CN106085264A - Anti tear Honey comb like package carton and preparation method thereof - Google Patents

Anti tear Honey comb like package carton and preparation method thereof Download PDF

Info

Publication number
CN106085264A
CN106085264A CN201610436527.8A CN201610436527A CN106085264A CN 106085264 A CN106085264 A CN 106085264A CN 201610436527 A CN201610436527 A CN 201610436527A CN 106085264 A CN106085264 A CN 106085264A
Authority
CN
China
Prior art keywords
consumption
weight portion
preparation
honey comb
weight portions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610436527.8A
Other languages
Chinese (zh)
Inventor
解和锋
沐磊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongling Feng Feng Color Printing Co Ltd
Original Assignee
Tongling Feng Feng Color Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tongling Feng Feng Color Printing Co Ltd filed Critical Tongling Feng Feng Color Printing Co Ltd
Priority to CN201610436527.8A priority Critical patent/CN106085264A/en
Publication of CN106085264A publication Critical patent/CN106085264A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a kind of anti tear Honey comb like package carton and preparation method thereof, wherein, described preparation method includes: 1) water, polyvinyl alcohol, vinyl acetate, dibutyl phthalate, ethylene glycol, sodium hexameta phosphate, nano magnesia and bentonite are mixed, and prepares adhesive M1;2) honeycomb cardboard is used step 1) in prepare adhesive M1 gluing, prepare anti tear Honey comb like package carton;Wherein, the water of relative 100 weight portions, the consumption of vinyl alcohol is 30 50 weight portions, the consumption of vinyl acetate is 10 20 weight portions, the consumption of dibutyl phthalate is 3 10 weight portions, and the consumption of ethylene glycol is 5 15 weight portions, and the consumption of sodium hexameta phosphate is 15 weight portions, the consumption of nano magnesia is 15 weight portions, and bentonitic consumption is 10 30 weight portions.By above-mentioned design, it is achieved that energy anti tear, it is greatly improved the effect in the service life of Honey comb like package carton.

