CN106090945A - A kind of heat accumulating type incineration apparatus and method processing dust-laden VOC waste gas - Google Patents

A kind of heat accumulating type incineration apparatus and method processing dust-laden VOC waste gas Download PDF

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Publication number
CN106090945A
CN106090945A CN201610617956.5A CN201610617956A CN106090945A CN 106090945 A CN106090945 A CN 106090945A CN 201610617956 A CN201610617956 A CN 201610617956A CN 106090945 A CN106090945 A CN 106090945A
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China
Prior art keywords
heat
accumulation
temperature
gas
waste gas
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CN201610617956.5A
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CN106090945B (en
Inventor
王亚飞
任春晓
吕正林
李明
樊魁
安兵涛
时明伟
高宇
殷义
罗秀鹏
刘静
陶富贵
鲁伟
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Beijing Aerospace Propulsion Institute
Beijing Aerospace Petrochemical Technology and Equipment Engineering Corp Ltd
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Beijing Aerospace Propulsion Institute
Beijing Aerospace Petrochemical Technology and Equipment Engineering Corp Ltd
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Priority to CN201610617956.5A priority Critical patent/CN106090945B/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • F23G7/061Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/06Arrangements of devices for treating smoke or fumes of coolers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23NREGULATING OR CONTROLLING COMBUSTION
    • F23N1/00Regulating fuel supply
    • F23N1/007Regulating fuel supply using mechanical means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23NREGULATING OR CONTROLLING COMBUSTION
    • F23N3/00Regulating air supply or draught
    • F23N3/007Regulating air supply or draught using mechanical means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23NREGULATING OR CONTROLLING COMBUSTION
    • F23N5/00Systems for controlling combustion
    • F23N5/02Systems for controlling combustion using devices responsive to thermal changes or to thermal expansion of a medium
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2202/00Combustion
    • F23G2202/10Combustion in two or more stages
    • F23G2202/102Combustion in two or more stages with supplementary heating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2204/00Supplementary heating arrangements
    • F23G2204/10Supplementary heating arrangements using auxiliary fuel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2206/00Waste heat recuperation
    • F23G2206/20Waste heat recuperation using the heat in association with another installation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2207/00Control
    • F23G2207/20Waste supply
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2207/00Control
    • F23G2207/30Oxidant supply
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00Specific waste
    • F23G2209/14Gaseous waste or fumes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/30Technologies for a more efficient combustion or heat usage

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Environmental & Geological Engineering (AREA)
  • Incineration Of Waste (AREA)

Abstract

A kind of heat accumulating type incineration apparatus and method processing dust-laden VOC waste gas of the present invention, finally to realize the energy-efficient process of high dust-laden VOC waste gas.The present invention includes linkage valve combination, accumulation of heat deashing device, regenerator, oxidation Burning Room, burner, waste heat boiler and chilling absorption plant;Described regenerator top is the oxidation Burning Room of connection, regenerator lower disposed accumulation of heat deashing device, and regenerator connects exhaust piping, back-blowing pipeline and flue by linkage valve combination;Arrange for several combustion-supporting burners on oxidation Burning Room;Regenerator includes several accumulation of heat storehouses, is evenly equipped with identical linkage valve combination below every accumulation of heat storehouse.The present invention be capable of dust-laden, sulfur-bearing, containing harmful VOC waste gas such as halogen and the energy-efficient process of bigger fluctuation of operating conditions.The present invention is capable of the heat recovery rate of more than 95%, combustible component and harmful constituent clearance up to more than 99%, generates NOXSeldom, it is the ideal scheme processing high dust-laden VOC waste gas.

Description

A kind of heat accumulating type incineration apparatus and method processing dust-laden VOC waste gas
Technical field
The present invention relates to the industry height dust-laden VOC exhaust-gas treatment such as petrochemical industry, external coating field, at one The heat accumulating type incineration apparatus and method of reason dust-laden VOC waste gas.
Background technology
VOC Volatile Organic Compounds, VOC are petrochemical industry and various use The common contaminant of organic solvent industry discharge.The dimethylbenzene that contains in VOC waste gas, toluene, butanone, halogen compounds etc. belong to In toxic gas, this compounds majority has penetrating odor, and health can be worked the mischief by direct contact, and part group Divide and be listed in carcinogen.VOC organic exhaust gas also has certain calorific value, without processing directly discharge, i.e. pollutes environment, again The waste energy.
