CN106113870B - A kind of sheet material and its manufacture method - Google Patents

A kind of sheet material and its manufacture method Download PDF

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Publication number
CN106113870B
CN106113870B CN201610427528.6A CN201610427528A CN106113870B CN 106113870 B CN106113870 B CN 106113870B CN 201610427528 A CN201610427528 A CN 201610427528A CN 106113870 B CN106113870 B CN 106113870B
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panel
substrate
layer
sheet material
drying
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CN106113870A (en
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张钟阳
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/322Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • B32B27/365Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates

Abstract

The present invention relates to a kind of sheet material and its manufacture method, the sheet material is combined by substrate and panel, and the substrate doubles aftershaping through layer again after chemical blowing, and the panel doubles aftershaping through layer, carries out cure process while the panel forming.The sheet material is handled through layer multiplication process, and external impact force is alleviated in the micro-shifting position mutually slided using interlayer, improves impact resistance.The present invention has filled up house ornamentation, furniture, the vacancy of upholstery industry Novel environment-friendlymaterial material.

Description

A kind of sheet material and its manufacture method
Technical field
The present invention relates to field of plate manufacture, more particularly to a kind of sheet material and its manufacture method.
Background technology
Common sheet material has aluminium-plastic panel, AEP plates, paint free plate, PVC (polyethylene) plate, acrylic (PMMA) in the market Plate, PP (polypropylene) plate, PS (polystyrene) plate etc..Aluminium-plastic panel, AEP plates are only used for engineering decoration and outdoor decoration, exempt to paint Plate has for manufacturing furniture panel, but wearability, impact resistance are poor.The sheet materials such as PVC, PMMA, PP, PS are not suitable for house ornamentation man Tool field.
And traditional house ornamentation technique brushes paint again after being molded using plank.The shortcomings that traditional method is:Cost of labor is high, work Phase is grown, and lines color is single, paints taste weight, and finishing will have very long idle periods just to move in later.
Layer doubling technology is prior art, and material carries out doubling operations through layer multiplier module, forms sandwich construction.Its In, the first order is provided with 1 splitter in layer multiplication modules, and each splitter is provided with 1 entrance and 2 outlets, and material is by the One-level splitter is converted into 2 layers;Above-mentioned 2 layers of material respectively enters second level splitter, and the level is provided with 2 splitters, thus 2 layers Material conversion is 4 layers;The rest may be inferred, and the quantity of every grade of splitter is all 2 times of upper level.
The content of the invention
The purpose of the present invention is to overcome above-mentioned deficiency, has filled up house ornamentation, furniture, upholstery industry Novel environment-friendlymaterial material Vacancy, there is provided a kind of board and its manufacture method.The sheet material is handled through layer multiplication process, is mutually slided using interlayer External impact force is alleviated in micro-shifting position, improves impact resistance.
The present invention provides a kind of sheet material, is combined by substrate and panel, and the substrate is after chemical blowing again layer multiplication Shaping, the panel double aftershaping through layer, carry out cure process while the panel forming.
Further, the Nth power that the number of plies of substrate or the panel layer multiplication is 2, N are the integer more than or equal to 1, respectively Interlayer forms small space.
Further, auxiliary agent is added in the substrate foamed forming process to control the color of product, word, lines, figure Case.
