CN106084628B - A kind of hollow glass is rigid to warm up side spacer bar and preparation method thereof - Google Patents
A kind of hollow glass is rigid to warm up side spacer bar and preparation method thereof Download PDFInfo
- Publication number
- CN106084628B CN106084628B CN201610479490.7A CN201610479490A CN106084628B CN 106084628 B CN106084628 B CN 106084628B CN 201610479490 A CN201610479490 A CN 201610479490A CN 106084628 B CN106084628 B CN 106084628B
- Authority
- CN
- China
- Prior art keywords
- spacer bar
- hollow glass
- side spacer
- rigidly
- reinforcing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/02—Condensation polymers of aldehydes or ketones only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/14—Gas barrier composition
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of hollow glass, rigidly warm side spacer bar, primary raw material include polyketone POK, filling reinforcing agent, other auxiliary agents etc.；Wherein polyketone POK accounts for the 40-90% of the weight percent of total weight, and filling reinforcing agent accounts for the 10-60% of the weight percent of total weight, and other auxiliary agents account for the 0.1%-1.5% of the weight percent of total weight.Key property of the invention is: rigidly warm side spacer bar has lower thermal coefficient to hollow glass produced by the invention compared with stainless steel and the compound spacer bar of plastics and production is easier more convenient, lower cost of material and lower production cost；Rigidly warm side spacer bar has more excellent watertightness and air-tightness compared with glass fibre reinforced composite material pastes composite membrane spacer bar to hollow glass produced by the invention, it is easier to which clod wash is easier to assemble.Production method of the invention is scientific and reasonable, it is simple and easy, be conducive to implement.The C-factor that hollow glass of the invention rigidly warms up side spacer bar can reach 0.0003-0.0006W/K.
Description
Technical field
The present invention relates to a kind of energy-saving building materials, and in particular to a kind of hollow glass rigidly warm side spacer bar and its preparation
Method.
Background technique
At present in the case where China carries forward vigorously the big situation of energy-saving and emission-reduction, building energy conservation is the most important thing.Building energy consumption is complete
30% or more of social total energy consumption.And door and window energy conservation is the most important thing of building energy conservation, it is to pass through door that building energy consumption, which has half,
Window loss.Having any in door and window energy conservation is that cannot be neglected, that is, hollow glass spaceband, hollow glass edge pass through
Spacer bar carries out heat transfer, and thermal loss is made to cause the waste of whole society's energy.Have in Chinese market at present cold side spacer bar and
Warm side spacer bar, cold side spacer bar is using aluminum strip as representative, thermal coefficient about 160W/MK, and thermal loss is very big and can make
It condenses on the inside of empty glass chamber and generates bacterium.Warm side spacer bar has stainless steel spacer bar, stainless steel and the compound spacer bar of plastics, glass
Fibre reinforced composite material pastes composite membrane spacer bar etc..Since the thermal coefficient for warming up side spacer bar is low, such as: stainless steel thermal coefficient
About 15W/MK, polypropylene thermal coefficient about 0.19W/MK, polyvinyl chloride thermal coefficient about 0.17W/MK, hollow glass side
Portion, which carries out heat transfer by warm side spacer bar, to be greatly reduced, and thermal loss greatly reduces.
Chinese architecture glass and industrial glass association have issued Chinese architecture glass and industrial glass on 2 1st, 2016
Association criterion " warm side spacer bar " HBZ/T 003-2016, implements on April 1st, 2016 in the whole nation.According to Chinese architecture
Glass and industrial glass association criterion " warm side spacer bar " HBZ/T 003-2016, heat transfer performance is evaluated with C-factor
Parameter is indicated by the weighted value of the product d. λ of the thickness and thermal coefficient of spacer material.
Warm side spacer bar needs to have following performance characteristics:
1. spacer bar of the C-factor no more than 0.007W/K is only warm side spacer bar.C-factor is by spacer material
The weighted value of the product d. λ of thickness and thermal coefficient indicates.Need to bear the weight and wind load of hollow glass due to warming up side spacer bar
Lotus, warm side spacer bar need to have certain intensity, and the thickness to material is to have certain requirements, then will try to reduce warm
The thermal coefficient of side spacer material.
