CN106109361A - A kind of toothpaste containing activated carbon from bamboo - Google Patents
A kind of toothpaste containing activated carbon from bamboo Download PDFInfo
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- CN106109361A CN106109361A CN201610740049.XA CN201610740049A CN106109361A CN 106109361 A CN106109361 A CN 106109361A CN 201610740049 A CN201610740049 A CN 201610740049A CN 106109361 A CN106109361 A CN 106109361A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
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Abstract
The invention provides a kind of toothpaste containing activated carbon from bamboo, the formula meter of this toothpaste includes: toothpaste base material 45-55 part, Rhizoma Drynariae 8-10 part, Fructus Psoraleae 8-10 part, Radix Polygoni Multiflori 4-8 part, Folium Ginkgo 5-7 part, Herba Asari 4-6 part, Olibanum 1-3 part, Borneolum Syntheticum 3-5 part and activated carbon from bamboo 12-16 part.Wherein, the manufacturing process of activated carbon from bamboo includes kneading step and carbonization, activation step.This toothpaste can carry out the cleaning of profound level to oral cavity, has fabulous removal ability particularly with the concealment particle diameter in the position such as teeth space, the dental bed fine particle less than 100nm and food debris, is effectively improved the cleaning efficiency of foreign body in mouth.Additionally, the activated carbon from bamboo that this toothpaste is contained within can also remove the mottle of deposition on intraoral abnormal flavour and tooth, make breath freshening, tooth brilliant white.
Description
Technical field
The present invention relates to field of toothpaste, in particular to a kind of toothpaste containing activated carbon from bamboo.
Background technology
Toothpaste is the oral cavity cleaning hygienic article that people's daily life is indispensable, its basic function be clean tooth,
Fresh breath, to reach to keep the purpose of oral cavity cleaning.Traditional toothpaste mainly act as master, the work of bactericidal antiphlogistic with clean
With for auxiliary.
Owing in oral cavity, structure is complicated, the harmful substance remaining dead angle in oral cavity can not be removed in time and produce abnormal flavour, and
Become the prolific hotbed of noxious bacteria.Therefore, this toothpaste can not remove food scraps and abnormal flavour comprehensively and effectively.Due to
Harmful substance can not thoroughly be removed, and this toothpaste of life-time service can cause dental plaque, dental calculus etc. to be formed.
Additionally, in recent years, air quality runs down, and is suspended with substantial amounts of fine particle in air, wherein contains a large amount of
Heavy metal, the harmful substance such as microorganism.The diameter of this fine particle is less than 2.5 microns, and particle diameter is little, and activity is strong, easily glues
Investing the position such as teeth space, dental bed, if can not get cleaning for a long time, then can cause the biggest impact to human health.At present, market
On toothpaste, the cleaning capacity for diameter fine particle in the range of 4-100nm is very poor, and these fine particles are the most heavy
Amass in teeth space, if clearing up not in time, it is easy to the appearance of the ill symptoms such as cause red swelling of gingiva, inflammation the most hemorrhage.
And current, hole is that the production method of the activated carbon of transitional pore (a diameter of 4-100nm) only has two kinds, Yi Zhongshi
The activated carbon produced for raw material with coal, another kind is that the activated carbon after using carries out activating and regenerating.Both approaches is raw
The activated carbon produced, although hole is many based on transitional pore, but activated carbon is contained within substantial amounts of heavy metal so that it is purposes is limited only to
In the industry such as sewage disposal, and cannot be used for washing product field.Therefore, up to now, in washing product field, for diameter
At molecule or the fine particle of 4-100nm, existing activated carbon all can not effectively carry out adsorption treatment.
Summary of the invention
It is an object of the invention to provide a kind of toothpaste containing activated carbon from bamboo, oral cavity can be carried out deeply by this toothpaste
The cleaning of level, has particularly with the concealment particle diameter in the position such as teeth space, the dental bed fine particle less than 100nm and food debris
Fabulous removal ability, is effectively improved the cleaning efficiency of foreign body in mouth.Additionally, the activated carbon from bamboo that this toothpaste is contained within is also
The mottle of deposition on intraoral abnormal flavour and tooth can be removed, make breath freshening, tooth brilliant white.
In order to realize the above-mentioned purpose of the present invention, spy by the following technical solutions:
A kind of toothpaste containing activated carbon from bamboo, the formula meter of this toothpaste includes:
Toothpaste base material 45-55 part, Rhizoma Drynariae 8-10 part, Fructus Psoraleae 8-10 part, Radix Polygoni Multiflori 4-8 part, Folium Ginkgo 5-7
Part, Herba Asari 4-6 part, Olibanum 1-3 part, Borneolum Syntheticum 3-5 part and activated carbon from bamboo 12-16 part；
Wherein, activated carbon from bamboo is prepared from accordance with the following methods:
Bamboo bits mix with phosphoric acid solution and carry out mediating 10-30min, and wherein, bamboo bits with the impregnating ratio of phosphoric acid solution are
1:1.4-1.6；The granularity of bamboo bits is 6-35 mesh, and the water content of bamboo bits is 12-20%；The concentration of phosphoric acid solution is 50-
55%；
The material after the mediating flue gas with 400-650 DEG C carries out adverse current and directly contacts 3.5-4.5h, so that material charcoal
Obtain activated material after changing and activating, after activated material is by washing, being dried and pulverize, obtain activated carbon from bamboo.
