CN106100518B - The implementation method of passive low-grade fever photoelectricity, low-grade fever electricity and low-grade fever combined power system - Google Patents

The implementation method of passive low-grade fever photoelectricity, low-grade fever electricity and low-grade fever combined power system Download PDF

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Publication number
CN106100518B
CN106100518B CN201610414850.5A CN201610414850A CN106100518B CN 106100518 B CN106100518 B CN 106100518B CN 201610414850 A CN201610414850 A CN 201610414850A CN 106100518 B CN106100518 B CN 106100518B
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low
grade fever
electricity
passive
unit
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CN106100518A (en
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曹伟
付军
陈杰
高博
张志强
陈治江
袁登鹏
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Institute of Materials of CAEP
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    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02SGENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S10/00PV power plants; Combinations of PV energy systems with other systems for the generation of electric power
    • H02S10/30Thermophotovoltaic systems
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K27/00Plants for converting heat or fluid energy into mechanical energy, not otherwise provided for
    • F01K27/02Plants modified to use their waste heat, other than that of exhaust, e.g. engine-friction heat
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Fuel Cell (AREA)

Abstract

The invention discloses a kind of passive low-grade fever photoelectricity, low-grade fever electricity and low-grade fever combined power system, including for gaseous hydrocarbon fuel and air to be carried out catalysis reaction, to generate the passive heat source unit of thermal energy, it is connect by pipeline with the passive heat source unit, for thermal energy to be first converted into light reconvert into electricity and forms the low-grade fever photovoltaic element of level-one electricity production output, it is connect by pipeline with the low-grade fever photovoltaic element, the low-grade fever electric unit exported is produced electricity for converting thermal energy into electricity and forming second level, and it is connect by pipeline with the low-grade fever electric unit, the low-grade fever power unit exported is produced electricity for converting thermal energy into electricity and forming three-level.Structure of the invention is reasonable, ingenious in design, and the output energy efficiency of total system greatly improved, and meets higher energy density output demand, therefore, the present invention is suitable for popularization and application.