Further, the auxiliary agent added in the substrate foamed forming process is azodicarbonamide, peroxidating two is different One or more of group that propyl benzene, zinc oxide, color masterbatch, polyvinyl alcohol, vinyl acetate, natural rubber, adhesive form.
Further, the material of the substrate or panel is makrolon, polyvinyl chloride, polyethylene terephthalate Ester, polyethylene or polypropylene any of which.
Further, the substrate thickness is 1mm to 150mm, and the plate thickness is 0.02mm to 20mm.
The present invention provides a kind of manufacture method of sheet material, comprises the following steps:
S1. manufacture of substrates, including:
Step 1, by the single makrolon of 1000 parts by weight, polypropylene, polyethylene, polyethylene terephthalate or The pellet or powder of polyvinyl chloride add 1 parts by weight auxiliary agent to insert baking oven progress drying and processing, and auxiliary agent is azodicarbonamide, peroxide Change one or more of group of diisopropylbenzene (DIPB), zinc oxide, color masterbatch, polyvinyl alcohol, vinyl acetate, natural rubber, adhesive composition, 50 degrees Celsius to 95 degrees Celsius of oven temperature, drying time 12 to 24 hours, makes the aridity of above-mentioned material reach more than 98%;
Extruder is directly entered after step 2, drying materials, by extruder screw rotate caused by pressure and shearing force So that material and auxiliary agent are fully plastified and uniformly mixed;
Step 3, material remove impurity by filter screen, and filter screen requires 80 to 100 mesh;
Step 4, material carry out foaming processing;
Step 5, material enter the Nth power that mould number of plies after the multiplication of n times layer reaches 2, and wherein N is more than or equal to 1 Integer, layer multiplication after each interlayer form small space, be often laminated plus weight, volume, thickness, spend by mould come appoint Meaning control;
Step 6, it is material bed be multiplied to accord with roller group entered by the power and revolving force of extruder after requirement, pressure Flat, press polish, embossing, cooling and shaping;
S2. method for producing panel, including:
Step 1, by the single makrolon of 1000 parts by weight, polypropylene, polyethylene, polyethylene terephthalate or The pellet or powder of polyvinyl chloride insert baking oven and carry out drying and processing, 50 degrees Celsius to 95 degrees Celsius of oven temperature, drying time 12 to 24 hours, the aridity of above-mentioned material is set to reach more than 98%;
Extruder is directly entered after step 2, drying materials, by extruder screw rotate caused by pressure and shearing force So that material is fully plastified and uniformly mixed;
Step 3, material remove impurity by filter screen, and filter screen requires 80 to 100 mesh;
Step 4, material enter the Nth power that mould number of plies after the multiplication of n times layer reaches 2, and wherein N is more than or equal to 1 Integer, layer multiplication after each interlayer form small space, be often laminated plus weight, volume, thickness, spend by mould come appoint Meaning control;
Step 5, it is material bed be multiplied to accord with roller group entered by the power and revolving force of extruder after requirement, pressure Flat, press polish, blast, cooling, shaping;
Cure process is carried out to material while step 6, material are cooled and shaped, adds 1 parts by weight panel hardening bath, makes hardness 2H is brought up to 7H;
S3. compound adhesive is consolidated:
Step 1, gluing:Glue application device gluing, drying are directly entered after the completion of substrate and panel cooling, gluing mode includes Glue spraying or gluing, thickness is 0.2 μm to 20 μm after adhesive curing;
Step 2, compound evacuation:After the completion of gluing, drying, substrate and panel are directly overlapped into compression, into evacuating equipment Evacuate the air between substrate and panel;
Step 3, solidification:Completing to enter solidifying channel after compound evacuation makes it thoroughly solidify, curing mode be heat cure or Photocuring.
Further, the process S3 can also use direct combination method, directly be carried out before substrate and panel cooling Compound, substrate described in compound tense and panel enter composite die, and compound tense temperature control is more than 100 degrees Celsius, by roller group Complete compound to be cooled and shaped again.