Compared with prior art, the invention have the benefit that
(1) activated carbon from bamboo contained in the formula of this toothpaste is with bamboo as raw material and use special process produce and
, belong to natural product, do not contain any chemical composition that human body is had side effect.Use this bamboo that special process prepares
In activated carbon, containing abundant transitional pore (pore diameter is 4-100nm) and a small amount of aperture (pore diameter is less than 4nm),
Specific surface area is big, high adsorption capacity, has well absorption particularly with the diameter fine particle less than 100nm and food debris
Effect.This toothpaste containing activated carbon from bamboo, it is possible to be effectively improved the cleaning efficiency of foreign body in mouth, removes intraoral different
On taste and tooth, the mottle of deposition, makes breath freshening, tooth brilliant white.
(2) Rhizoma Drynariae has effect of promoting blood circulation and stopping pain, strengthening the tendons and bones, it is possible to strengthen the blood circulation at gingiva position, alleviates
The symptoms such as toothache, tooth acid, can also improve cementum, it is to avoid odontoseisis simultaneously.Fructus Psoraleae has effect of warming the kidney to activate YANG, energy
Enough effectively treatment long pains of tooth.Herba Asari has the effect of expelling wind and promoting diuresis, it is possible to effectively treat toothache.Herba Asari and Rhizoma Drynariae and Psoralen
This two tastes medical material compatibility of fat, makes this toothpaste alleviate toothache, strong cemental effect enhancing at double.
(3) Radix Polygoni Multiflori has the effect of tonification essence and blood, it is possible to promote gingiva position blood circulation, increase gingiva position with
And the blood carrying capacity of dental nerve blood vessel.Folium Ginkgo has blood circulation promoting and blood stasis dispelling, effect of removing obstruction in the collateral to relieve pain；Olibanum has to invigorate blood circulation to be determined
Bitterly, effect of detumescence and promoting granulation.Folium Ginkgo, Olibanum and Radix Polygoni Multiflori compatibility, it is possible to strengthen the effect of Radix Polygoni Multiflori tonification essence and blood, make oral cavity
Interior blood circulation strengthens, and eliminates the symptom that swelling and aching of gum is hemorrhage.
(4) Borneolum Syntheticum has sensible, effect of reducing swelling and alleviating pain, it is possible to effectively treat the symptom such as oral ulcer, swelling and aching of gum.
The abnormal smells from the patient delicate fragrance of Borneolum Syntheticum, taste are cool, it is easy to through mucous membrane and subcutaneous tissue absorb, it is possible to strengthen this toothpaste capable of clearing heat and reducing internal heat, detumescence
Effect of pain relieving, and make this toothpaste abnormal smells from the patient salubrious, it is effectively improved halitosis.
Detailed description of the invention
Below in conjunction with embodiment, embodiment of the present invention are described in detail, but those skilled in the art will
Understanding, the following example is merely to illustrate the present invention, and is not construed as limiting the scope of the present invention.In embodiment unreceipted specifically
Condition person, the condition advised according to normal condition or manufacturer is carried out.Agents useful for same or instrument unreceipted production firm person, be
Can be by the commercially available conventional products bought and obtain.
Present embodiment provides a kind of toothpaste containing activated carbon from bamboo, and the formula meter of this toothpaste includes:
Toothpaste base material 45-55 part, Rhizoma Drynariae 8-10 part, Fructus Psoraleae 8-10 part, Radix Polygoni Multiflori 4-8 part, Folium Ginkgo 5-7
Part, Herba Asari 4-6 part, Olibanum 1-3 part, Borneolum Syntheticum 3-5 part and activated carbon from bamboo 12-16 part.
The activated carbon from bamboo contained in the formula of this toothpaste is with bamboo as raw material and uses special process to produce and obtain,
Belong to natural product, do not contain any chemical composition that human body is had side effect.Use this bamboo matter that special process prepares
In activated carbon, containing abundant transitional pore and a small amount of aperture, specific surface area is big, and high adsorption capacity is less than particularly with diameter
The fine particle of 100nm and food debris have good adsorption.This toothpaste containing activated carbon from bamboo, it is possible to effectively
Improve the cleaning efficiency of foreign body in mouth, remove the mottle of deposition on intraoral spot, antibacterial, abnormal flavour and tooth, make mouth
Gas is pure and fresh, tooth brilliant white.
Rhizoma Drynariae has effect of promoting blood circulation and stopping pain, strengthening the tendons and bones, it is possible to strengthen the blood circulation at gingiva position, alleviates tooth
Bitterly, the symptom such as tooth acid, simultaneously can also improve cementum, it is to avoid odontoseisis.Fructus Psoraleae has effect of warming the kidney to activate YANG, it is possible to
The effectively treatment long pain of tooth.Herba Asari has the effect of expelling wind and promoting diuresis, it is possible to effectively treat toothache.Herba Asari and Rhizoma Drynariae and Fructus Psoraleae
This two tastes medical material compatibility, makes this toothpaste alleviate toothache, strong cemental effect enhancing at double.
Radix Polygoni Multiflori has the effect of tonification essence and blood, it is possible to promote gingiva position blood circulation, increase gingiva position and
The blood carrying capacity of dental nerve blood vessel.Folium Ginkgo has blood circulation promoting and blood stasis dispelling, effect of removing obstruction in the collateral to relieve pain；Olibanum have analgesic therapy of invigorating blood circulation,
Effect of detumescence and promoting granulation.Folium Ginkgo, Olibanum and Radix Polygoni Multiflori compatibility, it is possible to strengthen the effect of Radix Polygoni Multiflori tonification essence and blood, in making oral cavity
Blood circulation strengthens, and eliminates the symptom that swelling and aching of gum is hemorrhage.
