CN106070358A - A kind of novel agrochemical and production technology thereof - Google Patents
A kind of novel agrochemical and production technology thereof Download PDFInfo
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- CN106070358A CN106070358A CN201610470172.4A CN201610470172A CN106070358A CN 106070358 A CN106070358 A CN 106070358A CN 201610470172 A CN201610470172 A CN 201610470172A CN 106070358 A CN106070358 A CN 106070358A
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- sulfur
- alumen
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/02—Sulfur; Selenium; Tellurium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/30—Polygonaceae [Buckwheat family], e.g. red-knees or rhubarb
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Mycology (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of novel agrochemical and production technology thereof, relate to technical field of pesticide, a kind of novel agrochemical, by mass percentage, described novel agrochemical contains: 5% 10% Chinese herbal medicine, 20% 28% sulfur, 7% 12% Alumens, 30% 55% calcium lime powders, 2% 5% wetting agent, 4% 8% dispersants, 1.5% 2% anticaking agents, 1% 1.5% defoamer, 5% 7% suspending agents, remaining is filler, use technical scheme, production stage is reasonable, production efficiency is high, containing the indispensable various trace elements of crop growthing development, crops robust growth can be made to grow, play efficiently, nuisanceless, effect of noresidue, and the property of medicine is gentle, there is sterilization, virus killing, the effect encouraged.
Description
Technical field
The present invention relates to technical field of pesticide, be specifically related to a kind of novel agrochemical and production technology thereof.
Background technology
Domestic existing sterilization and disinfection class pesticide is the most all chemical pesticide, uses this type of pesticide to easily cause a large amount of the toxin remains
In crops, vegetable and melon and fruit, make natural environment heavily contaminated, destroy natural environment and ecological balance, have resulted in
Public hazards, directly threaten the living environment of the mankind, are unfavorable for developing green agriculture and pollution-free food.
In recent years, occurring in that several environment friendly agricultural on the market, the insecticidal effect of this type of pesticide preferably, but sterilizes, go out poison
Effect more weak, more not to the growth encourage of crops, help strong function, and production technology be more complicated, apparatus expensive, cost
Height, production scale is very limited, it is difficult to promotes and implements.
Patent No. CN 103828830 A disclose a kind of containing Diacloden and the pesticide of Bravo and
Production technology, belongs to technical field of pesticide.This agriculture the effective elements of the medicine be Diacloden 5～10% and Bravo 50～
70%, remaining is auxiliary agent.This pesticide only need to reduce spraying times 1 time Caulis Sacchari sinensis grand period of growth dispenser 1 time than prior art,
The dispenser when mixing of the Caulis Sacchari sinensis grand period of growth multiple disease pest occurs, can effectively control sugar cane cottony aphid, thrips and sugarcane toppers maize ear rot, brown streak
Etc. multiple disease pest, the preventive effect of sugar cane cottony aphid is reached 98-100%, preventive effect to Sugarcane Thrips reaches 91-94%, to sugarcane toppers maize ear rot
Preventive effect reaches 81-87%, preventive effect to Caulis Sacchari sinensis brown streak reaches 80-82%, efficiently solves the mixing of the Caulis Sacchari sinensis grand period of growth multiple disease pest and sends out
Raw and shortage composite highly effective low toxicity disinsection prophylaxis pesticide again industrial technology problem.
Although the pesticide production cost that technique scheme is produced is relatively low and insecticidal effect preferable, but it is not to farming
The growth encourage of thing, help strong function, and the property of medicine is the gentleest, accordingly, it would be desirable to design a kind of Novel rural that can solve the problem that problem above
Medicine and production technology thereof.
Summary of the invention
Problem to be solved by this invention is to provide a kind of novel agrochemical and production technology thereof.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of novel agrochemical, by mass percentage, described novel agrochemical contains: 5%-10% Chinese herbal medicine, 20%-28% sulfur, 7%-
12% Alumen, 30%-55% calcium lime powder, 2%-5% wetting agent, 4%-8% dispersant, 1.5%-2% anticaking agent, 1%-1.5% froth breaking
Agent, 5%-7% suspending agent, remaining is filler.
