CN106086946A - A kind of holding plating solution stable in properties electroplating additive - Google Patents
A kind of holding plating solution stable in properties electroplating additive Download PDFInfo
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- CN106086946A CN106086946A CN201610653336.7A CN201610653336A CN106086946A CN 106086946 A CN106086946 A CN 106086946A CN 201610653336 A CN201610653336 A CN 201610653336A CN 106086946 A CN106086946 A CN 106086946A
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- China
- Prior art keywords
- acid
- properties
- plating solution
- acetoglycocoll
- benzenesulfonimide
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Pyridine Compounds (AREA)
Abstract
The invention discloses a kind of holding plating solution stable in properties electroplating additive, every kilogram of additive is containing following component: pyridinium hydroxy propyl sulfobetaine 30 60g, hydracrylic acid 1 5g, pyrovinic acid 20 30g, vanillin 0.1 1g, strontium sulfate 1 3g, PTPP (potassium tripolyphosphate) 20 30g, hydrogen peroxide 10 20g, two benzenesulfonimide 1 5g, propilolic alcohol 20 30g, potassium pyrophosphate 15 25g, hydroxyl sulfoacid sodium 10 20g, acetoglycocoll 10 20g, tri-chlorination ammonium 10 20g, remaining is deionized water.
Description
Technical field
The invention belongs to spare parts processing machinery technical field, be specifically related to a kind of holding plating solution stable in properties plating and add
Agent.
Background technology
Plating utilizes electrolysis principle to plate the process of other metal or alloy of a thin layer on some metal surface exactly, is
Utilize electrolysis to make the technique thus play of surface attachment layer of metal film of metal or other materials product prevent corrosion, carry
High-wearing feature, electric conductivity, reflective and having improved aesthetic appearance etc. act on.
Electrolysis is utilized to deposit attachment on machinework good, but the metal coating that performance is different with matrix material
Technology, electrodeposited coating is more uniform than hot dipping layer, and the most all ratios are relatively thin, from several microns to tens micron.By plating, can
To obtain decoration protectiveness and various functional surface layer on machinework, it is also possible to repair abrasion and the work of processing error
Part.
But at present, there is serious pollution problem in electroplating technology.
Summary of the invention
Goal of the invention: the problem and shortage existed for above-mentioned prior art, it is an object of the invention to provide a kind of holding
Plating solution stable in properties electroplating additive.
Technical scheme: the invention discloses a kind of holding plating solution stable in properties electroplating additive, every kilogram of additive contains
Following component: pyridinium hydroxy propyl sulfobetaine 30-60g, hydracrylic acid 1-5g, pyrovinic acid 20-30g, vanillin 0.1-1g,
Strontium sulfate 1-3g, PTPP (potassium tripolyphosphate) 20-30g, hydrogen peroxide 10-20g, two benzenesulfonimide 1-5g, propilolic alcohol 20-30g, burnt phosphorus
Acid potassium 15-25g, hydroxyl sulfoacid sodium 10-20g, acetoglycocoll 10-20g, tri-chlorination ammonium 10-20g, remaining is deionized water.
As the further optimization of the present invention, the present invention every kilogram additive is containing following component: hydroxypropanesulfonic acid pyridine
Drone salt 30g, hydracrylic acid 1g, pyrovinic acid 20g, vanillin 0.1g, strontium sulfate 1g, PTPP (potassium tripolyphosphate) 20g, hydrogen peroxide 10g,
Two benzenesulfonimide 1g, propilolic alcohol 20g, potassium pyrophosphate 15g, hydroxyl sulfoacid sodium 10g, acetoglycocoll 10g, tri-chlorination ammonium
10g, remaining is deionized water.
As the further optimization of the present invention, the present invention every kilogram additive is containing following component: hydroxypropanesulfonic acid pyridine
Drone salt 60g, hydracrylic acid 5g, pyrovinic acid 30g, vanillin 1g, strontium sulfate 3g, PTPP (potassium tripolyphosphate) 30g, hydrogen peroxide 20g, two
Benzenesulfonimide 5g, propilolic alcohol 30g, potassium pyrophosphate 25g, hydroxyl sulfoacid sodium 20g, acetoglycocoll 20g, tri-chlorination ammonium 20g,
Remaining is deionized water.
As the further optimization of the present invention, the present invention every kilogram additive is containing following component: hydroxypropanesulfonic acid pyridine
Drone salt 46g, hydracrylic acid 3.8g, pyrovinic acid 22g, vanillin 0.6g, strontium sulfate 2.7g, PTPP (potassium tripolyphosphate) 26g, hydrogen peroxide
19g, two benzenesulfonimide 4g, propilolic alcohol 24g, potassium pyrophosphate 19g, hydroxyl sulfoacid sodium 14g, acetoglycocoll 14g, tri-chlorination
Ammonium 14g, remaining is deionized water.