Borneolum Syntheticum has sensible, effect of reducing swelling and alleviating pain, it is possible to effectively treat the symptom such as oral ulcer, swelling and aching of gum.Ice
The abnormal smells from the patient delicate fragrance of sheet, taste are cool, it is easy to through mucous membrane and subcutaneous tissue absorb, it is possible to only strengthen this toothpaste capable of clearing heat and reducing internal heat, detumescence
Effect of pain, and make this toothpaste abnormal smells from the patient salubrious, it is effectively improved halitosis.
In preferred embodiment of the present invention, above-mentioned formula more preferably: toothpaste base material is 50 parts, and Rhizoma Drynariae is 9
Part, Fructus Psoraleae is 9 parts, and Radix Polygoni Multiflori is 6 parts, and Folium Ginkgo is 6 parts, and Herba Asari is 5 parts, and Olibanum is 2 parts, and Borneolum Syntheticum is 4 parts, and bamboo matter
Activated carbon is 14 parts.Use the toothpaste of this formula, its cleaning oral cavity, alleviate swelling and aching of gum, eliminate abnormal flavour, improve halitosis
Effect more significantly.
In preferred embodiment of the present invention, above-mentioned toothpaste base material includes interfacial agent, binding agent, wetting agent, foaming
Agent, sweeting agent, sodium chloride and water.These compositions are all the conventional ingredients in toothpaste, by its active ingredient with the present invention and
Activated carbon from bamboo combines, it is possible to further enhances the drug effect of this toothpaste, and improves comfort level when using this toothpaste.
It is further preferred that above-mentioned interfacial agent is sodium lauroyl sarcosine.Sodium lauroyl sarcosine has washing, breast
The characteristics such as change and infiltration, its foam performance is superior, and foam is fine and smooth persistently, can alleviate the medicine in above-mentioned medical material in toothpaste
The effect composition stimulation to skin, increases the effect of the antibacterial sterilization of toothpaste.
In preferred embodiment of the present invention, above-mentioned toothpaste base material mark meter by weight includes: interfacial agent is 14-
16 parts, binding agent be 4-6 part, wetting agent be 14-16 part, foaming agent be 6-8 part, sweeting agent be that 3-5 part, sodium chloride are
2-4 part and water are 18-24 part.Use the toothpaste base material of this ratio, and with above-mentioned active ingredient and activated carbon from bamboo
Coordinating, the toothpaste exquisite quality of making is soft, and tooth does not have abrasion, and the parts such as gingiva are also had certain repairing effect,
Effectively keep oral health.
Activated carbon from bamboo is prepared from accordance with the following methods:
(1) kneading step: bamboo bits mix with phosphoric acid solution and carry out mediating 10-30min, and wherein, bamboo bits are molten with phosphoric acid
The impregnating ratio of liquid is 1:1.4-1.6；The granularity of bamboo bits is 6-35 mesh, and the water content of bamboo bits is 12-20%；Phosphoric acid solution
Concentration is 50-55%；
Herein, bamboo bits are expressed as with the impregnating ratio of phosphoric acid solution: the mass ratio of over dry bamboo bits/pure phosphoric acid, wherein over dry bamboo
Bits refer to that in bamboo bits, moisture is more than 98%.Phosphoric acid used in the present invention is food grade phosphoric acid.
The bamboo bits using granularity to be 6-35 mesh, the span of its granularity is little, advantageously forms hole uniform, constitutionally stable
Activated carbon from bamboo.Additionally, granularity is less than the fine powder burning of 6 mesh in bamboo bits, it is possible to the dry offer energy considered to be worth doing for bamboo, to realize thing
Its use to the greatest extent, reduces cost.The water content of bamboo bits is 12-20%, preferably 16%, be conducive to improving between bamboo bits and phosphoric acid
Kneading effect.The concentration of phosphoric acid solution is 50-55%, preferably 52%, be conducive to making phosphoric acid penetrate in bamboo cell, and then
The pore structure making activated carbon from bamboo is transitional pore.
In this approach, the concentration of phosphoric acid solution is 50-55%, and bamboo bits are 1:1.4-with the impregnating ratio of phosphoric acid solution
1.6, preferably 1:1.5, use this impregnating ratio to mediate 10-30min, preferably 20min, it is possible to promotes cellulose in bamboo bits
After acid hydrolysis, form moderate topological structure staggered floor graphite microcrystal, and the cellulose having during more phosphoric acid is considered to be worth doing with bamboo occurs
Esterification combines, the formation of the transitional pore of the most this activated carbon from bamboo and the increase of specific surface area.
Bamboo bits mixed with phosphoric acid solution and mediates, making bamboo bits be fully contacted with phosphoric acid solution, rub pressure, make further
Phosphoric acid can within a short period of time through the cell wall of bamboo cell and in entering the protoplast of cell, be conducive to strengthening phosphoric acid
Catalytic degradation effect, and then make the reducing sugar of intracellular low-molecular-weight increase.And during the carbonization-activation in later stage, this
The amount of reducing sugar is the most, and it is the most that reducing sugar can form gas under the action of heat, these gas effusion material system, makes
After hole in the activated carbon that obtains more.
In preferred embodiment of the present invention, using kneader to mediate, the conduction oil temperature of kneader is 195-
205℃.Combine under these conditions, make kneading effect more preferably, be conducive to the degree controlling to mediate, make the activated carbon finally obtained
In pore size.
(2) carbonization-activation step: the flue gas with 400-650 DEG C of the material after mediating carries out adverse current and directly contacts 3.5-
4.5h, so that obtaining activated material after material carbonization activation.
