CN106084926A - A kind of antique copper colour code board - Google Patents
A kind of antique copper colour code board Download PDFInfo
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- CN106084926A CN106084926A CN201610608518.2A CN201610608518A CN106084926A CN 106084926 A CN106084926 A CN 106084926A CN 201610608518 A CN201610608518 A CN 201610608518A CN 106084926 A CN106084926 A CN 106084926A
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- China
- Prior art keywords
- parts
- antique
- colour code
- code board
- coating
- Prior art date
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- Granted
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 239000010949 copper Substances 0.000 title claims abstract description 25
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 25
- -1 (2 aminoethylamino) propyl Chemical group 0.000 claims abstract description 20
- 238000000576 coating method Methods 0.000 claims abstract description 19
- 239000011248 coating agent Substances 0.000 claims abstract description 18
- 239000000654 additive Substances 0.000 claims abstract description 13
- 230000000996 additive effect Effects 0.000 claims abstract description 13
- 230000002421 anti-septic effect Effects 0.000 claims abstract description 12
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000005507 spraying Methods 0.000 claims abstract description 10
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 8
- 239000004111 Potassium silicate Substances 0.000 claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000049 pigment Substances 0.000 claims abstract description 7
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052913 potassium silicate Inorganic materials 0.000 claims abstract description 7
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims abstract description 7
- 239000004593 Epoxy Substances 0.000 claims abstract description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 6
- 239000001301 oxygen Substances 0.000 claims abstract description 6
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 229940048086 sodium pyrophosphate Drugs 0.000 claims abstract description 6
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims abstract description 6
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims abstract description 4
- 238000007761 roller coating Methods 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 230000001680 brushing effect Effects 0.000 claims abstract description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 12
- 239000011777 magnesium Substances 0.000 claims description 12
- 229910052749 magnesium Inorganic materials 0.000 claims description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 11
- 229910000166 zirconium phosphate Inorganic materials 0.000 claims description 10
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 claims description 10
- WTBZOQYZCMRMIO-UHFFFAOYSA-M [Br-].C(CCCCCCCCCCCCCCCCC)CC[N+](O)(O)C Chemical compound [Br-].C(CCCCCCCCCCCCCCCCC)CC[N+](O)(O)C WTBZOQYZCMRMIO-UHFFFAOYSA-M 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 7
- 229910000838 Al alloy Inorganic materials 0.000 claims description 6
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 4
- AISMNBXOJRHCIA-UHFFFAOYSA-N trimethylazanium;bromide Chemical compound Br.CN(C)C AISMNBXOJRHCIA-UHFFFAOYSA-N 0.000 claims description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 2
- HRHBQGBPZWNGHV-UHFFFAOYSA-N azane;bromomethane Chemical compound N.BrC HRHBQGBPZWNGHV-UHFFFAOYSA-N 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 10
- 229910052782 aluminium Inorganic materials 0.000 abstract description 10
- 239000004411 aluminium Substances 0.000 abstract description 7
- 230000000845 anti-microbial effect Effects 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 5
- 238000010276 construction Methods 0.000 abstract description 2
- 230000001953 sensory effect Effects 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 description 7
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000003921 oil Substances 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000031709 bromination Effects 0.000 description 3
- 238000005893 bromination reaction Methods 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- 241000588724 Escherichia coli Species 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- SDKTUKJXHDZWMB-UHFFFAOYSA-N phosphoric acid zirconium Chemical compound [Zr].P(O)(O)(O)=O SDKTUKJXHDZWMB-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 210000003739 neck Anatomy 0.000 description 1
- RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical class CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
- C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of antique copper colour code board, described antique copper colour code board is prepared from by the raw material of following weight parts: include base plate, and described backplate surface uses spraying, roller coating and/or brushing mode uniform application to have coppery coating modelled after an antique；Described coppery coating modelled after an antique is prepared from by the raw material of following weight parts: potassium silicate 35 45 parts, Ludox 12 18 parts, 3 (2 aminoethylamino) propyl trimethoxy silicane 13 parts, 3 (2,3 epoxy the third oxygen) propyl trimethoxy silicane 13 parts, sodium pyrophosphate 0.1 1 parts, 10 15 parts of bronze-colored pearlescent pigment powder, 30 50 parts of water, inorganic antiseptic 24 parts, 0.6 1.2 parts of antistatic additive.Antique copper colour code board of the present invention, processing step is simple, easy to process, and efficiency of construction is high, and the aluminium section bar after spraying has good anti-microbial property and antistatic property, and closely, sensory effects is good, has permanent weather resistance, and service life is long in coating attachment.
Description
Technical field
The present invention relates to aluminium type material technical field, particularly relate to a kind of antique copper colour code board.
Background technology
Shape, with the feature of durability, dicoration and the processing forming of its excellence, is widely used in building
Various aspects.And aluminium section bar is because of its feature such as excellent processing performance, light weight, consumption accounts for more than the 80% of shape.Aluminium section bar is made
One of principal item for aluminum processing material, is widely used in the dicoration of its uniqueness, excellent sound insulation, insulation and recuperability
Building field, and by its most extruded and higher mechanical and physical performance, good heat conductivility and higher ratio
The advantages such as intensity, are more and more widely used for the necks such as transportation, electronics, machinery, light industry, oil, chemical industry, Aeronautics and Astronautics
Territory.
In order to make aluminium section bar have better performance, it usually needs aluminium section bar is sprayed.The quality of spraying coating process, directly
Connect and affect the adhesive force of coating, outward appearance, the humidity of coating and the aspect such as corrosion-resistant, because of best film be all adhere to by
The surface conscientiously cleared up.It is loaded down with trivial details that spraying aluminum profile technique in the past not only walks sequence, and the lacquer painting of the surface of aluminum plate processed is the most not
Smooth, do not reach the requirement of client, visual effect is not good enough, haves much room for improvement.
The invention provides a kind of antique copper colour code board, there is antibacterial, the antistatic property of excellence.
Summary of the invention
For above-mentioned deficiency present in prior art, the technical problem to be solved is to provide a kind of antique copper
Colour code board.
The present invention seeks to be achieved through the following technical solutions:
A kind of antique copper colour code board, including base plate, described backplate surface uses spraying, roller coating and/or the mode of brushing uniform
It is coated with coppery coating modelled after an antique.
Preferably, described coppery coating modelled after an antique is prepared from by the raw material of following weight parts: potassium silicate 35-45 part, silicon are molten
Glue 12-18 part, 3-(2-aminoethylamino) propyl trimethoxy silicane 1-3 part, 3-(2,3-epoxy the third oxygen) propyl group trimethoxy
Base silane 1-3 part, sodium pyrophosphate 0.1-1 part, bronze-colored pearlescent pigment powder 10-15 part, water 30-50 part, inorganic antiseptic 2-4
Part, antistatic additive 0.6-1.2 part.
Preferably, described inorganic antiseptic is mixed by zirconium phosphate, magnesium titanate, magnesium-niobate, described zirconium phosphate, metatitanic acid
Magnesium, the mass ratio of magnesium-niobate are (1-3): (1-3): (1-3).
Preferably, described antistatic additive by double octadecyl methyl tertiary amines, octadecyl methyl dihydroxy ethyl ammonium bromide,
Dodecyl trimethyl ammonium chloride mixes, described pair of octadecyl methyl tertiary amine, octadecyl methyl dihydroxy ethyl bromination
Ammonium, the mass ratio of Dodecyl trimethyl ammonium chloride are (1-3): (1-3): (1-3).
Preferably, described potassium silicate modulus is 2.4-3.2.
Preferably, described Ludox particle diameter is 5.0-22.5nm.
Preferably, described base plate is aluminium alloy plate.
Present invention also offers the preparation method of above-mentioned antique copper colour code board, comprise the following steps:
(1) backplate surface is carried out oil removal treatment；
(2) coppery coating modelled after an antique is used spraying, roller coating and/or brushes mode uniform application base plate after oil removal treatment
Surface, then drying.
Antique copper colour code board of the present invention, processing step is simple, easy to process, and efficiency of construction is high, the aluminium section bar tool after spraying
Having good anti-microbial property and antistatic property, closely, sensory effects is good, has permanent weather resistance in coating attachment, uses
Life-span is long.
Detailed description of the invention
Each raw material introduction in embodiment:
Potassium silicate, No. CAS: 1312-76-1, modulus is 2.55.
Ludox, uses number of patent application: in 201210235302.8 prepared by the method for embodiment 2, particle diameter 8nm.
3-(2-aminoethylamino) propyl trimethoxy silicane, No. CAS: 1760-24-3.
3-(2,3-epoxy the third oxygen) propyl trimethoxy silicane, No. CAS: 2530-83-8.
Sodium pyrophosphate, No. CAS: 7722-88-5.
Bronze-colored pearlescent pigment powder, the model using An De Lun Science & technology Co., Ltd of Shenzhen to provide is the bronze-colored of L500
Pearlescent pigment, particle diameter is 10-15 μm.
Zirconium phosphate, No. CAS: 13772-29-7, particle diameter 20-40nm.
Magnesium titanate, No. CAS: 12032-35-8, particle diameter 20-40nm.
Magnesium-niobate, No. CAS: 12163-26-7, particle diameter 20-40nm.
Double octadecyl methyl tertiary amines, No. CAS: 4088-22-6.
Octadecyl methyl dihydroxy ethyl ammonium bromide, No. CAS: 97508-23-1.
Dodecyl trimethyl ammonium chloride, No. CAS: 1119-94-4.
Aluminium alloy plate, with reference to number of patent application: in 201310176055.3 prepared by the method for embodiment 1, thickness is 3mm,
A length of 0.8 meter, width is 0.4 meter.
Embodiment 1
Coppery coating raw material (weight portion) modelled after an antique: potassium silicate 40 parts, Ludox 15 parts, 3-(2-aminoethylamino) propyl group
Trimethoxy silane 1 part, 3-(2,3-epoxy the third oxygen) propyl trimethoxy silicane 1 part, sodium pyrophosphate 0.3 part, bronze-colored pearly-lustre
Pigment 12 parts, 40 parts of water, inorganic antiseptic 3 parts, 0.9 part of antistatic additive.
Described inorganic antiseptic is uniformly mixed for 1:1:1 in mass ratio by zirconium phosphate, magnesium titanate, magnesium-niobate
Arrive.
Described antistatic additive is by double octadecyl methyl tertiary amines, octadecyl methyl dihydroxy ethyl ammonium bromide, dodecane
Base trimethylammonium bromide is uniformly mixed for 1:1:1 in mass ratio and obtains.
Prepared by coppery coating modelled after an antique: 40 weight portion potassium silicates, at 20 DEG C, are joined in 25 weight parts waters by (1), to turn
Speed is 400 revs/min and stirs 15 minutes；Being subsequently adding 15 weight portion Ludox with rotating speed is 400 revs/min of stirrings 15 minutes；Add again
Enter 1 weight portion 3-(2-aminoethylamino) propyl trimethoxy silicane and 1 weight portion 3-(2,3-epoxy the third oxygen) propyl group front three
TMOS, is 400 revs/min with rotating speed and stirs 50 minutes, add 3 parts by weight of inorganic antibacterial, 0.9 weight portion antistatic additive
It is 400 revs/min with rotating speed to stir 10 minutes, prepares A liquid；(2) at 20 DEG C, by the 12 bronze-colored pearlescent pigments of weight portion, 0.3 weight
Amount part sodium pyrophosphate add in 17 weight parts waters with rotating speed be 400 revs/min stir 360 minutes, prepare B liquid；(3) B liquid is added
In A liquid, it is 400 revs/min with rotating speed stir 50 minutes；Obtain coppery coating modelled after an antique.
Present invention also offers the preparation method of above-mentioned antique copper colour code board, comprise the following steps:
(1) aluminium alloy plate being immersed in the electrochemical deoiling liquid of 80 DEG C immersion 5 minutes, wherein, electrochemical deoiling liquid is by 60 weights
Amount part sodium hydroxide, 30 parts by weight sodium carbonate, 35 parts by weight of phosphoric acid trisodiums join mix homogeneously in 1000 weight parts waters and obtain；
(2) coppery coating modelled after an antique is used spraying method uniform application aluminium alloy plate surface after oil removal treatment, spray
Pressure is 0.05Mpa, obtains paint film, and film thickness is 20 μm；By the aluminium alloy plate after spraying in the baking oven that temperature is 150 DEG C
After baking 5min, it is cooled to 30 DEG C.Obtain the antique copper colour code board of embodiment 1.
Embodiment 2
Substantially the same manner as Example 1, differ only in: described inorganic antiseptic is by magnesium titanate, magnesium-niobate in mass ratio
It is uniformly mixed for 1:1 and obtains.Obtain the antique copper colour code board of embodiment 2.
Embodiment 3
Substantially the same manner as Example 1, differ only in: described inorganic antiseptic is by zirconium phosphate, magnesium-niobate in mass ratio
It is uniformly mixed for 1:1 and obtains.Obtain the antique copper colour code board of embodiment 3.
Embodiment 4
Substantially the same manner as Example 1, differ only in: described inorganic antiseptic is by zirconium phosphate, magnesium titanate in mass ratio
It is uniformly mixed for 1:1 and obtains.Obtain the antique copper colour code board of embodiment 4.
Embodiment 5
Substantially the same manner as Example 1, differ only in: described antistatic additive is by octadecyl methyl dihydroxy ethyl bromination
Ammonium, Dodecyl trimethyl ammonium chloride are uniformly mixed for 1:1 in mass ratio and obtain.Obtain the antique copper colour code of embodiment 5
Board.
Embodiment 6
Substantially the same manner as Example 1, differ only in: described antistatic additive by double octadecyl methyl tertiary amines, 12
Alkyl trimethyl ammonium bromide is uniformly mixed for 1:1 in mass ratio and obtains.Obtain the antique copper colour code board of embodiment 6.
Embodiment 7
Substantially the same manner as Example 1, differ only in: described antistatic additive by double octadecyl methyl tertiary amines, 18
Alkyl methyl dihydroxy ethyl ammonium bromide is uniformly mixed for 1:1 in mass ratio and obtains.Obtain the antique copper colour code of embodiment 7
Board.
Test case 1
The anti-microbial property of the coppery coating modelled after an antique of embodiment 1-7 is tested, uses the detection of conventional microbiological sterilizing power,
Escherichia coli ATYCC 25922, staphylococcus aureus ATCC 6538.Concrete test result is shown in Table 1.
Table 1: the anti-microbial property test data of coppery coating modelled after an antique
| Escherichia coli sterilizing rate, % | Staphylococcus aureus sterilizing rate, % | |
| Embodiment 1 | 96.2 | 98.1 |
| Embodiment 2 | 92.4 | 92.9 |
| Embodiment 3 | 92.2 | 93.2 |
| Embodiment 4 | 93.1 | 93.0 |
| Embodiment 5 | 93.4 | 94.8 |
| Embodiment 6 | 93.7 | 95.4 |
| Embodiment 7 | 93.6 | 94.2 |
Comparing embodiment 1 and embodiment 2-4, in the case of inorganic antiseptic addition total amount is identical, embodiment 1 (phosphoric acid
Zirconium, magnesium titanate, magnesium-niobate are compounding) anti-microbial property be substantially better than embodiment 2-4 (in zirconium phosphate, magnesium titanate, magnesium-niobate arbitrarily the two
Compounding).Comparing embodiment 1 and embodiment 5-7, in the case of antistatic additive addition total amount is identical, embodiment 1 (double octadecanes
Ylmethyl tertiary amine, octadecyl methyl dihydroxy ethyl ammonium bromide, Dodecyl trimethyl ammonium chloride are compounding) anti-microbial property is the most excellent
In embodiment 5-7 (double octadecyl methyl tertiary amines, octadecyl methyl dihydroxy ethyl ammonium bromide, trimethyl bromination
In ammonium, arbitrarily the two is compounding).
Test case 2
The coating surface resistivity of embodiment 1-7 antique copper colour code board is tested, sheet resistance Shanghai the 6th electricity
The ZC36 type super-high resistance instrument that Watch Factory produces measures.Concrete outcome is shown in Table 2.
Table 2: the antistatic property test table of antique copper colour code board
Comparing embodiment 1 and embodiment 2-4, in the case of inorganic antiseptic addition total amount is identical, embodiment 1 (phosphoric acid
Zirconium, magnesium titanate, magnesium-niobate are compounding) antistatic property is substantially better than embodiment 2-4 (in zirconium phosphate, magnesium titanate, magnesium-niobate any two
Person compounds).Comparing embodiment 1 and embodiment 5-7, in the case of antistatic additive addition total amount is identical, embodiment 1 (double 18
Alkyl methyl tertiary amine, octadecyl methyl dihydroxy ethyl ammonium bromide, Dodecyl trimethyl ammonium chloride are compounding) antistatic property is bright
Show and be better than embodiment 5-7 (double octadecyl methyl tertiary amines, octadecyl methyl dihydroxy ethyl ammonium bromide, trimethyl
In ammonium bromide, arbitrarily the two is compounding).
Claims (4)
1. an antique copper colour code board, it is characterised in that: including base plate, described backplate surface uses spraying, roller coating and/or brushing
Mode uniform application has coppery coating modelled after an antique；
Described coppery coating modelled after an antique is prepared from by the raw material of following weight parts: potassium silicate 35-45 part, Ludox 12-18 part, 3-
(2-aminoethylamino) propyl trimethoxy silicane 1-3 part, 3-(2,3-epoxy the third oxygen) propyl trimethoxy silicane 1-3 part,
Sodium pyrophosphate 0.1-1 part, bronze-colored pearlescent pigment powder 10-15 part, water 30-50 part, inorganic antiseptic 2-4 part, antistatic additive
0.6-1.2 part.
Described inorganic antiseptic is mixed by zirconium phosphate, magnesium titanate, magnesium-niobate, described zirconium phosphate, magnesium titanate, magnesium-niobate
Mass ratio is (1-3): (1-3): (1-3).
Described antistatic additive is by double octadecyl methyl tertiary amines, octadecyl methyl dihydroxy ethyl ammonium bromide, dodecyl three
Methyl bromide ammonium mixes, described pair of octadecyl methyl tertiary amine, octadecyl methyl dihydroxy ethyl ammonium bromide, dodecyl
The mass ratio of trimethylammonium bromide is (1-3): (1-3): (1-3).
2. antique copper colour code board as claimed in claim 1, it is characterised in that: described potassium silicate modulus is 2.4-3.2.
3. antique copper colour code board as claimed in claim 1, it is characterised in that: described Ludox particle diameter is 5.0-22.5nm.
4. the antique copper colour code board as according to any one of claim 1-3, it is characterised in that: described base plate is aluminium alloy
Plate.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102408220A (en) * | 2011-08-08 | 2012-04-11 | 华南理工大学 | All-in-one water-borne inorganic-organic hybrid architectural coating and preparation method thereof |
| CN103665973A (en) * | 2013-12-11 | 2014-03-26 | 哈尔滨工业大学 | Preparation process of inorganic copper imitation coating and process for replacing protective and decorative copper layer of metal surface with inorganic copper imitation coating |
| CN104177877A (en) * | 2014-03-14 | 2014-12-03 | 哈尔滨蕴力达科技开发有限公司 | Inorganic silicate coating with both flexibility and heat resistance |
| CN105551373A (en) * | 2016-01-30 | 2016-05-04 | 安徽星光标识系统有限公司 | Manufacturing method of antique-brass technological label |
-
2016
- 2016-07-29 CN CN201610608518.2A patent/CN106084926B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102408220A (en) * | 2011-08-08 | 2012-04-11 | 华南理工大学 | All-in-one water-borne inorganic-organic hybrid architectural coating and preparation method thereof |
| CN103665973A (en) * | 2013-12-11 | 2014-03-26 | 哈尔滨工业大学 | Preparation process of inorganic copper imitation coating and process for replacing protective and decorative copper layer of metal surface with inorganic copper imitation coating |
| CN104177877A (en) * | 2014-03-14 | 2014-12-03 | 哈尔滨蕴力达科技开发有限公司 | Inorganic silicate coating with both flexibility and heat resistance |
| CN105551373A (en) * | 2016-01-30 | 2016-05-04 | 安徽星光标识系统有限公司 | Manufacturing method of antique-brass technological label |
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| CN106084926B (en) | 2018-05-15 |
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Effective date of registration: 20190128 Address after: 510080 No. 98 Guangcong Road, Yongping Street, Baiyun District, Guangzhou City, Guangdong Province Patentee after: Guangzhou Ruifeng Logo Engineering Co., Ltd. Address before: 200092 302, 3 Lane 248 lane, Tianbao West Road, Hongkou District, Shanghai. Patentee before: Wang Feifen |
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