Description

The implementation method of passive low-grade fever photoelectricity, low-grade fever electricity and low-grade fever combined power system
Technical field
The present invention relates to a kind of dynamical systems, and in particular to be a kind of passive low-grade fever photoelectricity, low-grade fever electricity and low-grade fever connection Close the implementation method of dynamical system.
Background technique
With the fast development of MEMS (Micro-electromechanical System) MEMS, to having The demand of micro- energy conversion system of high specific energy also rapid growth.Energy conversion is realized in miniature scale, in addition to traditional electricity Other than pond, there are also micro fuel cell, micro- gas turbine, Mini Rotary Engine, micro TE generator, low-grade fever photocurrent generators etc.. These realize that the device or system of energy conversion is known as power MEMS (Power MEMS) in minute yardstick.Microkinetic machine Electric system is that international research thermoelectricity, distinguishing feature are to be burnt in microdevice using hydrocarbon fuel and be made over the past decade It obtains chemical energy and is converted to electric energy.The ratio of hydrocarbon fuel can be very high, can achieve 45MJ/kg, and lithium ion best at present can Rechargeable battery is then about 1.2MJ/kg, the former is the decades of times of the latter.
Using hydrocarbon fuel, the PowerMEMS of minute yardstick is hopeful to realize the micro- energy conversion for decupling battery, meets high The power resources of the micromechanics industry of speed development need.Traditional large scale energy conversion system is compared, PowerMEMS is equally accounted for According to advantage.By taking the engine of jet plane as an example, energy density 10W/g, the 1W/g relative to ordinary internal combustion engine is It is promoted to about 10 times.But PowerMEMS can break through 100W/g, also 10 times higher than the energy density of jet engine.So High energy density makes many applications for needing high energy to supply have the possibility realized, while also to the hair of the following dynamic power machine Exhibition generates and greatly facilitates effect.Further, since the storage characteristics of hydrocarbon fuel, can realize on minute yardstick PowerMEMS Prolonged supply, so as to generate prolonged continuous electric energy.This dot characteristics needs long-time electric energy to supply for many Application, there is great realistic meaning, such as field work, aerospace etc..
PowerMEMS can be divided into micro fuel cell, micro- gas turbine, micro- turn according to the difference of its energy conversion mode Sub- engine, micro TE generator, low-grade fever photocurrent generator etc. are a variety of.Different PowerMEMS is in energy density, application requirement Etc. have different features.Using the PowerMEMS of hydrocarbon fuel, long-time and high-energy density can be realized simultaneously Electric energy supply, so being hopeful to reach the inaccessiable height of conventional batteries institute in terms of micro- energy conversion, to be expected in army Thing and civilian aspect, which can obtain, widely answers.
Power resources can be used as using the PowerMEMS of hydrocarbon fuel in military aspect, apply and needing long continuation of the journey In the unmanned plane of the high-energy density energy, robot dog, battlefield robot and exoskeleton device, so that these high new equipments is continuous Boat is promoted to 24 hours or more from the magnitude of dozens of minutes, so that the high intensity for these battlefields machinery fights one battle after another and provides The basis of realization.And at civilian aspect, the PowerMEMS of high specific energy can be used as the power supply source of mobile power source.Such as The joint of dozens of PowerMEMS when using hydrogen as fuel, can substitute the internal combustion engine of current automobile, to realize automobile Cleaning discharge and permanent continuation of the journey.Compared to the battery of electric vehicle and the energy output of ordinary internal combustion engine, using PowerMEMS's Automobile is hopeful to obtain the continuation of the journey for decupling current automobile, and low-down power dissipation obj ectives may be implemented.Distributed minute yardstick Small-size energy system can provide efficient electric energy supply then for remote districts.If adopted extensively in terms of military and civilian Use PowerMEMS as the converting system of the mobile energy, can be greatly energy saving, and the generation probability of haze can be reduced, And then it is provided safeguard for environmental protection.
However, enough energy could be obtained since low-grade fever photoelectricity and low-grade fever electricity need hydrocarbon fuel to react at relatively high temperatures Amount output, therefore, the transfer efficiency of current photoelectricity and thermoelectric material is lower, and it is not high to result in overall output energy efficiency, and Although low-grade fever mechanical driver unit energy delivery efficiency is higher, since there are mechanical moving elements, for high-speed motion portion The sealing of part and loss problem also need further to solve.Therefore, existing power MEMS is due to complete not enough in design It is kind, thus also it is unable to satisfy above-mentioned theory energy output needs.
Summary of the invention
In view of the above shortcomings of the prior art, the present invention provides a kind of passive low-grade fever photoelectricity, low-grade fever electricity and low-grade fever connection The implementation method for closing dynamical system, can greatly improve the delivery efficiency of integral energy.
To achieve the above object, The technical solution adopted by the invention is as follows:
Passive low-grade fever photoelectricity, low-grade fever electricity and low-grade fever combined power system, including be used for gaseous hydrocarbon fuel and sky Gas carries out catalysis reaction, the passive heat source unit to generate thermal energy, is connect, is used with the passive heat source unit by pipeline In thermal energy is first converted into light reconvert into electricity and forms the low-grade fever photovoltaic element of level-one electricity production output, pass through pipeline and the low-grade fever Photovoltaic element connection, for convert thermal energy into electricity and formed second level electricity production output low-grade fever electric unit, and by pipeline with Low-grade fever electric unit connection produces electricity the low-grade fever power unit exported for converting thermal energy into electricity and forming three-level.
It is urged specifically, the passive heat source unit has loaded Cu, Pd, Pt or Ni by ultrasonic immersing method for surface The catalytic member of agent.
Further, the catalytic member is cylindricality, plate shape or the double-deck column construction.
Still further, the low-grade fever photovoltaic element includes glass container, the radiation being deposited on the glass container inner wall Luminescent layer, and the photoelectric conversion unit being arranged on glass container outer wall;The radioluminescence layer and passive heat source unit Connection.
Preferably, the radioluminescence layer is by SiC, Al2O3Or MgO material is made.
Preferably, the photoelectric conversion unit is made of GaSb material.
Further, the low-grade fever power unit includes low-grade fever mechanical driver unit, and with the low-grade fever machine power The microgenerator of device connection.
Based on above system, the present invention also provides the implementation methods of the combined power system, comprising the following steps:
(1) it is filled with hydrocarbon fuel and air into passive heat source unit to mix with catalyst, it is anti-that passive catalysis occurs It answers, generates gaseous products and high temperature hot gas;
(2) high temperature hot gas is first into low-grade fever photoelectric conversion unit, makes the radioluminescence layer in low-grade fever photovoltaic element High-energy photon is issued, then high-energy photon generates electronics on photoelectric conversion unit surface, forms level-one electricity production, and output electricity outward Can, meanwhile, high temperature hot gas temperature reduces, and forms medium temperature gas;
(3) medium temperature gas continues into low-grade fever electric unit, and thermal energy is converted to electric energy, forms second level electricity production, and outward Output, meanwhile, medium temperature gas temperature reduces, cryogenic gas in formation;
(4) cryogenic gas continues into low-grade fever power unit in, and thermal energy is first converted to mechanical energy, is then reconverted into Electric energy forms three-level electricity production, and exports outward.
Design principle of the invention is that the present invention is effectively combined three kinds of PowerMEMS, has developed micro combined Energy power system.The system uses passive design, so that fuel reacts under relatively lower temp, passes through low-grade fever light first Electrical components generate electricity, then waste heat are generated electricity by low-grade fever electrical components again, finally by residual fuel in low-grade fever mechanical driver unit Interior reaction, to be produced electricity compared with the slow-speed of revolution.The design of triplicity can maximally utilize the heat that fuel and fuel generate, so that mesh The problem of preceding overall output energy efficiency lower (less than 1%), is hopeful to be resolved.
Compared with prior art, the invention has the following advantages:
(1) structure of the invention is reasonable, ingenious in design, passes through the advantages of combining different power MEMSs, to carbon Hydrogen fuel and its generation heat can produce the electric power of more current higher energy density output after adequately utilizing, thus into The driving of one step needs the equipment of electric power to work, and provides the power of high-energy density output for small-sized movables machinery such as the following unmanned planes Source provides safeguard.
(2) present invention in, low-grade fever photoelectricity, low-grade fever electrical components material development to joint energy power system energy export There is an important relationship, the photoelectric conversion material (such as GaSb) of low band-gap and efficient hot light conversion material (such as SiC, Al2O3Or MgO) there is biggish facilitation to the overall output efficiency of the system of raising.And since thermo-electric converting material is limited to mesh The Development Status of preceding material is unable to reach the heat to electricity conversion of high conversion efficiency, therefore, using the medium temperature after low-grade fever optoelectronic components It is more feasible mode that heat, which carries out heat to electricity conversion, and remaining heat energy utilization low-grade fever dynamic power machine (such as microgenerator) adds To utilize, then the delivery efficiency of integral energy can be preferably improved.
(3) present invention also reduces the requirement to three kinds of microkinetic units respectively, is designing and manufacturing the cost of aspect more It is low, to probably obtain actual engineer application.In addition, passive fuel reaction mode, it is anti-to not only reduce fuel Seasonable security risk, and the cost of security protection is reduced, thus also it is very beneficial for the engineering of the micro combined system Application.
Detailed description of the invention
Fig. 1 is system block diagram of the invention.
Wherein, the corresponding title of appended drawing reference are as follows:
The passive heat source unit of 1-, 2- low-grade fever photovoltaic element, 3- low-grade fever electric unit, 4- low-grade fever power unit.
Specific embodiment
