CN106058180A - Anode lead paste for lead-acid storage batteries - Google Patents
Anode lead paste for lead-acid storage batteries Download PDFInfo
- Publication number
- CN106058180A CN106058180A CN201610525723.2A CN201610525723A CN106058180A CN 106058180 A CN106058180 A CN 106058180A CN 201610525723 A CN201610525723 A CN 201610525723A CN 106058180 A CN106058180 A CN 106058180A
- Authority
- CN
- China
- Prior art keywords
- parts
- lead
- acid
- storage batteries
- anode diachylon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/56—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of lead
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/06—Lead-acid accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Abstract
The invention discloses anode lead paste for lead-acid storage batteries. The anode lead paste is prepared from, by weight, 100 parts of lead powder, 10-12 parts of sulfuric acid, 10-12 parts of deionized water, 2-5 parts of stannous sulfate, 0.1-1 part of lignin fibers, 0.4-0.8 part of phosphoric acid, 1-3 parts of fumed silica and 1-6 parts of humic acid. The storage batteries prepared from the anode lead paste are high in initial capacity and long in cycle life, and charging speed and discharging speed of the lead-acid storage batteries are increased; due to intrinsic structural strength and dispersed network connection of the fumed silica, strength of battery plates is greatly improved, softening and shedding of lead-acid battery plate active materials in long-time charge-discharge cycles are avoided, and accordingly service lives of the lead-acid storage batteries are greatly prolonged.
Description
Technical field
The present invention relates to technical field of electrochemistry, be specifically related to the anode diachylon of a kind of lead-acid accumulator.
Background technology
Lead plaster be a kind of be made up of Hydrocerussitum (Ceruse), sulphuric acid, water and additive mix and blend concurrently biological reason, chemical change can
Plasticity paste mixture.In pipe, lead-acid accumulator grid type plate or pipe is manufactured respectively for filling on grid or squeezing to fill
Formula pole plate, its effect in lead-acid battery is mainly for the material needed for electrochemical reaction offer and storage.The lead plaster made
Having preferable plasticity, when making coated plate, lead plaster is with good adherence of on grid and be coated with uniformly and be full of grid lattice body, the most also needs
There is certain intensity, be amenable to the vibration of roll-in tool on opportunity and percussion after machine coated plate.When during manual pasting, pole plate is picked up
Lead plaster difficult drop-off also has some strength.Performance and the quality of lead-acid accumulator are mainly affected by lead paste formula.At present, domestic
The lead paste formula of electric boosted automobile-used lead-acid accumulator is different, the most directly uses the formula of common valve-regulated lead-acid battery, general
The formula of logical valve-control storage battery cannot solve resistance to over-discharge property and the problem of charge acceptance difference of accumulator.
Summary of the invention
The invention aims to the anode diachylon solving current lead-acid accumulator about above-mentioned problem, it is provided that
A kind of anode diachylon of lead-acid accumulator.
The present invention solves the technical scheme of above-mentioned technical problem employing: the anode diachylon of a kind of lead-acid accumulator, including
The raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), 10 ~ 12 parts of sulphuric acid, deionized water 10 ~ 12 parts, stannous sulfate 2 ~ 5 parts, lignin
Fiber 0.1 ~ 1 part, phosphoric acid 0.4 ~ 0.8 part, aerosil 1 ~ 3 part, humic acids 1 ~ 6 part.
Further, the anode diachylon of described a kind of lead-acid accumulator, including the raw material of following parts by weight: Hydrocerussitum (Ceruse) 100
Part, 11 parts of sulphuric acid, deionized water 11 parts, stannous sulfate 3 parts, lignin fibre 0.6 part, phosphoric acid 0.6 part, aerosil 2
Part, humic acids 4 parts.