As the further optimization of the present invention, the present invention every kilogram additive is containing following component: hydroxypropanesulfonic acid pyridine
Drone salt 52g, hydracrylic acid 4.8g, pyrovinic acid 27g, vanillin 0.4g, strontium sulfate 2.7g, PTPP (potassium tripolyphosphate) 22g, hydrogen peroxide
12g, two benzenesulfonimide 2g, propilolic alcohol 22g, potassium pyrophosphate 22, hydroxyl sulfoacid sodium 12g, acetoglycocoll 12g, tri-chlorination ammonium
12g, remaining is deionized water.
Beneficial effect: the present invention compared with prior art, has the advantage that plating solution stable in properties, it is possible to protect for a long time
Holding limpid the most turbid, coating crystallization refinement, uniformity is good.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail, but protection scope of the present invention is described also simultaneously
Being not limited to the concrete scope of the present embodiment, based on the embodiment in the present invention, those of ordinary skill in the art are not making
The every other embodiment obtained under creative work premise, broadly falls into the scope of protection of the invention.
Embodiment 1
Every kilogram of additive of the present embodiment is containing following component: pyridinium hydroxy propyl sulfobetaine 30g, hydracrylic acid 1g, methyl
Sulfonic acid 20g, vanillin 0.1g, strontium sulfate 1g, PTPP (potassium tripolyphosphate) 20g, hydrogen peroxide 10g, two benzenesulfonimide 1g, propilolic alcohol
20g, potassium pyrophosphate 15g, hydroxyl sulfoacid sodium 10g, acetoglycocoll 10g, tri-chlorination ammonium 10g, remaining is deionized water.
Embodiment 2
Every kilogram of additive of the present embodiment is containing following component: pyridinium hydroxy propyl sulfobetaine 60g, hydracrylic acid 5g, methyl
Sulfonic acid 30g, vanillin 1g, strontium sulfate 3g, PTPP (potassium tripolyphosphate) 30g, hydrogen peroxide 20g, two benzenesulfonimide 5g, propilolic alcohol 30g,
Potassium pyrophosphate 25g, hydroxyl sulfoacid sodium 20g, acetoglycocoll 20g, tri-chlorination ammonium 20g, remaining is deionized water.
Embodiment 3
Every kilogram of additive of the present embodiment is containing following component: pyridinium hydroxy propyl sulfobetaine 46g, hydracrylic acid 3.8g, first
Base sulfonic acid 22g, vanillin 0.6g, strontium sulfate 2.7g, PTPP (potassium tripolyphosphate) 26g, hydrogen peroxide 19g, two benzenesulfonimide 4g, propine
Alcohol 24g, potassium pyrophosphate 19g, hydroxyl sulfoacid sodium 14g, acetoglycocoll 14g, tri-chlorination ammonium 14g, remaining is deionized water.
Embodiment 4
Every kilogram of additive of the present embodiment is containing following component: pyridinium hydroxy propyl sulfobetaine 52g, hydracrylic acid 4.8g, first
Base sulfonic acid 27g, vanillin 0.4g, strontium sulfate 2.7g, PTPP (potassium tripolyphosphate) 22g, hydrogen peroxide 12g, two benzenesulfonimide 2g, propine
Alcohol 22g, potassium pyrophosphate 22, hydroxyl sulfoacid sodium 12g, acetoglycocoll 12g, tri-chlorination ammonium 12g, remaining is deionized water.
Claims (5)
1. one kind keeps plating solution stable in properties electroplating additive, it is characterised in that: every kilogram of additive is containing following component: hydroxyl
Propane sulfonic acid pyridinium salt 30-60g, hydracrylic acid 1-5g, pyrovinic acid 20-30g, vanillin 0.1-1g, strontium sulfate 1-3g, three
PA 800K 20-30g, hydrogen peroxide 10-20g, two benzenesulfonimide 1-5g, propilolic alcohol 20-30g, potassium pyrophosphate 15-25g,
Hydroxyl sulfoacid sodium 10-20g, acetoglycocoll 10-20g, tri-chlorination ammonium 10-20g, remaining is deionized water.
A kind of holding plating solution stable in properties electroplating additive the most according to claim 1, it is characterised in that: every kilogram adds
Add agent containing following component: pyridinium hydroxy propyl sulfobetaine 30g, hydracrylic acid 1g, pyrovinic acid 20g, vanillin 0.1g, sulphuric acid
Strontium 1g, PTPP (potassium tripolyphosphate) 20g, hydrogen peroxide 10g, two benzenesulfonimide 1g, propilolic alcohol 20g, potassium pyrophosphate 15g, hydroxyl sulfoacid
Sodium 10g, acetoglycocoll 10g, tri-chlorination ammonium 10g, remaining is deionized water.
A kind of holding plating solution stable in properties electroplating additive the most according to claim 1, it is characterised in that: every kilogram adds
Add agent containing following component: pyridinium hydroxy propyl sulfobetaine 60g, hydracrylic acid 5g, pyrovinic acid 30g, vanillin 1g, strontium sulfate
3g, PTPP (potassium tripolyphosphate) 30g, hydrogen peroxide 20g, two benzenesulfonimide 5g, propilolic alcohol 30g, potassium pyrophosphate 25g, hydroxyl sulfoacid sodium
20g, acetoglycocoll 20g, tri-chlorination ammonium 20g, remaining is deionized water.