This mode uses the mode of carbonization, activation integral, simplify production process, shorten material carbonization and activation time
Between, save material and energy consumption.Wherein, the temperature of material carbonization and activation is 400-650 DEG C, preferably 500-550 DEG C；Material
The time of carbonization and activation is 3.5-4.5h, preferably 4h, is conducive to, while forming the activated material of better quality, saving
Energy consumption, reduces production cost.
In preferred embodiment of the present invention, the carbonization of material and activation process are to carry out in rotary furnace, rotary furnace
Rotating speed is 1-3 rev/min, and the rotational axis line of rotary furnace angle of inclination with respect to the horizontal plane is 2-4 degree.In this condition
Under, material from stove tail to burner, experience be dried, fibre structure dehydration, material carbonization, organic polymer decomposition, loose structure fixed
In each stage such as type, eventually enter into the fast charring activation of the discharge chamber of burner, beneficially material.
(3) post-processing step: by activated material by washing, be dried and after pulverizing, obtaining activated carbon from bamboo.
In preferred embodiment of the present invention, after pulverizing, the granularity of the activated carbon from bamboo of gained is 400-600 mesh.This
The activated carbon dispersive property of granularity is good, finer and smoother, is conducive to improving the cleaning effect of this toothpaste.
The preparation method of this toothpaste containing activated carbon from bamboo is:
(1) toothpaste base material is conventionally prepared, standby；
(2) Borneolum Syntheticum powder is broken to 400-800 mesh, standby；Use microwave-assisted extraction extract Rhizoma Drynariae, Fructus Psoraleae, what
Effective ingredient in the Radix Polygoni Multiflori, Folium Ginkgo, Herba Asari and Olibanum.The parameter of microwave-assisted extraction is: power is 250-350W, carries
The time of taking is 15-25min, and Extraction solvent is the alcoholic solution of 70-80%；Filter and be concentrated to give extractum, described leaching after extraction
Cream is 1.16-1.18 when 70-80 DEG C relative to the relative density of water.
(3) above-mentioned extractum is mixed homogeneously with the Borneolum Syntheticum after pulverizing, obtain medical material essence, subsequently by this medical material elite
Liquid, activated carbon from bamboo and toothpaste base material mix homogeneously, stir 30-40min at 70-80 DEG C and obtain emulsion, to be emulsified
When liquid is cooled to 10-25 DEG C, it is in harmonious proportion concentration with water, obtains toothpaste.
Embodiment 1
The present embodiment provides a kind of toothpaste containing activated carbon from bamboo, and the formula meter of this toothpaste includes:
Toothpaste base material 50 parts, Rhizoma Drynariae 9 parts, Fructus Psoraleae 9 parts, Radix Polygoni Multiflori 6 parts, Folium Ginkgo 6 parts, Herba Asari 5 parts, Olibanum 2 parts,
Borneolum Syntheticum 4 parts and activated carbon from bamboo 14 parts.
Wherein, activated carbon from bamboo is prepared from accordance with the following methods:
Bamboo bits and phosphoric acid solution are mixed in being incorporated in kneader and carry out mediating 20min, wherein, the conduction oil temperature of kneader
Being 200 DEG C, bamboo bits are 1:1.5 with the impregnating ratio of phosphoric acid solution；The granularity of bamboo bits is 6-35 mesh, and the water content of bamboo bits is 16%；
The concentration of phosphoric acid solution is 52%.
The material flue gas with 500-550 DEG C after mediating carries out countercurrently directly contacting 4h so that material carbonization activating
After obtain activated material, activated material by washing, be dried and pulverize after, obtain activated carbon from bamboo.
The preparation method of this toothpaste is:
(1) toothpaste base material is conventionally prepared, standby；
(2) Borneolum Syntheticum powder is broken to 600 mesh, standby；Use microwave-assisted extraction extract Rhizoma Drynariae, Fructus Psoraleae, Radix Polygoni Multiflori,
Effective ingredient in Folium Ginkgo, Herba Asari and Olibanum.The parameter of microwave-assisted extraction is: power is 300W, and extraction time is
20min, Extraction solvent is the alcoholic solution of 75%；Filter and be concentrated to give extractum after extraction, described extractum when 75 DEG C relative to
The relative density of water is 1.17.
(3) above-mentioned extractum is mixed homogeneously with the Borneolum Syntheticum after pulverizing, obtain medical material essence, subsequently by this medical material elite
Liquid, activated carbon from bamboo and toothpaste base material mix homogeneously, stir 35min at 75 DEG C and obtain emulsion, and liquid to be emulsified is cooled to
When 20 DEG C, it is in harmonious proportion concentration with water, obtains toothpaste.
Embodiment 2
The present embodiment provides a kind of toothpaste containing activated carbon from bamboo, and its formula and preparation method are consistent with embodiment 1, no
It is with part:
Activated carbon from bamboo is prepared from accordance with the following methods:
Bamboo bits mix with phosphoric acid solution and carry out mediating 10min, and wherein, bamboo bits are 1 with the impregnating ratio of phosphoric acid solution:
1.6；The granularity of bamboo bits is 6-35 mesh, and the water content of bamboo bits is 12%；The concentration of phosphoric acid solution is 55%；
The material after the mediating flue gas with 400-500 DEG C carries out adverse current and directly contacts 4.5h, so that material carbonization work
Obtain activated material after change, after activated material is by washing, being dried and pulverize, obtain activated carbon from bamboo.