Further, the anode diachylon of described a kind of lead-acid accumulator, including the raw material of following parts by weight: Hydrocerussitum (Ceruse) 100
Part, 10 parts of sulphuric acid, deionized water 10 parts, stannous sulfate 2 parts, lignin fibre 0.1 part, phosphoric acid 0.4 part, aerosil 1
Part, humic acids 1 part.
Further, the anode diachylon of described a kind of lead-acid accumulator, including the raw material of following parts by weight: Hydrocerussitum (Ceruse) 100
Part, 12 parts of sulphuric acid, deionized water 12 parts, stannous sulfate 5 parts, lignin fibre 1 part, phosphoric acid 0.8 part, aerosil 3 parts,
Humic acids 6 parts.
Further, described sulphuric acid is the sulfuric acid solution of 25 DEG C of lower densities 1.40.
The anode diachylon of above-mentioned a kind of lead-acid accumulator, after being on the waiting list raw material according to described parts by weight, by Hydrocerussitum (Ceruse), sulfur
Acid stannous, lignin fibre, aerosil and humic acids are placed in stirring container and carry out being dry mixed to uniform state, and addition is gone
Ionized water is stirred until homogeneous, and is subsequently adding sulphuric acid and after phosphoric acid stirs, and detects, goes out cream and obtain the lead plaster of the present invention.
Compared with prior art, beneficial effects of the present invention:
After the lead plaster using the present invention to prepare makes accumulator, there is the highest initial capacity and cycle life, improve plumbic acid
The charging rate of battery and the velocity of discharge, simultaneously because aerosil self structure intensity and scatternet thereof connect, electricity
The intensity of pond pole plate is greatly improved, it is to avoid lead-acid battery softening of plate active material when long-time charge and discharge cycles
With come off, so drastically increasing the service life of lead-acid battery.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described further.
Embodiment 1: the anode diachylon of a kind of lead-acid accumulator, including the raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), sulfur
Acid 11 parts, deionized water 11 parts, stannous sulfate 3 parts, lignin fibre 0.6 part, phosphoric acid 0.6 part, aerosil 2 parts, corruption
Phytic acid 4 parts.
Embodiment 2: the anode diachylon of a kind of lead-acid accumulator, including the raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), sulfur
Acid 10 parts, deionized water 10 parts, stannous sulfate 2 parts, lignin fibre 0.1 part, phosphoric acid 0.4 part, aerosil 1 part, corruption
Phytic acid 1 part.
Embodiment 3: the anode diachylon of a kind of lead-acid accumulator, including the raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), sulfur
Acid 12 parts, deionized water 12 parts, stannous sulfate 5 parts, lignin fibre 1 part, phosphoric acid 0.8 part, aerosil 3 parts, corruption are planted
Acid 6 parts.
Further, the sulphuric acid described in above-described embodiment 1-3 is the sulfuric acid solution of 25 DEG C of lower densities 1.40.
The anode diachylon of a kind of lead-acid accumulator described in the above embodiments 1-3, standby according to described parts by weight
After taking raw material, Hydrocerussitum (Ceruse), stannous sulfate, lignin fibre, aerosil and humic acids are placed in stirring container and do
Mix to uniform state, add deionized water and be stirred until homogeneous, be subsequently adding sulphuric acid and after phosphoric acid stirs, detect, go out
Cream obtains the lead plaster of the present invention.
Claims (5)
1. the anode diachylon of a lead-acid accumulator, it is characterised in that include the raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), sulfur
Acid 10 ~ 12 parts, deionized water 10 ~ 12 parts, stannous sulfate 2 ~ 5 parts, lignin fibre 0.1 ~ 1 part, phosphoric acid 0.4 ~ 0.8 part, gas phase
Silica 1 ~ 3 part, humic acids 1 ~ 6 part.
The anode diachylon of a kind of lead-acid accumulator the most according to claim 1, it is characterised in that include following parts by weight
Raw material: 100 parts of Hydrocerussitum (Ceruse), 11 parts of sulphuric acid, deionized water 11 parts, stannous sulfate 3 parts, lignin fibre 0.6 part, phosphoric acid 0.6 part,
Aerosil 2 parts, humic acids 4 parts.
