CN106058120B - Battery current collector and alkaline battery - Google Patents

Battery current collector and alkaline battery Download PDF

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Publication number
CN106058120B
CN106058120B CN201610571591.7A CN201610571591A CN106058120B CN 106058120 B CN106058120 B CN 106058120B CN 201610571591 A CN201610571591 A CN 201610571591A CN 106058120 B CN106058120 B CN 106058120B
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CN
China
Prior art keywords
breathable
battery
air hole
lamina
sealing ring
Prior art date
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Application number
CN201610571591.7A
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Chinese (zh)
Other versions
CN106058120A (en
Inventor
钱明君
施斌斌
胡春益
陈国标
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhongyin Ningbo Battery Co Ltd
Original Assignee
Zhongyin Ningbo Battery Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Priority to CN201610571591.7A priority Critical patent/CN106058120B/en
Publication of CN106058120A publication Critical patent/CN106058120A/en
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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30Arrangements for facilitating escape of gases
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/24Alkaline accumulators
    • H01M10/28Construction or manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/102Primary casings; Jackets or wrappings characterised by their shape or physical structure
    • H01M50/107Primary casings; Jackets or wrappings characterised by their shape or physical structure having curved cross-section, e.g. round or elliptic
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/183Sealing members
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30Arrangements for facilitating escape of gases
    • H01M50/35Gas exhaust passages comprising elongated, tortuous or labyrinth-shaped exhaust passages
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30Arrangements for facilitating escape of gases
    • H01M50/394Gas-pervious parts or elements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/572Means for preventing undesired use or discharge
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sealing Battery Cases Or Jackets (AREA)
  • Gas Exhaust Devices For Batteries (AREA)

Abstract

The invention discloses battery collector and alkaline batteries,Including seal ring assembly,Cathode bottom cover and conductor nail,Seal ring assembly includes the center column for inserting conductor nail,The peripheral part fitted closely with battery case inner wall and the interconnecting piece between center column and peripheral part,Air hole is provided on interconnecting piece,The centre or side of air hole are provided with breathable lamina or breathable films made of expanded PTFE or ptfe composite,Breathable lamina or breathable films prevent the alkalies of inside battery from being reserved outward from air hole,Its advantage is that being adopted as the air hole in breathable lamina that expanded PTFE or ptfe composite make or breathable films combination sealing ring to substitute the weak floor in conventional seals circle,Utilize polytetrafluoroethylene (PTFE) alkali resistant,High temperature resistant,Advantage least easy to aging makes the service life of collector greatly increase in plastics.The good gas permeability of polytetrafluoroethylene (PTFE) is utilized simultaneously, the gas that inside battery slowly generates is discharged, and inside battery is made not generate gas accumulation.