The invention will be further described with embodiment for explanation with reference to the accompanying drawing, and mode of the invention includes but not only limits In following embodiment.
As shown in Figure 1, the present invention provides a kind of miniature joint energy power system, compared to traditional PowerMEMS, The present invention is contained through the sequentially connected passive heat source unit 1 of pipeline, low-grade fever photovoltaic element 2, low-grade fever electric unit 3 and low-grade fever Power unit 4.
The passive heat source unit 1 is used to gaseous hydrocarbon fuel and air carrying out catalysis reaction, to generate Thermal energy, in the present embodiment, passive heat source unit 1 have loaded Cu, Pd, Pt or Ni catalysis by ultrasonic immersing method for surface The shape of the catalytic member (such as porous stainless steel or ceramic honeycomb) of agent, catalytic member can be cylindricality, plate shape or the double-deck cylindricality. Experiment shows using catalytic member of the present invention, can start reaction in 10s, reaction efficiency up to 99%, and In air atmosphere can anti-foreign gas poison and 10000h or more can be used for a long time.
The low-grade fever photovoltaic element 2 is used to for thermal energy being first converted into light reconvert into electricity and forms level-one electricity production output, Specifically, the low-grade fever photovoltaic element 2 include glass container, the radioluminescence layer being deposited on the glass container inner wall, and Photoelectric conversion unit on glass container outer wall is set.In the present embodiment, radioluminescence layer is by SiC, Al2O3Or MgO material system At being used to absorb hot gas, and generate high-energy photon;And photoelectric conversion unit is then by the GaSb material (photoelectricity of low band-gap turn Conversion materials) it is made, for the photon of sending to be converted into electric energy.
The low-grade fever electric unit 3 forms second level electricity production output for converting thermal energy into electric energy, and low-grade fever power list Member 4 forms three-level electricity production output then for converting thermal energy into electric energy.In the present embodiment, the low-grade fever power unit 4 is wrapped Include low-grade fever mechanical driver unit, and the microgenerator connecting with the low-grade fever mechanical driver unit.
The course of work of the invention is as follows:
It is mixed firstly, being filled with hydrocarbon fuel and air into passive heat source unit 1 with catalyst, passive catalysis occurs Reaction generates gaseous products and high temperature hot gas.High temperature hot gas is entered in low-grade fever photoelectric conversion unit 2 by pipeline, makes low-grade fever Radioluminescence layer in photovoltaic element 2 issues high-energy photon, and then high-energy photon generates electronics, shape on photoelectric conversion unit surface It is produced electricity at level-one, electric energy is then exported by external transmission lines road direction external equipment (such as electronic device or battery), meanwhile, it is high Warm hot air temperature reduces, and forms medium temperature gas.
Then, medium temperature gas continues through pipeline and enters in low-grade fever electric unit 3, and thermal energy continues to be converted to electric energy, is formed Second level electricity production, and electric energy is exported outward.Due to the limitation of current thermoelectric material, the gas of excessive temperature is difficult to obtain maximal efficiency Electricity output, therefore, the present invention is passed through medium temperature gas to low-grade fever electric unit, can be not unrestrained while realizing maximum electricity output Take thermal energy.
Medium temperature gas temperature after low-grade fever electric unit 3 reduces, cryogenic gas in formation, next proceed through pipeline into Enter into low-grade fever power unit 4, at this point, remaining thermal energy is largely converted to mechanical energy, is then converted again by microgenerator For electric energy, three-level electricity production is formed, and is exported outward.In the process, since high-temperature gas drives the meeting of low-grade fever mechanical driver unit Cause internal mechanical revolving speed excessively high, causes more demanding (such as sealing and damage to low-grade fever dynamic power machine material and processing technology Consume rate requirement), and cryogenic gas drives low-grade fever mechanical driver unit in present invention use, can be greatly reduced to low-grade fever power The requirement of mechanical material and processing technology.Also, from the delivery efficiency of total system, middle cryogenic gas substantially belongs to give up Gas is produced electricity output as three-level in the present invention and is utilized, can effectively improve the output electrical efficiency of total system.
The present invention is gradually reduced as guiding with gas temperature by reasonable structure and process design, realizes multistage production The purpose of electricity meets higher energy density output demand so that the efficiency of fuel cell generation of dynamical system greatly improved.And this hair It is bright carry out material and structure advanced optimize research after, also can further improve overall output efficiency.Therefore, with existing skill Art is compared, and progress of the present invention is fairly obvious, with substantive distinguishing features outstanding and significant progress.
Above-described embodiment is only one of the preferred embodiment of the present invention, should not be taken to limit protection model of the invention Enclose, it is all in body design thought of the invention and mentally make have no the change of essential meaning or polishing, solved Technical problem is still consistent with the present invention, should all be included within protection scope of the present invention.