2. needing filling with inert gas, such as argon gas in hollow glass chamber to obtain hollow glass low heat conductivity, in hollow glass
In glass period whole service life, inert gas cannot all be leaked.The steam outside hollow glass can not be by warming up side simultaneously
Spacer bar frame enters hollow glass chamber, to avoid hollow glass failure.This requires warm side spacer bars to have barrier gas well
The performance of body and steam.
In the production process of warm side spacer bar, have the following problems:
If 1) warm side spacer bar is made with stainless steel, due to the compactness of stainless steel material itself, gas can be obstructed
Hollow glass chamber is penetrated into steam.But since stainless steel thermal coefficient is higher, and the density of load that stainless steel is born causes
The thickness of stainless steel cannot be too thin, so the C-factor of stainless steel heating side spacer bar is closest to limiting value, and heat
Amount loss is more.Simultaneously because stainless steel own mechanical performance characteristics, roll in continuous bending in corner often
The problems such as disconnected, breakage and gauffer.If the sawed-off use plastics limb of stainless steel spacer bar is connected, can be leaked in junction
Gas drainage.
If 2), can be continuous at normal temperature with full-automatic or half-automatic folding bender with stainless steel and the compound spacer bar of plastics
Bending, and be not in gas leakage drainage in corner.Due to the compactness of stainless steel material itself, it is of course possible to obstruct
Gas leak and steam penetrate into hollow glass chamber.But since stainless steel thermal coefficient is higher, for certain thickness stainless steel
Piece C-factor is also higher, is also certainly relatively more by the heat that this part stainless steel substrates loses.Simultaneously not
The production technology and equipment of rust steel and the compound spacer bar of plastics are all more complicated, higher cost.
If 3) composite membrane spacer bar is pasted with glass fibre reinforced composite material, due to the barrier gas and steam of composite membrane itself
Performance, it is of course possible to obstruct hollow glass intracavity gas leak and external moisture penetrate into hollow glass chamber.But fiberglass reinforced
The elongation percentage of composite material at normal temperature is lower, poor toughness, full-automatic or half-automatic folding bender cannot be used continuous at normal temperature
Bending.Use bending or warm side interval strap saw again after the full-automatic or half-automatic folding bender heating with heating device
It has no progeny and is connected using plastics limb.The warm side spacer bar frame that both modes make is existing in corner's leak that can all leak air
As.Because heating before warm side spacer bar bending in corner, glass fibre reinforced composite material temperature distortion can be made, lead to warm side interval
Corner's dimension overproof, while heating warm side spacer bar and can also reduce production efficiency.If warm side spacer bar it is sawed-off after make
It is connected, then can leaked air drainage in junction with plastics limb.Glass fibre reinforced composite material pastes composite membrane interval simultaneously
The production technology and equipment of item are all more complicated, higher cost.
Polyketone is a kind of novel high polymer crystalline material just to have emerged, has high barrier, high self-lubrication, high rigidity
And high impact resistance, high heat distortion temperature, short molding cycle, excellent high resiliency and have polypropylene PP possessed by hundred foldings
The characteristic of glue.But how polyketone is used as glass and warms up side spacer bar, make full use of the characteristic of polyketone, to make the warm side interval of rigidity
Item is with excellent watertightness and air-tightness, low thermal conductivity, high rigidity and excellent high resiliency and has clod wash characteristic,
There is presently no relevant document explanations.
Summary of the invention
The object of the present invention is to provide a kind of hollow glasses rigidly to warm up side spacer bar, between the warm side of the traditional hollow glass of solution
High, not easy to produce, the other type of parting bead thermal coefficient warm up side spacer bar do not heat can not bending and assembly in excessive ask is lost
Topic.
For achieving the above object, the present invention the following technical schemes are provided:
A kind of warm side spacer bar of hollow glass rigidity, the spacer bar are polyketone POK, fill reinforcing agent and other auxiliary agent systems
At the formula of each component is by weight percentage are as follows: polyketone POK 40-90% fills reinforcing agent 10-60%, other auxiliary agents
0.1-1.5%.
Further, filling reinforcing agent is one or both of glass fibre and talcum powder, and filling reinforcing agent is two kinds
Group timesharing, talcum powder account for the weight percent 5-25% of spacer bar each component total weight,；Other auxiliary agents be antioxidant, lubricant,
One or more of ultraviolet absorber, light stabilizer.
