CN106065154A - A kind of transparent flame-retardant antistatic ABS material and preparation method thereof - Google Patents
A kind of transparent flame-retardant antistatic ABS material and preparation method thereof Download PDFInfo
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- CN106065154A CN106065154A CN201610405041.8A CN201610405041A CN106065154A CN 106065154 A CN106065154 A CN 106065154A CN 201610405041 A CN201610405041 A CN 201610405041A CN 106065154 A CN106065154 A CN 106065154A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2355/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2323/00 - C08J2353/00
- C08J2355/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2455/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2423/00 - C08J2453/00
- C08J2455/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
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Abstract
The invention provides a kind of transparent flame-retardant antistatic ABS material and preparation method thereof, described transparent flame-retardant antistatic ABS material, is made up of the raw material including following weight portion: Resin A 60 85 parts, 10 15 parts of antistatic additive, fire-retardant master granule 10 20 parts, toughener 5 25 parts.Described fire-retardant master granule is made up of the raw material including following weight portion: resin B 60 90 parts, phosphorus-nitrogen containing flame retardant 10 30 parts, Firebrake ZB 5 20 parts；Described Resin A is identical with the specification of resin B.Transparent flame-retardant antistatic ABS material of the present invention, by adding antistatic additive, can make the surface resistivity of composite from 1016Ω is reduced to 108Ω, antistatic effect is good.
Description
Technical field
The invention belongs to polymeric material field, especially relate to a kind of transparent flame-retardant antistatic ABS material and preparation thereof
Method.
Background technology
The terpolymer that ABS resin is made up of styrene, butadiene, acrylonitrile, has concentrated cinnamic high flowing
Property, the rubber toughness of butadiene and the chemicals-resistant characteristic of acrylonitrile, there is excellent processing characteristics, resistance to low temperature, electricity absolutely
Edge performance, resistance to chemical corrosion and high glaze and the plating performance of excellence, have that creep resistant is good, dimensional stability simultaneously
The excellent characteristics such as height, molding shrinkage are little, apply widely in fields such as military project, automobile, electronic apparatus.But on the one hand ABS
The oxygen index (OI) of resin only has 18, belongs to combustible material.Therefore, carrying out ABS resin flame-retardant modified is the most conventional a kind of ABS
Resin modified method.On the other hand, along with socioeconomic development, people are except more and more higher to the requirement of materials'use performance
Outward, more the aesthetic of material surface is increasingly favored, therefore develop and not only there is serviceability, have more transparent texture
Material modified be a current trend.There are many macromolecular materials at present without accomplishing transparent stage before modified, as
Clear polycarbonate, acrylic, Transparent ABS Resin, saturating benzene etc., but these materials are by after flame-retardant modified, all become nontransparent
Material.While obtaining its requirement to performance, it is lost the aesthetic values of its outward appearance.
Further, due to the non-conductor that ABS material is electricity, during processing and use, electrostatic charge is easily accumulated, when quiet
To a certain extent, electrostatic can cause material to adsorb dust to electricity charge accumulated, and causes material damage, it is also possible to produces electrostatic fire
Flower electric discharge, causes chemical products storehouse etc. on fire from explosion, causes great personal injury.
Therefore, develop a kind of transparent flame-retardant antistatic ABS material and be particularly important, there is the huge market space.
Summary of the invention
In view of this, it is contemplated that propose a kind of transparent flame-retardant antistatic ABS material and preparation method thereof, transparent flame-retarding
Antistatic ABS material mechanical performance is excellent, and preparation method is simple, and handling ease is with low cost.
For reaching above-mentioned purpose, the technical scheme is that and be achieved in that:
A kind of transparent flame-retardant antistatic ABS material, is made up of the raw material including following weight portion:
Wherein, described Resin A is MABS.
Further, the raw material by including following weight portion that consists of of described fire-retardant master granule is made:
Resin B 60-90 part,
Phosphorus-nitrogen containing flame retardant 10-30 part,
Firebrake ZB 5-20 part；
Wherein, described resin B is MABS；Described Resin A is identical or different with the specification of resin B.
Further, described phosphorus-nitrogen containing flame retardant is one or both in Quadrafos, melamine cyanurate
Mixture；The particle diameter of described Firebrake ZB is 2-4 μm.
Further, the light transmittance of described Resin A > 80%, Izod notched impact strength > 10kJ/m2；Described resin
The light transmittance of B > 80%, Izod notched impact strength > 10kJ/m2。
Further, described toughener is that MMB methyl methacrylate butadiene styrene copolymer (MBS) type increases
Tough dose, acrylonitrile-styrene-acrylic ester graft copolymer (ASA) type toughener, ethylene-vinyl acetate copolymer (EVA)
One or more in type toughener；Described antistatic additive is permanent antistatic agent.
Described high transparency, the component of high rigidity flame-retardant ABS compound material also include that weight portion is helping of 0.1-3 part
Agent.
Described auxiliary agent is heat stabilizer, light stabilizer, processing aid or pigment.
Described heat stabilizer can improve material heat aging property during processing and use, is generally selected from
Phenols, phosphorous acid esters, monothioester class complex in one or more.
Described light stabilizer can improve material light aging resisting property in use, can be hindered amines or purple
Ultraviolet absorbers.
Described processing aid is that low molecule esters stearic acid, metallic soap are (selected from calcium stearate Cast, zinc stearate
Znst), one or more in stearic acid complex ester or amide-type (erucyl amide).
The preparation method of described transparent flame-retardant antistatic ABS material, comprises the steps:
(1) resin B, phosphorus-nitrogen containing flame retardant and Firebrake ZB are joined in high-temperature mixing machine, at a temperature of 170-250 DEG C
Carry out premixing, after pelletize cooling, obtain fire-retardant master granule；
(2) Resin A, fire-retardant master granule, toughener, antistatic additive are sufficiently mixed 10-60 minute at high-speed mixer, obtain
Premix material；
(3) premix material is transported in double screw extruder through the pay-off of delicate metering, each section of spiral shell of extruder
Bar temperature controls between 180-230 DEG C, and the draw ratio of double screw extruder is 25-40:1, screw speed be 200-800 turn/
Minute, under the shearing, mixing and conveying of screw rod, material fully melted, compound, then through extruding pelletization, be dried to obtain
Transparent flame-retardant antistatic ABS material.
Described transparent flame-retardant antistatic ABS material joins and is processed into required batten in injection machine, described injection machine
Barrel temperature 190-240 DEG C, mold temperature 60-70 DEG C, injection pressure 6-10MPa.
The application of described transparent flame-retardant antistatic ABS material, this transparent flame-retardant antistatic ABS material is applied to electrical equipment instrument
Table, medical equipment, electron trade.
Relative to prior art, transparent flame-retardant antistatic ABS material of the present invention and preparation method thereof has following
Advantage:
(1) transparent flame-retardant antistatic ABS material of the present invention is through test, and its flame retardant rating reaches V-2 or V-1 level
Not, excellent in mechanical performance.
(2) transparent flame-retardant antistatic ABS material transparency of the present invention is more than 70%.
(3) transparent flame-retardant antistatic ABS material of the present invention is by adding antistatic additive, can make composite
Surface resistivity is from 1016Ω is reduced to 108Ω, antistatic effect is good.
(4) fire retardant is prepared as master batch by transparent flame-retardant antistatic ABS material of the present invention, and fire retardant can be made to exist
In blend scattered more uniform；The fire retardant using particle diameter little can make the light transmittance of material improve.
(5) preparation method of transparent flame-retardant antistatic ABS material of the present invention contributes to improving working environment.
(6) preparation method of transparent flame-retardant antistatic ABS material of the present invention is simple, handling ease, cost
Cheap, being highly suitable for electrical instrumentation, medical equipment, electron trade etc. i.e. needs fire-retardant, needs again the fields such as certain transparency
Popularization and application.
Detailed description of the invention
Unless otherwise indicated, term used herein is respectively provided with the implication that those skilled in the art's routine understands, in order to
Readily appreciate the present invention, terms more used herein have been carried out following definitions.
All of Digital ID, such as pH, temperature, time, concentration, including scope, be all approximation.It is to be understood that, although
Term " about " is all added before all of Digital ID of the clearest and the most definite narration.Simultaneously it will also be understood that, although the clearest and the most definite
Narration, reagent described herein is only example, and its equivalent is known in the art.
MABS described in the embodiment of the present invention selects the MABS TE-10S of NEC chemistry；
The MBS EM-500 of Korea S LG chemistry selected by toughener described in the embodiment of the present invention；
Antistatic additive described in the embodiment of the present invention is selected from the PELESTAT 6500 of Sanyo's chemical conversion；
Phosphorus-nitrogen containing flame retardant described in the embodiment of the present invention is Quadrafos, and described Quadrafos selects Ai Dike's
FP-2200；
Firebrake ZB described in the embodiment of the present invention selects the ZB-500 of Chengdu Kai Fei high-energy chemistry Industrial Co., Ltd；
Brominated triazine described in comparative example of the present invention selects the FR-245 of Dead Sea bromine company of Israel；
Fire retarding synergist described in comparative example of the present invention selects the S-05N of Yunnan Mu Liti industry company limited；
Melamine cyanurate described in comparative example of the present invention selects the MC-25 of BASF；
Tetrabromobisphenol A described in comparative example of the present invention selects the FR-1524 of Dead Sea bromine company of Israel；
Brominated epoxy described in comparative example of the present invention selects the CXB-714C that Korea S's space enters；
TDE described in comparative example of the present invention selects the 4010 of Ya Bao company of the U.S.；
The compositions that embodiment of the present invention and comparative example obtain uses iso standard to test its correlated performance.Test
The UL-94 vertical combustion Yi Shi U.S. ATLAS HVUL-2 that flame retardant rating uses；It is science and technology on woods that test light transmittance uses
Ls Cable Ltd.'s 105A luminous transmittance measuring；Antistatic behaviour tests its surface resistivity according to GB/T1410-2006.
The present invention is described in detail below in conjunction with embodiment.
A kind of transparent flame-retardant antistatic ABS material, is made up of the raw material including following weight portion: MABS60-85 part, anti-quiet
Electricity agent 10-15 part, fire-retardant master granule 10-20 part, toughener 5-25 part.
Described fire-retardant master granule is made up of the raw material including following weight portion: MABS 60-90 part, phosphorus-nitrogen containing flame retardant 10-
30 parts, Firebrake ZB 5-20 part.
The preparation method of described transparent flame-retardant antistatic ABS material, comprises the steps:
(1) joining in high-temperature mixing machine by MABS, phosphorus-nitrogen containing flame retardant and Firebrake ZB, carry out premixing, pelletize cools down
After obtain fire-retardant master granule；
(2) MABS, antistatic additive, fire-retardant master granule, toughener are sufficiently mixed 10-60 minute at high-speed mixer, obtain
Premix material；
(3) premix material is transported in double screw extruder through the pay-off of delicate metering, in the shearing, mixed of screw rod
Under refining and conveying, material fully melted, compound, then through extruding pelletization, be dried to obtain transparent flame-retarding antistatic ABS material
Material.
The processing conditions that described double screw extruder melt extrudes is as follows: district's temperature 180 DEG C, two district's temperature 190 DEG C,
Three district's temperature 200 DEG C, four district's temperature 210 DEG C, five district's temperature 220 DEG C, six district's temperature 220 DEG C, seven district's temperature 220 DEG C, eight district's temperature
Spend 220 DEG C, nine district's temperature 220 DEG C, ten district's temperature 220 DEG C, head temperature 230 DEG C；Screw speed is 200-800 rev/min；Double
The draw ratio of screw extruder is 40:1, and screw speed is 200-800 rev/min.
The application of described transparent flame-retardant antistatic ABS material, described transparent flame-retardant antistatic ABS material is applied to electricity
Instruments and meters, medical equipment or electron trade.
Embodiment 1-4, comparative example 1-4
The ABS composite material obtained after being prepared by the raw material that table 1 is listed with table 2 is molded into test by standard size
Standard batten, and carry out each performance test by testing standard.
Each material content (percentage by weight) of table 1 fire-retardant master granule
The concrete proportioning of each raw material and performance test data in table 2 embodiment and comparative example
From the embodiment of table 2 with in comparative example it can be seen that bromide fire retardant comparing, the present invention selects with MABS tree
Fat is the phosphorus-nitrogen containing flame retardant of carrier and Firebrake ZB fire-retardant master granule is used as fire retardant, and mechanical property is the most excellent, mobile performance
More excellent than traditional flame-proof ABS.The more important thing is, the more traditional flame-proof ABS of its light transmittance is greatly improved, and light transmittance can
To accomplish more than 70%.
It addition, by adding antistatic additive, the surface resistivity of compositions can be made from 1016Ω is reduced to 108Ω, anti-quiet
Electricity is respond well.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention
Within god and principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.
Claims (7)
1. a transparent flame-retardant antistatic ABS material, it is characterised in that: it is made up of the raw material including following weight portion:
Wherein, described Resin A is MABS.
Transparent flame-retardant antistatic ABS material the most according to claim 1, it is characterised in that: described fire-retardant master granule is by wrapping
The raw material including following weight portion is made:
Resin B 60-90 part,
Phosphorus-nitrogen containing flame retardant 10-30 part,
Firebrake ZB 5-20 part；
Wherein, described resin B is MABS；Described Resin A is identical or different with the specification of resin B.
Transparent flame-retardant antistatic ABS material the most according to claim 2, it is characterised in that: described phosphorus-nitrogen containing flame retardant
For one or both the mixture in Quadrafos, melamine cyanurate；The particle diameter of described Firebrake ZB is 2-4 μm.
Transparent flame-retardant antistatic ABS material the most according to claim 2, it is characterised in that: the light transmittance of described Resin A
> 80%, Izod notched impact strength > 10kJ/m2；The light transmittance of described resin B > 80%, Izod notched impact strength >
10kJ/m2。
Transparent flame-retardant antistatic ABS material the most according to claim 1, it is characterised in that: described toughener is that MBS type increases
Tough dose, ASA type toughener, one or more in EVA type toughener；Described antistatic additive is permanent type antistatic
Agent.
6. the preparation method of the transparent flame-retardant antistatic ABS material according to any one of claim 2-5, it is characterised in that: bag
Include following steps:
(1) resin B, phosphorus-nitrogen containing flame retardant and Firebrake ZB are joined in high-temperature mixing machine, carry out at a temperature of 170-250 DEG C
Premixing, obtains fire-retardant master granule after pelletize cooling；
(2) Resin A, fire-retardant master granule, toughener, antistatic additive are sufficiently mixed 10-60 minute at high-speed mixer, are premixed
Material；
(3) premix material is transported in double screw extruder through the pay-off of delicate metering, each section of screw rod temperature of extruder
Degree controls between 180-230 DEG C, and the draw ratio of double screw extruder is 25-40:1, and screw speed is 200-800 rev/min,
Under the shearing, mixing and conveying of screw rod, material fully melted, compound, then through extruding pelletization, be dried to obtain transparent resistance
Combustion antistatic ABS material.
7. the application of the transparent flame-retardant antistatic ABS material according to any one of claim 1-5, it is characterised in that: this is transparent
Flame-retardant and antistatic ABS materials application is in electrical instrumentation, medical equipment, electron trade.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106700390A (en) * | 2016-11-28 | 2017-05-24 | 广东聚航新材料研究院有限公司 | High specific gravity high-dispersibility and anti-impact ABS (Acrylonitrile Butadiene Styrene) material and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106700390A (en) * | 2016-11-28 | 2017-05-24 | 广东聚航新材料研究院有限公司 | High specific gravity high-dispersibility and anti-impact ABS (Acrylonitrile Butadiene Styrene) material and preparation method thereof |
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Application publication date: 20161102 |