Claims (5)

1. the implementation method of passive low-grade fever photoelectricity, low-grade fever electricity and low-grade fever combined power system, which is characterized in that the system Including leading to for gaseous hydrocarbon fuel and air to be carried out catalysis reaction, to generate the passive heat source unit (1) of thermal energy Piping is connect, for thermal energy to be first converted into light reconvert into electricity and forms level-one electricity production with the passive heat source unit (1) The low-grade fever photovoltaic element (2) of output is connect, for converting thermal energy into electricity and shape with the low-grade fever photovoltaic element (2) by pipeline At the low-grade fever electric unit (3) of second level electricity production output, and passes through pipeline and connect with the low-grade fever electric unit (3), for turning thermal energy It changes electricity into and forms the low-grade fever power unit (4) of three-level electricity production output;The passive heat source unit (1) is that surface passes through ultrasound Infusion process has loaded the catalytic member of Cu, Pd, Pt or Ni catalyst;The low-grade fever photovoltaic element (2) includes glass container, is sunk Radioluminescence layer of the product on the glass container inner wall, and the photoelectric conversion unit being arranged on glass container outer wall;It is described Radioluminescence layer is connect with passive heat source unit;
The implementation method the following steps are included:
(1) it is filled with hydrocarbon fuel and air into passive heat source unit to mix with catalyst, passive catalysis reaction occurs, it is raw At gaseous products and high temperature hot gas;
(2) high temperature hot gas is first into low-grade fever photoelectric conversion unit, issues the radioluminescence layer in low-grade fever photovoltaic element High-energy photon, then high-energy photon generates electronics on photoelectric conversion unit surface, forms level-one electricity production, and export electric energy outward, Meanwhile high temperature hot gas temperature reduces, and forms medium temperature gas;
(3) medium temperature gas continues into low-grade fever electric unit, and thermal energy is converted to electric energy, forms second level electricity production, and export outward, Meanwhile medium temperature gas temperature reduces, cryogenic gas in formation;
(4) cryogenic gas continues into low-grade fever power unit in, and thermal energy is first converted to mechanical energy, is then reconverted into electricity Can, three-level electricity production is formed, and export outward.
2. the implementation method of passive low-grade fever photoelectricity according to claim 1, low-grade fever electricity and low-grade fever combined power system, It is characterized in that, the catalytic member is cylindricality, plate shape or the double-deck column construction.
3. the implementation method of passive low-grade fever photoelectricity according to claim 2, low-grade fever electricity and low-grade fever combined power system, It is characterized in that, the radioluminescence layer is by SiC, Al2O3Or MgO material is made.
4. the implementation method of passive low-grade fever photoelectricity according to claim 3, low-grade fever electricity and low-grade fever combined power system, It is characterized in that, the photoelectric conversion unit is made of GaSb material.
5. the implementation method of passive low-grade fever photoelectricity according to claim 4, low-grade fever electricity and low-grade fever combined power system, It is characterized in that, the low-grade fever power unit (4) includes low-grade fever mechanical driver unit, and is connect with the low-grade fever mechanical driver unit Microgenerator.
CN201610414850.5A 2016-06-14 2016-06-14 The implementation method of passive low-grade fever photoelectricity, low-grade fever electricity and low-grade fever combined power system Expired - Fee Related CN106100518B (en)

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