Further, the glass fibre in above-mentioned filling reinforcing agent is replaced by carbon fiber or processing silicate mineral is fine
Dimension；Talcum powder in the filling reinforcing agent is replaced by glass microballoon, calcium carbonate, mica powder or wollastonite.
Further, above-mentioned glass fibre is long glass fibres or short glass fiber or continuous glass fibre.
Further, when above-mentioned polyketone POK is POK/PA6 alloy, it is 10-15% that PA6, which accounts for spacer bar each component total weight,；
The filling reinforcing agent is two kinds of group timesharing, and the weight percent that talcum powder accounts for spacer bar each component total weight is 10-15%.
Further, above-mentioned hollow glass rigid warm up side spacer bar the preparation method comprises the following steps: by polyketone POK, filling reinforcing agent
It is blended with other auxiliary agents, then is granulated with double screw extruder in a high speed mixer, last extrusion molding.
Further, above-mentioned hollow glass rigid warm up side spacer bar the preparation method comprises the following steps: by polyketone POK, filling reinforcing agent
With other auxiliary agents after high-speed mixer blending, with molding machine direct extrusion molding.
Further, above-mentioned hollow glass rigid warm up side spacer bar be added in extrusion molding or after extrusion molding metal or
Enhanced non-metallic part.
The present invention can bring it is following the utility model has the advantages that
1) ability of the warm side spacer bar itself of rigidity barrier gas and steam with super strength, can obstruct hollow glass chamber
Interior gas leak and external moisture penetrate into hollow glass chamber, without adding metal or non-in warm side spacer bar two sides and bottom edge
Metal barrier layer.
2) the excellent mechanical performance of side spacer bar itself is warmed up due to rigid, the warm side spacer bar of rigidity can be with automatically or partly
Automatic bending machine continuous bending at normal temperature, substantially increases production efficiency, and not damaged in bending corner, does not crack,
It is non-wrinkled etc., it is not in gas leakage drainage.
3) thermal coefficient of the warm side spacer bar of rigidity is 0.2W/mK to 0.3W/mK, and hollow glass edge passes through the warm side of rigidity
Spacer bar, which carries out heat transfer, to be greatly reduced, and C-factor can reach 0.0003 to 0.0006W/K, be conducive to hollow glass guarantor
Hold good thermal and insulating performance.
It 4), can be intracavitary in warm side spacer bar when the warm intracavitary molecular sieve of side spacer bar encounters the Trace Water Vapor in hollow glass
Form weak acid or alkali environment.Rigidly warm side spacer bar has excellent chemical resistance for this, can keep making for warm side spacer bar overlength
Use the service life.
5) since China is vast in territory, local gas holdup range is wider.Warm side spacer bar in the present invention can be wider
There is excellent shock resistance within the scope of climate change, the wind load and glass weight in Different climate variation range can be born
Amount.
6) either can continuous clod wash stainless steel and the compound spacer bar of plastics, the fiberglass reinforced for being still unable to clod wash is multiple
Condensation material paste composite membrane spacer bar, their common features be use metal or nonmetallic composite membrane as barrier layer so that
Production technology and equipment are all very complicated.And the former loses heat, and the latter reduces production efficiency and there are leak gas leakage risks.This
Rigidity in invention warms up side spacer bar due to the ability of itself superpower barrier gas and steam, it is not necessary in rigidly warm side spacer bar
Two sides and bottom edge add metal or nonmetallic barrier layer, so that production technology and equipment are all no so complicated, and both will not
Too many heat is lost, production efficiency will not be lost, more without leak gas leakage risk.
Detailed description of the invention
Fig. 1 is the section A -1 that hollow glass of the present invention rigidly warms up side spacer bar；
Fig. 2 is the section A -2 that hollow glass of the present invention rigidly warms up side spacer bar；
Fig. 3 is the section A -3 that hollow glass of the present invention rigidly warms up side spacer bar；
Fig. 4 is the section B-1 that hollow glass of the present invention rigidly warms up side spacer bar；
Fig. 5 is the section B-2 that hollow glass of the present invention rigidly warms up side spacer bar；
Fig. 6 is the section B-3 that hollow glass of the present invention rigidly warms up side spacer bar；
Fig. 7 is the section C-1 that hollow glass of the present invention rigidly warms up side spacer bar；
Fig. 8 is the section C-2 that hollow glass of the present invention rigidly warms up side spacer bar；
Fig. 9 is the section C-3 that hollow glass of the present invention rigidly warms up side spacer bar；
Figure 10 is the section D-1 that hollow glass of the present invention rigidly warms up side spacer bar；
Figure 11 is the section D-2 that hollow glass of the present invention rigidly warms up side spacer bar；
Figure 12 is the section D-3 that hollow glass of the present invention rigidly warms up side spacer bar；
Figure 13 is the section E-1 that hollow glass of the present invention rigidly warms up side spacer bar；
Figure 14 is the section E-2 that hollow glass of the present invention rigidly warms up side spacer bar；
Figure 15 is the section E-3 that hollow glass of the present invention rigidly warms up side spacer bar.