Further, the substrate layer multiplication number of plies is 2 to 1024 layers, and the panel layer multiplication number of plies is 2 to 512 layers.
Present invention contrast prior art can realize following beneficial effect:Good energy saving property, amount of insulation is up to 50%;Impact resistance energy Power is high, and impact strength is 200 times of glass, 30 times of PMMA;Anti-wear performance is good, and case hardness is up to 2H to 7H;Plasticity is strong, It is flexible, can hot bending, can carve, it is cleavable;It is in light weight, density 0.7g/cm3;Sound insulation, 2 to 3DB are improved than Equivalent glasses;No Condensation, in humidity 75%, more than 20 degrees Celsius of the temperature difference does not condense;Waterproof, washable, water absorption rate is below 10%.
Embodiment
Embodiment one:
A kind of polycarbonate plate, is combined by substrate and panel, the substrate through chemical blowing again layer multiplication after into Type, the superposition number of plies are 128 layers, and the panel doubles aftershaping through layer, and the superposition number of plies is 256 layers, while the panel forming Cure process is carried out, each interlayer forms small space, auxiliary agent is added to control product in the substrate foamed forming process Color, the auxiliary agent added in the substrate foamed forming process is azodicarbonamide, cumyl peroxide, zinc oxide, color Mother, polyvinyl alcohol, vinyl acetate, natural rubber, adhesive composition, the material of the substrate or panel is makrolon, described Substrate thickness is 100mm, and the plate thickness is 10mm.
The manufacture method of the polycarbonate plate, comprises the following steps:
S1. manufacture of substrates, including:
Step 1, add 1 parts by weight auxiliary agent to insert baking oven the pellet of the single makrolon of 1000 parts by weight to carry out at drying Reason, auxiliary agent be azodicarbonamide, cumyl peroxide, zinc oxide, color masterbatch, polyvinyl alcohol, vinyl acetate, natural rubber, Adhesive, 90 degrees Celsius of oven temperature, drying time 24 hours, the aridity of above-mentioned material is set to reach more than 98%;
Extruder is directly entered after step 2, drying materials, by extruder screw rotate caused by pressure and shearing force So that material and auxiliary agent are fully plastified and uniformly mixed;
Step 3, material remove impurity by filter screen, and filter screen is 100 mesh;
Step 4, material carry out foaming processing;
Step 5, material enter layer multiplication die number of plies after the multiplication of 8 sublevels and reach 128 layers, each interlayer shape after layer multiplication Into small space, be often laminated plus weight, volume, thickness, spend by mould to control;
Step 6, it is material bed be multiplied to accord with roller group entered by the power and revolving force of extruder after requirement, pressure Flat, press polish, embossing, cooling and shaping;
S2. method for producing panel, including:
Step 1, the single polycarbonate pellet of 1000 parts by weight is inserted to baking oven progress drying and processing, oven temperature 90 is taken the photograph Family name's degree degree, drying time 24 hours, makes the aridity of above-mentioned material reach more than 98%;
Extruder is directly entered after step 2, drying materials, by extruder screw rotate caused by pressure and shearing force So that material is fully plastified and uniformly mixed;
Step 3, material remove impurity by filter screen, and filter screen is 100 mesh;
Step 4, material enter mould number of plies after the multiplication of 9 sublevels and reach 256 layers, and each interlayer is formed small after layer multiplication Space, be often laminated plus weight, volume, thickness, spend by mould to control;
Step 5, it is material bed be multiplied to accord with roller group entered by the power and revolving force of extruder after requirement, pressure Flat, press polish, cooling and shaping;
Cure process is carried out to material while step 6, material are cooled and shaped, adds the 1 special hardening bath of parts by weight panel, makes Hardness brings up to 7H;