Embodiment 3
The present embodiment provides a kind of toothpaste containing activated carbon from bamboo, and its formula and preparation method are consistent with embodiment 1, no
It is with part:
Activated carbon from bamboo is prepared from accordance with the following methods:
Bamboo bits and phosphoric acid solution are mixed in being incorporated in kneader and carry out mediating 20min, wherein, the conduction oil temperature of kneader
Being 195 DEG C, wherein, bamboo bits are 1:1.4 with the impregnating ratio of phosphoric acid solution；The granularity of bamboo bits is 6-35 mesh, and the water content of bamboo bits is
20%；The concentration of phosphoric acid solution is 50%；
The material after the mediating flue gas with 550-650 DEG C carries out adverse current and directly contacts 3.5h, so that material carbonization work
Obtain activated material after change, after activated material is by washing, being dried and pulverize, obtain activated carbon from bamboo.
Embodiment 4
The present embodiment provides a kind of toothpaste containing activated carbon from bamboo, and the formula meter of this toothpaste includes:
Toothpaste base material 45 parts, Rhizoma Drynariae 10 parts, Fructus Psoraleae 8 parts, Radix Polygoni Multiflori 8 parts, Folium Ginkgo 5 parts, Herba Asari 4 parts, Olibanum 3
Part, Borneolum Syntheticum 5 parts and activated carbon from bamboo 16 parts.
The preparation method of the preparation method of activated carbon from bamboo and this toothpaste is consistent with embodiment 1.
Embodiment 5
The present embodiment provides a kind of toothpaste containing activated carbon from bamboo, and the formula meter of this toothpaste includes:
Toothpaste base material 55 parts, Rhizoma Drynariae 8 parts, Fructus Psoraleae 10 parts, Radix Polygoni Multiflori 4 parts, Folium Ginkgo 7 parts, Herba Asari 6 parts, Olibanum 1
Part, Borneolum Syntheticum 3 parts and activated carbon from bamboo 12 parts.
The preparation method of the preparation method of activated carbon from bamboo and this toothpaste is consistent with embodiment 1.
Embodiment 6
The present embodiment provides a kind of toothpaste containing activated carbon from bamboo, and the formula meter of this toothpaste includes:
Rhizoma Drynariae 9 parts, Fructus Psoraleae 9 parts, Radix Polygoni Multiflori 6 parts, Folium Ginkgo 6 parts, Herba Asari 5 parts, Olibanum 2 parts, Borneolum Syntheticum 4 parts, bamboo matter
Activated carbon 14 parts, sodium lauroyl sarcosine are 15 parts, binding agent is 5 parts, wetting agent is 15 parts, foaming agent is 7 parts, sweeting agent is
4 parts, sodium chloride is 3 parts and water is 22 parts.
The preparation method of the preparation method of activated carbon from bamboo and this toothpaste is consistent with embodiment 1.
Embodiment 7
The present embodiment provides a kind of toothpaste containing activated carbon from bamboo, and the formula meter of this toothpaste includes:
Rhizoma Drynariae 9 parts, Fructus Psoraleae 9 parts, Radix Polygoni Multiflori 6 parts, Folium Ginkgo 6 parts, Herba Asari 5 parts, Olibanum 2 parts, Borneolum Syntheticum 4 parts, bamboo matter
Activated carbon 14 parts, interfacial agent are 14 parts, binding agent is 6 parts, wetting agent is 14 parts, foaming agent is 8 parts, sweeting agent is 5 parts,
It is 18 parts with water that sodium chloride is 2 parts.
The preparation method of the preparation method of activated carbon from bamboo and this toothpaste is consistent with embodiment 1.
Embodiment 8
The present embodiment provides a kind of toothpaste containing activated carbon from bamboo, and the formula meter of this toothpaste includes:
Rhizoma Drynariae 9 parts, Fructus Psoraleae 9 parts, Radix Polygoni Multiflori 6 parts, Folium Ginkgo 6 parts, Herba Asari 5 parts, Olibanum 2 parts, Borneolum Syntheticum 4 parts, bamboo matter
Activated carbon 14 parts, interfacial agent are 16 parts, binding agent is 4 parts, wetting agent is 16 parts, foaming agent is 6 parts, sweeting agent is 3 parts,
It is 24 parts with water that sodium chloride is 4 parts.
The preparation method of the preparation method of activated carbon from bamboo and this toothpaste is consistent with embodiment 1.
Embodiment 9
The present embodiment provides a kind of toothpaste containing activated carbon from bamboo, formula of this toothpaste and preparation method thereof and embodiment
1 is consistent, and difference is:
Activated carbon from bamboo is prepared as follows and forms:
Bamboo bits and phosphoric acid solution are mixed in being incorporated in kneader and carry out mediating 20min, wherein, the conduction oil temperature of kneader
Being 195 DEG C, bamboo bits are 1:1.4 with the impregnating ratio of phosphoric acid solution；The granularity of bamboo bits is 6-35 mesh, and the water content of bamboo bits is 20%；
The concentration of phosphoric acid solution is 50%；
The material flue gas with 550-650 DEG C after mediating carries out adverse current and directly contacts 3.5h so that material carbonization work
Obtain activated material after change, after activated material is by washing, being dried and pulverize, obtain activated carbon from bamboo.
Embodiment 10
The present embodiment provides a kind of toothpaste containing activated carbon from bamboo, formula of this toothpaste and preparation method thereof and embodiment
1 is consistent, and difference is:
Activated carbon from bamboo is prepared as follows and forms:
Bamboo bits and phosphoric acid solution are mixed in being incorporated in kneader and carry out mediating 20min, wherein, the conduction oil temperature of kneader
Being 205 DEG C, bamboo bits are 1:1.4 with the impregnating ratio of phosphoric acid solution；The granularity of bamboo bits is 6-35 mesh, and the water content of bamboo bits is 20%；
The concentration of phosphoric acid solution is 50%；
The material flue gas with 500-550 DEG C after mediating carries out countercurrently directly contacting 4h so that material carbonization activating
After obtain activated material.The carbonization of material and activation process are to carry out in rotary furnace, and the rotating speed of rotary furnace is 1-3 rev/min, return
The rotational axis line of converter angle of inclination with respect to the horizontal plane is 2-4 degree.After activated material is by washing, being dried and pulverize, i.e.