Specific embodiment:
It is illustrated below with reference to preferred embodiment in the modified polyketone formula of the present invention, so that features and advantages energy of the invention
It is easier to those skilled in the art to be understood, more specifically be defined to be made to protection scope of the present invention.
The present invention is a kind of warm side spacer bar of hollow glass rigidity, which is polyketone POK, fills enhancing
Agent and other auxiliary agents are made, and the formula of each component is by weight percentage are as follows: polyketone POK 40-90% fills reinforcing agent 10-
60%, other auxiliary agent 0.1-1.5%.
Further, when above-mentioned polyketone POK is POK/PA6 alloy, it is 10-15% that PA6, which accounts for spacer bar each component total weight,；
The filling reinforcing agent is two kinds of group timesharing, and the weight percent that talcum powder accounts for spacer bar each component total weight is 10-15%.
Preferably 10-15%；Filling reinforcing agent is one or both of glass fibre and talcum powder, and talcum powder accounts for gross weight
The weight percent of amount is 5-25%, preferably 10-15%；Other auxiliary agents are that antioxidant, lubricant, ultraviolet absorber, light are steady
Determine one or more of agent.
Further, the glass fibre in above-mentioned filling reinforcing agent is replaced by carbon fiber or processing silicate mineral is fine
Dimension；Talcum powder in the filling reinforcing agent is replaced by glass microballoon, calcium carbonate, mica powder or wollastonite.
Further, above-mentioned glass fibre is long glass fibres or short glass fiber or continuous glass fibre.
Further, above-mentioned hollow glass rigid warm up side spacer bar the preparation method comprises the following steps: by polyketone POK, filling reinforcing agent
It is blended with other auxiliary agents, then is granulated with double screw extruder in a high speed mixer, last extrusion molding.
Further, above-mentioned hollow glass rigid warm up side spacer bar the preparation method comprises the following steps: by polyketone POK, filling reinforcing agent
With other auxiliary agents after high-speed mixer blending, with molding machine direct extrusion molding.
Further, above-mentioned hollow glass rigid warm up side spacer bar be added in extrusion molding or after extrusion molding metal or
Enhanced non-metallic part.
Below by specific embodiment, 1 couple of present invention is specifically described, and hollow glass rigidly warms up the raw material of side spacer bar
Including polyketone, glass fibre, talcum powder, modified additive.Weight percentage of each component accounts for 43.9%, PA6 for polyketone POK and accounts for
15%, glass fibre accounts for 20%, and talcum powder accounts for 10%, and antioxidant accounts for 0.3%, and ultraviolet absorber accounts for 0.5%, and lubricant accounts for
0.3%.
Each component is mixed in the ratio in specific embodiment 1, with double screw extruder extruding pelletization, grain will have been made
Son injected sample strip in injection molding machine.
It further illustrates, above injected sample strip is placed 24 hours indoors, and sample room temperature is kept for 23 DEG C, phase
50% is kept to humidity.
| Detection project | Examination criteria | Unit | Measured data |
| Tensile strength | GB/T1040 | MPa | 89 |
| Elongation at break | GB/T1040 | % | 18.5 |
| Bending strength | GB/T9341 | MPa | 110 |
| Bending modulus | GB/T9341 | GPa | 6.1 |
| Izod notch shock | GB/T1843 | KJ/m2 | 12 |
| - 30 DEG C of notch shocks | GB/T1843 | KJ/m2 | 5.5 |
| Thermal coefficient | GB/T10294 | W/mk | 0.26 |
The pellet of granulation is put into draw ratio to be less than the single screw extrusion machine for being 1 to 38 to squeeze out, extrusion temperature 220-240
Degree；Then spacer bar when production rigidity warms up is had more according to a mould in spacer bar width size according to warm；Side spacer bar is warmed up from mold
After extrusion, sizing is vacuumized by stock mould and is cooled and shaped；Online puncher punches on rigidly warm side spacer bar visible surface, passes through
Servo traction machine travel is crossed, and tracks customized cut-off online.