In prior art, the optimal processing mode of VOC waste gas uses RTO, i.e. heat accumulating type thermal oxidizer exactly.Its work It is by being warming up to the regenerator of higher temperature at a upper circulation heat absorption by VOC waste gas as principle, then relies at oxidizing chamber Own combustion is warm or burner is combustion-supporting is warming up to more than 800 DEG C, makes the VOC in waste gas resolve into CO2And water.Then high-temperature flue gas Pass through heat storage, make heat storage heat up " accumulation of heat " and be recycled into VOC waste gas or the VOC of this regenerator for heating the next one Waste gas and the gaseous mixture of air, so that burner hearth maintains relatively elevated operating temperature all the time, improve heat recovery rate and firing efficiency.
VOC waste gas in industry is many containing easily absorption or the bonding material such as dust or tar, and the pottery that regenerator is conventional Honeycomb regenerator body aperture is less, and in heat-accumulating process, dust or tar in waste gas easily make aperture block, and then cause heat exchange Deteriorating, the serious heat storage overtemperature that more causes burns, it is seen that easily absorption or the bonding material such as dust in waste gas or tar are to RTO Impact in service life relatively big, removing or filtered out this type of material before waste gas enters heat storage is to extend RTO service life Effective way.The purpose of the present invention is contemplated to solve problems.
Summary of the invention
It is an object of the invention to provide a kind of heat accumulating type incineration apparatus and method processing dust-laden VOC waste gas, with final real The energy-efficient process of existing high dust-laden VOC waste gas.
Realize the technical scheme of the object of the invention: a kind of heat accumulating type incineration device processing dust-laden VOC waste gas, it includes connection Movable valve combination, accumulation of heat deashing device, regenerator, oxidation Burning Room, burner, waste heat boiler and chilling absorption plant;Described Regenerator top be connection oxidation Burning Room, regenerator lower disposed accumulation of heat deashing device, regenerator passes through linkage valve Combination connects exhaust piping, back-blowing pipeline and flue;Arrange for several combustion-supporting burners on oxidation Burning Room; Described regenerator includes several accumulation of heat storehouses, is evenly equipped with identical linkage valve combination below every accumulation of heat storehouse;Described valve Linkage combination includes waste gas stop valve, exhaust gas valve linkage plate washer, exhaust gas entrance, back-blowing stop valve, flue gas stop valve, smoke valve Linkage plate washer and exhanst gas outlet;Wherein, exhaust piping is provided with waste gas stop valve and exhaust gas valve linked-baffle, on back-blowing pipeline Being provided with back-blowing stop valve, flue is provided with flue gas stop valve and smoke valve linked-baffle;Waste gas stop valve drives waste gas Before and after valve linked-baffle, periodic movement realizes waste gas and enters accumulation of heat storehouse periodically by exhaust gas entrance;The back-blowing stop valve cycle Property switch realize back-blowing periodically by back-blowing pipeline enter accumulation of heat storehouse, flue gas stop valve drive smoke valve linked-baffle Front and back periodic movement realizes flue gas and discharges accumulation of heat storehouse periodically by exhanst gas outlet;Under each accumulation of heat storehouse of described regenerator Side is evenly equipped with identical accumulation of heat deashing device;Oxidation Burning Room is provided with pressure-measuring device one, below accumulation of heat deashing device It is provided with pressure-measuring device two.
A kind of heat accumulating type incineration device processing dust-laden VOC waste gas as above, its described accumulation of heat deashing device bag Including casing, arrange accumulation of heat bulk cargo at box house, arrange pulley at body side, casing is with moveable machine power mechanism even Connect, moved by machine power mechanism and drive the casing with pulley to move.
A kind of heat accumulating type incineration device processing dust-laden VOC waste gas as above, fills pottery in its described accumulation of heat storehouse Porcelain honeycomb heat accumulation body, is furnished with the temperature control device of heat storage in the middle of ceramic honeycomb thermal accumulator body;Accumulation of heat bulk cargo uses saddle ring to store Hot bulk cargo.
A kind of heat accumulating type incineration device processing dust-laden VOC waste gas as above, its described each burner with Fuel inlet, is provided with the controlling organization for regulating fuel flow rate at fuel inlet;Described each burner is also with combustion-supporting Wind entrance, combustion air porch is provided with the controlling organization for regulating described combustion air flow.
A kind of heat accumulating type incineration device processing dust-laden VOC waste gas as above, above its described oxidation Burning Room The left and right sides is respectively disposed with temperature control device one and temperature control device two, be used for regulate fuel flow rate controlling organization and The controlling organization of combustion air flow.
A kind of heat accumulating type incineration device processing dust-laden VOC waste gas as above, if its described regenerator includes 3 Individual, 5 or 7 accumulation of heat storehouses;Described burner (500) includes 1,2 or 3.
