CN106084997A - A kind of water color ink of high patience high stable and preparation method thereof - Google Patents
A kind of water color ink of high patience high stable and preparation method thereof Download PDFInfo
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- CN106084997A CN106084997A CN201610630306.4A CN201610630306A CN106084997A CN 106084997 A CN106084997 A CN 106084997A CN 201610630306 A CN201610630306 A CN 201610630306A CN 106084997 A CN106084997 A CN 106084997A
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- parts
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- color ink
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- defoamer
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/108—Hydrocarbon resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/14—Printing inks based on carbohydrates
Abstract
The invention discloses the water color ink of a kind of high patience high stable, including the raw material of following weight portion: water soluble acrylic resin 20 30 parts, halogen-free vinyl 10 15 parts, plant cellulose 5 10 parts, vegetable oil 5 10 parts, pigment 10 15 parts, dibutyl phthalate 25 parts, defoamer 13 parts, initiator 14 parts, 20 40 parts of water；The invention allows for the preparation method of the water color ink of a kind of high patience high stable, comprise the following steps: S1, water soluble acrylic resin, halogen-free vinyl, plant cellulose, vegetable oil is weighed according to deal proportioning, above-mentioned raw materials is sequentially added in reactor, make it be sufficiently stirred for, it is slowly added to water, continuously stirred 20 30min；S2, weighs dibutyl phthalate, defoamer, initiator according to deal proportioning, is slowly added in reactor by above-mentioned raw materials, low rate mixing 10 15min；S3, puts into pigment in reactor.The preparation method of the present invention is simple, and the water color ink of preparation has the feature of high patience, high stability, is suitable for promoting.
Description
Technical field
The present invention relates to water color ink technical field, particularly relate to water color ink and the preparation thereof of a kind of high patience high stable
Method.
Background technology
Along with the fast development of Printing Industry, demand and the state of development of printing-ink grow with each passing day, water color ink master
To be formed through abrasive machining by water-soluble resin, organic pigment, solvent and related auxiliaries.Water color ink is particularly well-suited to
The sanitary conditions such as cigarette, wine, food, beverage, medicine, toy for children require strict Packaging Printing Product, existing water color ink
Anti-wear performance is inadequate, it is impossible to ensure the high stability of ink, and its adhesive force is not strong, we have proposed a kind of high patience for this high steady
Fixed water color ink and preparation method thereof, is used for solving the problems referred to above.
Summary of the invention
Based on background technology exist technical problem, the present invention propose a kind of high patience high stable water color ink and
Preparation method.
The water color ink of a kind of high patience high stable that the present invention proposes, including the raw material of following weight portion: water solublity third
Olefin(e) acid resin 20-30 part, halogen-free vinyl 10-15 part, plant cellulose 5-10 part, vegetable oil 5-10 part, pigment 10-15
Part, dibutyl phthalate 2-5 part, defoamer 1-3 part, initiator 1-4 part, water 20-40 part.
Preferably, including the raw material of following weight portion: water soluble acrylic resin's 22-28 part, halogen-free vinyl 11-
14 parts, plant cellulose 6-9 part, vegetable oil 6-9 part, pigment 11-14 part, dibutyl phthalate 3-4 part, defoamer 1.5-2.5 part, initiation
Agent 2-3 part, water 25-35 part.
Preferably, including the raw material of following weight portion: water soluble acrylic resin 25 parts, halogen-free vinyl 12.5
Part, plant cellulose 7.5 parts, vegetable oil 7.5 parts, pigment 12.5 parts, dibutyl phthalate 3.5 parts, defoamer 2 parts, initiator 2.5 parts,
30 parts of water.
Preferably, described water soluble acrylic resin, halogen-free vinyl, the weight ratio of plant cellulose are 22-28:
11-14:6-9.
Preferably, described initiator is Ammonium persulfate..
Preferably, described defoamer is silicone defoamer.
