CN106085264A - Anti tear Honey comb like package carton and preparation method thereof - Google Patents
Anti tear Honey comb like package carton and preparation method thereof Download PDFInfo
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- CN106085264A CN106085264A CN201610436527.8A CN201610436527A CN106085264A CN 106085264 A CN106085264 A CN 106085264A CN 201610436527 A CN201610436527 A CN 201610436527A CN 106085264 A CN106085264 A CN 106085264A
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- consumption
- weight portion
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- honey comb
- weight portions
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of anti tear Honey comb like package carton and preparation method thereof, wherein, described preparation method includes: 1) water, polyvinyl alcohol, vinyl acetate, dibutyl phthalate, ethylene glycol, sodium hexameta phosphate, nano magnesia and bentonite are mixed, and prepares adhesive M1;2) honeycomb cardboard is used step 1) in prepare adhesive M1 gluing, prepare anti tear Honey comb like package carton;Wherein, the water of relative 100 weight portions, the consumption of vinyl alcohol is 30 50 weight portions, the consumption of vinyl acetate is 10 20 weight portions, the consumption of dibutyl phthalate is 3 10 weight portions, and the consumption of ethylene glycol is 5 15 weight portions, and the consumption of sodium hexameta phosphate is 15 weight portions, the consumption of nano magnesia is 15 weight portions, and bentonitic consumption is 10 30 weight portions.By above-mentioned design, it is achieved that energy anti tear, it is greatly improved the effect in the service life of Honey comb like package carton.
Description
Technical field
The present invention relates to the production preparation field of Honey comb like package carton, in particular it relates to anti tear Honey comb like package carton and
Its preparation method.
Background technology
Honey comb like package carton makes its application in daily production and life extremely wide with its superior serviceability,
But in use, Honey comb like package carton is often prepared, so that it is easy to be torn by couch board bonding because of it
Split, and then cause carton to be scrapped.
Therefore it provides a kind of energy anti tear, it is greatly improved the anti tear Honey comb like package in the service life of Honey comb like package carton
Carton and preparation method thereof is the problem that the present invention needs solution badly.
Summary of the invention
For above-mentioned prior art, it is an object of the invention to overcome in prior art Honey comb like package carton often because of its by
Couch board bonding prepares, so that it is easily torn, and then causes the problem that carton scraps, thus provides a kind of energy
Anti tear, anti tear Honey comb like package carton in service life being greatly improved Honey comb like package carton and preparation method thereof.
To achieve these goals, the invention provides the preparation method of a kind of anti tear Honey comb like package carton, wherein, institute
State preparation method to include:
1) by water, polyvinyl alcohol, vinyl acetate, dibutyl phthalate, ethylene glycol, sodium hexameta phosphate, nano oxygen
Change magnesium and bentonite mixing, prepare adhesive M1;
2) honeycomb cardboard is used step 1) in prepare adhesive M1 gluing, prepare anti tear Honey comb like package carton;Its
In,
The described water of relative 100 weight portions, the consumption of described vinyl alcohol is 30-50 weight portion, described vinyl acetate
Consumption is 10-20 weight portion, and the consumption of described dibutyl phthalate is 3-10 weight portion, and the consumption of described ethylene glycol is 5-
15 weight portions, the consumption of described sodium hexameta phosphate is 1-5 weight portion, and the consumption of described nano magnesia is 1-5 weight portion, described
Bentonitic consumption is 10-30 weight portion.
Present invention also offers a kind of anti tear Honey comb like package carton prepared according to preparation method described above.
By technique scheme, the present invention is by water, polyvinyl alcohol, vinyl acetate, dibutyl phthalate, second two
Alcohol, sodium hexameta phosphate, nano magnesia and bentonite prepare adhesive after mixing according to a certain percentage, then use above-mentioned adhesive
Bonding honeycomb cardboard, so that have good resisting by the Honey comb like package carton of above-mentioned adhesive bond when actually used
Tear resistance, further increases the service life of Honey comb like package carton.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the detailed description of the invention of the present invention is described in detail.It should be appreciated that described herein specifically
Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
The invention provides the preparation method of a kind of anti tear Honey comb like package carton, wherein, described preparation method includes:
1) by water, polyvinyl alcohol, vinyl acetate, dibutyl phthalate, ethylene glycol, sodium hexameta phosphate, nano oxygen
Change magnesium and bentonite mixing, prepare adhesive M1;
2) honeycomb cardboard is used step 1) in prepare adhesive M1 gluing, prepare anti tear Honey comb like package carton;Its
In,
The described water of relative 100 weight portions, the consumption of described vinyl alcohol is 30-50 weight portion, described vinyl acetate
Consumption is 10-20 weight portion, and the consumption of described dibutyl phthalate is 3-10 weight portion, and the consumption of described ethylene glycol is 5-
15 weight portions, the consumption of described sodium hexameta phosphate is 1-5 weight portion, and the consumption of described nano magnesia is 1-5 weight portion, described
Bentonitic consumption is 10-30 weight portion.
