CN106084630A - A kind of decoration sound insulation environment-friendly materials and preparation method thereof - Google Patents

A kind of decoration sound insulation environment-friendly materials and preparation method thereof Download PDF

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Publication number
CN106084630A
CN106084630A CN201610404607.5A CN201610404607A CN106084630A CN 106084630 A CN106084630 A CN 106084630A CN 201610404607 A CN201610404607 A CN 201610404607A CN 106084630 A CN106084630 A CN 106084630A
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parts
polyacrylamide
zinc fluosilicate
sound insulation
friendly materials
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CN201610404607.5A
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CN106084630B (en
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刘高志
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Guangdong Sichuang Building Materials Technology Co.,Ltd.
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刘高志
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/12Applications used for fibers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

The invention discloses a kind of decoration sound insulation environment-friendly materials and preparation method thereof, be prepared from by the raw material of following weight portion: thermoplastic phenolic resin, 45~55 parts;Expanded vermiculite, 20~30 parts;Polystyrene foam plastics, 6~8 parts;Isobutyl triethoxy silane, 2~4 parts;Nano carbon black, 1~3 part;Nano silicon, 2~4 parts;Bentonite, 3~5 parts;Antioxidant 264,0.2~0.6 part;Aluminium isopropoxide, 0.6~0.8 part;Pentaerythritol ester, 6~8 parts;Polyacrylamide and zinc fluosilicate totally 4~6 parts, the weight ratio of polyacrylamide and zinc fluosilicate is 3~5:1.The decoration sound insulation environment-friendly materials that the present invention provides have outstanding sound insulation value, and this effect is relevant with the weight part ratio of polyacrylamide in raw material and zinc fluosilicate, and when the weight ratio of polyacrylamide and zinc fluosilicate is 3~5:1, soundproof effect is optimum.