Preferably, by mass percentage, described novel agrochemical contains: 8% Chinese herbal medicine, 25% sulfur, 9% Alumen, 40% life
Pulverized limestone, 3% wetting agent, 6% dispersant, 1.5% anticaking agent, 1% defoamer, 6% suspending agent, remaining is filler.
A kind of production technology of novel agrochemical, described production technology specifically includes following steps:
Step one: raw material configure, wherein 5%-10% Chinese herbal medicine, 20%-28% sulfur, 7%-12% Alumen, 30%-55% calcium lime powder,
2%-5% wetting agent, 4%-8% dispersant, 1.5%-2% anticaking agent, 1%-1.5% defoamer, 5%-7% suspending agent, remaining is filler；
Step 2: according to composition each in above-mentioned requirements and proportioning thereof by wetting agent, dispersant, anticaking agent, defoamer, suspending
Agent, filler are put in mixer after weighing by consumption and are mixed 40 minutes；
Step 3: raw material step 2 prepared adds in jet mill makes 200-500 mesh fine powder；
Step 4: sulfur and Alumen are put into pot and is heated to 120-150 DEG C, after sulfur and Alumen melt, stirs；
Step 5: after sulfur quick lime addition melted and Alumen dissolve, stir, the mixture of powder, sulfur and Alumen
Fry to yellowish-brown, add and the clear water of quick lime equal quality, boil with moderate heat, and be stirred continuously, when medicine arsenic reaches thickness
Time, taken the dish out of the pot, be placed in settling vessel, in settling vessel, added the clear water more than medicine arsenic two volumes immediately, by medicine arsenic
Stir with clear water, quiet put 15-35 hour after, extract supernatant, be semi-finished product liquid；
Step 6: put into pot after the semi-finished product liquid mixing that fine powder step 3 obtained and step 5 obtain, add preparation
Good Chinese herbal medicine, boils, the most boiled to after boiling, and uses slow fire instead, ceases fire after boiling 30-50 minute；
Step 7: taken the dish out of the pot by the medicinal liquid boiled out, adds after filtration and mixes after 20 minutes quantitative package in mixer
To this Pesticidal products, through after the assay was approved, can canned warehouse-in.
Preferably, by mass percentage, described Chinese herbal medicine contains: 4%-6% Radix Isatidis, 5%-8% Flos Chrysanthemi Indici, 5%-7% are expensive
Secondary, 2%-5% Herba Violae, 5%-10% Rhizoma Polygoni Cuspidati, 8%-12% Folium Isatidis, 2%-3% Flos Carthami, 3%-6% Fructus Gardeniae, 4%-7% Radix Gentianae, remaining
For Radix Sophorae Flavescentis.
Preferably, the time boiling medicinal liquid in step 6 is 40 minutes.
Preferably, mixer described in step 7 uses double-spiral conical mixer.
Using technical scheme, production stage is reasonable, and production efficiency is high, indispensable containing crop growthing development
Much less plants trace element, it is possible to makes crops robust growth grow, plays efficient, nuisanceless, effect of noresidue, and the property of medicine
Gentleness, has sterilization, the effect killed virus, encourage.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below in conjunction with
Detailed description of the invention, is expanded on further the present invention.
Embodiment 1:
A kind of novel agrochemical, by mass percentage, described novel agrochemical contains: 5% Chinese herbal medicine, 20% sulfur, 7% Alumen, 30%
Calcium lime powder, 2% wetting agent, 4% dispersant, 1.5% anticaking agent, 1% defoamer, 5% suspending agent, remaining is filler.
