CN106084869A - A kind of modified ion polymer metal composite and preparation method thereof - Google Patents
A kind of modified ion polymer metal composite and preparation method thereof Download PDFInfo
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- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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Abstract
The invention discloses a kind of modified ion polymer metal composite, it is prepared by the raw materials in: perfluorinated sulfonic acid 25 35 parts, N, N dimethylformamide 10 15 parts, aniline 59 parts, sodium borohydride 37 parts, oxammonium hydrochloride. 25 parts, imidazole radicals sodium tetrafluoroborate 37 parts, ilmenite 15 20 parts, platinum ammonium complex 10 15 parts, nikel powder 5 17 parts, copper powder 39 parts, lithium carbonate 6 12 parts, methyl benzotriazazole 23 parts, denaturant 35 parts, heat stabilizer 5 10 parts.The modified ion polymer metal composite being prepared from, its driving voltage is low, response speed is fast, deformational displacement is big.Meanwhile, corresponding preparation method is also disclosed.
Description
Technical field
The present invention relates to technical field of metal, particularly to a kind of modified ion polymer metal composite and
Preparation method.
Background technology
Along with the development of science and technology, the exploitation of novel intelligent material with apply promote in the reach of science play huge
Effect.These information materials include: piezoelectric ceramics, electromagnetism become liquid, current liquid, memorial alloy etc..But they because of
For having as deformation quantity is little, signal stimulus is relatively blunt, the extremely brittle shortcoming such as broken, bring to their promotion and application simultaneously
Limitation.
Ionic polymer metal composite material is a kind of emerging electric actuation composite, can produce under specific voltage
Bending Deformation, and then produce certain power output and output displacement, there is preferable pliability simultaneously, can appoint within the specific limits
Meaning cuts into the shape of needs.Ionic polymer metal composite material is carried out grinding widely as a kind of new things
Study carefully.The material similar with other is compared, and ionic polymer metal composite material preparation technology is simple, driving voltage is low, response
The advantages such as speed is fast, output displacement is big, noiselessness does not produce garbage environmental issue, pliability is good.So develop a entirely
The demand that new modified ion polymer metal composite tackles industry is relative particularly important with requirement.
Summary of the invention
For solving above-mentioned technical problem, the present invention provides a kind of modified ion polymer metal composite and preparation side thereof
Method, by using specified raw material to be combined, coordinates corresponding production technology, has obtained a kind of modified ion polymer metal multiple
Condensation material, its driving voltage is low, response speed is fast, deformational displacement is big, it is possible to meet the requirement of industry, before having preferably application
Scape.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of modified ion polymer metal composite, is prepared by the raw materials in: perfluorinated sulfonic acid 25-35 part, N,
Dinethylformamide 10-15 part, aniline 5-9 part, sodium borohydride 3-7 part, oxammonium hydrochloride. 2-5 part, imidazole radicals sodium tetrafluoroborate
3-7 part, ilmenite 15-20 part, platinum ammonium complex 10-15 part, nikel powder 5-17 part, copper powder 3-9 part, lithium carbonate 6-12 part, methyl
BTA 2-3 part, denaturant 3-5 part, heat stabilizer 5-10 part.
Preferably, described denaturant is selected from para hydroxybenzene amine, paranitrophenol, aminopropyl triethoxysilane, six Asias
One or more in tetramine.
Preferably, described heat stabilizer is selected from dioctyl adipate, propylene glycol methyl ether acetate, double isooctyl mercaptoacetate
One or more in dioctyltin, double acrylic acid fourth diester.