Above-mentioned design is by by water, polyvinyl alcohol, vinyl acetate, dibutyl phthalate, ethylene glycol, hexa metaphosphoric acid
Sodium, nano magnesia and bentonite prepare adhesive, then by above-mentioned adhesive bond honeycomb paper after mixing according to a certain percentage
Plate, so that there is when actually used good tear resistance by the Honey comb like package carton of above-mentioned adhesive bond,
Further increase the service life of Honey comb like package carton.
The present invention one preferred embodiment in, in order to make the tear resistance of Honey comb like package carton for preparing more
Good, the described water of relative 100 weight portions, the consumption of described vinyl alcohol is 35-45 weight portion, and the consumption of described vinyl acetate is
13-17 weight portion, the consumption of described dibutyl phthalate is 5-8 weight portion, and the consumption of described ethylene glycol is 8-12 weight
Part, the consumption of described sodium hexameta phosphate is 2-4 weight portion, and the consumption of described nano magnesia is 2-4 weight portion, described bentonite
Consumption be 15-25 weight portion.
Described polyvinyl alcohol can be type commonly used in the art, such as, one preferred embodiment in, described
The alcoholysis degree of polyvinyl alcohol is not less than 85%.
In a kind of embodiment being more highly preferred to, the particle diameter of described nano magnesia is 50-300nm.
Step 1) in mixed process can carry out in a conventional manner, such as, one preferred embodiment in, step
1) it is mixed into stirring mixing in, and the speed of stirring is 200-800r/min.
In a kind of embodiment being more highly preferred to, in order to make mixing be more uniformly distributed, step 1) in mixing temperature be 60-80
℃。
Present invention also offers a kind of anti tear Honey comb like package carton prepared according to preparation method described above.
Hereinafter will be described the present invention by embodiment.In following example, described polyvinyl alcohol is Shanxi
The commercially available product that the trade mark is 100-40H of three-dimensional brand, described vinyl acetate, described dibutyl phthalate, described second two
Alcohol, described sodium hexameta phosphate, described nano magnesia and described bentonite are conventional commercial product.
Embodiment 1
1) by 100g water, 35g polyvinyl alcohol, 13g vinyl acetate, 5g dibutyl phthalate, 8g ethylene glycol, 2g six
Polymeric sodium metaphosphate., 2g nano magnesia and 15g bentonite are placed under conditions of 60 DEG C to stir with the stir speed (S.S.) of 200r/min and mix,
Prepare adhesive M1;
2) honeycomb cardboard is used step 1) in prepare adhesive M1 gluing, prepare anti tear Honey comb like package carton A1.
Embodiment 2
1) by 100g water, 45g polyvinyl alcohol, 17g vinyl acetate, 8g dibutyl phthalate, 12g ethylene glycol, 4g
Sodium hexameta phosphate, 4g nano magnesia and 25g bentonite are placed under conditions of 80 DEG C and stir mixed with the stir speed (S.S.) of 800r/min
Close, prepare adhesive M1;
2) honeycomb cardboard is used step 1) in prepare adhesive M1 gluing, prepare anti tear Honey comb like package carton A2.
Embodiment 3
1) by 100g water, 40g polyvinyl alcohol, 15g vinyl acetate, 6g dibutyl phthalate, 10g ethylene glycol, 3g
Sodium hexameta phosphate, 3g nano magnesia and 20g bentonite are placed under conditions of 70 DEG C and stir mixed with the stir speed (S.S.) of 500r/min
Close, prepare adhesive M1;
2) honeycomb cardboard is used step 1) in prepare adhesive M1 gluing, prepare anti tear Honey comb like package carton A3.
Embodiment 4
Being prepared according to the preparation method of embodiment 1, except for the difference that, the consumption of described vinyl alcohol is 30g, described acetic acid
The consumption of vinyl acetate is 10g, and the consumption of described dibutyl phthalate is 3g, and the consumption of described ethylene glycol is 5g, described six
The consumption of Polymeric sodium metaphosphate. is 1g, and the consumption of described nano magnesia is 1g, and described bentonitic consumption is 10g, prepares anti tear
Honey comb like package carton A4.
Embodiment 5
Being prepared according to the preparation method of embodiment 2, except for the difference that, the consumption of described vinyl alcohol is 50g, described acetic acid
The consumption of vinyl acetate is 20g, and the consumption of described dibutyl phthalate is 10g, and the consumption of described ethylene glycol is 15g, described
The consumption of sodium hexameta phosphate is 5g, and the consumption of described nano magnesia is 5g, and described bentonitic consumption is 30g, prepares anti-tear
Split Honey comb like package carton A5.
Comparative example 1
Being prepared according to the preparation method of embodiment 3, except for the difference that, the consumption of described vinyl alcohol is 10g, described acetic acid
The consumption of vinyl acetate is 5g, and the consumption of described dibutyl phthalate is 1g, and the consumption of described ethylene glycol is 2g, described six inclined
The consumption of sodium phosphate is 0.5g, and the consumption of described nano magnesia is 0.5g, and described bentonitic consumption is 5g, prepares anti tear
Honey comb like package carton D1.