The invention allows for the preparation method of the water color ink of a kind of high patience high stable, comprise the following steps:
S1, weighs water soluble acrylic resin, halogen-free vinyl, plant cellulose, vegetable oil according to deal proportioning, by upper
State raw material to be sequentially added in reactor so that it is be sufficiently stirred for, be slowly added to water, continuously stirred 20-30min；
S2, weighs dibutyl phthalate, defoamer, initiator according to deal proportioning, is slowly added in reactor by above-mentioned raw materials, stirs at a slow speed
Mix 10-15min；
S3, puts into pigment in reactor, after stirring 5-10min, i.e. can get a kind of high patience high at a temperature of 60-80 DEG C
Stable water color ink.
Preferably, in described S3, pigment is put in reactor, after stirring 7.5min at a temperature of 70 DEG C,
Water color ink to a kind of high patience high stable.
In the present invention, water soluble acrylic resin is as conventional ink raw materials, and it is convenient, by the selection system of raw material to obtain
Standby go out suitability patience wide, high and the water color ink of high stability, the group such as its halogen-free vinyl used, plant cellulose
Point so that the adhesive force of ink is greatly improved so that the wearability of ink strengthens, and the preparation method of the present invention is simple, preparation
Water color ink has the feature of high patience, high stability, is suitable for promoting.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is explained orally further.
Embodiment one
The water color ink of a kind of high patience high stable that the present invention proposes, including the raw material of following weight portion: water-soluble acrylic
Resin 20 parts, plant cellulose 5 parts, vegetable oil 5 parts, pigment 10 parts, dibutyl phthalate 2 parts, defoamer 1 part, initiator 1 part, water 20
Part.
Its preparation method comprises the following steps:
S1, weighs water soluble acrylic resin, plant cellulose, vegetable oil according to deal proportioning, is sequentially added into by above-mentioned raw materials
In reactor so that it is be sufficiently stirred for, it is slowly added to water, continuously stirred 20min；
S2, weighs dibutyl phthalate, defoamer, initiator according to deal proportioning, is slowly added in reactor by above-mentioned raw materials, stirs at a slow speed
Mix 10min；
S3, puts into pigment in reactor, after stirring 5min, i.e. can get a kind of high patience high stable at a temperature of 60 DEG C
Water color ink.
Embodiment two
The water color ink of a kind of high patience high stable that the present invention proposes, including the raw material of following weight portion: water-soluble acrylic
Resin 22 parts, halogen-free vinyl 11 parts, plant cellulose 6 parts, vegetable oil 6 parts, pigment 11 parts, dibutyl phthalate 3 parts, defoamer
1.5 parts, initiator 2 parts, 25 parts of water.
Its preparation method comprises the following steps:
S1, weighs water soluble acrylic resin, halogen-free vinyl, plant cellulose, vegetable oil according to deal proportioning, by upper
State raw material to be sequentially added in reactor so that it is be sufficiently stirred for, be slowly added to water, continuously stirred 22min；
S2, weighs dibutyl phthalate, defoamer, initiator according to deal proportioning, is slowly added in reactor by above-mentioned raw materials, stirs at a slow speed
Mix 11min；
S3, puts into pigment in reactor, after stirring 6min, i.e. can get a kind of high patience high stable at a temperature of 65 DEG C
Water color ink.
Embodiment three
The water color ink of a kind of high patience high stable that the present invention proposes, including the raw material of following weight portion: water-soluble acrylic
Resin 25 parts, halogen-free vinyl 12.5 parts, plant cellulose 7.5 parts, vegetable oil 7.5 parts, pigment 12.5 parts, dibutyl phthalate
3.5 parts, defoamer 2 parts, initiator 2.5 parts, 30 parts of water.