Obtaining activated carbon from bamboo, its granularity is 400-600 mesh.
Embodiment 11
The present embodiment provides a kind of toothpaste containing activated carbon from bamboo, formula of this toothpaste and preparation method thereof and embodiment
1 is consistent, and difference is:
Activated carbon from bamboo is prepared as follows and forms:
Bamboo bits and phosphoric acid solution are mixed in being incorporated in kneader and carry out mediating 20min, wherein, the conduction oil temperature of kneader
Being 200 DEG C, bamboo bits are 1:1.4 with the impregnating ratio of phosphoric acid solution；The granularity of bamboo bits is 6-35 mesh, and the water content of bamboo bits is 20%；
The concentration of phosphoric acid solution is 50%；
The material flue gas with 550-650 DEG C after mediating carries out adverse current and directly contacts 3.5h so that material carbonization work
Activated material is obtained after change.The carbonization of material and activation process are to carry out in rotary furnace, and the rotating speed of rotary furnace is 2 revs/min, revolution
The rotational axis line of stove angle of inclination with respect to the horizontal plane is 3 degree.After activated material is by washing, being dried and pulverize, obtain bamboo
Activated carbon, its granularity is 500 mesh.
Comparative example 1
This comparative example provides a kind of toothpaste without activated carbon from bamboo, and this formulation of tooth-paste is counted by weight and included:
Toothpaste base material 50 parts, Rhizoma Drynariae 9 parts, Fructus Psoraleae 9 parts, Radix Polygoni Multiflori 6 parts, Folium Ginkgo 6 parts, Herba Asari 5 parts, Olibanum 2 parts,
And Borneolum Syntheticum 4 parts.
The preparation method of this toothpaste is consistent with embodiment 1.
Comparative example 2
This comparative example provides a kind of toothpaste containing common commercially available activated carbon from bamboo, and this formulation of tooth-paste counts bag by weight
Include:
Toothpaste base material 50 parts, Rhizoma Drynariae 9 parts, Fructus Psoraleae 9 parts, Radix Polygoni Multiflori 6 parts, Folium Ginkgo 6 parts, Herba Asari 5 parts, Olibanum 2 parts,
Borneolum Syntheticum 4 parts and common commercially available activated carbon from bamboo 14 parts.
The preparation method of this toothpaste is consistent with embodiment 1.
Comparative example 3
This comparative example provides a kind of toothpaste containing commercially available active fruit shell carbon, and this formulation of tooth-paste is counted by weight and included:
Toothpaste base material 50 parts, Rhizoma Drynariae 9 parts, Fructus Psoraleae 9 parts, Radix Polygoni Multiflori 6 parts, Folium Ginkgo 6 parts, Herba Asari 5 parts, Olibanum 2 parts,
Borneolum Syntheticum 4 parts and active fruit shell carbon 14 parts.
The preparation method of this toothpaste is consistent with embodiment 1.
Comparative example 4
This comparative example provides a kind of toothpaste containing activated carbon from bamboo, and this formulation of tooth-paste is counted by weight and included:
Toothpaste base material 50 parts, Radix Polygoni Multiflori 6 parts, Folium Ginkgo 6 parts, Herba Asari 5 parts, Olibanum 2 parts, Borneolum Syntheticum 4 parts and bamboo matter activity
Charcoal 14 parts.
The preparation method of this toothpaste and the preparation method of activated carbon from bamboo are consistent with embodiment 1.
Experimental example 1
Use and test:
Choose and there is odontoseisis, gingival hemorrhage, oral ulcer and the patient of at least one symptom of halitosis, as test
Person, totally 600, age distribution is in 30-50 year.It is randomly divided into 15 groups, often organizes 40 people.
Having 11 groups in 15 groups is experimental group, and other 4 groups is matched group.Wherein, experimental group uses embodiment of the present invention 1-11
The toothpaste prepared by formula；Matched group uses the toothpaste prepared by comparative example 1-4 of the present invention respectively.
Every experimenter brushes teeth 2 every day, and the most once, each 3-5min, between the amount of everyone toothpaste the most used
There was no significant difference, using method is consistent with ordinary toothpaste, is a course for the treatment of with 1 month.
Tester according to oneself feel mark.Standards of grading use ten point system, and 1 point worst, before and after being use
Unchanged；10 points best, is transference cure after use.It addition, use implication test instrunment to measure each experimenter a treatment
Implication value after journey.
Result is as shown in table 1:
The using effect of each toothpaste sample of table 1.
