mol/L sodium hydroxide ethanol solutions, and glass is moved into 65~75 DEG C of water-bath, it is placed on magnetic stirring apparatus,
It is stirred to react 1~2h with 400~500r/min rotating speeds and obtains saponification liquor；A concentration of 0.5mol/L vinegar is added into above-mentioned saponification liquor again
Acid for adjusting pH is moved into 4~6 DEG C of ice-water baths after 30~40min of stirring reduction reaction and is stood overnight to 3~4, isolated upper layer
Lard fatty acid mixed is washed to leacheate with 30~40 DEG C of warm water and is in neutrality；It is 2 by volume:1 by lard obtained above
It is fitted into beaker after fatty acid mixed and lauryl alcohol mixing, the fatty amide polyoxyethylene ether of the two gross mass 10~15% is added,
It moves into ultrasonic disperse instrument, 30~40min is disperseed with 200~300W power ultrasonics at 35~45 DEG C, energy storage emulsion is made,
It is spare；It weighs 40~50g perlite ores to be put into Muffle furnace, 15~20min of preheating and calcining at 300~400 DEG C, then will be pre-
Ore in sand form after heat moves into tube type resistance furnace, and instant heating continues 10~15min of high-temperature calcination, obtain swollen to 1000~1100 DEG C
Swollen perlite；Expanded perlite obtained above is immersed in the spare energy storage emulsion of 3~5 times of its volume, vortex oscillation is used
Instrument vibrates steeped overnight with 30~40W power vortexs, the expanded perlite of adsorption energy-storing lotion is obtained by filtration, and moved rapidly
Enter vacuum tank, pour into and fill in the tray that grain size is 3~5 μm of Ultra-fine Bentonites, rolls one layer of Ultra-fine Bentonite of cladding, be put into baking
Case dry 2~3h at 105~110 DEG C, obtains energy storage filler；Meter weighs 50~60 parts of cement, 10~20 parts of stones in parts by weight
English fiber, 10~15 parts of Ludox, 3~5 parts of boron carbides and 30~40 parts of energy storage fillers obtained above and 200~300 parts
Deionized water is fitted into Horizontal type mixer together, and 3~5h of batch mixing obtains slurry；Slurry obtained above injection bottom is carried 300
In the tile mould of mesh screen, and the moisture in slurry is set to extrude mould pressurizing to 100~140kPa pressurizes, 40~60min,
Place it in spontaneous curing at room temperature dry 3~5 days after form removal to get biomass energy-storage thermal-insulating tile.
Example 1
It weighs 1kg leaf fats and is cut into the fritter that grain size is 2cm by knife, put it into iron pan and 200mL deionizations are added
Water, first big fire change into small fire after enduring to boiling water, continue to boil 40min, the filtering removal dregs of fat obtain lard；It measures on 400mL
It states boiled lard to move into glass, is by volume 1:5 a concentration of 0.3mol/L sodium hydroxides second is added into lard
Alcoholic solution, and glass is moved into 65 DEG C of water-bath, it is placed on magnetic stirring apparatus, is stirred to react with 400r/min rotating speeds
1h obtains saponification liquor；A concentration of 0.5mol/L vinegar acid for adjusting pH is added into above-mentioned saponification liquor again to 3, stirs reduction reaction 30min
It moves into 4 DEG C of ice-water baths and stands overnight afterwards, isolated upper layer lard fatty acid mixed is washed to leacheate with 30 DEG C of warm water and is in
It is neutral；It is 2 by volume:Both 1 will be fitted into after lard fatty acid mixed obtained above and lauryl alcohol mixing in beaker, be added
The fatty amide polyoxyethylene ether of gross mass 10% moves into ultrasonic disperse instrument, is disperseed with 200W power ultrasonics at 35 DEG C
Energy storage emulsion is made in 30min, spare；It weighs 40g perlite ores to be put into Muffle furnace, the preheating and calcining at 300 DEG C
15min, then the ore in sand form after preheating is moved into tube type resistance furnace, instant heating continues high-temperature calcination 10min, obtains to 1000 DEG C
Expanded perlite；Expanded perlite obtained above is immersed in the spare energy storage emulsion of 3 times of its volume, vortex oscillation instrument is used
Steeped overnight is vibrated with 30W power vortexs, the expanded perlite of adsorption energy-storing lotion is obtained by filtration, and move it into vacuum rapidly
Case is poured into and is filled in the tray that grain size is 3 μm of Ultra-fine Bentonites, is rolled one layer of Ultra-fine Bentonite of cladding, is put into baking oven in 105 DEG C
Lower dry 2h, obtains energy storage filler；Meter weighs 50 parts of cement, 10 parts of quartz fibres, 10 parts of Ludox, 3 parts of carbonizations in parts by weight
Boron and 30 parts of energy storage fillers obtained above and 200 parts of deionized waters, are fitted into Horizontal type mixer, batch mixing 3h must be starched together
Material；In the tile mould that slurry obtained above injection bottom is carried to 300 mesh screens, and to mould pressurizing to 100kPa pressurizes
40min makes the moisture in slurry extrude, place it in spontaneous curing at room temperature dry 3 days after form removal to get biomass energy storage every
Hot tile.