Description

A kind of decoration sound insulation environment-friendly materials and preparation method thereof
Technical field
The invention belongs to environment-friendly materials field, be specifically related to a kind of decoration sound insulation environment-friendly materials and preparation method thereof.
Background technology
With the continuous acceleration of urbanization, noise pollution also becomes increasingly severe.In order to effectively cut off noise, generally Settling mode be use acoustic material.Existing acoustic material is generally cement concrete, glass plate etc., these acoustic materials Soundproof effect be not very well, therefore common solution is to strengthen the thickness of acoustic material.The problem so causing is Acoustic material quality is overweight, high cost, and installation process is inconvenient for.
Content of the invention
It is an object of the invention to provide a kind of decoration sound insulation environment-friendly materials and preparation method thereof.
The above-mentioned purpose of the present invention is achieved by techniques below scheme:
Sound insulation environment-friendly materials are used in a kind of decoration, are prepared from by the raw material of following weight portion: thermoplastic phenolic resin, 45 ~55 parts;Expanded vermiculite, 20~30 parts;Polystyrene foam plastics, 6~8 parts;Isobutyl triethoxy silane, 2~4 parts;Receive Rice carbon black, 1~3 part;Nano silicon, 2~4 parts;Bentonite, 3~5 parts;Antioxidant 264,0.2~0.6 part;Three isopropyl oxygen Base aluminium, 0.6~0.8 part;Pentaerythritol ester, 6~8 parts;Polyacrylamide and zinc fluosilicate totally 4~6 parts, polyacrylamide and fluorine The weight ratio of zinc silicate is 3~5:1.
Further, described decoration sound insulation environment-friendly materials are prepared from by the raw material of following weight portion: thermoplasticity phenol Urea formaldehyde, 50 parts;Expanded vermiculite, 25 parts;Polystyrene foam plastics, 7 parts;Isobutyl triethoxy silane, 3 parts;Nano carbon Black, 2 parts;Nano silicon, 3 parts;Bentonite, 4 parts;Antioxidant 264,0.4 part;Aluminium isopropoxide, 0.7 part;Ji Wusi Alcohol ester, 7 parts;Polyacrylamide and zinc fluosilicate totally 5 parts, the weight ratio of polyacrylamide and zinc fluosilicate is 4:1.
Further, described decoration sound insulation environment-friendly materials are prepared from by the raw material of following weight portion: thermoplasticity phenol Urea formaldehyde, 45 parts;Expanded vermiculite, 20 parts;Polystyrene foam plastics, 6 parts;Isobutyl triethoxy silane, 2 parts;Nano carbon Black, 1 part;Nano silicon, 2 parts;Bentonite, 3 parts;Antioxidant 264,0.2 part;Aluminium isopropoxide, 0.6 part;Ji Wusi Alcohol ester, 6 parts;Polyacrylamide and zinc fluosilicate totally 4 parts, the weight ratio of polyacrylamide and zinc fluosilicate is 3:1.
Further, described decoration sound insulation environment-friendly materials are prepared from by the raw material of following weight portion: thermoplasticity phenol Urea formaldehyde, 55 parts;Expanded vermiculite, 30 parts;Polystyrene foam plastics, 8 parts;Isobutyl triethoxy silane, 4 parts;Nano carbon Black, 3 parts;Nano silicon, 4 parts;Bentonite, 5 parts;Antioxidant 264,0.6 part;Aluminium isopropoxide, 0.8 part;Ji Wusi Alcohol ester, 8 parts;Polyacrylamide and zinc fluosilicate totally 6 parts, the weight ratio of polyacrylamide and zinc fluosilicate is 5:1.
The preparation method of above-mentioned decoration sound insulation environment-friendly materials, comprises the steps:
Step S1, by nano carbon black, nano silicon, expanded vermiculite, aluminium isopropoxide, zinc fluosilicate, isobutyl group Triethoxysilane mixed grinding disperses 1~2h, and gained material mixes with other surplus stocks, puts into double after stirring Screw extruder melt extrudes granulation at a temperature of 180~190 DEG C, obtains master batch;
Above-mentioned master batch is put in screw extruder melted at 170~190 DEG C by step S2, melt through temperature be 220~ 240 DEG C meltblown beam spinneret orifice ejection, and stretch under the high velocity, hot air stream effect of 250~270 DEG C laggard enter receive dress Put and get final product.
Advantages of the present invention:
The decoration sound insulation environment-friendly materials that the present invention provides have an outstanding sound insulation value, in this effect and raw material poly-third Acrylamide is relevant with the weight part ratio of zinc fluosilicate, the sound insulation when weight ratio of polyacrylamide and zinc fluosilicate is 3~5:1 Effect is optimum.
Detailed description of the invention
Further illustrate the essentiality content of the present invention below in conjunction with embodiment, but do not limit the present invention with this and protect model Enclose.Although the present invention being explained in detail with reference to preferred embodiment, it will be understood by those within the art that, can be right Technical scheme is modified or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Embodiment 1: the decoration preparation of sound insulation environment-friendly materials