S3. compound adhesive is consolidated:
Step 1, gluing:Glue application device gluing, drying are directly entered after the completion of substrate and panel cooling, gluing mode includes Glue spraying, gluing or spray, thickness is 10 μm after adhesive curing;
Step 2, compound evacuation:After the completion of gluing, drying, substrate and panel are directly overlapped into compression, into evacuating equipment Evacuate the air between substrate and panel;
Step 3, solidification:Completing to enter solidifying channel after compound evacuation makes it thoroughly solidify, curing mode be heat cure or Photocuring.
Embodiment two:
A kind of polyvinyl-chloride plate material, is combined by substrate and panel, the substrate through chemical blowing again layer multiplication after into Type, the superposition number of plies are 256 layers, and the panel doubles aftershaping through layer, and the superposition number of plies is 512 layers, while the panel forming Cure process is carried out, each interlayer forms small space, auxiliary agent is added to control product in the substrate foamed forming process Color, the auxiliary agent added in the substrate foamed forming process is azodicarbonamide, cumyl peroxide, zinc oxide, color Mother, polyvinyl alcohol, vinyl acetate, natural rubber, adhesive composition, the material of the substrate or panel is makrolon, described Substrate thickness is 150mm, and the plate thickness is 20mm.
The manufacture method of the polycarbonate plate, comprises the following steps:
S1. manufacture of substrates, including:
Step 1, add 1 parts by weight auxiliary agent to insert baking oven the pellet of the single polyvinyl chloride of 1000 parts by weight to carry out at drying Reason, auxiliary agent be azodicarbonamide, cumyl peroxide, zinc oxide, color masterbatch, polyvinyl alcohol, vinyl acetate, natural rubber, Adhesive, oven temperature 90 degrees centigrade, drying time 24 hours, the aridity of above-mentioned material is set to reach more than 98%;
Extruder is directly entered after step 2, drying materials, by extruder screw rotate caused by pressure and shearing force So that material and auxiliary agent are fully plastified and uniformly mixed;
Step 3, material remove impurity by filter screen, and filter screen is 100 mesh;
Step 4, material carry out foaming processing;
Step 5, material enter layer multiplication die number of plies after the multiplication of 9 sublevels and reach 256 layers, each interlayer shape after layer multiplication Into small space, be often laminated plus weight, volume, thickness, spend by mould to control;
Step 6, it is material bed be multiplied to accord with roller group entered by the power and revolving force of extruder after requirement, pressure Flat, press polish, embossing, cooling and shaping;
S2. method for producing panel, including:
Step 1, the single polyvinyl chloride granules of 1000 parts by weight are inserted to baking oven progress drying and processing, oven temperature is Celsius 90 degree, drying time 24 hours, the aridity of above-mentioned material is set to reach more than 98%;
Extruder is directly entered after step 2, drying materials, by extruder screw rotate caused by pressure and shearing force So that material is fully plastified and uniformly mixed;
Step 3, material remove impurity by filter screen, and filter screen is 100 mesh;
Step 4, material enter mould number of plies after the multiplication of 10 sublevels and reach 512 layers, and each interlayer is formed micro- after layer multiplication Small space, be often laminated plus weight, volume, thickness, spend by mould to control;
Step 5, it is material bed be multiplied to accord with roller group entered by the power and revolving force of extruder after requirement, pressure Flat, press polish, cooling and shaping;
Cure process is carried out to material while step 6, material are cooled and shaped, adds 1 parts by weight panel hardening bath, makes hardness Bring up to 7H;
S3. direct combination:
Directly carry out compound before substrate and panel cooling, substrate described in compound tense and panel enter composite die, answer Temperature control is more than 100 degrees Celsius during conjunction, completes compound to be cooled and shaped again by roller group.