Fig. 1-15 is the sectional view that hollow glass of the present invention rigidly warms up side spacer bar, wherein the section A-1 of Fig. 1-3, section
In A-2, section A -3,1 is warm edge strip, and 2 be air hole.The section Fig. 4-6 B-1, section B-2, in the B-3 of section, 1 is warm edge strip, 2
It is air hole for reinforcement, 3.The section Fig. 7-9 C-1, section C-2, in the C-3 of section, 1 is warm edge strip, and 2 be air hole.Figure 10-12
Section D-1, section D-2, in the D-3 of section, 1 is warm edge strip, and 2 be air hole.The section Figure 13-15 E-1, section E-2, section E-3
In, 1 is warm edge strip, and 2 be reinforcement, and 3 be air hole.
Claims (5)
1. a kind of rigid warm side spacer bar of hollow glass, which is characterized in that the spacer bar is polyketone POK, filling reinforcing agent and
Other auxiliary agents are made, and the formula of each component is by weight percentage are as follows: and polyketone POK 40-90% fills reinforcing agent 10-60%,
Other auxiliary agent 0.1-1.5%；Filling reinforcing agent is one or both of glass fibre and talcum powder, and filling reinforcing agent is two kinds
Group timesharing, talcum powder account for the weight percent 5-25% of spacer bar each component total weight；Other auxiliary agents be antioxidant, lubricant,
One or more of ultraviolet absorber, light stabilizer；The weight percent summation of each component is 100%.
2. hollow glass as described in claim 1 rigidly warms up side spacer bar, which is characterized in that the glass fibre is long glass
Fiber or short glass fiber or continuous glass fibre.
3. hollow glass as described in claim 1 rigidly warms up side spacer bar, which is characterized in that the spacer bar is using the following method
Preparation: polyketone POK, filling reinforcing agent and other auxiliary agents are blended in a high speed mixer, then are granulated with double screw extruder, most
Extrusion molding afterwards.
4. hollow glass as described in claim 1 rigidly warms up side spacer bar, which is characterized in that the spacer bar is using the following method
Preparation: by polyketone POK, filling reinforcing agent and other auxiliary agents after high-speed mixer blending, with molding machine direct extrusion molding.
5. hollow glass as described in claim 3 or 4 rigidly warms up side spacer bar, which is characterized in that the hollow glass rigidity
Metal or enhanced non-metallic part is added in warm side spacer bar in extrusion molding or after extrusion molding.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610479490.7A CN106084628B (en) | 2016-06-27 | 2016-06-27 | A kind of hollow glass is rigid to warm up side spacer bar and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610479490.7A CN106084628B (en) | 2016-06-27 | 2016-06-27 | A kind of hollow glass is rigid to warm up side spacer bar and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106084628A CN106084628A (en) | 2016-11-09 |
| CN106084628B true CN106084628B (en) | 2019-03-05 |
Family
ID=57253994
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610479490.7A Active CN106084628B (en) | 2016-06-27 | 2016-06-27 | A kind of hollow glass is rigid to warm up side spacer bar and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106084628B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20180055370A (en) * | 2016-11-17 | 2018-05-25 | 현대자동차주식회사 | Polyketone composite resin composition |
| CN106800739A (en) * | 2017-01-20 | 2017-06-06 | 南京南优新材料有限公司 | Acrylonitrile styrene copolymer composition and profiled spacer therefrom for preparing profiled spacer |
| CN109971074B (en) * | 2019-04-17 | 2022-03-25 | 余姚中国塑料城塑料研究院 | Multilayer co-extrusion composite hollow glass warm edge spacing bar and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1226582A (en) * | 1997-12-23 | 1999-08-25 | 埃姆斯-因文塔股份公司 | Polyamide/polyketone blend compositions |
| CN102079871A (en) * | 2010-12-06 | 2011-06-01 | 余姚维普工程塑料有限公司 | Warm-edge spacing bar material used for hollow glass and preparation method thereof |