Parts by weight of raw materials compares:
Thermoplastic phenolic resin, 50 parts;Expanded vermiculite, 25 parts;Polystyrene foam plastics, 7 parts;Isobutyl group triethoxy Silane, 3 parts;Nano carbon black, 2 parts;Nano silicon, 3 parts;Bentonite, 4 parts;Antioxidant 264,0.4 part;Three isopropoxies Aluminium, 0.7 part;Pentaerythritol ester, 7 parts;Polyacrylamide and zinc fluosilicate totally 5 parts, the weight of polyacrylamide and zinc fluosilicate The ratio of part is 4:1.
Preparation method:
Step S1, by nano carbon black, nano silicon, expanded vermiculite, aluminium isopropoxide, zinc fluosilicate, isobutyl group Triethoxysilane mixed grinding disperses 1.5h, and gained material mixes with other surplus stocks, puts into double after stirring Screw extruder melt extrudes granulation at a temperature of 185 DEG C, obtains master batch;
Above-mentioned master batch is put in screw extruder melted at 180 DEG C by step S2, and melt is 230 DEG C molten through temperature Jet mould head spinneret orifice sprays, and stretches laggard to enter receive device and get final product under the high velocity, hot air stream effect of 260 DEG C.
Embodiment 2: the decoration preparation of sound insulation environment-friendly materials
Parts by weight of raw materials compares:
Thermoplastic phenolic resin, 45 parts;Expanded vermiculite, 20 parts;Polystyrene foam plastics, 6 parts;Isobutyl group triethoxy Silane, 2 parts;Nano carbon black, 1 part;Nano silicon, 2 parts;Bentonite, 3 parts;Antioxidant 264,0.2 part;Three isopropoxies Aluminium, 0.6 part;Pentaerythritol ester, 6 parts;Polyacrylamide and zinc fluosilicate totally 4 parts, the weight of polyacrylamide and zinc fluosilicate The ratio of part is 3:1.
Preparation method:
Step S1, by nano carbon black, nano silicon, expanded vermiculite, aluminium isopropoxide, zinc fluosilicate, isobutyl group Triethoxysilane mixed grinding disperses 1.5h, and gained material mixes with other surplus stocks, puts into double after stirring Screw extruder melt extrudes granulation at a temperature of 185 DEG C, obtains master batch;
Above-mentioned master batch is put in screw extruder melted at 180 DEG C by step S2, and melt is 230 DEG C molten through temperature Jet mould head spinneret orifice sprays, and stretches laggard to enter receive device and get final product under the high velocity, hot air stream effect of 260 DEG C.
Embodiment 3: the decoration preparation of sound insulation environment-friendly materials
Parts by weight of raw materials compares:
Thermoplastic phenolic resin, 55 parts;Expanded vermiculite, 30 parts;Polystyrene foam plastics, 8 parts;Isobutyl group triethoxy Silane, 4 parts;Nano carbon black, 3 parts;Nano silicon, 4 parts;Bentonite, 5 parts;Antioxidant 264,0.6 part;Three isopropoxies Aluminium, 0.8 part;Pentaerythritol ester, 8 parts;Polyacrylamide and zinc fluosilicate totally 6 parts, the weight of polyacrylamide and zinc fluosilicate The ratio of part is 5:1.
Preparation method:
Step S1, by nano carbon black, nano silicon, expanded vermiculite, aluminium isopropoxide, zinc fluosilicate, isobutyl group Triethoxysilane mixed grinding disperses 1.5h, and gained material mixes with other surplus stocks, puts into double after stirring Screw extruder melt extrudes granulation at a temperature of 185 DEG C, obtains master batch;
Above-mentioned master batch is put in screw extruder melted at 180 DEG C by step S2, and melt is 230 DEG C molten through temperature Jet mould head spinneret orifice sprays, and stretches laggard to enter receive device and get final product under the high velocity, hot air stream effect of 260 DEG C.
Embodiment 4: the decoration preparation of sound insulation environment-friendly materials
Parts by weight of raw materials compares:
Thermoplastic phenolic resin, 50 parts;Expanded vermiculite, 25 parts;Polystyrene foam plastics, 7 parts;Isobutyl group triethoxy Silane, 3 parts;Nano carbon black, 2 parts;Nano silicon, 3 parts;Bentonite, 4 parts;Antioxidant 264,0.4 part;Three isopropoxies Aluminium, 0.7 part;Pentaerythritol ester, 7 parts;Polyacrylamide and zinc fluosilicate totally 5 parts, the weight of polyacrylamide and zinc fluosilicate The ratio of part is 3:1.
Preparation method:
Step S1, by nano carbon black, nano silicon, expanded vermiculite, aluminium isopropoxide, zinc fluosilicate, isobutyl group Triethoxysilane mixed grinding disperses 1.5h, and gained material mixes with other surplus stocks, puts into double after stirring Screw extruder melt extrudes granulation at a temperature of 185 DEG C, obtains master batch;
Above-mentioned master batch is put in screw extruder melted at 180 DEG C by step S2, and melt is 230 DEG C molten through temperature Jet mould head spinneret orifice sprays, and stretches laggard to enter receive device and get final product under the high velocity, hot air stream effect of 260 DEG C.
