CN106092957A - The near infrared spectrum recognition methods of mahogany furniture - Google Patents

The near infrared spectrum recognition methods of mahogany furniture Download PDF

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CN106092957A
CN106092957A CN201610384194.9A CN201610384194A CN106092957A CN 106092957 A CN106092957 A CN 106092957A CN 201610384194 A CN201610384194 A CN 201610384194A CN 106092957 A CN106092957 A CN 106092957A
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spectrum
near infrared
furniture
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model
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寿国忠
顾玉琦
张雯雅
王佩欣
赵大旭
陈浩
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Near Hangzhou, photoelectric technology Co. Ltd.
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Zhejiang A&F University ZAFU
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/359Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light using near infrared light

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Abstract

The present invention proposes the near infrared spectrum recognition methods of a kind of mahogany furniture, including furniture sample prepare near infrared spectrum gather selecting and the step such as the checking setting up discrimination model extracting discrimination model of Pretreated spectra characteristic wavelength.The present invention uses the near infrared light spectrum signal of miniature near infrared spectra collection sample, differentiate with chemometrics method, by setting up the discrimination model of true and false mahogany furniture, the quick nondestructive utilizing the true and false mahogany furniture of model realization built up differentiates, has the various features such as lossless, efficient, quick, portable, low cost, favorable reproducibility and accuracy rate height.