A kind of heat accumulating type incineration device processing dust-laden VOC waste gas as above, its described oxidation Burning Room downstream Connect waste heat boiler, the high-temperature flue gas that waste heat boiler is discharged in the case of processing oxidation Burning Room overtemperature, waste heat boiler downstream Being provided with low-temperature flue gas outlet, low-temperature flue gas exit is provided with the controlling organization for regulating low-temperature flue gas flow.
A kind of heat accumulating type incineration device processing dust-laden VOC waste gas as above, its described described oxidation Burning Room Connecting chilling absorption plant with waste heat boiler downstream, chilling absorption plant still contains for processing in the flue gas that oxidation Burning Room is discharged Some harmful constituents, chilling absorption plant is provided with absorbent entrance, and absorbent porch is provided with the control machine of absorbent flow Structure;Chilling absorption plant downstream is provided with purifying smoke outlet, purifying smoke outlet linking parsing instrument, can analyze in purifying smoke Harmful gas concentration, and for regulating the controlling organization of absorbent flow.
A kind of heat accumulating type incineration method processing dust-laden VOC waste gas of the present invention, it comprises the steps: to start combustion Burner firing up, is warming up to 850-950 DEG C, switches into mode of operation: waste gas passes through several accumulation of heat storehouse quilts of regenerator It is preheated to 800-900 DEG C, subsequently into oxidation Burning Room burning, accumulation of heat storehouse remains untreated exhaust gas by clean gas simultaneously Blowback is returned oxidation Burning Room and is carried out burning disposal, and the purifying smoke after decomposition is discharged through accumulation of heat storehouse, and accumulation of heat storehouse is heated simultaneously; By controlling the cycle movement of linkage valve combination, it is achieved above-mentioned mode of operation;When oxidation burns indoor temperature more than 870 DEG C, then need not combustion-supporting fuel and carry out afterburning, by control and regulation, keep waste gas in oxidation Burning Room to be chronically at spontaneous combustion shape State, maximally ensures the efficient utilization of energy;When pressure-measuring device one and pressure-measuring device two) pressure reduction that detects exceedes setting During value, take out accumulation of heat deashing device.
A kind of heat accumulating type incineration method processing dust-laden VOC waste gas, it controls when temperature control device one and temperature When mechanism two detects oxidation Burning Room flue-gas temperature less than the burner start-up temperature set, open the control of regulation fuel flow rate Mechanism processed and the controlling organization of regulation combustion air flow, and then change fuel quantity and the combustion air volume of supplied burner, until oxygen Change Burning Room flue-gas temperature and reach normal temperature range;When temperature control device one and temperature control device two detect that oxidation is burnt When burning the burner stopping temperature that room flue-gas temperature exceedes setting, close the controlling organization of regulation fuel flow rate, regulate combustion air The controlling organization of flow, and then cut off the fuel supply of burner, reduce combustion air flow, until oxidation Burning Room flue-gas temperature Return normal temperature range;When the temperature control device one in oxidation Burning Room and temperature control device two detect the flat of burner hearth When equal flue-gas temperature exceedes the startup waste heat boiler temperature of setting, open and regulate the controlling organization of low-temperature flue gas flow, until The flue gas mean temperature of oxidation Burning Room, less than the stopping waste heat boiler temperature set, is then turned off the control of low-temperature flue gas flow Mechanism;The temperature detected when the temperature control device of the heat storage in regenerator exceedes the maximum allowable temperature of heat-storing material of setting When spending, start parking chain, cut off waste gas simultaneously and fuel feeds, open purge mode;When dividing of chilling absorption plant outlet Analyzer detects when the harmful constituent content in purifying smoke exceedes setting value, the controlling organization of regulation absorbent flow, and then The concentration of regulation absorbent and flow, until harmful constituent content is less than setting value in chilling absorption plant exiting flue gas.
Effect of the invention is that: a kind of heat accumulating type incineration device processing dust-laden VOC waste gas of the present invention and side Method, it uses heat accumulating type incineration technology, it is provided that a whole set of incinerator processing high dust-laden VOC waste gas and method, it is possible to realize Dust-laden, sulfur-bearing, containing harmful VOC waste gas such as halogen and the energy-efficient process of bigger fluctuation of operating conditions.Storage provided by the present invention Hot type CIU is capable of the heat recovery rate of more than 95%, combustible component and harmful constituent clearance up to more than 99%, Generate NOXSeldom, it is the ideal scheme processing high dust-laden VOC waste gas.