Its preparation method comprises the following steps:
S1, weighs water soluble acrylic resin, halogen-free vinyl, plant cellulose, vegetable oil according to deal proportioning, by upper
State raw material to be sequentially added in reactor so that it is be sufficiently stirred for, be slowly added to water, continuously stirred 25min；
S2, weighs dibutyl phthalate, defoamer, initiator according to deal proportioning, is slowly added in reactor by above-mentioned raw materials, stirs at a slow speed
Mix 12.5min；
S3, puts into pigment in reactor, after stirring 7.5min, i.e. can get a kind of high patience high stable at a temperature of 70 DEG C
Water color ink.
Embodiment four
The water color ink of a kind of high patience high stable that the present invention proposes, including the raw material of following weight portion: water-soluble acrylic
Resin 28 parts, halogen-free vinyl 14 parts, plant cellulose 9 parts, vegetable oil 9 parts, pigment 14 parts, dibutyl phthalate 4 parts, defoamer
2.5 parts, initiator 3 parts, 35 parts of water.
Its preparation method comprises the following steps:
S1, weighs water soluble acrylic resin, halogen-free vinyl, plant cellulose, vegetable oil according to deal proportioning, by upper
State raw material to be sequentially added in reactor so that it is be sufficiently stirred for, be slowly added to water, continuously stirred 28min；
S2, weighs dibutyl phthalate, defoamer, initiator according to deal proportioning, is slowly added in reactor by above-mentioned raw materials, stirs at a slow speed
Mix 14min；
S3, puts into pigment in reactor, after stirring 9min, i.e. can get a kind of high patience high stable at a temperature of 75 DEG C
Water color ink.
Embodiment five
The water color ink of a kind of high patience high stable that the present invention proposes, including the raw material of following weight portion: water-soluble acrylic
Resin 30 parts, halogen-free vinyl 15 parts, plant cellulose 10 parts, vegetable oil 10 parts, pigment 15 parts, dibutyl phthalate 5 parts, froth breaking
Agent 3 parts, initiator 4 parts, 40 parts of water.
Its preparation method comprises the following steps:
S1, weighs water soluble acrylic resin, halogen-free vinyl, plant cellulose, vegetable oil according to deal proportioning, by upper
State raw material to be sequentially added in reactor so that it is be sufficiently stirred for, be slowly added to water, continuously stirred 30min；
S2, weighs dibutyl phthalate, defoamer, initiator according to deal proportioning, is slowly added in reactor by above-mentioned raw materials, stirs at a slow speed
Mix 15min；
S3, puts into pigment in reactor, after stirring 10min, i.e. can get a kind of high patience high stable at a temperature of 80 DEG C
Water color ink.
In the present invention, water soluble acrylic resin is as conventional ink raw materials, and it is convenient, by the selection system of raw material to obtain
Standby go out suitability patience wide, high and the water color ink of high stability, the group such as its halogen-free vinyl used, plant cellulose
Point so that the adhesive force of ink is greatly improved so that the wearability of ink strengthens.
In order to verify the ink performance of embodiments of the invention three, carry out ink performance test, test result such as following table:
| Test event | Testing standard | Test result |
| Wet-heat resisting is tested | Temperature 65 DEG C, humidity 96%, to place 24 hours, layer of ink is unchanged | Qualified |
| Wear-resisting experiment | RCA tests, and load 200g power, paper tape rotates 150 times continuously, and layer of ink is the most show-through | Qualified |
| Resistance to perspiration is tested | Smearing perspiration, place 24 hours under room temperature, layer of ink is unchanged | Qualified |
As seen from the above table, the water color ink that prepared by the present invention has the feature of high patience, high stability.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (8)
1. the water color ink of one kind high patience high stable, it is characterised in that include the raw material of following weight portion: water-soluble acrylic
Resin 20-30 part, halogen-free vinyl 10-15 part, plant cellulose 5-10 part, vegetable oil 5-10 part, pigment 10-15 part,
Dibutyl phthalate 2-5 part, defoamer 1-3 part, initiator 1-4 part, water 20-40 part.