Description

Anti tear Honey comb like package carton and preparation method thereof
Technical field
The present invention relates to the production preparation field of Honey comb like package carton, in particular it relates to anti tear Honey comb like package carton and Its preparation method.
Background technology
Honey comb like package carton makes its application in daily production and life extremely wide with its superior serviceability, But in use, Honey comb like package carton is often prepared, so that it is easy to be torn by couch board bonding because of it Split, and then cause carton to be scrapped.
Therefore it provides a kind of energy anti tear, it is greatly improved the anti tear Honey comb like package in the service life of Honey comb like package carton Carton and preparation method thereof is the problem that the present invention needs solution badly.
Summary of the invention
For above-mentioned prior art, it is an object of the invention to overcome in prior art Honey comb like package carton often because of its by Couch board bonding prepares, so that it is easily torn, and then causes the problem that carton scraps, thus provides a kind of energy Anti tear, anti tear Honey comb like package carton in service life being greatly improved Honey comb like package carton and preparation method thereof.
To achieve these goals, the invention provides the preparation method of a kind of anti tear Honey comb like package carton, wherein, institute State preparation method to include:
1) by water, polyvinyl alcohol, vinyl acetate, dibutyl phthalate, ethylene glycol, sodium hexameta phosphate, nano oxygen Change magnesium and bentonite mixing, prepare adhesive M1;
2) honeycomb cardboard is used step 1) in prepare adhesive M1 gluing, prepare anti tear Honey comb like package carton;Its In,
The described water of relative 100 weight portions, the consumption of described vinyl alcohol is 30-50 weight portion, described vinyl acetate Consumption is 10-20 weight portion, and the consumption of described dibutyl phthalate is 3-10 weight portion, and the consumption of described ethylene glycol is 5- 15 weight portions, the consumption of described sodium hexameta phosphate is 1-5 weight portion, and the consumption of described nano magnesia is 1-5 weight portion, described Bentonitic consumption is 10-30 weight portion.
Present invention also offers a kind of anti tear Honey comb like package carton prepared according to preparation method described above.
By technique scheme, the present invention is by water, polyvinyl alcohol, vinyl acetate, dibutyl phthalate, second two Alcohol, sodium hexameta phosphate, nano magnesia and bentonite prepare adhesive after mixing according to a certain percentage, then use above-mentioned adhesive Bonding honeycomb cardboard, so that have good resisting by the Honey comb like package carton of above-mentioned adhesive bond when actually used Tear resistance, further increases the service life of Honey comb like package carton.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the detailed description of the invention of the present invention is described in detail.It should be appreciated that described herein specifically Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
The invention provides the preparation method of a kind of anti tear Honey comb like package carton, wherein, described preparation method includes:
1) by water, polyvinyl alcohol, vinyl acetate, dibutyl phthalate, ethylene glycol, sodium hexameta phosphate, nano oxygen Change magnesium and bentonite mixing, prepare adhesive M1;
2) honeycomb cardboard is used step 1) in prepare adhesive M1 gluing, prepare anti tear Honey comb like package carton;Its In,
The described water of relative 100 weight portions, the consumption of described vinyl alcohol is 30-50 weight portion, described vinyl acetate Consumption is 10-20 weight portion, and the consumption of described dibutyl phthalate is 3-10 weight portion, and the consumption of described ethylene glycol is 5- 15 weight portions, the consumption of described sodium hexameta phosphate is 1-5 weight portion, and the consumption of described nano magnesia is 1-5 weight portion, described Bentonitic consumption is 10-30 weight portion.
Above-mentioned design is by by water, polyvinyl alcohol, vinyl acetate, dibutyl phthalate, ethylene glycol, hexa metaphosphoric acid Sodium, nano magnesia and bentonite prepare adhesive, then by above-mentioned adhesive bond honeycomb paper after mixing according to a certain percentage Plate, so that there is when actually used good tear resistance by the Honey comb like package carton of above-mentioned adhesive bond, Further increase the service life of Honey comb like package carton.
The present invention one preferred embodiment in, in order to make the tear resistance of Honey comb like package carton for preparing more Good, the described water of relative 100 weight portions, the consumption of described vinyl alcohol is 35-45 weight portion, and the consumption of described vinyl acetate is 13-17 weight portion, the consumption of described dibutyl phthalate is 5-8 weight portion, and the consumption of described ethylene glycol is 8-12 weight Part, the consumption of described sodium hexameta phosphate is 2-4 weight portion, and the consumption of described nano magnesia is 2-4 weight portion, described bentonite Consumption be 15-25 weight portion.
Described polyvinyl alcohol can be type commonly used in the art, such as, one preferred embodiment in, described The alcoholysis degree of polyvinyl alcohol is not less than 85%.
In a kind of embodiment being more highly preferred to, the particle diameter of described nano magnesia is 50-300nm.
Step 1) in mixed process can carry out in a conventional manner, such as, one preferred embodiment in, step 1) it is mixed into stirring mixing in, and the speed of stirring is 200-800r/min.
In a kind of embodiment being more highly preferred to, in order to make mixing be more uniformly distributed, step 1) in mixing temperature be 60-80 ℃。
Present invention also offers a kind of anti tear Honey comb like package carton prepared according to preparation method described above.
Hereinafter will be described the present invention by embodiment.In following example, described polyvinyl alcohol is Shanxi The commercially available product that the trade mark is 100-40H of three-dimensional brand, described vinyl acetate, described dibutyl phthalate, described second two Alcohol, described sodium hexameta phosphate, described nano magnesia and described bentonite are conventional commercial product.
Embodiment 1
1) by 100g water, 35g polyvinyl alcohol, 13g vinyl acetate, 5g dibutyl phthalate, 8g ethylene glycol, 2g six Polymeric sodium metaphosphate., 2g nano magnesia and 15g bentonite are placed under conditions of 60 DEG C to stir with the stir speed (S.S.) of 200r/min and mix, Prepare adhesive M1;
2) honeycomb cardboard is used step 1) in prepare adhesive M1 gluing, prepare anti tear Honey comb like package carton A1.
Embodiment 2
1) by 100g water, 45g polyvinyl alcohol, 17g vinyl acetate, 8g dibutyl phthalate, 12g ethylene glycol, 4g Sodium hexameta phosphate, 4g nano magnesia and 25g bentonite are placed under conditions of 80 DEG C and stir mixed with the stir speed (S.S.) of 800r/min Close, prepare adhesive M1;
2) honeycomb cardboard is used step 1) in prepare adhesive M1 gluing, prepare anti tear Honey comb like package carton A2.
Embodiment 3
1) by 100g water, 40g polyvinyl alcohol, 15g vinyl acetate, 6g dibutyl phthalate, 10g ethylene glycol, 3g Sodium hexameta phosphate, 3g nano magnesia and 20g bentonite are placed under conditions of 70 DEG C and stir mixed with the stir speed (S.S.) of 500r/min Close, prepare adhesive M1;
2) honeycomb cardboard is used step 1) in prepare adhesive M1 gluing, prepare anti tear Honey comb like package carton A3.
Embodiment 4
Being prepared according to the preparation method of embodiment 1, except for the difference that, the consumption of described vinyl alcohol is 30g, described acetic acid The consumption of vinyl acetate is 10g, and the consumption of described dibutyl phthalate is 3g, and the consumption of described ethylene glycol is 5g, described six The consumption of Polymeric sodium metaphosphate. is 1g, and the consumption of described nano magnesia is 1g, and described bentonitic consumption is 10g, prepares anti tear Honey comb like package carton A4.
Embodiment 5
Being prepared according to the preparation method of embodiment 2, except for the difference that, the consumption of described vinyl alcohol is 50g, described acetic acid The consumption of vinyl acetate is 20g, and the consumption of described dibutyl phthalate is 10g, and the consumption of described ethylene glycol is 15g, described The consumption of sodium hexameta phosphate is 5g, and the consumption of described nano magnesia is 5g, and described bentonitic consumption is 30g, prepares anti-tear Split Honey comb like package carton A5.
Comparative example 1
Being prepared according to the preparation method of embodiment 3, except for the difference that, the consumption of described vinyl alcohol is 10g, described acetic acid The consumption of vinyl acetate is 5g, and the consumption of described dibutyl phthalate is 1g, and the consumption of described ethylene glycol is 2g, described six inclined The consumption of sodium phosphate is 0.5g, and the consumption of described nano magnesia is 0.5g, and described bentonitic consumption is 5g, prepares anti tear Honey comb like package carton D1.
Comparative example 2
Being prepared according to the preparation method of embodiment 3, except for the difference that, the consumption of described vinyl alcohol is 80g, described acetic acid The consumption of vinyl acetate is 40g, and the consumption of described dibutyl phthalate is 20g, and the consumption of described ethylene glycol is 30g, described The consumption of sodium hexameta phosphate is 10g, and the consumption of described nano magnesia is 10g, and described bentonitic consumption is 50g, prepares anti- Tear Honey comb like package carton D2.
Test case
Above-mentioned prepared A1-A5, D1 and D2 are pullled respectively, detects its Splitting, the result obtained such as table 1 institute Show.
Table 1
Numbering Splitting
A1 Without tear
A2 Without tear
A3 Without tear
A4 Without substantially tear
A5 Without substantially tear
D1 Substantially tear
D2 Substantially tear
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment Detail, in the technology concept of the present invention, technical scheme can be carried out multiple simple variant, this A little simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technical characteristic described in above-mentioned detailed description of the invention, at not lance In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to various can The compound mode of energy illustrates the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as it is without prejudice to this The thought of invention, it should be considered as content disclosed in this invention equally.