A kind of production technology of novel agrochemical, described production technology specifically includes following steps:
Step one: raw material configures, wherein 5% Chinese herbal medicine, 20% sulfur, 7% Alumen, 30% calcium lime powder, 2% wetting agent, 4% dispersion
Agent, 1.5% anticaking agent, 1% defoamer, 5% suspending agent, remaining is filler；
Step 2: according to composition each in above-mentioned requirements and proportioning thereof by wetting agent, dispersant, anticaking agent, defoamer, suspending
Agent, filler are put in mixer after weighing by consumption and are mixed 40 minutes；
Step 3: raw material step 2 prepared adds in jet mill makes 200 mesh fine powders；
Step 4: sulfur and Alumen are put into pot and is heated to 120 DEG C, after sulfur and Alumen melt, stirs；
Step 5: after sulfur quick lime addition melted and Alumen dissolve, stir, the mixture of powder, sulfur and Alumen
Fry to yellowish-brown, add and the clear water of quick lime equal quality, boil with moderate heat, and be stirred continuously, when medicine arsenic reaches thickness
Time, taken the dish out of the pot, be placed in settling vessel, in settling vessel, added the clear water more than medicine arsenic two volumes immediately, by medicine arsenic
Stir with clear water, quiet put 15 hours after, extract supernatant, be semi-finished product liquid；
Step 6: put into pot after the semi-finished product liquid mixing that fine powder step 3 obtained and step 5 obtain, add preparation
Good Chinese herbal medicine, boils, the most boiled to after boiling, and uses slow fire instead, ceases fire after boiling 30 minutes；
Step 7: taken the dish out of the pot by the medicinal liquid boiled out, adds after filtration and mixes after 20 minutes quantitative package in mixer
To this Pesticidal products, through after the assay was approved, can canned warehouse-in.
Wherein, by mass percentage, described Chinese herbal medicine contains: 4% Radix Isatidis, 5% Flos Chrysanthemi Indici, 5% expensive secondary, 2% pale reddish brownlyly
Fourth, 5% Rhizoma Polygoni Cuspidati, 8% Folium Isatidis, 2% Flos Carthami, 3% Fructus Gardeniae, 4% Radix Gentianae, remaining is Radix Sophorae Flavescentis.
Wherein, mixer described in step 7 uses double-spiral conical mixer.
Embodiment 2:
A kind of novel agrochemical, by mass percentage, described novel agrochemical contains: 10% Chinese herbal medicine, 28% sulfur, 12% Alumen,
55% calcium lime powder, 5% wetting agent, 8% dispersant, 2% anticaking agent, 1.5% defoamer, 7% suspending agent, remaining is filler.
A kind of production technology of novel agrochemical, described production technology specifically includes following steps:
Step one: raw material configures, wherein 10% Chinese herbal medicine, 28% sulfur, 12% Alumen, 55% calcium lime powder, 5% wetting agent, 8% dispersion
Agent, 2% anticaking agent, 1.5% defoamer, 7% suspending agent, remaining is filler；
Step 2: according to composition each in above-mentioned requirements and proportioning thereof by wetting agent, dispersant, anticaking agent, defoamer, suspending
Agent, filler are put in mixer after weighing by consumption and are mixed 40 minutes；
Step 3: raw material step 2 prepared adds in jet mill makes 500 mesh fine powders；
Step 4: sulfur and Alumen are put into pot and is heated to 150 DEG C, after sulfur and Alumen melt, stirs；
Step 5: after sulfur quick lime addition melted and Alumen dissolve, stir, the mixture of powder, sulfur and Alumen
Fry to yellowish-brown, add and the clear water of quick lime equal quality, boil with moderate heat, and be stirred continuously, when medicine arsenic reaches thickness
Time, taken the dish out of the pot, be placed in settling vessel, in settling vessel, added the clear water more than medicine arsenic two volumes immediately, by medicine arsenic
Stir with clear water, quiet put 35 hours after, extract supernatant, be semi-finished product liquid；
Step 6: put into pot after the semi-finished product liquid mixing that fine powder step 3 obtained and step 5 obtain, add preparation
Good Chinese herbal medicine, boils, the most boiled to after boiling, and uses slow fire instead, ceases fire after boiling 50 minutes；
Step 7: taken the dish out of the pot by the medicinal liquid boiled out, adds after filtration and mixes after 20 minutes quantitative package in mixer
To this Pesticidal products, through after the assay was approved, can canned warehouse-in.
Wherein, by mass percentage, described Chinese herbal medicine contains: 6% Radix Isatidis, 8% Flos Chrysanthemi Indici, 7% expensive secondary, 5% pale reddish brownlyly
Fourth, 10% Rhizoma Polygoni Cuspidati, 12% Folium Isatidis, 3% Flos Carthami, 6% Fructus Gardeniae, 7% Radix Gentianae, remaining is Radix Sophorae Flavescentis.
Wherein, mixer described in step 7 uses double-spiral conical mixer.
Embodiment 3: a kind of novel agrochemical, by mass percentage, described novel agrochemical contains: 8% Chinese herbal medicine, 25% sulfur
Sulphur, 9% Alumen, 40% calcium lime powder, 3% wetting agent, 6% dispersant, 1.5% anticaking agent, 1% defoamer, 6% suspending agent, remaining is
Filler.
A kind of production technology of novel agrochemical, described production technology specifically includes following steps:
Step one: raw material configures, wherein 8% Chinese herbal medicine, 25% sulfur, 9% Alumen, 40% calcium lime powder, 3% wetting agent, 6% dispersion
Agent, 1.5% anticaking agent, 1% defoamer, 6% suspending agent, remaining is filler；
Step 2: according to composition each in above-mentioned requirements and proportioning thereof by wetting agent, dispersant, anticaking agent, defoamer, suspending
Agent, filler are put in mixer after weighing by consumption and are mixed 40 minutes；
Step 3: raw material step 2 prepared adds in jet mill makes 300 mesh fine powders；
Step 4: sulfur and Alumen are put into pot and is heated to 130 DEG C, after sulfur and Alumen melt, stirs；
Step 5: after sulfur quick lime addition melted and Alumen dissolve, stir, the mixture of powder, sulfur and Alumen
Fry to yellowish-brown, add and the clear water of quick lime equal quality, boil with moderate heat, and be stirred continuously, when medicine arsenic reaches thickness
Time, taken the dish out of the pot, be placed in settling vessel, in settling vessel, added the clear water more than medicine arsenic two volumes immediately, by medicine arsenic
Stir with clear water, quiet put 20 hours after, extract supernatant, be semi-finished product liquid；
Step 6: put into pot after the semi-finished product liquid mixing that fine powder step 3 obtained and step 5 obtain, add preparation
Good Chinese herbal medicine, boils, the most boiled to after boiling, and uses slow fire instead, ceases fire after boiling 40 minutes；
Step 7: taken the dish out of the pot by the medicinal liquid boiled out, adds after filtration and mixes after 20 minutes quantitative package in mixer
To this Pesticidal products, through after the assay was approved, can canned warehouse-in.
Wherein, by mass percentage, described Chinese herbal medicine contains: 5% Radix Isatidis, 6% Flos Chrysanthemi Indici, 6% expensive secondary, 3% pale reddish brownlyly
Fourth, 8% Rhizoma Polygoni Cuspidati, 10% Folium Isatidis, 3% Flos Carthami, 5% Fructus Gardeniae, 5% Radix Gentianae, remaining is Radix Sophorae Flavescentis.
Wherein, mixer described in step 7 uses double-spiral conical mixer.
Based on above-mentioned, using technical scheme, production stage is reasonable, and production efficiency is high, containing crop growth
Grow indispensable various trace elements, it is possible to make crops robust growth grow, play efficient, nuisanceless, noresidue
Effect, and the property of medicine is gentle, has sterilization, the effect killed virus, encourage.
Obviously the present invention implements and is not subject to the restrictions described above, as long as have employed method design and the skill of the present invention
The improvement of the various unsubstantialities that art scheme is carried out, or the most improved design by the present invention and technical scheme directly apply to it
Its occasion, all within protection scope of the present invention.
Claims (6)
1. a novel agrochemical, it is characterised in that by mass percentage, described novel agrochemical contains: 5%-10% Chinese herbal medicine,
20%-28% sulfur, 7%-12% Alumen, 30%-55% calcium lime powder, 2%-5% wetting agent, 4%-8% dispersant, 1.5%-2% anti-caking
Agent, 1%-1.5% defoamer, 5%-7% suspending agent, remaining is filler.
A kind of novel agrochemical the most according to claim 1, it is characterised in that: by mass percentage, described novel agrochemical
Contain: 8% Chinese herbal medicine, 25% sulfur, 9% Alumen, 40% calcium lime powder, 3% wetting agent, 6% dispersant, 1.5% anticaking agent, 1% disappear
Infusion, 6% suspending agent, remaining is filler.
3. the technique of the novel agrochemical produced described in claim 1-2 any one, it is characterised in that described production technology
Specifically include following steps:
Step one: raw material configure, wherein 5%-10% Chinese herbal medicine, 20%-28% sulfur, 7%-12% Alumen, 30%-55% calcium lime powder,
2%-5% wetting agent, 4%-8% dispersant, 1.5%-2% anticaking agent, 1%-1.5% defoamer, 5%-7% suspending agent, remaining is filler；
Step 2: according to composition each in above-mentioned requirements and proportioning thereof by wetting agent, dispersant, anticaking agent, defoamer, suspending
Agent, filler are put in mixer after weighing by consumption and are mixed 40 minutes；
Step 3: raw material step 2 prepared adds in jet mill makes 200-500 mesh fine powder；
Step 4: sulfur and Alumen are put into pot and is heated to 120-150 DEG C, after sulfur and Alumen melt, stirs；
Step 5: after sulfur quick lime addition melted and Alumen dissolve, stir, the mixture of powder, sulfur and Alumen
Fry to yellowish-brown, add and the clear water of quick lime equal quality, boil with moderate heat, and be stirred continuously, when medicine arsenic reaches thickness
Time, taken the dish out of the pot, be placed in settling vessel, in settling vessel, added the clear water more than medicine arsenic two volumes immediately, by medicine arsenic
Stir with clear water, quiet put 15-35 hour after, extract supernatant, be semi-finished product liquid；
Step 6: put into pot after the semi-finished product liquid mixing that fine powder step 3 obtained and step 5 obtain, add preparation
Good Chinese herbal medicine, boils, the most boiled to after boiling, and uses slow fire instead, ceases fire after boiling 30-50 minute；
Step 7: taken the dish out of the pot by the medicinal liquid boiled out, adds after filtration and mixes after 20 minutes quantitative package in mixer
To this Pesticidal products, through after the assay was approved, can canned warehouse-in.
A kind of novel agrochemical the most according to claim 1, it is characterised in that: by mass percentage, described Chinese herbal medicine contains
Have: 4%-6% Radix Isatidis, 5%-8% Flos Chrysanthemi Indici, 5%-7% expensive secondary, 2%-5% Herba Violae, 5%-10% Rhizoma Polygoni Cuspidati, 8%-12% Folium Isatidis,
2%-3% Flos Carthami, 3%-6% Fructus Gardeniae, 4%-7% Radix Gentianae, remaining is Radix Sophorae Flavescentis.
The production technology of a kind of novel agrochemical the most according to claim 3, it is characterised in that: step 6 boils medicinal liquid
Time is 40 minutes.
The production technology of a kind of novel agrochemical the most according to claim 3, it is characterised in that: mixer described in step 7
Use double-spiral conical mixer.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610470172.4A CN106070358A (en) | 2016-06-26 | 2016-06-26 | A kind of novel agrochemical and production technology thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201610470172.4A CN106070358A (en) | 2016-06-26 | 2016-06-26 | A kind of novel agrochemical and production technology thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106106547A (en) * | 2016-06-27 | 2016-11-16 | 安徽梅兰园林景观工程有限公司 | A kind of novel agrochemical and production technology thereof |
| CN106135308A (en) * | 2016-06-30 | 2016-11-23 | 安徽金培因科技有限公司 | A kind of novel agrochemical and production technology thereof |
| CN106962418A (en) * | 2017-05-22 | 2017-07-21 | 东至县珊瑚生态农业发展有限公司 | The formula and technology for producing of a kind of environment friendly agricultural |
| CN107509749A (en) * | 2017-09-05 | 2017-12-26 | 南通派斯第农药化工股份有限公司 | A kind of eco-friendly pesticide |
-
2016
- 2016-06-26 CN CN201610470172.4A patent/CN106070358A/en not_active Withdrawn
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106106547A (en) * | 2016-06-27 | 2016-11-16 | 安徽梅兰园林景观工程有限公司 | A kind of novel agrochemical and production technology thereof |
| CN106135308A (en) * | 2016-06-30 | 2016-11-23 | 安徽金培因科技有限公司 | A kind of novel agrochemical and production technology thereof |
| CN106962418A (en) * | 2017-05-22 | 2017-07-21 | 东至县珊瑚生态农业发展有限公司 | The formula and technology for producing of a kind of environment friendly agricultural |
| CN107509749A (en) * | 2017-09-05 | 2017-12-26 | 南通派斯第农药化工股份有限公司 | A kind of eco-friendly pesticide |
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Application publication date: 20161109 |
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