The preparation method of described modified ion polymer metal composite, comprises the following steps:
(1) each raw material is weighed according to weight portion；
(2) ilmenite, platinum ammonium complex, nikel powder, copper powder, lithium carbonate, methyl benzotriazazole, heat stabilizer are added mixing
Tank, stirs 3-5 hour with the speed of 1000-1500 rev/min, sends into high temperature furnace pre-burning, and calcined temperature is 500-700 DEG C, pre-burning
Time is 2-3 hour；
(3) again the mixture after preheating is added in ball mill, adds the isopropanol of mixture weight 20%, carry out ball
Mill processes, and obtains powder mixture；
(4) by perfluorinated sulfonic acid, N,N-dimethylformamide, aniline, sodium borohydride, oxammonium hydrochloride., imidazole radicals sodium tetrafluoroborate, change
Property agent add in ultrasonator, be uniformly dispersed under conditions of 50kHz, 250W, obtain mixed slurry；
(5) powder mixture that step (3) obtains is added in the mixed slurry that step (4) obtains, is stirring evenly and then adding into
Spray drying tower, inlet temperature is 500-600 DEG C, and outlet temperature is 220-280 DEG C, obtains granular material, then crosses 20 mesh
Sieve；
(6) it is compressing that mould put into by the material after sieving, and is directly placed in the cryostat of-30 DEG C cold by the material after molding
But 20-30 minute；
(7) molding materials after sub-cooled is sintered, is cooled to room temperature after having sintered, obtains finished product.
Preferably, being sintered to vacuum-sintering in step (7), vacuum is 1.5 × 10-1Pa, sintering temperature is 700-850
DEG C, sintering time is 2-3 hour.
Compared with prior art, it has the beneficial effect that the present invention
(1) the modified ion polymer metal composite of the present invention is with perfluorinated sulfonic acid, ilmenite, platinum ammonium complex, nikel powder, copper
Powder, lithium carbonate are main component, by adding methyl benzotriazazole, DMF, aniline, sodium borohydride, salt
Acid azanol, imidazole radicals sodium tetrafluoroborate, denaturant, heat stabilizer, be aided with high-temperature calcination, stirring ball-milling, ultrasonic disperse, dried
The techniques such as sieve, pressing mold cooling, sintering, machine-shaping so that the modified ion polymer metal composite being prepared from, it drives
Galvanic electricity forces down, response speed is fast, deformational displacement is big, it is possible to meet the requirement of industry, has preferable application prospect.
(2) the modified ion polymer metal composite cheaper starting materials of the present invention, technique simply, are suitable to large-scale industry
Change and use, practical.
Detailed description of the invention
Below in conjunction with specific embodiment, the technical scheme of invention is described in detail.
Embodiment 1
(1) weigh perfluorinated sulfonic acid 25 parts, N,N-dimethylformamide 10 parts, aniline 5 parts, sodium borohydride 3 parts, oxammonium hydrochloride. 2 parts,
Imidazole radicals sodium tetrafluoroborate 3 parts, ilmenite 15 parts, platinum ammonium complex 10 parts, nikel powder 5 parts, copper powder 3 parts, lithium carbonate 6 parts, methyl
BTA 2 parts, para hydroxybenzene amine 3 parts, dioctyl adipate 5 parts；
(2) ilmenite, platinum ammonium complex, nikel powder, copper powder, lithium carbonate, methyl benzotriazazole, dioctyl adipate are added mixed
Closing tank, stir 3 hours with the speed of 1000 revs/min, send into high temperature furnace pre-burning, calcined temperature is 500 DEG C, and burn-in time is 2 little
Time；
(3) again the mixture after preheating is added in ball mill, adds the isopropanol of mixture weight 20%, carry out ball
Mill processes, and obtains powder mixture；
(4) by perfluorinated sulfonic acid, N,N-dimethylformamide, aniline, sodium borohydride, oxammonium hydrochloride., imidazole radicals sodium tetrafluoroborate, right
Hydroxyanilines adds in ultrasonator, is uniformly dispersed, obtains mixed slurry under conditions of 50kHz, 250W；
(5) powder mixture that step (3) obtains is added in the mixed slurry that step (4) obtains, is stirring evenly and then adding into
Spray drying tower, inlet temperature is 500 DEG C, and outlet temperature is 220 DEG C, obtains granular material, then crosses 20 mesh sieves；
(6) it is compressing that mould put into by the material after sieving, and is directly placed in the cryostat of-30 DEG C cold by the material after molding
But 20 minutes；
(7) molding materials after sub-cooled is sintered, is cooled to room temperature after having sintered, obtains finished product, be sintered to true
Empty sintering, vacuum is 1.5 × 10-1Pa, sintering temperature is 700 DEG C, and sintering time is 2 hours.
The performance test results of the modified ion polymer metal composite prepared is as shown in table 1.
Embodiment 2
(1) perfluorinated sulfonic acid 29 parts, N,N-dimethylformamide 102 parts, aniline 7 parts, sodium borohydride 4 parts, oxammonium hydrochloride. 3 are weighed
Part, imidazole radicals sodium tetrafluoroborate 4 parts, ilmenite 17 parts, platinum ammonium complex 12 parts, nikel powder 9 parts, copper powder 5 parts, lithium carbonate 8 parts, first
Base BTA 2 parts, paranitrophenol 4 parts, propylene glycol methyl ether acetate 7 parts；
(2) ilmenite, platinum ammonium complex, nikel powder, copper powder, lithium carbonate, methyl benzotriazazole, propylene glycol methyl ether acetate are added
Entering blending tank, stir 4 hours with the speed of 1200 revs/min, send into high temperature furnace pre-burning, calcined temperature is 550 DEG C, and burn-in time is
2.4 hour；
(3) again the mixture after preheating is added in ball mill, adds the isopropanol of mixture weight 20%, carry out ball
Mill processes, and obtains powder mixture；
(4) by perfluorinated sulfonic acid, N,N-dimethylformamide, aniline, sodium borohydride, oxammonium hydrochloride., imidazole radicals sodium tetrafluoroborate, right
Nitrophenol adds in ultrasonator, is uniformly dispersed, obtains mixed slurry under conditions of 50kHz, 250W；
(5) powder mixture that step (3) obtains is added in the mixed slurry that step (4) obtains, is stirring evenly and then adding into
Spray drying tower, inlet temperature is 530 DEG C, and outlet temperature is 240 DEG C, obtains granular material, then crosses 20 mesh sieves；
(6) it is compressing that mould put into by the material after sieving, and is directly placed in the cryostat of-30 DEG C cold by the material after molding
But 24 minutes；
(7) molding materials after sub-cooled is sintered, is cooled to room temperature after having sintered, obtains finished product, be sintered to true
Empty sintering, vacuum is 1.5 × 10-1Pa, sintering temperature is 750 DEG C, and sintering time is 2.4 hours.
The performance test results of the modified ion polymer metal composite prepared is as shown in table 1.
Embodiment 3
(1) weigh perfluorinated sulfonic acid 32 parts, N,N-dimethylformamide 14 parts, aniline 8 parts, sodium borohydride 6 parts, oxammonium hydrochloride. 4 parts,
Imidazole radicals sodium tetrafluoroborate 6 parts, ilmenite 18 parts, platinum ammonium complex 14 parts, nikel powder 15 parts, copper powder 8 parts, lithium carbonate 10 parts, first
Base BTA 3 parts, aminopropyl triethoxysilane 4 parts, Imarcaptoacetate dioctyltin 8 parts；
(2) by ilmenite, platinum ammonium complex, nikel powder, copper powder, lithium carbonate, methyl benzotriazazole, double isooctyl mercaptoacetate two
N-octyl stannum adds blending tank, stirs 4.5 hours with the speed of 1400 revs/min, sends into high temperature furnace pre-burning, and calcined temperature is 600
DEG C, burn-in time is 2.8 hours；
(3) again the mixture after preheating is added in ball mill, adds the isopropanol of mixture weight 20%, carry out ball
Mill processes, and obtains powder mixture；
(4) by perfluorinated sulfonic acid, N,N-dimethylformamide, aniline, sodium borohydride, oxammonium hydrochloride., imidazole radicals sodium tetrafluoroborate, ammonia
Propyl-triethoxysilicane adds in ultrasonator, is uniformly dispersed, obtains mixed slurry under conditions of 50kHz, 250W；
(5) powder mixture that step (3) obtains is added in the mixed slurry that step (4) obtains, is stirring evenly and then adding into
Spray drying tower, inlet temperature is 580 DEG C, and outlet temperature is 260 DEG C, obtains granular material, then crosses 20 mesh sieves；
(6) it is compressing that mould put into by the material after sieving, and is directly placed in the cryostat of-30 DEG C cold by the material after molding
But 28 minutes；
(7) molding materials after sub-cooled is sintered, is cooled to room temperature after having sintered, obtains finished product, be sintered to true
Empty sintering, vacuum is 1.5 × 10-1Pa, sintering temperature is 800 DEG C, and sintering time is 2.8 hours.
The performance test results of the modified ion polymer metal composite prepared is as shown in table 1.
Embodiment 4
(1) weigh perfluorinated sulfonic acid 35 parts, N,N-dimethylformamide 15 parts, aniline 9 parts, sodium borohydride 7 parts, oxammonium hydrochloride. 5 parts,
Imidazole radicals sodium tetrafluoroborate 7 parts, ilmenite 20 parts, platinum ammonium complex 15 parts, nikel powder 17 parts, copper powder 9 parts, lithium carbonate 12 parts, first
Base BTA 3 parts, hexamethylenetetramine 5 parts, double acrylic acid fourth diester 10 parts；
(2) ilmenite, platinum ammonium complex, nikel powder, copper powder, lithium carbonate, methyl benzotriazazole, double acrylic acid fourth diester are added
Blending tank, stirs 5 hours with the speed of 1500 revs/min, sends into high temperature furnace pre-burning, and calcined temperature is 700 DEG C, and burn-in time is 3
Hour；
(3) again the mixture after preheating is added in ball mill, adds the isopropanol of mixture weight 20%, carry out ball
Mill processes, and obtains powder mixture；
(4) by perfluorinated sulfonic acid, N,N-dimethylformamide, aniline, sodium borohydride, oxammonium hydrochloride., imidazole radicals sodium tetrafluoroborate, six
Methenamine adds in ultrasonator, is uniformly dispersed, obtains mixed slurry under conditions of 50kHz, 250W；
(5) powder mixture that step (3) obtains is added in the mixed slurry that step (4) obtains, is stirring evenly and then adding into
Spray drying tower, inlet temperature is 600 DEG C, and outlet temperature is 280 DEG C, obtains granular material, then crosses 20 mesh sieves；
(6) it is compressing that mould put into by the material after sieving, and is directly placed in the cryostat of-30 DEG C cold by the material after molding
But 30 minutes；
(7) molding materials after sub-cooled is sintered, is cooled to room temperature after having sintered, obtains finished product, be sintered to true
Empty sintering, vacuum is 1.5 × 10-1Pa, sintering temperature is 850 DEG C, and sintering time is 3 hours.
The performance test results of the modified ion polymer metal composite prepared is as shown in table 1.
Comparative example 1
(1) weigh perfluorinated sulfonic acid 25 parts, aniline 5 parts, sodium borohydride 3 parts, oxammonium hydrochloride. 2 parts, imidazole radicals sodium tetrafluoroborate 3 parts,
Ilmenite 15 parts, platinum ammonium complex 10 parts, nikel powder 5 parts, copper powder 3 parts, lithium carbonate 6 parts, para hydroxybenzene amine 3 parts, adipic acid two are pungent
Ester 5 parts；
(2) by ilmenite, platinum ammonium complex, nikel powder, copper powder, lithium carbonate, dioctyl adipate add blending tank, with 1000 turns/
The speed divided stirs 3 hours, sends into high temperature furnace pre-burning, and calcined temperature is 500 DEG C, and burn-in time is 2 hours；
(3) again the mixture after preheating is added in ball mill, adds the isopropanol of mixture weight 20%, carry out ball
Mill processes, and obtains powder mixture；
(4) perfluorinated sulfonic acid, aniline, sodium borohydride, oxammonium hydrochloride., imidazole radicals sodium tetrafluoroborate, para hydroxybenzene amine are added ultrasonic
In oscillator, it is uniformly dispersed under conditions of 50kHz, 250W, obtains mixed slurry；
(5) powder mixture that step (3) obtains is added in the mixed slurry that step (4) obtains, is stirring evenly and then adding into
Spray drying tower, inlet temperature is 500 DEG C, and outlet temperature is 220 DEG C, obtains granular material, then crosses 20 mesh sieves；
(6) it is compressing that mould put into by the material after sieving, and is directly placed in the cryostat of-30 DEG C cold by the material after molding
But 20 minutes；
(7) molding materials after sub-cooled is sintered, is cooled to room temperature after having sintered, obtains finished product, be sintered to true
Empty sintering, vacuum is 1.5 × 10-1Pa, sintering temperature is 700 DEG C, and sintering time is 2 hours.
The performance test results of the modified ion polymer metal composite prepared is as shown in table 1.
Comparative example 2
(1) weigh perfluorinated sulfonic acid 35 parts, N,N-dimethylformamide 15 parts, oxammonium hydrochloride. 5 parts, imidazole radicals sodium tetrafluoroborate 7 parts,
Ilmenite 20 parts, platinum ammonium complex 15 parts, nikel powder 17 parts, copper powder 9 parts, methyl benzotriazazole 3 parts, hexamethylenetetramine 5 parts,
Double acrylic acid fourth diester 10 parts；
(2) ilmenite, platinum ammonium complex, nikel powder, copper powder, methyl benzotriazazole, double acrylic acid fourth diester are added blending tank,
Stirring 5 hours with the speed of 1500 revs/min, send into high temperature furnace pre-burning, calcined temperature is 700 DEG C, and burn-in time is 3 hours；
(3) again the mixture after preheating is added in ball mill, adds the isopropanol of mixture weight 20%, carry out ball
Mill processes, and obtains powder mixture；
(4) perfluorinated sulfonic acid, N,N-dimethylformamide, oxammonium hydrochloride., imidazole radicals sodium tetrafluoroborate, hexamethylenetetramine are added
In ultrasonator, it is uniformly dispersed under conditions of 50kHz, 250W, obtains mixed slurry；
(5) powder mixture that step (3) obtains is added in the mixed slurry that step (4) obtains, is stirring evenly and then adding into
Spray drying tower, inlet temperature is 600 DEG C, and outlet temperature is 280 DEG C, obtains granular material, then crosses 20 mesh sieves；
(6) it is compressing that mould put into by the material after sieving, and is directly placed in the cryostat of-30 DEG C cold by the material after molding
But 30 minutes；
(7) molding materials after sub-cooled is sintered, is cooled to room temperature after having sintered, obtains finished product, be sintered to true
Empty sintering, vacuum is 1.5 × 10-1Pa, sintering temperature is 850 DEG C, and sintering time is 3 hours.
The performance test results of the modified ion polymer metal composite prepared is as shown in table 1.
The modified ion polymer metal composite of embodiment 1-4 and comparative example 1-2 is driven respectively voltage, anti-
Answer speed, the test of deformational displacement performance.