A kind of holding plating solution stable in properties electroplating additive the most according to claim 1, it is characterised in that: every kilogram adds
Add agent containing following component: pyridinium hydroxy propyl sulfobetaine 46g, hydracrylic acid 3.8g, pyrovinic acid 22g, vanillin 0.6g, sulfur
Acid strontium 2.7g, PTPP (potassium tripolyphosphate) 26g, hydrogen peroxide 19g, two benzenesulfonimide 4g, propilolic alcohol 24g, potassium pyrophosphate 19g, hydroxyl
Sodium sulfonate 14g, acetoglycocoll 14g, tri-chlorination ammonium 14g, remaining is deionized water.
A kind of holding plating solution stable in properties electroplating additive the most according to claim 1, it is characterised in that: every kilogram adds
Add agent containing following component: pyridinium hydroxy propyl sulfobetaine 52g, hydracrylic acid 4.8g, pyrovinic acid 27g, vanillin 0.4g, sulfur
Acid strontium 2.7g, PTPP (potassium tripolyphosphate) 22g, hydrogen peroxide 12g, two benzenesulfonimide 2g, propilolic alcohol 22g, potassium pyrophosphate 22, hydroxyl
Sodium sulfonate 12g, acetoglycocoll 12g, tri-chlorination ammonium 12g, remaining is deionized water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610653336.7A CN106086946A (en) | 2016-08-11 | 2016-08-11 | A kind of holding plating solution stable in properties electroplating additive |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610653336.7A CN106086946A (en) | 2016-08-11 | 2016-08-11 | A kind of holding plating solution stable in properties electroplating additive |
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| CN106086946A true CN106086946A (en) | 2016-11-09 |
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| CN201610653336.7A Pending CN106086946A (en) | 2016-08-11 | 2016-08-11 | A kind of holding plating solution stable in properties electroplating additive |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108866587A (en) * | 2018-07-11 | 2018-11-23 | 安徽鼎旺环保材料科技有限公司 | A kind of electroplating additive enhancing electroplated product corrosion resistance |
| CN108866588A (en) * | 2018-07-11 | 2018-11-23 | 安徽鼎旺环保材料科技有限公司 | A kind of electroplating additive improving zinc-nickel electroplated stabilizer |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB191509957A (en) * | 1915-07-08 | 1916-03-30 | Pascal Marino | Improvements in the Preparation of Electrolytes for use in the Electrolytic Deposition of Metals. |
| CN1733977A (en) * | 2004-08-03 | 2006-02-15 | 上海新阳半导体材料有限公司 | Electroplating additive and its preparation method |
| CN101942684A (en) * | 2010-10-09 | 2011-01-12 | 济南德锡科技有限公司 | Alkaline electroplating Zn-Ni alloy additive, electroplating solution and preparation method |
| CN103173819A (en) * | 2011-12-21 | 2013-06-26 | 李平 | Tinning stabilization additive |
| CN103397357A (en) * | 2013-07-23 | 2013-11-20 | 湖北大学 | Electroplating solution additive for electroplating bright nickel-titanium alloy |
| CN105040051A (en) * | 2015-08-31 | 2015-11-11 | 武汉吉和昌化工科技股份有限公司 | Subacidity-system bright zinc-nickel alloy electroplating solution |
| CN105603470A (en) * | 2016-03-31 | 2016-05-25 | 奕东电子(常熟)有限公司 | Satin nickel solution and nickel plating process thereof |
-
2016
- 2016-08-11 CN CN201610653336.7A patent/CN106086946A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB191509957A (en) * | 1915-07-08 | 1916-03-30 | Pascal Marino | Improvements in the Preparation of Electrolytes for use in the Electrolytic Deposition of Metals. |
| CN1733977A (en) * | 2004-08-03 | 2006-02-15 | 上海新阳半导体材料有限公司 | Electroplating additive and its preparation method |
| CN101942684A (en) * | 2010-10-09 | 2011-01-12 | 济南德锡科技有限公司 | Alkaline electroplating Zn-Ni alloy additive, electroplating solution and preparation method |
| CN103173819A (en) * | 2011-12-21 | 2013-06-26 | 李平 | Tinning stabilization additive |
| CN103397357A (en) * | 2013-07-23 | 2013-11-20 | 湖北大学 | Electroplating solution additive for electroplating bright nickel-titanium alloy |
| CN105040051A (en) * | 2015-08-31 | 2015-11-11 | 武汉吉和昌化工科技股份有限公司 | Subacidity-system bright zinc-nickel alloy electroplating solution |
| CN105603470A (en) * | 2016-03-31 | 2016-05-25 | 奕东电子(常熟)有限公司 | Satin nickel solution and nickel plating process thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108866587A (en) * | 2018-07-11 | 2018-11-23 | 安徽鼎旺环保材料科技有限公司 | A kind of electroplating additive enhancing electroplated product corrosion resistance |
| CN108866588A (en) * | 2018-07-11 | 2018-11-23 | 安徽鼎旺环保材料科技有限公司 | A kind of electroplating additive improving zinc-nickel electroplated stabilizer |
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Application publication date: 20161109 |