Accompanying drawing explanation
Fig. 1 is a kind of heat accumulating type incineration device processing dust-laden VOC waste gas of the present invention and controls logical schematic;
Fig. 2 is a kind of linkage valve involved by heat accumulating type incineration device processing dust-laden VOC waste gas of the present invention Combination;
Fig. 3 is a kind of accumulation of heat deashing involved by heat accumulating type incineration device processing dust-laden VOC waste gas of the present invention Device;
In figure: 100. linkage valve combinations;200. accumulation of heat deashing devices;300. regenerator;400. oxidation Burning Rooms;500. Burner;600. waste heat boiler;700. chilling absorption plants;110. exhaust piping;111. waste gas stop valves;112. exhaust gas valve connection Dynamic plate washer;113. exhaust gas entrance;120. back-blowing pipelines;121. back-blowing stop valves;130. flue;131. flue gases cut off Valve;132. smoke valve linkage plate washers;133. exhanst gas outlet;211. machine power mechanisms;212. pulley;213. metal cabinet; 214. accumulation of heat bulk cargos;215. pressure-measuring devices one;216. pressure-measuring devices two;310. accumulation of heat storehouses one;320. accumulation of heat storehouses two;330. Accumulation of heat storehouse three;The temperature control device one of 311. heat storages;The temperature control device two of 321. heat storages;The temperature of 331. heat storages Degree controlling organization three;410.RTO and waste heat boiler connect pipeline;401. temperature control devices one;402. temperature control devices two; 510. fuel inlet;The controlling organization one of 511. fuel flow rates;The controlling organization two of 512. fuel flow rates;520. combustion airs enter Mouthful;The controlling organization one of 521. combustion air flows;The controlling organization two of 522. combustion air flows;610. low-temperature flue gas outlets; The controlling organization of 611. low-temperature flue gas flows;710. absorbent entrances;The controlling organization of 711. absorbent flows;720. smoke-purifying Gas exports, 721. analysers.
Detailed description of the invention
Below in conjunction with the drawings and specific embodiments, a kind of heat accumulating type processing dust-laden VOC waste gas of the present invention is burnt Burning apparatus and method are further described.
Embodiment 1
As it is shown in figure 1, a kind of heat accumulating type incineration device processing dust-laden VOC waste gas of the present invention, it includes linkage Valve combination 100, accumulation of heat deashing device 200, regenerator 300, oxidation Burning Room 400, burner 500, waste heat boiler 600 and urgency Enfleurage receiving apparatus 700.
Described regenerator 300 top is the oxidation Burning Room 400 of connection, and regenerator 300 lower disposed accumulation of heat deashing fills Putting 200, regenerator 300 is by linkage valve combination 100 connection exhaust piping 110, back-blowing pipeline 120 and flue 130; Arrange for 2 combustion-supporting burners 500 on oxidation Burning Room 400.
Described regenerator 300 includes accumulation of heat storehouse 1, accumulation of heat storehouse 2 320 and accumulation of heat storehouse 3 330, under each accumulation of heat storehouse Side is evenly equipped with identical linkage valve combination 100;As in figure 2 it is shown, as a example by the linkage valve below accumulation of heat storehouse 310 combines 110: Described valve linkage combination 100 includes that waste gas stop valve 111, exhaust gas valve linkage plate washer 112, exhaust gas entrance 113, back-blowing are cut Disconnected valve 121, flue gas stop valve 131, smoke valve linkage plate washer 132 and exhanst gas outlet 133;Wherein, exhaust piping 110 is provided with useless Gas stop valve 111 and exhaust gas valve linked-baffle 112, back-blowing pipeline 120 is provided with back-blowing stop valve 121, flue 130 It is provided with flue gas stop valve 131 and smoke valve linked-baffle 132;Before and after waste gas stop valve 111 drives exhaust gas valve linked-baffle 112 Periodic movement realizes waste gas and enters accumulation of heat storehouse periodically by exhaust gas entrance 113;Back-blowing stop valve 121 periodic switch is real Existing back-blowing enters accumulation of heat storehouse periodically by back-blowing pipeline 120, and flue gas stop valve 131 drives smoke valve linked-baffle Before and after 132, periodic movement realizes flue gas and discharges accumulation of heat storehouse periodically by exhanst gas outlet 133.
It is evenly equipped with identical accumulation of heat deashing device below each accumulation of heat storehouse of described regenerator 300;At oxidation Burning Room 400 are provided with pressure-measuring device 1, are provided with pressure-measuring device 2 216 below accumulation of heat deashing device.As it is shown on figure 3, to store As a example by accumulation of heat deashing device 210 below hot storehouse 310, described accumulation of heat deashing device includes casing 213, inside casing 213 Arranging accumulation of heat bulk cargo 214, arrange pulley 212 at body side, casing 213 is connected with moveable machine power mechanism 211, logical Crossing machine power mechanism 211 drives the casing 213 with pulley 212 to move.