As shown in Table 1:
(1) by comparative example 1-3 compared with the using effect of embodiment 1-11, it appeared that the cleaning of embodiment 1-11
Effect is substantially better than (9.3-9.7 divides) cleaning effect (7.0-7.4 divides) of comparative example 1-3.Meanwhile, the changing of embodiment 1-11
The effect (8.6-9.7 divides) of kind halitosis is substantially better than the effect (4.2-6.8 divides) improving halitosis of comparative example 1-3.Additionally,
The implication value (13-25) of embodiment 1-11 is also significantly lower than the implication value (58-71) of comparative example 1-3.This illustrates activated carbon
The cleaning capacity of toothpaste can be improved, and improve the symptom of halitosis.And the effect of the activated carbon from bamboo that the present invention provides is excellent
In commercially available common activated carbon from bamboo and active fruit shell carbon.This is primarily due to the hole knot of commercially available common activated carbon from bamboo
Structure is many based on macropore, and its pore diameter is more than 100nm；And the pore structure of commercially available active fruit shell carbon is many based on micropore,
Its pore diameter is less than 4nm.Therefore, this two classes activated carbon for oral cavity interior diameter fine particle in the range of 4-100nm with
And food debris Scavenging activity is weak.And using the activated carbon from bamboo of the present invention, its hole is with transitional pore (a diameter of 4-100nm)
It is main and the most a small amount of aperture (diameter is less than 4nm), therefore, it is possible to diameter to be less than fine particle and the food thereof of 100nm
Residue has the strongest adsorption, moreover it is possible to adsorption of foreign matter and antibacterial so that the cleaning capacity of this toothpaste and improve halitosis
Ability is strong.
(2) by comparative example 1-3 compared with the using effect of embodiment 1-11, it appeared that use embodiment 1-11 to carry
The toothpaste of confession is after one month, and gingival hemorrhage and the oral ulcer symptom of patient are improved.This is primarily due to embodiment 1-11
Toothpaste in rich in activated carbon from bamboo strong to the cleaning capacity in oral cavity, it is possible to the effective intraoral foreign body and harmful micro-removed
Biological etc., thus the inflammation preventing harmful microbe amount reproduction and causing, improve oral ulcer.It addition, utilize this bamboo
The special hole gap structure of activated carbon, makes dental bed position obtain the cleaning of profound level, so that the active ingredient of medical material can be straight
Reach affected part, improve gingival hemorrhage and oral ulcer symptom.
(3) curative effect of comparative example 4 with embodiment 1 is compared, it appeared that use the toothpaste one month that embodiment 1 provides
After, the symptom of odontoseisis, gingival hemorrhage and oral ulcer is significantly improved.This explanation Rhizoma Drynariae is joined with Fructus Psoraleae
5 use, it is possible to significantly improve toothpaste and alleviate toothache, strengthen cementum, improve the ability of ulcer.
Experimental example 2
The performance characterization of the activated carbon from bamboo that the method using the present invention to provide prepares:
Due at present, hole is that the production method of the activated carbon of transitional pore (a diameter of 4-100nm) only has two kinds, a kind of
Being the activated carbon produced for raw material with coal, another kind is that the activated carbon after using carries out activating and regenerating.Both approaches
The activated carbon produced, although hole is many based on transitional pore, but activated carbon is contained within the heavy metal that content is numerous, it is impossible to be used for washing
Protect articles for use field.And the activated carbon sold on the market at present, how based on wood activated charcoal and active fruit shell carbon, therefore, at this
Embodiment uses commercially available wood activated charcoal and commercially available active fruit shell carbon compare, come the activated carbon from bamboo in the present invention
Performance characterize.
Sample comes from the activated carbon from bamboo produced according to the method for embodiment, and commercially available wood activated charcoal and shell
Activated carbon is as reference substance.
According to the method for regulation in GB/T 12496-1999, the traditional performance of above-mentioned sample is measured,
According to the method for regulation in GB/T13803.1-1999, the intensity of above-mentioned sample is measured.
Use the ASA full-automatic specific surface area of P2020 type and pore size distribution determining instrument, do adsorbate with liquid nitrogen, carry out static state
The mensuration of liquid nitrogen absorption method.
The result of embodiment 1 is as shown in table 2, and in other embodiments, the characterization result of activated carbon from bamboo is similar to Example 1.
The performance test results of table 2. activated carbon from bamboo
As shown in Table 2:
Owing to wood activated charcoal and active fruit shell carbon comprise only a small amount of transitional pore, so used by the toothpaste of the present invention
The performance of activated carbon from bamboo is substantially better than commercially available wood activated charcoal and active fruit shell carbon.
By the pore diameter of each sample in table 2 is contrasted, it appeared that the method using the present invention to provide is made
The pore diameter of standby activated carbon from bamboo ratio in the range of 4-100nm is many, illustrates that its hole mostly is transitional pore.Meanwhile, also
Containing a small amount of micropore, its diameter is less than 4nm.The quantity of macropore is the fewest a lot.As can be seen here, in the toothpaste of the present invention
Activated carbon from bamboo, containing abundant transitional pore and a small amount of aperture, specific surface area is big, to the diameter fine grained less than 100nm
The microorganism such as thing and antibacterial has good adsorption.This activated carbon from bamboo is joined in toothpaste, it is possible to strengthen toothpaste pair
The cleaning effect of oral cavity bacterium, residue and fine particle.
Additionally, the iodine sorption value of activated carbon from bamboo that provides of the present invention and methylene blue adsorption value are the highest commercially available wooden
Activated carbon and active fruit shell carbon, and the intensity of this activated carbon from bamboo is better than wood activated charcoal, is slightly weaker than active fruit shell carbon.Explanation
The absorption property of the activated carbon from bamboo prepared by method that the employing present invention provides is good, intensity is relatively big, quality is high.
Although illustrate and describing the present invention with specific embodiment, but it will be appreciated that without departing substantially from the present invention's
May be made that in the case of spirit and scope many other change and amendment.It is, therefore, intended that in the following claims
Including all such changes and modifications belonged in the scope of the invention.