Embodiment 5: the decoration preparation of sound insulation environment-friendly materials
Parts by weight of raw materials compares:
Thermoplastic phenolic resin, 50 parts;Expanded vermiculite, 25 parts;Polystyrene foam plastics, 7 parts;Isobutyl group triethoxy Silane, 3 parts;Nano carbon black, 2 parts;Nano silicon, 3 parts;Bentonite, 4 parts;Antioxidant 264,0.4 part;Three isopropoxies Aluminium, 0.7 part;Pentaerythritol ester, 7 parts;Polyacrylamide and zinc fluosilicate totally 5 parts, the weight of polyacrylamide and zinc fluosilicate The ratio of part is 5:1.
Preparation method:
Step S1, by nano carbon black, nano silicon, expanded vermiculite, aluminium isopropoxide, zinc fluosilicate, isobutyl group Triethoxysilane mixed grinding disperses 1.5h, and gained material mixes with other surplus stocks, puts into double after stirring Screw extruder melt extrudes granulation at a temperature of 185 DEG C, obtains master batch;
Above-mentioned master batch is put in screw extruder melted at 180 DEG C by step S2, and melt is 230 DEG C molten through temperature Jet mould head spinneret orifice sprays, and stretches laggard to enter receive device and get final product under the high velocity, hot air stream effect of 260 DEG C.
The weight ratio of embodiment 6: comparative example, polyacrylamide and zinc fluosilicate is 2:1
Parts by weight of raw materials compares:
Thermoplastic phenolic resin, 50 parts;Expanded vermiculite, 25 parts;Polystyrene foam plastics, 7 parts;Isobutyl group triethoxy Silane, 3 parts;Nano carbon black, 2 parts;Nano silicon, 3 parts;Bentonite, 4 parts;Antioxidant 264,0.4 part;Three isopropoxies Aluminium, 0.7 part;Pentaerythritol ester, 7 parts;Polyacrylamide and zinc fluosilicate totally 5 parts, the weight of polyacrylamide and zinc fluosilicate The ratio of part is 2:1.
Preparation method:
Step S1, by nano carbon black, nano silicon, expanded vermiculite, aluminium isopropoxide, zinc fluosilicate, isobutyl group Triethoxysilane mixed grinding disperses 1.5h, and gained material mixes with other surplus stocks, puts into double after stirring Screw extruder melt extrudes granulation at a temperature of 185 DEG C, obtains master batch;
Above-mentioned master batch is put in screw extruder melted at 180 DEG C by step S2, and melt is 230 DEG C molten through temperature Jet mould head spinneret orifice sprays, and stretches laggard to enter receive device and get final product under the high velocity, hot air stream effect of 260 DEG C.
The weight ratio of embodiment 7: comparative example, polyacrylamide and zinc fluosilicate is 6:1
Parts by weight of raw materials compares:
Thermoplastic phenolic resin, 50 parts;Expanded vermiculite, 25 parts;Polystyrene foam plastics, 7 parts;Isobutyl group triethoxy Silane, 3 parts;Nano carbon black, 2 parts;Nano silicon, 3 parts;Bentonite, 4 parts;Antioxidant 264,0.4 part;Three isopropoxies Aluminium, 0.7 part;Pentaerythritol ester, 7 parts;Polyacrylamide and zinc fluosilicate totally 5 parts, the weight of polyacrylamide and zinc fluosilicate The ratio of part is 6:1.
Preparation method:
Step S1, by nano carbon black, nano silicon, expanded vermiculite, aluminium isopropoxide, zinc fluosilicate, isobutyl group Triethoxysilane mixed grinding disperses 1.5h, and gained material mixes with other surplus stocks, puts into double after stirring Screw extruder melt extrudes granulation at a temperature of 185 DEG C, obtains master batch;
Above-mentioned master batch is put in screw extruder melted at 180 DEG C by step S2, and melt is 230 DEG C molten through temperature Jet mould head spinneret orifice sprays, and stretches laggard to enter receive device and get final product under the high velocity, hot air stream effect of 260 DEG C.
Embodiment 8: effect example
The performance of the acoustic material of testing example 1~7 preparation respectively, result such as following table.
Sound insulation coefficient (frequency of sound wave is 5KHz)
Embodiment 1 1.91
Embodiment 4 1.85
Embodiment 5 1.87
Embodiment 6 0.94
Embodiment 7 0.97
Embodiment the 2nd, 3 test results and embodiment are the 4th, 5 basically identical.
Above-mentioned result of the test shows, the decoration sound insulation environment-friendly materials that the present invention provides have outstanding sound insulation value, this Plant effect relevant with the weight part ratio of polyacrylamide in raw material and zinc fluosilicate, the weight portion of polyacrylamide and zinc fluosilicate Ratio when being 3~5:1 soundproof effect optimum.
The effect of above-described embodiment indicates that the essentiality content of the present invention, but does not limit the protection of the present invention with this Scope.It will be understood by those within the art that, technical scheme can be modified or equivalent, Essence and protection domain without deviating from technical solution of the present invention.