Described accumulation of heat storehouse 310,320,330 is filled ceramic honeycomb thermal accumulator body, in the middle of ceramic honeycomb thermal accumulator body, is furnished with storage The temperature control device 311,321,331 of hot body;Described accumulation of heat bulk cargo 214 uses saddle ring accumulation of heat bulk cargo, and can dam height Dust in dust-laden VOC waste gas.So accumulation of heat deashing device 200 had both served accumulation of heat effect, again can be with Chalk-dust filtering.
Described each burner, with fuel inlet 510, is provided with the control for regulating fuel flow rate at fuel inlet 510 Mechanism 511,512 processed;Described each burner also with combustion air entrance 520, is provided with for regulating at combustion air entrance 520 The controlling organization 521,522 of described combustion air flow.Above described oxidation Burning Room 400, the left and right sides is respectively disposed with temperature Controlling organization 1 and temperature control device 1, temperature control device 1 is used for regulating the controlling organization of fuel flow rate 511 and the controlling organization 521 of combustion air flow, temperature control device 2 402 be used for regulating fuel flow rate controlling organization 512, The controlling organization 522 of combustion air flow and the controlling organization 611 of low-temperature flue gas flow.Described oxidation Burning Room 400 downstream is even Connect waste heat boiler 600, the high-temperature flue gas that waste heat boiler 600 is discharged in the case of processing oxidation Burning Room 400 overtemperature, waste heat pot Stove 600 downstream is provided with low-temperature flue gas outlet 610, and low-temperature flue gas exports the control being provided with at 610 for regulating low-temperature flue gas flow Mechanism 611.
Described oxidation Burning Room 400 and waste heat boiler 600 downstream connect chilling absorption plant 700, chilling absorption plant 700 for processing the harmful constituent still contained in the flue gas that oxidation Burning Room 400 is discharged, and chilling absorption plant 700 is provided with suction Receive agent entrance 710, at absorbent entrance 710, be provided with the controlling organization 711 of absorbent flow;Chilling absorption plant 700 downstream sets Having purifying smoke outlet 720, purifying smoke exports 720 linking parsing instrument 721, can analyze the harmful gas in purifying smoke dense Degree, and for regulating the controlling organization 711 of absorbent flow.
Embodiment 2
Using the heat accumulating type incineration method processing dust-laden VOC waste gas of device described in embodiment 1, it comprises the steps: Containing component in the harmful gass such as toluene, dimethylbenzene, sulfur-containing compound and a large amount of dust, and operating condition in this VOC waste gas Relatively big with flowed fluctuation, bring hot-restriking die the biggest, design exhaust-gas treatment amount 30000Nm3/h。
Heat storage 300 and oxidation Burning Room 400 are pre-purged three minutes by the freshest wind fan starting, burning are filled Put interior residual exhaust gases to discharge;Start burner 500 firing up, be warming up to 850-950 DEG C (such as: 850 DEG C, 900 DEG C or 950 DEG C), switch into mode of operation:
The first step, waste gas is preheated to higher temperature 800-900 DEG C (such as: 800 DEG C, 850 DEG C by accumulation of heat storehouse 1 Or 900 DEG C), burn subsequently into oxidation Burning Room 400, accumulation of heat storehouse 3 330 remains untreated exhaust gas by clean gas simultaneously Body blowback is returned oxidation Burning Room 400 and is carried out burning disposal, in oxidation Burning Room 400 ignition temperature 850 DEG C-950 DEG C (such as: 850 DEG C, 900 DEG C or 950 DEG C) between, the purifying smoke mean temperature after decomposition, at about 230 DEG C, is then passed through accumulation of heat storehouse two 320 discharge, and accumulation of heat storehouse 2 320 is heated simultaneously;Second step, waste gas is preheated to higher temperature 800-by accumulation of heat storehouse 2 320 900 DEG C, burn subsequently into oxidation Burning Room 400, accumulation of heat storehouse 1 remains the gas after untreated exhaust gas is cleaned simultaneously Blowback is returned oxidation Burning Room 400 and is carried out burning disposal, ignition temperature (example between 850 DEG C-950 DEG C in oxidation Burning Room 400 As: 850 DEG C, 900 DEG C or 950 DEG C), the purifying smoke mean temperature after decomposition, at about 230 DEG C, is then passed through accumulation of heat storehouse three 330 discharge, and accumulation of heat storehouse 3 330 is heated simultaneously;3rd step, waste gas is preheated to higher temperature 800-by accumulation of heat storehouse 3 330 900 DEG C (such as: 800 DEG C, 850 DEG C or 900 DEG C), burns subsequently into oxidation Burning Room 400, remains and do not locate in accumulation of heat storehouse 320 Blow-back after reason waste gas is cleaned returns oxidation Burning Room 400 and carries out burning disposal, and in oxidation Burning Room 400, ignition temperature exists Between 850 DEG C-950 DEG C (such as: 850 DEG C, 900 DEG C or 950 DEG C), the purifying smoke mean temperature after decomposition at about 230 DEG C, Being then passed through accumulation of heat storehouse 1 to discharge, accumulation of heat storehouse 1 is heated simultaneously;By controlling the periodicity of linkage valve combination 100 Motion, it is achieved the samsara of above-mentioned one, two, three step mode of operations.