Comparative example 2
Being prepared according to the preparation method of embodiment 3, except for the difference that, the consumption of described vinyl alcohol is 80g, described acetic acid
The consumption of vinyl acetate is 40g, and the consumption of described dibutyl phthalate is 20g, and the consumption of described ethylene glycol is 30g, described
The consumption of sodium hexameta phosphate is 10g, and the consumption of described nano magnesia is 10g, and described bentonitic consumption is 50g, prepares anti-
Tear Honey comb like package carton D2.
Test case
Above-mentioned prepared A1-A5, D1 and D2 are pullled respectively, detects its Splitting, the result obtained such as table 1 institute
Show.
Table 1
Numbering | Splitting |
A1 | Without tear |
A2 | Without tear |
A3 | Without tear |
A4 | Without substantially tear |
A5 | Without substantially tear |
D1 | Substantially tear |
D2 | Substantially tear |
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment
Detail, in the technology concept of the present invention, technical scheme can be carried out multiple simple variant, this
A little simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technical characteristic described in above-mentioned detailed description of the invention, at not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to various can
The compound mode of energy illustrates the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as it is without prejudice to this
The thought of invention, it should be considered as content disclosed in this invention equally.
Claims (7)
1. the preparation method of an anti tear Honey comb like package carton, it is characterised in that described preparation method includes:
1) by water, polyvinyl alcohol, vinyl acetate, dibutyl phthalate, ethylene glycol, sodium hexameta phosphate, nano magnesia
Mix with bentonite, prepare adhesive M1;
2) honeycomb cardboard is used step 1) in prepare adhesive M1 gluing, prepare anti tear Honey comb like package carton;Wherein,
The described water of relative 100 weight portions, the consumption of described vinyl alcohol is 30-50 weight portion, the consumption of described vinyl acetate
For 10-20 weight portion, the consumption of described dibutyl phthalate is 3-10 weight portion, and the consumption of described ethylene glycol is 5-15 weight
Amount part, the consumption of described sodium hexameta phosphate is 1-5 weight portion, and the consumption of described nano magnesia is 1-5 weight portion, described swelling
The consumption of soil is 10-30 weight portion.
Preparation method the most according to claim 1, wherein, the described water of relative 100 weight portions, the consumption of described vinyl alcohol
For 35-45 weight portion, the consumption of described vinyl acetate is 13-17 weight portion, and the consumption of described dibutyl phthalate is
5-8 weight portion, the consumption of described ethylene glycol is 8-12 weight portion, and the consumption of described sodium hexameta phosphate is 2-4 weight portion, described in receive
The consumption of rice magnesium oxide is 2-4 weight portion, and described bentonitic consumption is 15-25 weight portion.
Preparation method the most according to claim 1 and 2, wherein, the alcoholysis degree of described polyvinyl alcohol is not less than 85%.
Preparation method the most according to claim 1 and 2, wherein, the particle diameter of described nano magnesia is 50-300nm.
Preparation method the most according to claim 1 and 2, wherein, step 1) in be mixed into stirring mixing, and the speed of stirring
For 200-800r/min.
Preparation method the most according to claim 1 and 2, wherein, step 1) in mixing temperature be 60-80 DEG C.
7. the anti tear Honey comb like package carton prepared according to the preparation method described in any one in claim 1-6.
Priority Applications (1)
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CN201610436527.8A CN106085264A (en) | 2016-06-16 | 2016-06-16 | Anti tear Honey comb like package carton and preparation method thereof |
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CN201610436527.8A CN106085264A (en) | 2016-06-16 | 2016-06-16 | Anti tear Honey comb like package carton and preparation method thereof |
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CN201610436527.8A Pending CN106085264A (en) | 2016-06-16 | 2016-06-16 | Anti tear Honey comb like package carton and preparation method thereof |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101402835A (en) * | 2008-01-25 | 2009-04-08 | 盐城华贸包装有限公司 | White latex adhesive agent for packaging paper product and method of producing the same |
CN101709211A (en) * | 2009-12-03 | 2010-05-19 | 东营市盛基环保工程有限公司 | Nonformaldehyde nonpoisonous adhesive and preparation method thereof |
CN104789131A (en) * | 2015-04-22 | 2015-07-22 | 青岛康泰鑫环保科技有限公司 | Water-proof adhesive for carton |
CN104927726A (en) * | 2015-06-29 | 2015-09-23 | 蒋勇 | Paper tube adhesive and preparation method thereof |
-
2016
- 2016-06-16 CN CN201610436527.8A patent/CN106085264A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101402835A (en) * | 2008-01-25 | 2009-04-08 | 盐城华贸包装有限公司 | White latex adhesive agent for packaging paper product and method of producing the same |
CN101709211A (en) * | 2009-12-03 | 2010-05-19 | 东营市盛基环保工程有限公司 | Nonformaldehyde nonpoisonous adhesive and preparation method thereof |
CN104789131A (en) * | 2015-04-22 | 2015-07-22 | 青岛康泰鑫环保科技有限公司 | Water-proof adhesive for carton |
CN104927726A (en) * | 2015-06-29 | 2015-09-23 | 蒋勇 | Paper tube adhesive and preparation method thereof |
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Application publication date: 20161109 |
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