The anode diachylon of a kind of lead-acid accumulator the most according to claim 1, it is characterised in that described a kind of lead acid storage battery
The anode diachylon in pond, including the raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), 10 parts of sulphuric acid, deionized water 10 parts, stannous sulfate 2
Part, lignin fibre 0.1 part, phosphoric acid 0.4 part, aerosil 1 part, humic acids 1 part.
The anode diachylon of a kind of lead-acid accumulator the most according to claim 1, it is characterised in that described a kind of lead acid storage battery
The anode diachylon in pond, including the raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), 12 parts of sulphuric acid, deionized water 12 parts, stannous sulfate 5
Part, lignin fibre 1 part, phosphoric acid 0.8 part, aerosil 3 parts, humic acids 6 parts.
5. according to the anode diachylon of a kind of lead-acid accumulator described in any one of claim 1-4, it is characterised in that described sulphuric acid
It it is the sulfuric acid solution of 25 DEG C of lower densities 1.40.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610525723.2A CN106058180A (en) | 2016-07-06 | 2016-07-06 | Anode lead paste for lead-acid storage batteries |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610525723.2A CN106058180A (en) | 2016-07-06 | 2016-07-06 | Anode lead paste for lead-acid storage batteries |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106058180A true CN106058180A (en) | 2016-10-26 |
Family
ID=57200994
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610525723.2A Pending CN106058180A (en) | 2016-07-06 | 2016-07-06 | Anode lead paste for lead-acid storage batteries |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102496723A (en) * | 2011-12-31 | 2012-06-13 | 河南三丽电源股份有限公司 | Storage battery lead paste used for powering electric automobile and preparation method thereof |
| CN103000830A (en) * | 2011-09-12 | 2013-03-27 | 崔荣龙 | Exhaust type acid and flame resistant lead acid storage battery used for electric road vehicles |
| CN103199243A (en) * | 2013-03-14 | 2013-07-10 | 超威电源有限公司 | Positive lead paste of lead-acid storage battery |
| CN103236523A (en) * | 2013-04-16 | 2013-08-07 | 山东圣阳电源科技有限公司 | Vehicle battery positive plate lead paste formula |
| CN104466172A (en) * | 2014-11-24 | 2015-03-25 | 天能电池集团（安徽）有限公司 | High-performance lead paste composition |
| CN105489847A (en) * | 2016-01-07 | 2016-04-13 | 厦门马特高科新能源有限公司 | Lead-acid battery through-hole polar plate with high specific energy and long service life, and lead-acid battery constituted by same |
-
2016
- 2016-07-06 CN CN201610525723.2A patent/CN106058180A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103000830A (en) * | 2011-09-12 | 2013-03-27 | 崔荣龙 | Exhaust type acid and flame resistant lead acid storage battery used for electric road vehicles |
| CN102496723A (en) * | 2011-12-31 | 2012-06-13 | 河南三丽电源股份有限公司 | Storage battery lead paste used for powering electric automobile and preparation method thereof |
| CN103199243A (en) * | 2013-03-14 | 2013-07-10 | 超威电源有限公司 | Positive lead paste of lead-acid storage battery |
| CN103236523A (en) * | 2013-04-16 | 2013-08-07 | 山东圣阳电源科技有限公司 | Vehicle battery positive plate lead paste formula |
| CN104466172A (en) * | 2014-11-24 | 2015-03-25 | 天能电池集团（安徽）有限公司 | High-performance lead paste composition |
| CN105489847A (en) * | 2016-01-07 | 2016-04-13 | 厦门马特高科新能源有限公司 | Lead-acid battery through-hole polar plate with high specific energy and long service life, and lead-acid battery constituted by same |
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Application publication date: 20161026 |