When in oxidation Burning Room 400, temperature more than 870 DEG C, then need not combustion-supporting fuel and carries out afterburning, by control and regulation, Can keep aoxidizing waste gas in Burning Room 400 and be chronically at spontaneous combustion state, maximally ensure the efficient utilization of energy.
The pressure reduction detected when pressure-measuring device 1 and pressure-measuring device 2 216 exceedes setting value such as: 800Kpa Time, use machine power mechanism 211 to take out accumulation of heat deashing device 200, and use and there is the hot-air of certain pressure or steam is clear Except the solid dust dammed between saddle ring accumulation of heat bulk cargo, tar etc. are prone to absorption or the material of adhesion, when adhering substance is too many or Replaceable accumulation of heat bulk cargo during easy-clear, does not then reinstall to use.
When temperature control device 1 detects that on the left of oxidation Burning Room 400, flue-gas temperature opens less than the burner set , opening the controlling organization 511 of regulation fuel flow rate, regulation controls the control machine of combustion air flow during dynamic temperature such as: when 850 DEG C Structure 521, and then change fuel quantity and the combustion air volume of supplied burner 500, until oxidation Burning Room 400 flue-gas temperature just reaches Between normal temperature scope 850 DEG C-950 DEG C;When temperature control device 1 detects flue-gas temperature on the left of oxidation Burning Room 400 When exceeding the burner stopping temperature of setting such as: when 880 DEG C, close the controlling organization 511 of regulation fuel flow rate, regulation control The controlling organization 521 of combustion air flow, and then cut off the fuel supply of burner 500, reduce combustion air flow, until oxidation is burnt Burn room 400 flue-gas temperature to return between normal temperature range 850 DEG C-950 DEG C (such as: 850 DEG C, 900 DEG C or 950 DEG C).Oxidation On the right side of Burning Room 400, temperature control logic is identical with left side.
When the temperature control device 401 and 402 in oxidation Burning Room 400 detects that the average flue-gas temperature of burner hearth exceedes super When crossing the startup waste heat boiler temperature set, open and adjusting control mechanism 611, make the overtemperature cigarette that oxidation Burning Room 400 is discharged Air-flow is lowered the temperature through waste heat boiler 600 heat release, produces steam or hot water simultaneously, until the flue gas mean temperature of oxidation Burning Room 400 It revert between 850 DEG C-950 DEG C (such as: 850 DEG C, 900 DEG C or 950 DEG C), be then turned off the controlling organization of low-temperature flue gas flow 611。
The temperature detected when the temperature control device 311,321,331 of the heat storage in regenerator 300 exceedes setting During the maximum allowable temperature of heat-storing material, start parking chain, cut off waste gas simultaneously and fuel feeds, open purge mode;
When the analyser 721 of chilling absorption plant 700 outlet detects the CL in purifying smoke2Or SO2、SO3Etc. harmful group When dividing content to exceed setting value, the controlling organization 711 of regulation absorbent flow, and then regulate concentration and the flow of absorbent, directly To chilling absorption plant 700 exiting flue gas, harmful constituent content is less than setting value.
This part describes only for describing the technical scheme that the present invention provides in detail, and concrete description order and term should not When forming any restriction to scope.The invention is not restricted to above-mentioned specific embodiment, the common skill of this area Art personnel send out with above-mentioned visualizing, and without creative work, done all changes, all fall within protection scope of the present invention Among.