The principle of the present invention：Using energy storage material absorb solar radiant heat and cross-ventilation heat transfer and temperature rise, when up to
To energy storage material fusing point when, energy storage material is undergone phase transition, and becomes liquid from solid-state, while absorbing thermal energy and having been stored
Come, when temperature reduces, the temperature of energy storage material declines therewith, when temperature drops to the transformation temperature of energy storage material, generates inverse
Phase transformation is changed into solid-state by liquid, and the heat of storage is released, to play the role of controlling environment temperature.
Example 2
It weighs 2kg leaf fats and is cut into the fritter that grain size is 2cm by knife, put it into iron pan and 250mL deionizations are added
Water, first big fire change into small fire after enduring to boiling water, continue to boil 50min, the filtering removal dregs of fat obtain lard；It measures on 450mL
It states boiled lard to move into glass, is by volume 1:5 a concentration of 0.3mol/L sodium hydroxides second is added into lard
Alcoholic solution, and glass is moved into 70 DEG C of water-bath, it is placed on magnetic stirring apparatus, is stirred to react with 450r/min rotating speeds
1h obtains saponification liquor；A concentration of 0.5mol/L vinegar acid for adjusting pH is added into above-mentioned saponification liquor again to 3.5, stirs reduction reaction
It moves into 5 DEG C of ice-water baths and stands overnight after 35min, isolated upper layer lard fatty acid mixed is washed with 35 DEG C of warm water to leaching
Washing lotion is in neutrality；It is 2 by volume:1 will be fitted into after lard fatty acid mixed obtained above and lauryl alcohol mixing in beaker, add
Enter the fatty amide polyoxyethylene ether of the two gross mass 13%, move into ultrasonic disperse instrument, with 250W power ultrasonics point at 40 DEG C
35min is dissipated, energy storage emulsion is made, it is spare；It weighs 45g perlite ores to be put into Muffle furnace, the preheating and calcining at 350 DEG C
18min, then the ore in sand form after preheating is moved into tube type resistance furnace, instant heating continues high-temperature calcination 13min, obtains to 1050 DEG C
Expanded perlite；Expanded perlite obtained above is immersed in the spare energy storage emulsion of 4 times of its volume, vortex oscillation instrument is used
Steeped overnight is vibrated with 35W power vortexs, the expanded perlite of adsorption energy-storing lotion is obtained by filtration, and move it into vacuum rapidly
Case is poured into and is filled in the tray that grain size is 4 μm of Ultra-fine Bentonites, is rolled one layer of Ultra-fine Bentonite of cladding, is put into baking oven in 108 DEG C
Lower dry 2h, obtains energy storage filler；Meter weighs 55 parts of cement, 15 parts of quartz fibres, 13 parts of Ludox, 4 parts of carbonizations in parts by weight
Boron and 35 parts of energy storage fillers obtained above and 250 parts of deionized waters, are fitted into Horizontal type mixer, batch mixing 4h must be starched together
Material；In the tile mould that slurry obtained above injection bottom is carried to 300 mesh screens, and to mould pressurizing to 120kPa pressurizes
50min makes the moisture in slurry extrude, place it in spontaneous curing at room temperature dry 4 days after form removal to get biomass energy storage every
Hot tile.
The principle of the present invention：Using energy storage material absorb solar radiant heat and cross-ventilation heat transfer and temperature rise, when up to
To energy storage material fusing point when, energy storage material is undergone phase transition, and becomes liquid from solid-state, while absorbing thermal energy and having been stored
Come, when temperature reduces, the temperature of energy storage material declines therewith, when temperature drops to the transformation temperature of energy storage material, generates inverse
Phase transformation is changed into solid-state by liquid, and the heat of storage is released, to play the role of controlling environment temperature.
Example 3
It weighs 1kg leaf fats and is cut into the fritter that grain size is 3cm by knife, put it into iron pan and 300mL deionizations are added
Water, first big fire change into small fire after enduring to boiling water, continue to boil 60min, the filtering removal dregs of fat obtain lard；It measures on 500mL
It states boiled lard to move into glass, is by volume 1:5 a concentration of 0.3mol/L sodium hydroxides second is added into lard
Alcoholic solution, and glass is moved into 75 DEG C of water-bath, it is placed on magnetic stirring apparatus, is stirred to react with 500r/min rotating speeds
2h obtains saponification liquor；A concentration of 0.5mol/L vinegar acid for adjusting pH is added into above-mentioned saponification liquor again to 4, stirs reduction reaction 40min
It moves into 6 DEG C of ice-water baths and stands overnight afterwards, isolated upper layer lard fatty acid mixed is washed to leacheate with 40 DEG C of warm water and is in
It is neutral；It is 2 by volume:Both 1 will be fitted into after lard fatty acid mixed obtained above and lauryl alcohol mixing in beaker, be added
The fatty amide polyoxyethylene ether of gross mass 15% moves into ultrasonic disperse instrument, is disperseed with 300W power ultrasonics at 45 DEG C
Energy storage emulsion is made in 40min, spare；It weighs 50g perlite ores to be put into Muffle furnace, the preheating and calcining at 400 DEG C
20min, then the ore in sand form after preheating is moved into tube type resistance furnace, instant heating continues high-temperature calcination 15min, obtains to 1100 DEG C
Expanded perlite；Expanded perlite obtained above is immersed in the spare energy storage emulsion of 5 times of its volume, vortex oscillation instrument is used
Steeped overnight is vibrated with 40W power vortexs, the expanded perlite of adsorption energy-storing lotion is obtained by filtration, and move it into vacuum rapidly
Case is poured into and is filled in the tray that grain size is 5 μm of Ultra-fine Bentonites, is rolled one layer of Ultra-fine Bentonite of cladding, is put into baking oven in 110 DEG C
Lower dry 3h, obtains energy storage filler；Meter weighs 60 parts of cement, 20 parts of quartz fibres, 15 parts of Ludox, 5 parts of carbonizations in parts by weight
Boron and 40 parts of energy storage fillers obtained above and 300 parts of deionized waters, are fitted into Horizontal type mixer, batch mixing 5h must be starched together
Material；In the tile mould that slurry obtained above injection bottom is carried to 300 mesh screens, and to mould pressurizing to 140kPa pressurizes
60min makes the moisture in slurry extrude, place it in spontaneous curing at room temperature dry 5 days after form removal to get biomass energy storage every
Hot tile.
The principle of the present invention：Using energy storage material absorb solar radiant heat and cross-ventilation heat transfer and temperature rise, when up to
To energy storage material fusing point when, energy storage material is undergone phase transition, and becomes liquid from solid-state, while absorbing thermal energy and having been stored
Come, when temperature reduces, the temperature of energy storage material declines therewith, when temperature drops to the transformation temperature of energy storage material, generates inverse
Phase transformation is changed into solid-state by liquid, and the heat of storage is released, to play the role of controlling environment temperature.