Description

The near infrared spectrum recognition methods of mahogany furniture
Technical field
The present invention relates to spectral discrimination method, be specifically related to the near infrared spectrum recognition methods of a kind of mahogany furniture.
Background technology
Rare timber kind is various, and different types of timber price is widely different, causes the furniture price after making finished product Also there is huge difference, wherein the most expensive with mahogany furniture.Mahogany furniture has the strongest Chinese culture intension, and China is " red Wood " national standard (GB/T 18107-2000), 5 genus 33 kinds of rare timber of 8 class are classified as redwood.Mahogany furniture is as high-grade family The synonym of tool, integrates collectibles, consumer goods, investment goods, adds that raw material is the most rare, and its price soars all the way.Redwood When the river rises the boat goes up for furniture market, and many bad businessmans, in order to earn profit, use and have the low and middle-grade rare of similar features with redwood Timber pretends to be high-grade redwood, or other redwood inferior that adulterate in mahogany furniture, severe jamming market order, compromises wide The interests of big consumer.
Common redwood discrimination method mainly relies on special instrument or has the expert of abundant industry experience to put into extensive work Just can complete.These methods have the shortcomings such as time-consuming, cost is high, destructive, chemical reagent pollutes, operation is complicated, are only suitable for reality Test room to use, and the Study on Identification of the most a lot of timber is all built upon sample is carried out the processed such as pulverizing, stripping and slicing On the basis of, test format mostly is censorship or sampling observation, and coverage rate is greatly limited, and is difficult to ensure that whole finished product in actual applications Furniture true and false.The near-infrared spectrum technique being combined with Chemical Measurement in recent years develops in terms of log detection with timber identification Rapidly, it is lossless, efficient, quick, low cost, favorable reproducibility, be easy to the unique advantages such as on-line checking, differentiates to provide for timber A kind of new detection technique.At present, have numerous studies both at home and abroad and show that near-infrared spectrum technique differentiates the feasibility of timber, but Research is not the most deep into and quickly differentiates the near-infrared of some confusing rare wood furnitures in Chinese market.
Near infrared region refers to wavelength electromagnetic wave in the range of 780~2526 nm by ASTM definition.Near infrared spectrum belongs to Molecular vibration spectrum, results from the vibration of covalent chemical bond anharmonic energy level, is frequency multiplication and the combination frequency of anharmonic vibration, is positioned at visible ray And between mid-infrared light district, it is adaptable to measuring the material containing groups such as C-H, N-H, O-H, the spectrum produced due to different groups is inhaled Receiving peak position and intensity is the most different, according to Lambert-Beer absorption law, absorption spectrum can be along with sample composition composition or knot Fruit change and produce change.
Near-infrared spectrum technique mainly includes near infrared spectrometer, chemo metric software and multivariate calibration model etc..Closely Infrared spectrometer is the equipment for gathering sample near infrared spectrum, and chemo metric software is for associating spectrum and sample The instrument of moral character matter, and calibration model is for reflecting that between sample spectra and character, the quantitative or qualitative work of corresponding relation is bent Line.The chemometrics method of near-infrared spectrum technique relates generally to three aspect contents: one is preprocessing procedures research, right Sample spectrum carries out pretreatment, reduces to such an extent as to eliminates the impact that spectrum is caused by various Aimless factors;Two is spectral signature The selection of wavelength and extraction, extract the information relevant with class object selectively and suppress the shadow of irrelevant feature and noise Ring;Three is the research of near infrared light spectrum correction method, to setting up sane, reliable, highly sensitive calibration model.
In the initial data of near infrared spectrometer collection in addition to comprising the information relevant to simple chemical structure, also wrap simultaneously Containing spectrogram information being produced the noise signal disturbed, thus affect the foundation of model and the prediction to unknown sample.Therefore, adopt Carry out noise elimination by smoothing processing, improve signal to noise ratio;Method of Seeking Derivative is used to carry out baseline correction process;Use orthogonal signalling school Just carry out spectral filtering, delete system change undesirable in data, to improve the performance of model.
During near-infrared spectrum analysis, when using complete wavelength range to set up model, computationally intensive, calculate speed Slowly.And owing to the spectral information at some spectral region sample is the most weak or uncorrelated with the composition of sample or character, introduce this The variable of sample can cause the precision reduction of institute's established model even to make a mistake.The selection of characteristic wavelength can simplify mould with extracting Type, more importantly due to the rejecting of uncorrelated or non-linear variable, prediction rate and the stability of calibration model improve.Without letter It is a kind of wavelength extraction algorithm set up based on PLS coefficient that breath variable eliminates, for eliminating without information variable Method.The method carrys out the reliability of each variable in evaluation model by introducing stability value, thus chooses.The method is Being widely used in the selection of spectral variables, wherein Monte Carlo is best without information variable removing method effect.Successive projection is calculated Method is to find the set of variables containing MIN redundancy in light spectrum matrix so that the synteny between variable reaches Little, farthest decrease information overlap, simplify mathematical model, be widely used in the extraction of sample wavelength.
In the actual application of near-infrared spectral analysis technology, the most only need to know kind or the place of production etc. of sample, not It is to be appreciated that the constituent content in sample, i.e. qualitative analysis problem, at this moment need the pattern-recongnition method using in Chemical Measurement. Extreme learning machine randomly generates input layer and the connection weights of implicit interlayer and the threshold value of hidden layer neuron, in the training process Only the number of neuron in hidden layer need to be set, just can obtain unique optimal solution.Compared with traditional training method, the party Calligraphy learning speed is fast, Generalization Capability good.
To sum up, it is achieved mahogany furniture main on domestic market and the quick discriminating of the famous and precious hardwood furniture of non-redwood, to guarantor Protect consumer's interests, promote that the sound development in mahogany furniture market has important function.
Summary of the invention
The technical problem to be solved is to provide the near infrared spectrum recognition methods of a kind of mahogany furniture, and utilizing should Method can identify the true and false of mahogany furniture exactly.
For solving above-mentioned technical problem, the technical solution used in the present invention is: the near infrared spectrum of a kind of mahogany furniture Recognition methods, including following methods step:
(1). the preparation of furniture sample: selecting mahogany furniture and the non-redwood famous and precious hardwood furniture sample of standard, sample includes Lignum Santali Albi Lignum pterocarpi indici, Barry yellow wingceltis, toe yellow wingceltis, Burma padauk, Dalbergia louvelii, nick yellow wingceltis, Sulawesi Scobis Diospyroris Ebeni, kiaat, Africa acid branch, these 10 kinds of furniture samples of hardwood nanmu;
(2). the collection of near infrared spectrum: utilize miniature near infrared spectrometer to gather near infrared light at the diverse location of sample surface Spectrum, including the diverse location of every furniture, spectrum is converted into a spectrum after average and represents a sample;Gather spectrum model It is trapped among 1000nm 1650nm;
(3). Pretreated spectra: use Savitzky-Golay convolution smoothing techniques smooth high frequencies noise, improves signal to noise ratio, uses The spectrogram that the Savitzky-Golay convolution method of derivation near infrared spectrum to gathering occurs offsets or drift phenomenon, and spectrum spectrum Line overlap phenomenon carries out baseline correction, uses Orthogonal Signal Correction Analyze to eliminate part unrelated with predictive value in spectrum;
(4). the selection of characteristic wavelength and extraction: use Monte Carlo to carry out feature without information variable method of elimination and successive projection method The selection of wavelength and extraction;
(5). the foundation of discrimination model: select 2/3rds quantity respectively from mahogany furniture and the famous and precious hardwood furniture of non-redwood Sample constitutes the training set sample modeled, preprocessing procedures when modeling differentiates with reality and characteristic wavelength point necessary Cause, set up extreme learning machine model respectively;
(6). the checking of discrimination model: residue 1/3rd number of samples are verified by the model of call establishment, it determines accuracy Close to 100%.
The Savitzky-Golay convolution smoothing techniques of the present invention, smoothing processing is to eliminate a kind of method that noise is the most frequently used, Its basic assumption be the noise that spectrum contains be zero equal random white noise, if repetitive measurement is averaged just can effectively smooth height Frequently noise, improves signal to noise ratio.Conventional signal smoothing method has rolling average smoothing techniques and Savitzky-Golay convolution to smooth Method.The present invention uses Savitzky-Golay convolution smoothing techniques, compares rolling average smoothing techniques, Savitzky-Golay convolution Smoothing techniques is, by multinomial, the data in moving window are carried out polynomial least mean square fitting, is substantially a kind of weighting Averaging method, more emphasizes central role of central point.
The Savitzky-Golay convolution method of derivation of the present invention, owing to instrument, sample background and other factors affect, gathers Near infrared spectrum spectrogram skew or drift phenomenon often occur, and light is caused for interfering between sample different component The phenomenon of spectrum overlap of spectral lines, can use the method for derivation to carry out baseline correction process.Conventional spectrum Method of Seeking Derivative typically has two Kind: direct differential method and Savitzky-Golay convolution method of derivation.The spectrum high for resolution, wavelength sampled point is many, uses Spectrum after direct differential method derivation is more or less the same with actual, but for the few spectrum of wavelength sampled point, required by the method Derivative Error is relatively big, and Savitzky-Golay convolution method of derivation therefore can be used to calculate.
The Orthogonal Signal Correction Analyze (Orthogonal Signal Correction, OSC) of the present invention is Wold in 1998 Deng a kind of preprocessing procedures of proposition, its basic thought is to utilize orthogonalization method, eliminates in spectrum unrelated with predictive value Part, thus obtain the spectrum of " pure ".OSC is mainly used in spectral filtering, deletes system change undesirable in data such as Baseline drifts etc., to improve the performance of model.
The Monte Carlo of the present invention is without information variable method of elimination, and it is a kind of based on offset minimum binary for eliminating without information variable The wavelength extraction algorithm that (Partial Least Squares, PLS) regression coefficient is set up, for eliminating the side without information variable Method.The method carrys out the reliability of each variable in evaluation model by introducing stability value, thus chooses.The method by Being widely used in the selection of spectral variables, wherein Monte Carlo is best without information variable elimination (MC-UVE) method effect.
The successive projection method (Successive Projections Algorithm, SPA) of the present invention is at light spectrum matrix Middle searching contains the set of variables of MIN redundancy so that the synteny between variable minimizes, farthest Decrease information overlap, simplify mathematical model, be widely used in the extraction of sample wavelength.
Extreme learning machine model of the present invention, extreme learning machine (Extreme Learning Machine, ELM) produces at random Raw input layer connects weights and the threshold value of hidden layer neuron with implicit interlayer, the most only need to arrange in hidden layer The number of neuron, just can obtain unique optimal solution.Compared with traditional training method, the method pace of learning is fast, general Change performance good.
The present invention uses the near infrared spectrum recognition methods of the mahogany furniture designed by technique scheme, red by gathering Wooden furniture and non-redwood famous and precious hardwood furniture sample, utilize miniature near infrared spectrometer at the not coordination of every furniture sample surface Put collection near infrared spectrum, after Pretreated spectra, extract characteristic wavelength, by multivariate data analysis method, set up respectively The discrimination model of true and false mahogany furniture, utilizes the quick nondestructive of the true and false mahogany furniture of model realization built up to differentiate.The present invention carries The method of confession has lossless, efficient, quick, portable, low cost, favorable reproducibility and accuracy rate high, it is adaptable to redwood man Tool kind differentiates.
Accompanying drawing explanation
Fig. 1 represents 10 kinds of mahogany furnitures and the near infrared light spectrogram of the famous and precious hardwood furniture of non-redwood;
Fig. 2 represents present invention characteristic wavelength scattergram after characteristic wavelength selects and extracts.
Detailed description of the invention
The near infrared spectrum recognition methods of mahogany furniture of the present invention, including following methods:
(1). use miniature near infrared spectrometer to gather red sandalwood, Barry yellow wingceltis, toe yellow wingceltis, Burma padauk, the black Huang of Lushi Wingceltis, nick yellow wingceltis, Sulawesi Scobis Diospyroris Ebeni, kiaat, Africa acid branch, the spectrogram of 10 kinds of rare wood furnitures of hardwood nanmu are also protected Deposit.Diverse location in sample surface gathers near infrared spectrum, and including the diverse location of every furniture, spectrum turns after average Turn to a spectrum and represent a sample;Collection spectral region is at 1000nm 1650nm, and the spectral information in this region is main Relevant with redwood and the structure of non-redwood hardwood and chemical composition, including cellulose, hemicellulose, lignin (lignin) and extracting Thing etc.;As shown in Figure 1.
(2). by the relatively different preprocessing procedures impact on modeling accuracy, the optimum preprocess method of final selection For Savitzky-Golay smooth (SG smooths), Savitzky-Golay1 order derivative (SG1 leads on rank) and Orthogonal Signal Correction Analyze.Former Beginning spectrum will not have bigger change after SG smooths pretreatment to spectrum, but noise substantially weakens.Lead pre-through the smooth+SG1 rank of SG After process, overlapping absorbance peak spectrally is exaggerated, after+OSC pretreatment is led on the smooth+SG1 rank of SG, between one species sample Obvious difference reduce.
In the initial data of near infrared spectrometer collection in addition to comprising the information relevant to simple chemical structure, also wrap simultaneously Containing spectrogram information being produced the noise signal disturbed, thus affect the foundation of model and the prediction to unknown sample.Therefore, light Modal data pretreatment is mainly used in garbled data, eliminates noise and the impact on data message of other factors, for calibration model Set up and the Accurate Prediction of unknown sample lays the first stone.Use the Savitzky-Golay convolution smoothing techniques can smooth high frequencies effectively Noise, improves signal to noise ratio.Owing to instrument, sample background and other factors affect, often there is spectrogram in the near infrared spectrum of collection Skew or drift phenomenon, and for the phenomenon interfering derivative spectomstry overlap of spectral lines between sample different component, can use Savitzky-Golay convolution method of derivation is carried out at baseline correction.Orthogonal Signal Correction Analyze (Orthogonal Signal Correction, OSC) it is exactly to utilize orthogonalization method, eliminate part unrelated with predictive value in spectrum, thus obtain " pure Only " spectrum.OSC is mainly used in spectral filtering, deletes system change such as baseline drift etc. undesirable in data, to improve The performance of model.
(3). after characteristic wavelength is extracted without information variable method of elimination and successive projection method in Monte Carlo, number of features is nearly Reduce 97%, significantly have compressed wave band quantity, reduce the amount of storage of spectroscopic data, improve model and calculate speed, such as Fig. 2 institute Show.
(4). every kind of furniture is set up extreme learning machine model, and extreme learning machine model hidden layer excitation function selects " Sigmoidal " function, hidden layer neuron number is 70, and calibration set accuracy is 100%, and checking collection accuracy is 100%.Its In, extreme learning machine (Extreme Learning Machine, ELM) randomly generates the connection weight of input layer and implicit interlayer Value and the threshold value of hidden layer neuron, the most only need to arrange the number of neuron in hidden layer, just can obtain only The optimal solution of one.Compared with traditional training method, the method pace of learning is fast, Generalization Capability good." Sigmoidal " function (sigmoidal founction) if be f (x) with initial point as point symmetry, then have f (-x)=-f (x), when select " Sigmoidal " During function, Model checking performance is more stable, it determines precision is the highest.
The present invention uses the near infrared light spectrum signal of miniature near infrared spectra collection sample, carries out with chemometrics method Differentiate.First gather a number of sample spectrum for modeling, spectrum is carried out pretreatment the most again, extracts characteristic wavelength, The independent soft type method of rear employing offset minimum binary diagnostic method, bunch class, support vector machine and extreme learning machine are modeled point respectively By experiment, analysis, differentiates that result determines optimum modeling method.The present invention is not limited to the rare wood furniture of described above ten kind Sample, the rare wood furniture sample for other kind is equally applicable.

Claims (1)

1. the near infrared spectrum recognition methods of a mahogany furniture, it is characterised in that: include following methods step:
(1). the preparation of furniture sample: selecting mahogany furniture and the non-redwood famous and precious hardwood furniture sample of standard, sample includes Lignum Santali Albi Lignum pterocarpi indici, Barry yellow wingceltis, toe yellow wingceltis, Burma padauk, Dalbergia louvelii, nick yellow wingceltis, Sulawesi Scobis Diospyroris Ebeni, kiaat, Africa acid branch, these 10 kinds of furniture samples of hardwood nanmu;
(2). the collection of near infrared spectrum: utilize miniature near infrared spectrometer to gather near infrared light at the diverse location of sample surface Spectrum, including the diverse location of every furniture, spectrum is converted into a spectrum after average and represents a sample;Gather spectrum model It is trapped among 1000nm 1650nm;
(3). Pretreated spectra: use Savitzky-Golay convolution smoothing techniques smooth high frequencies noise, improves signal to noise ratio, uses The spectrogram that the Savitzky-Golay convolution method of derivation near infrared spectrum to gathering occurs offsets or drift phenomenon, and spectrum spectrum Line overlap phenomenon carries out baseline correction, uses Orthogonal Signal Correction Analyze to eliminate part unrelated with predictive value in spectrum;
(4). the selection of characteristic wavelength and extraction: use Monte Carlo to carry out feature without information variable method of elimination and successive projection method The selection of wavelength and extraction;
(5). the foundation of discrimination model: select 2/3rds quantity respectively from mahogany furniture and the famous and precious hardwood furniture of non-redwood Sample constitutes the training set sample modeled, preprocessing procedures when modeling differentiates with reality and characteristic wavelength point necessary Cause, set up extreme learning machine model respectively;
(6). the checking of discrimination model: residue 1/3rd number of samples are verified by the model of call establishment, it determines accuracy Close to 100%.
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CN106770003A (en) * 2016-11-21 2017-05-31 无锡迅杰光远科技有限公司 Wood Identification Method and system based on near-infrared spectrum technique
CN107091815A (en) * 2017-05-05 2017-08-25 张方达 A kind of method for identifying rosewood
CN107748144A (en) * 2017-11-13 2018-03-02 中国科学院昆明植物研究所 The middle infrared spectrum detecting system of quick measure SOIL CARBON AND NITROGEN and its stable isotope
CN108645809A (en) * 2018-06-27 2018-10-12 广西民族大学 A kind of method that near-infrared spectrum technique quickly identifies rosin original tree species
CN108956528A (en) * 2018-08-01 2018-12-07 浙江农林大学 The near-infrared Undamaged determination method of mahogany furniture
CN113392586A (en) * 2021-06-10 2021-09-14 闽江学院 Vegetable oil identification method based on R language and orthogonal partial least square discriminant analysis
CN113720797A (en) * 2021-08-30 2021-11-30 四川轻化工大学 Online rapid quality-measuring liquor taking method for liquor distillation

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Publication number Priority date Publication date Assignee Title
CN106770003A (en) * 2016-11-21 2017-05-31 无锡迅杰光远科技有限公司 Wood Identification Method and system based on near-infrared spectrum technique
CN106525756A (en) * 2016-12-02 2017-03-22 赣州市检验检疫科学技术研究院 Apparatus and method for rapid identification of timber varieties
CN107091815A (en) * 2017-05-05 2017-08-25 张方达 A kind of method for identifying rosewood
CN107748144A (en) * 2017-11-13 2018-03-02 中国科学院昆明植物研究所 The middle infrared spectrum detecting system of quick measure SOIL CARBON AND NITROGEN and its stable isotope
CN108645809A (en) * 2018-06-27 2018-10-12 广西民族大学 A kind of method that near-infrared spectrum technique quickly identifies rosin original tree species
CN108956528A (en) * 2018-08-01 2018-12-07 浙江农林大学 The near-infrared Undamaged determination method of mahogany furniture
CN113392586A (en) * 2021-06-10 2021-09-14 闽江学院 Vegetable oil identification method based on R language and orthogonal partial least square discriminant analysis
CN113392586B (en) * 2021-06-10 2022-06-14 闽江学院 Vegetable oil identification method based on R language and orthogonal partial least square discriminant analysis
CN113720797A (en) * 2021-08-30 2021-11-30 四川轻化工大学 Online rapid quality-measuring liquor taking method for liquor distillation
CN113720797B (en) * 2021-08-30 2024-02-09 四川轻化工大学 Online rapid quality measuring and liquor picking method for distilled liquor

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Application publication date: 20161109