Claims (10)

1. the heat accumulating type incineration device processing dust-laden VOC waste gas, it is characterised in that: this device includes that linkage valve combines (100), accumulation of heat deashing device (200), regenerator (300), oxidation Burning Room (400), burner (500), waste heat boiler (600) With chilling absorption plant (700);
Described regenerator (300) top is the oxidation Burning Room (400) of connection, regenerator (300) lower disposed accumulation of heat deashing Device (200), regenerator (300) by linkage valve combination (100) connect exhaust piping (110), back-blowing pipeline (120) and Flue (130);Oxidation Burning Room (400) is upper arranges for combustion-supporting several burners (500);
Described regenerator (300) includes several accumulation of heat storehouses, is evenly equipped with identical linkage valve combination below every accumulation of heat storehouse (100);Described valve linkage combination (100) includes waste gas stop valve (111), exhaust gas valve linkage plate washer (112), exhaust gas entrance (113), back-blowing stop valve (121), flue gas stop valve (131), smoke valve linkage plate washer (132) and exhanst gas outlet (133);Its In, exhaust piping (110) is provided with waste gas stop valve (111) and exhaust gas valve linked-baffle (112), on back-blowing pipeline (120) Being provided with back-blowing stop valve (121), flue (130) is provided with flue gas stop valve (131) and smoke valve linked-baffle (132);Waste gas stop valve (111) drive periodic movement before and after exhaust gas valve linked-baffle (112) realize waste gas periodically by Exhaust gas entrance (113) enters accumulation of heat storehouse;Back-blowing stop valve (121) periodic switch realizes back-blowing periodically by blowback Wind pipeline (120) enters accumulation of heat storehouse, and before and after flue gas stop valve (131) drives smoke valve linked-baffle (132), periodic movement realizes Flue gas discharges accumulation of heat storehouse periodically by exhanst gas outlet (133);
It is evenly equipped with identical accumulation of heat deashing device below each accumulation of heat storehouse of described regenerator (300);At oxidation Burning Room (400) it is provided with pressure-measuring device one (215), below accumulation of heat deashing device, is provided with pressure-measuring device two (216).
A kind of heat accumulating type incineration device processing dust-laden VOC waste gas the most according to claim 1, it is characterised in that: described Accumulation of heat deashing device include casing (213), accumulation of heat bulk cargo (214) is set casing (213) is internal, cunning is set at body side Wheel (212), casing (213) is connected with moveable machine power mechanism (211), by the mobile band of machine power mechanism (211) The dynamic casing (213) with pulley (212) is mobile.
A kind of heat accumulating type incineration device processing dust-laden VOC waste gas the most according to claim 2, it is characterised in that: described Accumulation of heat storehouse in fill ceramic honeycomb thermal accumulator body, be furnished with the temperature control device of heat storage in the middle of ceramic honeycomb thermal accumulator body;Accumulation of heat Bulk cargo uses saddle ring accumulation of heat bulk cargo.
A kind of heat accumulating type incineration device processing dust-laden VOC waste gas the most according to claim 1, it is characterised in that: described Each burner be provided with the controlling organization for regulating fuel flow rate with fuel inlet (510), fuel inlet (510) place; Described each burner is also with combustion air entrance (520), and combustion air entrance (520) place is provided with for regulating described combustion air The controlling organization of flow.
A kind of heat accumulating type incineration device processing dust-laden VOC waste gas the most according to claim 4, it is characterised in that: described Oxidation Burning Room (400) top the left and right sides be respectively disposed with temperature control device one (401) and temperature control device two (402), it is used for regulating controlling organization and the controlling organization of combustion air flow of fuel flow rate.
A kind of heat accumulating type incineration device processing dust-laden VOC waste gas the most according to claim 1, it is characterised in that: described If regenerator include 3,5 or 7 accumulation of heat storehouses;Described burner (500) includes 1,2 or 3.
A kind of heat accumulating type incineration device processing dust-laden VOC waste gas the most according to claim 1, it is characterised in that: described Oxidation Burning Room (400) downstream connect waste heat boiler (600), waste heat boiler (600) is used for processing oxidation Burning Room (400) and surpasses The high-temperature flue gas discharged in the case of temperature, waste heat boiler (600) downstream is provided with low-temperature flue gas outlet (610), and low-temperature flue gas exports (610) place is provided with the controlling organization (611) for regulating low-temperature flue gas flow.
A kind of heat accumulating type incineration device processing dust-laden VOC waste gas the most according to claim 6, it is characterised in that: described Described oxidation Burning Room (400) and waste heat boiler (600) downstream connect chilling absorption plant (700), chilling absorption plant (700) it is used for processing the harmful constituent still contained in the flue gas that oxidation Burning Room (400) is discharged, on chilling absorption plant (700) Being provided with absorbent entrance (710), absorbent entrance (710) place is provided with the controlling organization (711) of absorbent flow;Chilling absorbs dress Put (700) downstream and be provided with purifying smoke outlet (720), purifying smoke outlet (720) linking parsing instrument (721), purification can be analyzed Harmful gas concentration in flue gas, and for regulating the controlling organization (711) of absorbent flow.