Table 1
| Driving voltage/V | Response speed/microsecond | Deformational displacement/% | |
| Embodiment 1 | 2.1 | 3550 | 18.5 |
| Embodiment 2 | 1.9 | 4094 | 19.7 |
| Embodiment 3 | 1.8 | 3864 | 20.6 |
| Embodiment 4 | 1.9 | 3752 | 20.8 |
| Comparative example 1 | 4.5 | 978560 | 5.6 |
| Comparative example 2 | 5.3 | 387651 | 8.4 |
The modified ion polymer metal composite of the present invention with perfluorinated sulfonic acid, ilmenite, platinum ammonium complex, nikel powder, copper powder,
Lithium carbonate is main component, by adding methyl benzotriazazole, DMF, aniline, sodium borohydride, hydrochloric acid hydroxyl
Amine, imidazole radicals sodium tetrafluoroborate, denaturant, heat stabilizer, be aided with high-temperature calcination, stirring ball-milling, ultrasonic disperse, drying and screening,
The techniques such as pressing mold cooling, sintering, machine-shaping so that the modified ion polymer metal composite being prepared from, it drives
Voltage is low, response speed is fast, deformational displacement is big, it is possible to meet the requirement of industry, has preferable application prospect.The present invention changes
Property ionic polymer metal composite material cheaper starting materials, technique simple, being suitable to heavy industrialization uses, practical.
The foregoing is only embodiments of the invention, not thereby limit the scope of the claims of the present invention, every utilize this
Equivalent structure or equivalence flow process that bright description is made convert, or are directly or indirectly used in other relevant technology necks
Territory, is the most in like manner included in the scope of patent protection of the present invention.
Claims (5)
1. a modified ion polymer metal composite, it is characterised in that: it is prepared by the raw materials in: perfluor sulphur
Acid 25-35 part, N,N-dimethylformamide 10-15 part, aniline 5-9 part, sodium borohydride 3-7 part, oxammonium hydrochloride. 2-5 part, imidazoles
Base sodium tetrafluoroborate 3-7 part, ilmenite 15-20 part, platinum ammonium complex 10-15 part, nikel powder 5-17 part, copper powder 3-9 part, lithium carbonate
6-12 part, methyl benzotriazazole 2-3 part, denaturant 3-5 part, heat stabilizer 5-10 part.
Modified ion polymer metal composite the most according to claim 1, it is characterised in that: described denaturant choosing
One or more in para hydroxybenzene amine, paranitrophenol, aminopropyl triethoxysilane, hexamethylenetetramine.
Modified ion polymer metal composite the most according to claim 1, it is characterised in that: described heat stabilizer selects
In dioctyl adipate, propylene glycol methyl ether acetate, Imarcaptoacetate dioctyltin, double acrylic acid fourth diester
One or more.
4., according to the preparation method of the arbitrary described modified ion polymer metal composite of claim 1-3, its feature exists
In, comprise the following steps:
(1) each raw material is weighed according to weight portion；
(2) ilmenite, platinum ammonium complex, nikel powder, copper powder, lithium carbonate, methyl benzotriazazole, heat stabilizer are added mixing
Tank, stirs 3-5 hour with the speed of 1000-1500 rev/min, sends into high temperature furnace pre-burning, and calcined temperature is 500-700 DEG C, pre-burning
Time is 2-3 hour；
(3) again the mixture after preheating is added in ball mill, adds the isopropanol of mixture weight 20%, carry out ball
Mill processes, and obtains powder mixture；
(4) by perfluorinated sulfonic acid, N,N-dimethylformamide, aniline, sodium borohydride, oxammonium hydrochloride., imidazole radicals sodium tetrafluoroborate, change
Property agent add in ultrasonator, be uniformly dispersed under conditions of 50kHz, 250W, obtain mixed slurry；
(5) powder mixture that step (3) obtains is added in the mixed slurry that step (4) obtains, is stirring evenly and then adding into
Spray drying tower, inlet temperature is 500-600 DEG C, and outlet temperature is 220-280 DEG C, obtains granular material, then crosses 20 mesh
Sieve；
(6) it is compressing that mould put into by the material after sieving, and is directly placed in the cryostat of-30 DEG C cold by the material after molding
But 20-30 minute；
(7) molding materials after sub-cooled is sintered, is cooled to room temperature after having sintered, obtains finished product.
Preparation method the most according to claim 4, it is characterised in that be sintered to vacuum-sintering, vacuum in step (7)
It is 1.5 × 10-1Pa, sintering temperature is 700-850 DEG C, and sintering time is 2-3 hour.
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Application publication date: 20161109 |