The water color ink of a kind of high patience high stable the most according to claim 1, it is characterised in that include following weight portion
Raw material: water soluble acrylic resin's 22-28 part, halogen-free vinyl 11-14 part, plant cellulose 6-9 part, vegetable oil 6-
9 parts, pigment 11-14 part, dibutyl phthalate 3-4 part, defoamer 1.5-2.5 part, initiator 2-3 part, water 25-35 part.
The water color ink of a kind of high patience high stable the most according to claim 1, it is characterised in that include following weight portion
Raw material: water soluble acrylic resin 25 parts, halogen-free vinyl 12.5 parts, plant cellulose 7.5 parts, vegetable oil 7.5 parts,
Pigment 12.5 parts, dibutyl phthalate 3.5 parts, defoamer 2 parts, initiator 2.5 parts, 30 parts of water.
The water color ink of a kind of high patience high stable the most according to claim 1, it is characterised in that described water soluble propene
Acid resin, halogen-free vinyl, the weight ratio of plant cellulose are 22-28:11-14:6-9.
The water color ink of a kind of high patience high stable the most according to claim 1, it is characterised in that described initiator was
Ammonium sulfate.
The water color ink of a kind of high patience high stable the most according to claim 1, it is characterised in that described defoamer is for having
Machine silicon class defoamer.
7. the preparation method of the water color ink of one kind high patience high stable, it is characterised in that comprise the following steps:
S1, weighs water soluble acrylic resin, halogen-free vinyl, plant cellulose, vegetable oil according to deal proportioning, by upper
State raw material to be sequentially added in reactor so that it is be sufficiently stirred for, be slowly added to water, continuously stirred 20-30min；
S2, weighs dibutyl phthalate, defoamer, initiator according to deal proportioning, is slowly added in reactor by above-mentioned raw materials, stirs at a slow speed
Mix 10-15min；
S3, puts into pigment in reactor, after stirring 5-10min, i.e. can get a kind of high patience high at a temperature of 60-80 DEG C
Stable water color ink.
The preparation method of the water color ink of a kind of high patience high stable the most according to claim 7, it is characterised in that described
In S3, pigment is put in reactor, after stirring 7.5min at a temperature of 70 DEG C, i.e. can get a kind of high patience high stable
Water color ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610630306.4A CN106084997A (en) | 2016-08-04 | 2016-08-04 | A kind of water color ink of high patience high stable and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610630306.4A CN106084997A (en) | 2016-08-04 | 2016-08-04 | A kind of water color ink of high patience high stable and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106084997A true CN106084997A (en) | 2016-11-09 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610630306.4A Pending CN106084997A (en) | 2016-08-04 | 2016-08-04 | A kind of water color ink of high patience high stable and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN106084997A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5376169A (en) * | 1992-04-15 | 1994-12-27 | Minolta Camera Kabushiki Kaisha | Recording solution for ink jetting |
| CN105001704A (en) * | 2015-07-29 | 2015-10-28 | 李可 | Preparation method for novel water resistance printing ink |
| CN105713451A (en) * | 2016-04-18 | 2016-06-29 | 厦门欧化实业有限公司 | Benzene-free environment-friendly high-tolerance gravure ink |
-
2016
- 2016-08-04 CN CN201610630306.4A patent/CN106084997A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5376169A (en) * | 1992-04-15 | 1994-12-27 | Minolta Camera Kabushiki Kaisha | Recording solution for ink jetting |
| CN105001704A (en) * | 2015-07-29 | 2015-10-28 | 李可 | Preparation method for novel water resistance printing ink |
| CN105713451A (en) * | 2016-04-18 | 2016-06-29 | 厦门欧化实业有限公司 | Benzene-free environment-friendly high-tolerance gravure ink |
Non-Patent Citations (1)
| Title |
|---|
| 辛秀兰等: "《水性油墨》", 31 January 2005, 化学工业出版社 * |
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Application publication date: 20161109 |