Claims (1)
1. a kind of preparation method of biomass energy-storage thermal-insulating tile, it is characterised in that specifically preparation process is：
（1）It weighs 1~2kg leaf fats and is cut into the fritter that grain size is 2~3cm by knife, put it into iron pan and it is added 200~
300mL deionized waters, first big fire change into small fire after enduring to boiling water, continue 40~60min of tanning, and the filtering removal dregs of fat obtain pig
Oil；
（2）It measures the above-mentioned boiled lards of 400~500mL to move into glass, is by volume 1:5 be added into lard it is dense
Degree is 0.3mol/L sodium hydroxide ethanol solutions, and glass is moved into 65~75 DEG C of water-bath, is placed on magnetic agitation
On device, 1~2h is stirred to react with 400~500r/min rotating speeds and obtains saponification liquor；
（3）A concentration of 0.5mol/L vinegar acid for adjusting pH is added into above-mentioned saponification liquor again to 3~4, stirring reduction reaction 30~
It moves into 4~6 DEG C of ice-water baths and stands overnight after 40min, isolated upper layer lard fatty acid mixed is washed with 30~40 DEG C of warm water
It washs to leacheate and is in neutrality；
（4）It is 2 by volume:1 will be fitted into after lard fatty acid mixed obtained above and lauryl alcohol mixing in beaker, be added two
The fatty amide polyoxyethylene ether of person's gross mass 10~15% moves into ultrasonic disperse instrument, with 200~300W at 35~45 DEG C
Power ultrasonic disperses 30~40min, and energy storage emulsion is made, spare；
（5）It weighs 40~50g perlite ores to be put into Muffle furnace, 15~20min of preheating and calcining at 300~400 DEG C, then will
Ore in sand form after preheating moves into tube type resistance furnace, and instant heating continues 10~15min of high-temperature calcination, obtain to 1000~1100 DEG C
Expanded perlite；
（6）Expanded perlite obtained above is immersed in the spare energy storage emulsion of 3~5 times of its volume, vortex oscillation instrument is used
Steeped overnight is vibrated with 30~40W power vortexs, the expanded perlite of adsorption energy-storing lotion is obtained by filtration, and move it into rapidly
Vacuum tank is poured into and is filled in the tray that grain size is 3~5 μm of Ultra-fine Bentonites, is rolled one layer of Ultra-fine Bentonite of cladding, is put into baking oven
Dry 2~3h, obtains energy storage filler at 105~110 DEG C；
（7）Meter weighs 50~60 parts of cement, 10~20 parts of quartz fibres, 10~15 parts of Ludox, 3~5 parts of carbon in parts by weight
Change boron and 30~40 parts of energy storage fillers obtained above and 200~300 parts of deionized waters, be fitted into Horizontal type mixer together,
3~5h of batch mixing obtains slurry；
（8）By slurry obtained above injection bottom with 300 mesh screens tile mould in, and to mould pressurizing to 100~
40~60min of 140kPa pressurizes makes the moisture in slurry extrude, and places it in form removal after spontaneous curing at room temperature is dried 3~5 days,
Up to biomass energy-storage thermal-insulating tile.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610477192.4A CN106116423B (en) | 2016-06-27 | 2016-06-27 | A kind of preparation method of biomass energy-storage thermal-insulating tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610477192.4A CN106116423B (en) | 2016-06-27 | 2016-06-27 | A kind of preparation method of biomass energy-storage thermal-insulating tile |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106116423A CN106116423A (en) | 2016-11-16 |
| CN106116423B true CN106116423B (en) | 2018-08-24 |
Family
ID=57267311
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610477192.4A Expired - Fee Related CN106116423B (en) | 2016-06-27 | 2016-06-27 | A kind of preparation method of biomass energy-storage thermal-insulating tile |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106116423B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108841361A (en) * | 2018-05-15 | 2018-11-20 | 王雪峰 | A kind of preparation method of rancid object sizing heat-storing material |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101759416A (en) * | 2009-12-25 | 2010-06-30 | 唐山市思远涂料有限公司 | Thermal insulation building mortar and preparation process thereof |
| CA2818752C (en) * | 2010-11-23 | 2019-09-10 | Elevance Renewable Sciences, Inc. | Lipid-based wax compositions substantially free of fat bloom and methods of making |
| CN102031091B (en) * | 2010-11-24 | 2013-07-03 | 信阳师范学院 | Method for preparing bentonite-cladded expanded perlite-based phase-change energy-storing material |
| CN102531533A (en) * | 2010-12-20 | 2012-07-04 | 武汉优特斯节能建材研究所 | Building foamed cement phase-change heat-preserving board (building block) and manufacturing method thereof |
| CN103159437B (en) * | 2011-12-15 | 2016-08-03 | 张国庆 | A kind of conditioning coating and preparation method thereof |
| CN102732225B (en) * | 2012-06-07 | 2014-03-12 | 江苏汉诺斯化学品有限公司 | Thermal storage and insulation microcapsule for building material and preparation method thereof |
| CN102850007B (en) * | 2012-10-10 | 2013-12-18 | 信阳天意节能技术有限公司 | Phase change energy storage plant fiber composite heat insulation board and preparation method thereof |
| CN105314999A (en) * | 2014-07-29 | 2016-02-10 | 金承黎 | Nano porous high-temperature-insulating material taking thixotropic colloid as template agent and preparation method for high-temperature-insulating material |
| CN105363396A (en) * | 2014-08-26 | 2016-03-02 | 金承黎 | Aerogel core material capsule, paint prepared from same and preparation method of paint |
-
2016
- 2016-06-27 CN CN201610477192.4A patent/CN106116423B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN106116423A (en) | 2016-11-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104609791B (en) | Phase-change accumulation energy double limit homoiothermic mortar and preparation method thereof | |
| CN205037414U (en) | Phase -change thermal type solar energy low temperature hot water radiation heating floor | |
| CN102503319B (en) | Phase-change-energy-storage phase change concrete and preparation method | |
| CN101239798A (en) | Organic matter/expandable graphite composite phase change heat-storing building material and preparation method thereof | |
| CN101104550A (en) | Building wall phase change energy-storage type polymer thermal insulating mortar and preparation method thereof | |
| CN104829189B (en) | Phase-change energy-storing composite foam concrete block | |
| CN101759416A (en) | Thermal insulation building mortar and preparation process thereof | |
| CN105586012B (en) | A kind of aliphatic acid/PERFORMANCE OF MODIFIED VERMICULITE composite phase-change energy storage material and preparation method thereof | |
| CN101880149A (en) | Phase-change and energy-storage desulfurized gypsum interior wall thermal-insulation mortar | |
| CN105621918A (en) | Building phase-change heat storage composite material used as light aggregate | |
| CN107902984B (en) | A kind of glue powder polyphenyl particle slurry, preparation method and its application with heat preservation, anti-cracking function | |
| CN105060830A (en) | Waterproof phase-change heat storing plaster wallboard formed by reinforcing straw fibers | |
| CN109180125A (en) | A kind of porous graphite base phase-transition heat-storage plasterboard and preparation method thereof | |
| CN103770394B (en) | A kind of preparation method of phase change energy-storage type thermal insulating composite panel | |
| CN106116423B (en) | A kind of preparation method of biomass energy-storage thermal-insulating tile | |
| CN104357020B (en) | A kind of nano modified inorganic room temperature phase-change heat accumulating and preparation method thereof | |
| CN103541484A (en) | Internal and external multiple-phase-change thermal insulation building block | |
| CN104030590B (en) | A kind of vegetable fibre inorganic light weight is filled and is gathered materials | |
| CN104650812A (en) | Method for preparing stearic acid-silica composite phase-change heat storage slurry | |
| CN201045223Y (en) | Phase-change composite thermal insulation board | |
| CN103723982A (en) | Inorganic, insulating, and energy-saving slurry | |
| CN114890750A (en) | Intelligent temperature control concrete for bridge main tower in plateau environment and preparation method thereof | |
| CN103755263B (en) | A kind of preparation method of energy saving temperature controlling floor tile | |
| CN209163112U (en) | A kind of lattice heat-preserving wall based on phase-change material | |
| CN105647484A (en) | Preparing method for coated inorganic salt ceramic-based composite phase-change energy storage material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180712 Address after: 322100 Zhejiang, Jinhua, Dongyang, Jiangbei street, 1 New Village Applicant after: DONGYANG TEYI NEW MATERIAL TECHNOLOGY Co.,Ltd. Address before: 213164 Changzhou, Xinbei District, Jiangsu Province, No. 33 Applicant before: Mei Qingbo |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20220802 Address after: 528300 No. 9, Huanzhen East Road, Shunjiang Community Industrial Park, Beijiao Town, Shunde District, Foshan City, Guangdong Province (residence declaration) Patentee after: Foshan Shunde Haiwan plastic products Industrial Co.,Ltd. Address before: 322100 Zhejiang, Jinhua, Dongyang, Jiangbei street, 1 New Village Patentee before: DONGYANG TEYI NEW MATERIAL TECHNOLOGY Co.,Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180824 |