Claims (5)

1. sound insulation environment-friendly materials are used in a decoration, it is characterised in that be prepared from by the raw material of following weight portion: thermoplasticity phenol Urea formaldehyde, 45~55 parts;Expanded vermiculite, 20~30 parts;Polystyrene foam plastics, 6~8 parts;Isobutyl triethoxy silane, 2~4 parts;Nano carbon black, 1~3 part;Nano silicon, 2~4 parts;Bentonite, 3~5 parts;Antioxidant 264,0.2~0.6 Part;Aluminium isopropoxide, 0.6~0.8 part;Pentaerythritol ester, 6~8 parts;Polyacrylamide and zinc fluosilicate totally 4~6 parts, poly- The weight ratio of acrylamide and zinc fluosilicate is 3~5:1.
2. decoration sound insulation environment-friendly materials according to claim 1, it is characterised in that by the raw material system of following weight portion Standby form: thermoplastic phenolic resin, 50 parts;Expanded vermiculite, 25 parts;Polystyrene foam plastics, 7 parts;Isobutyl group triethoxy Silane, 3 parts;Nano carbon black, 2 parts;Nano silicon, 3 parts;Bentonite, 4 parts;Antioxidant 264,0.4 part;Three isopropoxies Aluminium, 0.7 part;Pentaerythritol ester, 7 parts;Polyacrylamide and zinc fluosilicate totally 5 parts, the weight of polyacrylamide and zinc fluosilicate The ratio of part is 4:1.
3. decoration sound insulation environment-friendly materials according to claim 1, it is characterised in that by the raw material system of following weight portion Standby form: thermoplastic phenolic resin, 45 parts;Expanded vermiculite, 20 parts;Polystyrene foam plastics, 6 parts;Isobutyl group triethoxy Silane, 2 parts;Nano carbon black, 1 part;Nano silicon, 2 parts;Bentonite, 3 parts;Antioxidant 264,0.2 part;Three isopropoxies Aluminium, 0.6 part;Pentaerythritol ester, 6 parts;Polyacrylamide and zinc fluosilicate totally 4 parts, the weight of polyacrylamide and zinc fluosilicate The ratio of part is 3:1.
4. decoration sound insulation environment-friendly materials according to claim 1, it is characterised in that by the raw material system of following weight portion Standby form: thermoplastic phenolic resin, 55 parts;Expanded vermiculite, 30 parts;Polystyrene foam plastics, 8 parts;Isobutyl group triethoxy Silane, 4 parts;Nano carbon black, 3 parts;Nano silicon, 4 parts;Bentonite, 5 parts;Antioxidant 264,0.6 part;Three isopropoxies Aluminium, 0.8 part;Pentaerythritol ester, 8 parts;Polyacrylamide and zinc fluosilicate totally 6 parts, the weight of polyacrylamide and zinc fluosilicate The ratio of part is 5:1.
5. the preparation method of the arbitrary described decoration sound insulation environment-friendly materials of Claims 1 to 4, it is characterised in that include walking as follows Rapid:
Step S1, by nano carbon black, nano silicon, expanded vermiculite, aluminium isopropoxide, zinc fluosilicate, isobutyl group three second TMOS mixed grinding disperses 1~2h, and gained material mixes with other surplus stocks, puts into twin-screw after stirring Extruder melt extrudes granulation at a temperature of 180~190 DEG C, obtains master batch;
Above-mentioned master batch is put in screw extruder melted at 170~190 DEG C by step S2, and melt is 220~240 through temperature DEG C the ejection of meltblown beam spinneret orifice, and stretch laggard to enter to receive device and be under the high velocity, hot air stream effect of 250~270 DEG C ?.
CN201610404607.5A 2016-06-08 2016-06-08 A kind of decoration sound insulation environment-friendly materials and preparation method thereof Active CN106084630B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107118511A (en) * 2017-06-22 2017-09-01 合肥易美特建材有限公司 A kind of building decoration environmentally friendly acoustic material and preparation method thereof
CN107246115A (en) * 2017-03-30 2017-10-13 合肥良骏汽车材料有限公司 A kind of novel sound insulating decorative panel
CN107915953A (en) * 2017-11-21 2018-04-17 南宁可煜能源科技有限公司 A kind of flat plate collector compound insulating material and preparation method thereof
CN109486096A (en) * 2018-09-04 2019-03-19 徐州市华天塑业有限公司 A kind of novel sound insulating high temperature resistant foam board

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104370574A (en) * 2014-10-27 2015-02-25 合肥诚信玻璃有限公司 Sound-absorption heat-insulation foamed brick and preparation method thereof
CN104861413A (en) * 2015-06-09 2015-08-26 李平兰 Method for preparing decorative interior acoustic insulating material
CN104987655A (en) * 2015-06-09 2015-10-21 李平兰 Preparation method of damping material used for installing draught fan

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104370574A (en) * 2014-10-27 2015-02-25 合肥诚信玻璃有限公司 Sound-absorption heat-insulation foamed brick and preparation method thereof
CN104861413A (en) * 2015-06-09 2015-08-26 李平兰 Method for preparing decorative interior acoustic insulating material
CN104987655A (en) * 2015-06-09 2015-10-21 李平兰 Preparation method of damping material used for installing draught fan

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107246115A (en) * 2017-03-30 2017-10-13 合肥良骏汽车材料有限公司 A kind of novel sound insulating decorative panel
CN107118511A (en) * 2017-06-22 2017-09-01 合肥易美特建材有限公司 A kind of building decoration environmentally friendly acoustic material and preparation method thereof
CN107915953A (en) * 2017-11-21 2018-04-17 南宁可煜能源科技有限公司 A kind of flat plate collector compound insulating material and preparation method thereof
CN109486096A (en) * 2018-09-04 2019-03-19 徐州市华天塑业有限公司 A kind of novel sound insulating high temperature resistant foam board

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