Claims (10)
1. the toothpaste containing activated carbon from bamboo, it is characterised in that the formula meter of described toothpaste includes:
Toothpaste base material 45-55 part, Rhizoma Drynariae 8-10 part, Fructus Psoraleae 8-10 part, Radix Polygoni Multiflori 4-8 part, Folium Ginkgo 5-7 part, thin
Pungent 4-6 part, Olibanum 1-3 part, Borneolum Syntheticum 3-5 part and activated carbon from bamboo 12-16 part；
Wherein, described activated carbon from bamboo is prepared from accordance with the following methods:
Bamboo bits mix with phosphoric acid solution and carry out mediating 10-30min, wherein, described bamboo bits and the dipping of described phosphoric acid solution
Ratio is 1:1.4-1.6；The granularity of described bamboo bits is 6-35 mesh, and the water content of described bamboo bits is 12-20%；Described phosphoric acid is molten
The concentration of liquid is 50-55%；
The material after the mediating flue gas with 400-650 DEG C carries out adverse current and directly contacts 3.5-4.5h, so that described material charcoal
Obtain activated material after changing and activating, after described activated material is by washing, being dried and pulverize, obtain described activated carbon from bamboo.
Toothpaste containing activated carbon from bamboo the most according to claim 1, it is characterised in that count by weight, described tooth
Cream base material is 50 parts, and described Rhizoma Drynariae is 9 parts, and described Fructus Psoraleae is 9 parts, and described Radix Polygoni Multiflori is 6 parts, and described Folium Ginkgo is 6 parts,
Described Herba Asari is 5 parts, and described Olibanum is 2 parts, and described Borneolum Syntheticum is 4 parts, and described activated carbon from bamboo is 14 parts.
Toothpaste containing activated carbon from bamboo the most according to claim 1, it is characterised in that count by weight, described tooth
Cream base material includes interfacial agent, binding agent, wetting agent, foaming agent, sweeting agent, sodium chloride and water.
Toothpaste containing activated carbon from bamboo the most according to claim 3, it is characterised in that count by weight, described boundary
Face activating agent is sodium lauroyl sarcosine.
Toothpaste containing activated carbon from bamboo the most according to claim 3, it is characterised in that described toothpaste base material parts by weights
Number meter includes:
Described interfacial agent be 14-16 part, described binding agent be 4-6 part, described wetting agent be 14-16 part, described foaming
Agent be 6-8 part, described sweeting agent be that 3-5 part, described sodium chloride are 2-4 part and described water is 18-24 part.
Toothpaste containing activated carbon from bamboo the most according to claim 1, it is characterised in that the concentration of described phosphoric acid solution is
52%, described bamboo bits are 1:1.5 with the impregnating ratio of described phosphoric acid solution.
Toothpaste containing activated carbon from bamboo the most according to claim 1, it is characterised in that use kneader to mediate,
The conduction oil temperature of described kneader is 195-205 DEG C.
Toothpaste containing activated carbon from bamboo the most according to claim 1, it is characterised in that the carbonization of described material and activation
Process is to carry out in rotary furnace, and the rotating speed of described rotary furnace is 1-3 rev/min, the rotational axis line of described rotary furnace relative to
The angle of inclination of horizontal plane is 2-4 degree.
Toothpaste containing activated carbon from bamboo the most according to claim 1, it is characterised in that the described material after mediating
When carrying out carbonization activation procedure, the temperature of described flue gas is 500-550 DEG C, the described material after kneading and described flue gas
The time of contact is 4h.
Toothpaste containing activated carbon from bamboo the most according to claim 1, it is characterised in that the grain of described activated carbon from bamboo
Degree is 400-600 mesh.
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| CN201610740049.XA CN106109361A (en) | 2016-08-27 | 2016-08-27 | A kind of toothpaste containing activated carbon from bamboo |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107280981A (en) * | 2017-04-24 | 2017-10-24 | 南昌登特科技有限公司 | A kind of activated carbon tooth powder |
| CN110540230A (en) * | 2019-09-25 | 2019-12-06 | 南昌师范学院 | Modified porous cattail straw biochar with tooth whitening and antibacterial effects |
| CN110897992A (en) * | 2020-01-02 | 2020-03-24 | 广东立爽生物科技有限公司 | Halitosis removing toothpaste and preparation method thereof |
| CN112675052A (en) * | 2020-12-31 | 2021-04-20 | 可普维尔(厦门)科技有限公司 | Toothpaste containing carbon compound and preparation method thereof |
| CN115040460A (en) * | 2022-07-12 | 2022-09-13 | 苏州清馨健康科技有限公司 | Oral cavity cleaning toothpaste for whitening teeth and preparation method thereof |
-
2016
- 2016-08-27 CN CN201610740049.XA patent/CN106109361A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107280981A (en) * | 2017-04-24 | 2017-10-24 | 南昌登特科技有限公司 | A kind of activated carbon tooth powder |
| CN107280981B (en) * | 2017-04-24 | 2020-07-28 | 南昌登特科技有限公司 | Activated carbon tooth powder |
| CN110540230A (en) * | 2019-09-25 | 2019-12-06 | 南昌师范学院 | Modified porous cattail straw biochar with tooth whitening and antibacterial effects |
| CN110897992A (en) * | 2020-01-02 | 2020-03-24 | 广东立爽生物科技有限公司 | Halitosis removing toothpaste and preparation method thereof |
| CN112675052A (en) * | 2020-12-31 | 2021-04-20 | 可普维尔(厦门)科技有限公司 | Toothpaste containing carbon compound and preparation method thereof |
| CN115040460A (en) * | 2022-07-12 | 2022-09-13 | 苏州清馨健康科技有限公司 | Oral cavity cleaning toothpaste for whitening teeth and preparation method thereof |
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