Claims (6)

1. a kind of sheet material, is combined by substrate and panel, it is characterised in that:The substrate doubles through layer again after chemical blowing Aftershaping, the panel double aftershaping through layer, carry out cure process, the substrate layer dynode layer while panel forming Number is 2 to 1024 layers, and the panel layer multiplication number of plies is 2 to 512 layers, and each interlayer forms small space.
A kind of 2. sheet material as claimed in claim 1, it is characterised in that:Auxiliary agent is added in the substrate foamed forming process, should Auxiliary agent is azodicarbonamide, cumyl peroxide, zinc oxide, color masterbatch, polyvinyl alcohol, vinyl acetate, natural rubber, gluing One or more of group of agent composition.
A kind of 3. sheet material as claimed in claim 1, it is characterised in that:The material of the substrate or panel is makrolon, gathered Vinyl chloride, polyethylene terephthalate, polyethylene or polypropylene any of which.
A kind of 4. sheet material as claimed in claim 1, it is characterised in that:The substrate thickness is 1mm to 150mm, the panel Thickness is 0.02mm to 20mm.
A kind of 5. manufacture method of sheet material, for the sheet material described in any one of manufacturing claims 1 to 4, it is characterised in that bag Include:
S1. manufacture of substrates, including:
Step 1, by the single makrolon of 1000 parts by weight, polypropylene, polyethylene, polyethylene terephthalate or polychlorostyrene The pellet or powder of ethene add the auxiliary agent of 1 parts by weight to insert baking oven progress drying and processing, and 50 degrees Celsius to 95 of oven temperature is Celsius Degree, drying time 12 to 24 hours, makes the aridity of above-mentioned material reach more than 98%;
Extruder is directly entered after step 2, drying materials, by extruder screw rotate caused by pressure and shearing force Material and auxiliary agent are fully plastified and uniformly mixed;
Step 3, material remove impurity by filter screen, and filter screen requires 80 to 100 mesh;
Step 4, material carry out foaming processing;
Step 5, material reach 2 to 1024 layers into mould number of plies after layer doubles, and each interlayer is formed small after layer multiplication Space, be often laminated plus weight, volume, thickness, spend by mould come any control;
Step 6, it is material bed be multiplied to meet the requirements after roller group entered by the power and revolving force of extruder, flatten, pressure Light, embossing, cooling and shaping;
S2. method for producing panel, including:
Step 1, by the single makrolon of 1000 parts by weight, polypropylene, polyethylene, polyethylene terephthalate or polychlorostyrene The pellet or powder of ethene insert baking oven carry out drying and processing, 50 degrees Celsius to 95 degrees Celsius of oven temperature, drying time 12 to 24 hours, the aridity of above-mentioned material is set to reach more than 98%;
Extruder is directly entered after step 2, drying materials, by extruder screw rotate caused by pressure and shearing force Material is fully plastified and uniformly mixed;
Step 3, material remove impurity by filter screen, and filter screen requires 80 to 100 mesh;
Step 4, material reach 2 to 512 layers into mould number of plies after layer doubles, and each interlayer forms small sky after layer multiplication Gap, be often laminated plus weight, volume, thickness, spend by mould come any control;
Step 5, it is material bed be multiplied to meet the requirements after roller group entered by the power and revolving force of extruder, flatten, pressure Light, cooling and shaping;
Cure process is carried out to material while step 6, material are cooled and shaped, adds 1 parts by weight panel hardening bath, improves hardness To 2H to 7H;
S3. compound adhesive is consolidated:
Step 1, gluing:Glue application device gluing, drying are directly entered after the completion of substrate and panel cooling, gluing mode includes glue spraying Or gluing, thickness is 0.2 μm to 20 μm after adhesive curing;
Step 2, compound evacuation:After the completion of gluing, drying, substrate and panel are directly overlapped into compression, evacuated into evacuating equipment Air between substrate and panel;
Step 3, solidification:Completing to enter solidifying channel after compound evacuation makes it thoroughly solidify, and curing mode is that heat cure or light are consolidated Change.
A kind of 6. manufacture method of sheet material as claimed in claim 5, it is characterised in that:The process S3 uses direct combination Method, directly carry out compound before substrate and panel cooling, substrate described in compound tense and panel enter composite die, compound tense temperature Degree control is completed compound to be cooled and shaped again more than 100 degrees Celsius, by roller group.
CN201610427528.6A 2016-06-16 2016-06-16 A kind of sheet material and its manufacture method Active CN106113870B (en)

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CN106113870B true CN106113870B (en) 2018-03-30

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201317092Y (en) * 2008-11-21 2009-09-30 翁文桂 Multi-layer material preparation device
CN101670655A (en) * 2009-06-19 2010-03-17 常州博双塑料有限公司 Co-extrusion foaming board and preparation method thereof
US20110285048A1 (en) * 2006-07-14 2011-11-24 Barger Mark A Anisotropic Foam-Film Composite Structures

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110285048A1 (en) * 2006-07-14 2011-11-24 Barger Mark A Anisotropic Foam-Film Composite Structures
CN201317092Y (en) * 2008-11-21 2009-09-30 翁文桂 Multi-layer material preparation device
CN101670655A (en) * 2009-06-19 2010-03-17 常州博双塑料有限公司 Co-extrusion foaming board and preparation method thereof

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