Claims (7)

1. the preparation method of an anti tear Honey comb like package carton, it is characterised in that described preparation method includes:
1) by water, polyvinyl alcohol, vinyl acetate, dibutyl phthalate, ethylene glycol, sodium hexameta phosphate, nano magnesia Mix with bentonite, prepare adhesive M1;
2) honeycomb cardboard is used step 1) in prepare adhesive M1 gluing, prepare anti tear Honey comb like package carton;Wherein,
The described water of relative 100 weight portions, the consumption of described vinyl alcohol is 30-50 weight portion, the consumption of described vinyl acetate For 10-20 weight portion, the consumption of described dibutyl phthalate is 3-10 weight portion, and the consumption of described ethylene glycol is 5-15 weight Amount part, the consumption of described sodium hexameta phosphate is 1-5 weight portion, and the consumption of described nano magnesia is 1-5 weight portion, described swelling The consumption of soil is 10-30 weight portion.
Preparation method the most according to claim 1, wherein, the described water of relative 100 weight portions, the consumption of described vinyl alcohol For 35-45 weight portion, the consumption of described vinyl acetate is 13-17 weight portion, and the consumption of described dibutyl phthalate is 5-8 weight portion, the consumption of described ethylene glycol is 8-12 weight portion, and the consumption of described sodium hexameta phosphate is 2-4 weight portion, described in receive The consumption of rice magnesium oxide is 2-4 weight portion, and described bentonitic consumption is 15-25 weight portion.
Preparation method the most according to claim 1 and 2, wherein, the alcoholysis degree of described polyvinyl alcohol is not less than 85%.
Preparation method the most according to claim 1 and 2, wherein, the particle diameter of described nano magnesia is 50-300nm.
Preparation method the most according to claim 1 and 2, wherein, step 1) in be mixed into stirring mixing, and the speed of stirring For 200-800r/min.
Preparation method the most according to claim 1 and 2, wherein, step 1) in mixing temperature be 60-80 DEG C.
7. the anti tear Honey comb like package carton prepared according to the preparation method described in any one in claim 1-6.
CN201610436527.8A 2016-06-16 2016-06-16 Anti tear Honey comb like package carton and preparation method thereof Pending CN106085264A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610436527.8A CN106085264A (en) 2016-06-16 2016-06-16 Anti tear Honey comb like package carton and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610436527.8A CN106085264A (en) 2016-06-16 2016-06-16 Anti tear Honey comb like package carton and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106085264A true CN106085264A (en) 2016-11-09