| CN102731932A (en) * | 2012-06-18 | 2012-10-17 | 成都新兴富皇高分子材料科技有限公司 | Bar inserting type heat insulation section material and preparation method thereof |
| CN102844378A (en) * | 2010-04-13 | 2012-12-26 | 罗地亚经营管理公司 | Thermoplastic composition based on polyamide, polyketone and novolac resin |
| CN105111734A (en) * | 2015-09-20 | 2015-12-02 | 成都育芽科技有限公司 | Building door and window heat insulation strip made of inorganic filling nylon composite material |
| CN105504805A (en) * | 2015-12-30 | 2016-04-20 | 天津金发新材料有限公司 | Polyamide composition for preparing specially-shaped heat insulation bar and preparation method thereof |
-
2016
- 2016-06-27 CN CN201610479490.7A patent/CN106084628B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1226582A (en) * | 1997-12-23 | 1999-08-25 | 埃姆斯-因文塔股份公司 | Polyamide/polyketone blend compositions |
| CN102844378A (en) * | 2010-04-13 | 2012-12-26 | 罗地亚经营管理公司 | Thermoplastic composition based on polyamide, polyketone and novolac resin |
| CN102079871A (en) * | 2010-12-06 | 2011-06-01 | 余姚维普工程塑料有限公司 | Warm-edge spacing bar material used for hollow glass and preparation method thereof |
| CN102731932A (en) * | 2012-06-18 | 2012-10-17 | 成都新兴富皇高分子材料科技有限公司 | Bar inserting type heat insulation section material and preparation method thereof |
| CN105111734A (en) * | 2015-09-20 | 2015-12-02 | 成都育芽科技有限公司 | Building door and window heat insulation strip made of inorganic filling nylon composite material |
| CN105504805A (en) * | 2015-12-30 | 2016-04-20 | 天津金发新材料有限公司 | Polyamide composition for preparing specially-shaped heat insulation bar and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106084628A (en) | 2016-11-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106084628B (en) | A kind of hollow glass is rigid to warm up side spacer bar and preparation method thereof | |
| CN102432998A (en) | Master bathes of polyamide heat insulating strip | |
| CN104086924A (en) | Carbon fiber-reinforced thermoplastic resin composite material and preparation method thereof | |
| CN109291525B (en) | Fiber-reinforced beta-crystal-form random copolymerization polypropylene composite pipe and preparation method thereof | |
| CN110406065B (en) | beta-PPR pipe and processing method thereof | |
| CN103289342A (en) | High heat conduction reinforced PC/PBT alloy | |
| CN202144913U (en) | U-PVC (U-polyvinyl chloride) steel belt-winding pipe | |
| CN206112298U (en) | Prefabricated direct -burried heat preservation composite plastic pipe of polypropylene | |
| CN103881231B (en) | A kind of thermal storage and energy accumulation spacer bar based on ethylene-vinyl acetate copolymer and preparation method thereof | |
| CN103275483B (en) | Method for manufacturing steel frame reinforced nylon pipeline | |
| CN100478161C (en) | PVC twisted pipe production process | |
| CN105175907A (en) | Thermal conductive plastic alloy, radiator based on alloy and preparation method | |
| CN108586940A (en) | A kind of preparation method of the weather-proof uvioresistant PP-R pipes of outdoor use | |
| CN109334040B (en) | Method for manufacturing fiber tube | |
| CN111393735A (en) | Plastic pipeline and preparation method thereof | |
| CN203215098U (en) | High-pressure antibacterial polypropylene pressure pipe | |
| CN207864798U (en) | A kind of high voltage and high-impact PPR pipe | |
| CN209146522U (en) | A kind of highly resistance punching press PVC pipe | |
| CN202901569U (en) | Impact-resistant high-strength PE (polyethylene) plastic alloy gas pipe | |
| CN201714232U (en) | Self-reinforced plastic door and window profile | |
| CN108676286A (en) | The preparation method of PVC pipe composition and PVC pipe | |
| CN113637193A (en) | Nylon heat-insulating strip material or reinforced nylon and glass fiber reinforced PA6/PA66 composite material | |
| CN202706781U (en) | Composite energy-saving door frame or door leaf frame | |
| CN202072653U (en) | Special section of polyurethane composite material for glass curtain wall and forming system | |
| CN106188873A (en) | A kind of PP fire-retardant master granule of potassium titanate crystal whisker enhancing modified and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |