CN106116274A - A kind of method that based crystal stone waste material prepares Environmental-friendconstruction construction decoration material - Google Patents
A kind of method that based crystal stone waste material prepares Environmental-friendconstruction construction decoration material Download PDFInfo
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- CN106116274A CN106116274A CN201610506756.2A CN201610506756A CN106116274A CN 106116274 A CN106116274 A CN 106116274A CN 201610506756 A CN201610506756 A CN 201610506756A CN 106116274 A CN106116274 A CN 106116274A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/28—Polysaccharides or derivatives thereof
- C04B26/285—Cellulose or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/30—Oxides other than silica
- C04B14/305—Titanium oxide, e.g. titanates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/12—Waste materials; Refuse from quarries, mining or the like
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/1018—Coating or impregnating with organic materials
- C04B20/1022—Non-macromolecular compounds
- C04B20/1025—Fats; Fatty oils; Ester type waxes; Higher fatty acids; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00008—Obtaining or using nanotechnology related materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Mining & Mineral Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Processing Of Solid Wastes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of method that based crystal stone waste material prepares Environmental-friendconstruction construction decoration material.Put in container including taking seeing stone waste material, be stirred filtering, seeing stone waste material after collecting and impurity removing, pulverize, cross 150 mesh sieves；Put in calcining furnace, be then ground, add pearly-lustre fat acid, flavanonol and Fatty acid methyl ester sodium sulfonate, after stirring, the ammonia regulation pH to 7.5～8.0 using mass fraction to be 25%；Obtain modified seeing stone waste material.The present invention is by making full use of seeing stone waste material, it is achieved that resource, it is to avoid environmental pollution；Water-fast fire-resistant, the indoor harmful substance of decomposable asymmetric choice net, and wear-resisting, by the TiO added2Absorbing harmful gas and decompose, removing the harmful gass such as formaldehyde, by the methanol added, this Environmental-friendconstruction construction decoration material surface of the system made has fineness, it is to avoid the adhesion of greasy dirt dust.
Description
Technical field
The invention belongs to technical field of construction and decoration materials, particularly relate to a kind of based crystal stone waste material and prepare environmental protection and build
The method building ornament materials.
Background technology
Crystal is a kind of rare mineral, the one of gem, and quartz crystals body mineralogically belongs to quartz race, mainly changes
Studying part is silicon dioxide.Along with the living standard of people improves constantly, increasing people use various ornament materials to fill
Repair room and various the articles for daily use.For saving timber, people employ substantial amounts of artificial decoration material when finishing.Produce now
The main method of artificial wooden ornament materials is: first Woody plant is ground into fiber powder, then by fiber powder and binding agent,
Firming agent mixes, then compressing on forcing press.The wood decorative material produced in this way also exist dull coloring,
Hardness is low, the most wear-resisting and shortcoming without natural vein.Traditional ornament materials needs to consume substantial amounts of timber and metal material, and
And also exist water funk inflammable, content of formaldehyde exceeds standard, installation is loaded down with trivial details, decorative effect is poor, maintenance is difficult, the life-span is short, price is high
Etc. problem.
Summary of the invention
It is an object of the invention to provide a kind of method that based crystal stone waste material prepares Environmental-friendconstruction construction decoration material, pass through
Remove impurity, dry, pulverize, and adds TiO2, then it is at high temperature carried out calcining and activating, the most again by pearly-lustre fat acid, fatty acid
The materials such as formicester sodium sulfonate carry out surface modification to it so that it is degradable harmful substance, finally mix with various auxiliary agents, hot pressing
For obtaining Environmental-friendconstruction construction decoration material.
For solving above-mentioned technical problem, the present invention is achieved by the following technical solutions:
The present invention is a kind of method that based crystal stone waste material prepares Environmental-friendconstruction construction decoration material, comprises the steps:
Step one, takes seeing stone waste material and puts in container, is added thereto to water logging and does not has waste material 5～7cm, re-uses agitator
It is stirred 20～30min with rotating speed 500r/min, stands 5～8min subsequently, remove the impurity swimming in the water surface, then carry out
Filter, seeing stone waste material after collecting and impurity removing, put in baking oven, be dried at 100 DEG C, then put it into pulverizing, mistake in pulverizer
150 mesh sieves；
Step 2, puts in calcining furnace by the seeing stone waste material granule of gained after above-mentioned sieving, at 800～900 DEG C, forges
After burning 1～2h, the hydrogen using temperature to be 5 DEG C is cooled to room temperature to the seeing stone waste material after calcining, after lowering the temperature subsequently
Seeing stone waste material take out, put in ball mill, select stainless-steel grinding ball, grind 40～50min, cross 200 mesh sieves, obtain pre-place
Reason seeing stone waste material granule；
Step 3, the pretreated water spar waste granules taking 500～800g above-mentioned gained is put into agitator, thermometer
And in the four-hole boiling flask of reflux condensing tube, then it is added thereto to 40～70g pearly-lustre fat acids, 50～70mL flavanonol and 20 respectively
～30g Fatty acid methyl ester sodium sulfonate, after stirring, it is added thereto to the ethanol that 200～300mL mass fractions are 30% molten
Liquid, the ammonia using mass fraction to be 25% regulation pH to 7.5～8.0；
Step 4, moves in water-bath by above-mentioned flask, is warming up to 70～80 DEG C, starts agitator simultaneously and stirs it
Mix, after insulation 1～2h, naturally cool to room temperature, filter subsequently, after using dehydrated alcohol that filter cake is rinsed 3～5 times
Put in baking oven and be dried, obtain modified seeing stone waste material；
Step 5, counts by weight, take 45～50 parts of modified seeing stone waste materials, 4～8 parts of polyvinyl alcohol, 1～2 part oneself
Two acid esters, 20～25 parts of polyethylene, 5～7 parts of carboxymethyl celluloses and 13～20 methanol, 20～30 parts of TiO2, put into mixer
After middle mix homogeneously, being put in stainless steel mould by mixture, then put into by mould in heat pressing forming machines, design temperature is 195
～220 DEG C, extruded, i.e. can get Environmental-friendconstruction construction decoration material.
Further, the TiO in described step 52Use nano-scale particle.
The method have the advantages that
The present invention makes full use of seeing stone waste material, it is achieved that resource, it is to avoid environmental pollution；Water-fast fire-resistant, decomposable asymmetric choice net
Indoor harmful substance, and wear-resisting, by the TiO added2Harmful gas absorbed and decomposes, removing harmful gas such as formaldehyde
Body, by the methanol added, this Environmental-friendconstruction construction decoration material surface of the system made has fineness, it is to avoid gluing of greasy dirt dust
Attached.
Certainly, the arbitrary product implementing the present invention it is not absolutely required to reach all the above advantage simultaneously.
Detailed description of the invention
Technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is only
The a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art
The all other embodiments obtained under not making creative work premise, broadly fall into the scope of protection of the invention.
The present invention is a kind of method that based crystal stone waste material prepares Environmental-friendconstruction construction decoration material, comprises the steps:
Step one, takes seeing stone waste material and puts in container, is added thereto to water logging and does not has waste material 5～7cm, re-uses agitator
It is stirred 20～30min with rotating speed 500r/min, stands 5～8min subsequently, remove the impurity swimming in the water surface, then carry out
Filter, seeing stone waste material after collecting and impurity removing, put in baking oven, be dried at 100 DEG C, then put it into pulverizing, mistake in pulverizer
150 mesh sieves；
Step 2, puts in calcining furnace by the seeing stone waste material granule of gained after above-mentioned sieving, at 800～900 DEG C, forges
After burning 1～2h, the hydrogen using temperature to be 5 DEG C is cooled to room temperature to the seeing stone waste material after calcining, after lowering the temperature subsequently
Seeing stone waste material take out, put in ball mill, select stainless-steel grinding ball, grind 40～50min, cross 200 mesh sieves, obtain pre-place
Reason seeing stone waste material granule；
Step 3, the pretreated water spar waste granules taking 500～800g above-mentioned gained is put into agitator, thermometer
And in the four-hole boiling flask of reflux condensing tube, then it is added thereto to 40～70g pearly-lustre fat acids, 50～70mL flavanonol and 20 respectively
～30g Fatty acid methyl ester sodium sulfonate, after stirring, it is added thereto to the ethanol that 200～300mL mass fractions are 30% molten
Liquid, the ammonia using mass fraction to be 25% regulation pH to 7.5～8.0；
Step 4, moves in water-bath by above-mentioned flask, is warming up to 70～80 DEG C, starts agitator simultaneously and stirs it
Mix, after insulation 1～2h, naturally cool to room temperature, filter subsequently, after using dehydrated alcohol that filter cake is rinsed 3～5 times
Put in baking oven and be dried, obtain modified seeing stone waste material；
Step 5, counts by weight, take 45～50 parts of modified seeing stone waste materials, 4～8 parts of polyvinyl alcohol, 1～2 part oneself
Two acid esters, 20～25 parts of polyethylene, 5～7 parts of carboxymethyl celluloses and 13～20 methanol, 20～30 parts of TiO2, TiO2Use nanometer
Grade particles；Put in mixer after mix homogeneously, mixture is put in stainless steel mould, then mould is put into heat pressing forming machines
In, design temperature is 195～220 DEG C, extruded, i.e. can get Environmental-friendconstruction construction decoration material.
In the description of this specification, the description of reference term " embodiment ", " example ", " concrete example " etc. means
Specific features, structure, material or feature in conjunction with this embodiment or example description is contained at least one enforcement of the present invention
In example or example.In this manual, the schematic representation to above-mentioned term is not necessarily referring to identical embodiment or example.
And, the specific features of description, structure, material or feature can be to close in any one or more embodiments or example
Suitable mode combines.
Present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention.Preferred embodiment is the most detailed
Describe all of details, be also not intended to the detailed description of the invention that this invention is only described.Obviously, according to the content of this specification,
Can make many modifications and variations.These embodiments are chosen and specifically described to this specification, is to preferably explain the present invention
Principle and actual application so that skilled artisan can be best understood by and utilize the present invention.The present invention is only
Limited by claims and four corner thereof and equivalent.
Claims (2)
1. the method that based crystal stone waste material prepares Environmental-friendconstruction construction decoration material, comprises the steps:
Step one, takes seeing stone waste material and puts in container, is added thereto to water logging and does not has waste material 5～7cm, re-uses agitator to turn
Speed 500r/min is stirred 20～30min, stands 5～8min subsequently, removes the impurity swimming in the water surface, then carried out
Filter, seeing stone waste material after collecting and impurity removing, put in baking oven, be dried at 100 DEG C, then put it into pulverizing in pulverizer, cross 150
Mesh sieve；
Step 2, puts in calcining furnace by the seeing stone waste material granule of gained after above-mentioned sieving, and at 800～900 DEG C, calcines 1
～after 2h, the hydrogen using temperature to be 5 DEG C is cooled to room temperature to the seeing stone waste material after calcining, subsequently by the water after cooling
Spar waste material takes out, and puts in ball mill, selects stainless-steel grinding ball, grinds 40～50min, crosses 200 mesh sieves, obtains pretreated water
Spar waste granules；
Step 3, the pretreated water spar waste granules taking 500～800g above-mentioned gained is put into agitator, thermometer and returns
Stream condensing tube four-hole boiling flask in, then be added thereto to respectively 40～70g pearly-lustre fat acids, 50～70mL flavanonol and 20～
30g Fatty acid methyl ester sodium sulfonate, after stirring, being added thereto to 200～300mL mass fractions is the ethanol solution of 30%,
The ammonia regulation pH to 7.5～8.0 using mass fraction to be 25%；
Step 4, moves in water-bath by above-mentioned flask, is warming up to 70～80 DEG C, starts agitator simultaneously and is stirred it,
After insulation 1～2h, naturally cool to room temperature, filter subsequently, use dehydrated alcohol to put after filter cake is rinsed 3～5 times
Enter in baking oven and be dried, obtain modified seeing stone waste material；
Step 5, counts by weight, takes 45～50 parts of modified seeing stone waste materials, 4～8 parts of polyvinyl alcohol, 1～2 part of adipic acid
Ester, 20～25 parts of polyethylene, 5～7 parts of carboxymethyl celluloses and 13～20 methanol, 20～30 parts of TiO2, put in mixer mixed
After closing uniformly, being put in stainless steel mould by mixture, then put into by mould in heat pressing forming machines, design temperature is 195～220
DEG C, extruded, i.e. can get Environmental-friendconstruction construction decoration material.
The method that a kind of based crystal stone waste material the most according to claim 1 prepares Environmental-friendconstruction construction decoration material, its feature
It is, the TiO in described step 52Use nano-scale particle.
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| CN201610506756.2A CN106116274A (en) | 2016-06-29 | 2016-06-29 | A kind of method that based crystal stone waste material prepares Environmental-friendconstruction construction decoration material |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108794882A (en) * | 2018-05-16 | 2018-11-13 | 黄欣 | A kind of architectural decoration environment-friendly materials and preparation method thereof |
| CN109928727A (en) * | 2019-04-15 | 2019-06-25 | 丽水学院 | A method of seeing stone waste material is prepared into environment protection architecture ceramic decoration material |
| CN114454506A (en) * | 2022-02-17 | 2022-05-10 | 李桂山 | Method for manufacturing building decoration material based on marble waste |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105541186A (en) * | 2016-02-03 | 2016-05-04 | 常州达奥新材料科技有限公司 | Method for preparing environment-friendly building decoration material by utilizing rock crystal wastes |
| CN105621958A (en) * | 2016-02-03 | 2016-06-01 | 江苏时空涂料有限公司 | Method for preparing environment-friendly building decoration material by using rock crystal waste |
-
2016
- 2016-06-29 CN CN201610506756.2A patent/CN106116274A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105541186A (en) * | 2016-02-03 | 2016-05-04 | 常州达奥新材料科技有限公司 | Method for preparing environment-friendly building decoration material by utilizing rock crystal wastes |
| CN105621958A (en) * | 2016-02-03 | 2016-06-01 | 江苏时空涂料有限公司 | Method for preparing environment-friendly building decoration material by using rock crystal waste |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108794882A (en) * | 2018-05-16 | 2018-11-13 | 黄欣 | A kind of architectural decoration environment-friendly materials and preparation method thereof |
| CN109928727A (en) * | 2019-04-15 | 2019-06-25 | 丽水学院 | A method of seeing stone waste material is prepared into environment protection architecture ceramic decoration material |
| CN114454506A (en) * | 2022-02-17 | 2022-05-10 | 李桂山 | Method for manufacturing building decoration material based on marble waste |
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