Family

ID=57235910

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610436527.8A Pending CN106085264A (en) 2016-06-16 2016-06-16 Anti tear Honey comb like package carton and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106085264A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101402835A (en) * 2008-01-25 2009-04-08 盐城华贸包装有限公司 White latex adhesive agent for packaging paper product and method of producing the same
CN101709211A (en) * 2009-12-03 2010-05-19 东营市盛基环保工程有限公司 Nonformaldehyde nonpoisonous adhesive and preparation method thereof
CN104789131A (en) * 2015-04-22 2015-07-22 青岛康泰鑫环保科技有限公司 Water-proof adhesive for carton
CN104927726A (en) * 2015-06-29 2015-09-23 蒋勇 Paper tube adhesive and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101402835A (en) * 2008-01-25 2009-04-08 盐城华贸包装有限公司 White latex adhesive agent for packaging paper product and method of producing the same
CN101709211A (en) * 2009-12-03 2010-05-19 东营市盛基环保工程有限公司 Nonformaldehyde nonpoisonous adhesive and preparation method thereof
CN104789131A (en) * 2015-04-22 2015-07-22 青岛康泰鑫环保科技有限公司 Water-proof adhesive for carton
CN104927726A (en) * 2015-06-29 2015-09-23 蒋勇 Paper tube adhesive and preparation method thereof

Similar Documents

Publication Publication Date Title
CN103360988B (en) A kind of Carton environment-friendlyformaldehyde-free formaldehyde-free adhesive and preparation method thereof
CN102977799A (en) Preparing method of high-strength woodworking adhesives
CN101307207B (en) Laser transfer coatings and method for preparing same
CN103992518A (en) Biodegradable packaging material
CN104312482A (en) Preparation method of rosin / starch based biodegradable hot melt adhesive
CN106085264A (en) Anti tear Honey comb like package carton and preparation method thereof
CN103360992B (en) A kind of wrapping paper tackiness agent and preparation method thereof
CN103804998B (en) A kind of PS/CTP version privacy protection glue and preparation method thereof
CN107365509A (en) A kind of banana stalks 3D printing environment-friendly materials and preparation method thereof
CN109320934A (en) A kind of novel environment friendly packaging film
CN106079016A (en) A kind of artificial board containing powder of straw
JP5812991B2 (en) Polyvinyl alcohol polymer and method for producing hydrolyzable cellulose using the same
CN109354841A (en) A kind of manioc waste composite material and preparation method
WO2010097024A1 (en) Solid universal glue slurry and preparation method thereof
CN108285650A (en) A kind of barley grain base composite package film and preparation method thereof
CN103396747A (en) Corrugated carton bonding agent and preparation method thereof
CN107586402A (en) A kind of preparation method of compound type starch
CN107459944A (en) A kind of environment-friendly water-based packaging glue and preparation method thereof
CN103360962A (en) Packaging adhesive and preparation method thereof
CN103360991B (en) A kind of water-based carton adhesive and preparation method thereof
CN106882467A (en) A kind of fire-type corrugated case
CN107541159A (en) A kind of water-soluble pressure-sensitive adhesive
CN104004455A (en) Adhesive composition and preparation method of adhesive
CN106087553A (en) Anti-skidding cardboard and preparation method thereof
CN102408849A (en) Ultrahigh viscosity cured adhesive powder and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20161109

RJ01 Rejection of invention patent application after publication