9. using the heat accumulating type incineration method processing dust-laden VOC waste gas of any device described in claim 1 to 8, it is special Levy and be: the method comprises the steps:
Start burner (500) firing up, be warming up to 850-950 DEG C, switch into mode of operation: waste gas passes through regenerator (300) several accumulation of heat storehouses are preheated to 800-900 DEG C, subsequently into oxidation Burning Room (400) burning, simultaneously in accumulation of heat storehouse Residual untreated exhaust gas is returned oxidation Burning Room (400) by clean blow-back and is carried out burning disposal, the purifying smoke after decomposition Discharging through accumulation of heat storehouse, accumulation of heat storehouse is heated simultaneously;By controlling the cycle movement of linkage valve combination (100), it is achieved on State mode of operation;
When in oxidation Burning Room (400), temperature more than 870 DEG C, then need not combustion-supporting fuel and carries out afterburning, by control and regulation, protect Hold waste gas in oxidation Burning Room (400) and be chronically at spontaneous combustion state, maximally ensure the efficient utilization of energy;
When the pressure reduction that pressure-measuring device one (215) and pressure-measuring device two (216) detect exceedes setting value, take out accumulation of heat clear Apparatus for ash (200).
A kind of heat accumulating type incineration method processing dust-laden VOC waste gas the most according to claim 9, it is characterised in that:
When temperature control device one (401) and temperature control device two (402) detect that oxidation Burning Room (400) flue-gas temperature is low When the burner start-up temperature set, open controlling organization and the control machine of regulation combustion air flow of regulation fuel flow rate Structure, and then change fuel quantity and the combustion air volume of supplied burner (500), until oxidation Burning Room (400) flue-gas temperature reaches Normal temperature range;When temperature control device one (401) and temperature control device two (402) detect oxidation Burning Room (400) When flue-gas temperature exceedes the burner stopping temperature of setting, close the controlling organization of regulation fuel flow rate, regulate combustion air flow Controlling organization, and then cut off burner (500) fuel supply, reduce combustion air flow, until oxidation Burning Room (400) cigarette Temperature returns normal temperature range;
When the temperature control device one (401) in oxidation Burning Room (400) and temperature control device two (402) detect burner hearth When average flue-gas temperature exceedes the startup waste heat boiler temperature of setting, open and regulate the controlling organization of low-temperature flue gas flow (611), until the flue gas mean temperature of oxidation Burning Room (400) is less than the stopping waste heat boiler temperature set, it is then turned off low The controlling organization (611) of temperature flue gas flow;
The temperature detected when the temperature control device of the heat storage in regenerator (300) exceedes the heat-storing material maximum of setting and permits When being permitted temperature, start parking chain, cut off waste gas simultaneously and fuel feeds, open purge mode;
The harmful constituent content that the analyser (721) exported when chilling absorption plant (700) detects in purifying smoke exceedes and sets During definite value, the controlling organization (711) of regulation absorbent flow, and then regulate concentration and the flow of absorbent, until chilling absorbs In device (700) exiting flue gas, harmful constituent content is less than setting value.
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CN107036109A (en) * 2017-04-19 2017-08-11 中盐安徽红四方股份有限公司 Sodium dithionite produces the processing system and processing method of waste gas
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CN107642789A (en) * 2017-09-26 2018-01-30 江苏中圣高科技产业有限公司 A kind of staged air distribution type thermal accumulating incinerator
CN108317524A (en) * 2017-01-17 2018-07-24 恩国环保科技(上海)有限公司 A kind of the heat accumulating type incineration device and its application process of oxidation furnace exhaust
CN108518695A (en) * 2018-04-10 2018-09-11 江苏大信环境科技有限公司 A kind of online coke removing appts and decoking for heat storage
CN108534136A (en) * 2017-03-03 2018-09-14 中外炉工业株式会社 regenerative burner system
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CN113776070A (en) * 2021-09-24 2021-12-10 大庆双玉鸿伟石油设备开发有限公司 Oil and gas field ground VOC treatment system and implementation method
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CN108317524A (en) * 2017-01-17 2018-07-24 恩国环保科技(上海)有限公司 A kind of the heat accumulating type incineration device and its application process of oxidation furnace exhaust
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CN113757692B (en) * 2021-07-26 2024-05-24 广州广钢气体能源股份有限公司 Multi-mode pure oxygen combustion method and device
CN113776070A (en) * 2021-09-24 2021-12-10 大庆双玉鸿伟石油设备开发有限公司 Oil and gas field ground VOC treatment system and implementation method
CN115183248A (en) * 2022-07-08 2022-10-14 江苏方诚环保科技有限公司 Chemical waste gas combustion treatment method and system based on RTO device
CN115183248B (en) * 2022-07-08 2023-08-11 江苏方诚环保科技有限公司 Chemical waste gas combustion treatment method and system based on RTO device
CN116464972A (en) * 2023-04-21 2023-07-21 江苏大信环境科技有限公司 High-tightness heat accumulating incinerator
CN116464972B (en) * 2023-04-21 2023-09-22 江苏大信环境科技有限公司 High-tightness heat accumulating incinerator

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