Description

Battery current collector and alkaline battery
Technical field
The present invention relates to a kind of cell sealing and blast resistance constructions, more particularly, to battery current collector and alkaline battery.
Background technology
The structure that alkaline battery plays sealing function includes battery bottom cover, the sealing ring on the inside of battery bottom cover and institute State bottom cover be integrated and across sealing ring newel conductive nail and battery outer surface box hat, and the box hat utilize its Together with the crimping force at edge seals bottom cover with the edge of sealing ring.
In general, the sealing ring of alkaline battery be there are the plastics with certain resilience to be made, such as PP and nylon, Ke Yishi Nylon66 fiber, nylon 610, nylon 612, nylon 1010.
Battery is during long term storage and use, because the reasons such as the self discharge of battery cathode, impurity liberation of hydrogen make in battery Air pressure increase.In order to make cell safety use, the sealing ring of present alkaline battery be designed with substantially thickness about 0.1~ The weak floor of 0.3mm.Weak floor and sealing ring single injection-molded.
PP or nylon material are easy aging in lye, and the aging phenomenon of weak layer surface can show even more serious, and And since inside battery air pressure makes the sealing ring moment of battery bear an outside stress, this can lead to the weak floor of sealing ring Accelerated ageing.If meeting severe external environment, such as high temperature, high humidity, the aging of sealing ring weak floor is with regard to even more serious.
After sealing ring weak floor cannot bear cell internal pressure, weak floor will be broken, inside battery gas and electricity The electrolyte in pond will be released out of battery, and such alkaline battery occurs as soon as leakage.
In the past, we were generally by reduction gas generated (adjustment house formulations, reduction impurity introducing etc.), sealing ring Protective rubber is applied at weak floor, changes the schemes such as sealing ring material to realize the promotion of leak resistance after its storage.
Invention content
Technical problem to be solved by the invention is to provide a kind of electricity that can be constantly discharged to inside battery gas Pond collector avoids the increase of inside battery air pressure, while can prevent the solution leakage of inside battery again.The present invention is further The technical issues of be to provide a kind of alkaline battery being equipped with above-mentioned battery current collector.
Technical solution is used by the present invention solves above-mentioned technical problem:Battery collector, including it is seal ring assembly, negative Pole bottom cover and conductor nail, seal ring assembly includes the center column for inserting conductor nail, it is outer to be fitted closely with battery case inner wall Circumference and the interconnecting piece between center column and peripheral part, it is characterised in that it is provided with air hole on the interconnecting piece, The centre or side of the air hole are provided with breathable lamina or breathable films made of polytetrafluoroethylene (PTFE), and described is ventilative Thin slice or breathable films prevent the alkalies of inside battery from being reserved outward from air hole.Can also be expanded PTFE or poly- Tetrafluoroethene composite material makes flakiness or form of film, simple in processing technology.
The further preferred embodiment of the present invention is:The breathable lamina or breathable films attaches and is fixed on air hole Inner or outer side.Breathable lamina or breathable films seal air hole, prevent the solution leakage of inside battery from going out, and electricity Gas inside pond is discharged by breathable lamina or breathable films, prevents inside battery air pressure excessive.
The further preferred embodiment of the present invention is:The seal ring assembly includes upper sealing ring and lower seal, described Air hole be made of the first air hole of lower seal and the second air hole of upper sealing ring, first air hole and Two air holes are aligned, and the breathable lamina or breathable films are crushed between the upper sealing ring and lower seal.It is ventilative Thin slice or breathable films can be entirely between upper sealing ring and lower seals, under the premise of ensureing good air permeability, energy Prevent the leakage of electrolyte inside.
The further preferred embodiment of the present invention is:The center column is located in lower seal, the periphery position In in lower seal.
The further preferred embodiment of the present invention is:The inner end of the breathable lamina or breathable films extends to center column Outer wall, the outer end of the breathable lamina or breathable films extends to the inner wall of peripheral part.
The further preferred embodiment of the present invention is:The Air permenbility of the breathable lamina or breathable films is 60-80L/ ㎡ .S。
The thickness of the breathable lamina or breathable films is the ㎜ of 0.01 ㎜~3.
The further preferred embodiment of the present invention is:The upper sealing ring include have centre bore lug boss and with protrusion The connected round plate in portion, multiple second air holes are distributed on the round plate.
The further preferred embodiment of the present invention is:With alkaline-resisting between the upper sealing ring, breathable lamina and lower seal The fluid sealant of property further seals.So that the electrolyte of inside battery will not leak.
The further preferred embodiment of the present invention is:Alkaline battery, it is characterised in that any described including claim 1-7 Battery current collector
Compared with prior art, it is an advantage of the invention that using breathable lamina made of polytetrafluoroethylene (PTFE) or breathable films knot The air hole in sealing ring is closed to substitute the weak floor in conventional seals circle, using in polytetrafluoroethylene (PTFE) alkali resistant, high temperature resistant, plastics Advantage least easy to aging makes the service life of collector greatly increase.In traditional handicraft, released because inside battery gas is unable to get It puts, control interior gas amount becomes the bottleneck of alkaline battery development.One comes the degree of purity to raw material, box hat and conductive nail coating Consistency, production process cleannes, production equipment material and wearability require it is all very high, this just considerably increase raw material at This and production management cost, product quality are influenced very big by human factor.Two come in order to keep internal gas yield small, it is ensured that electricity The safety in pond, the resistance to leakage of the resistance to ag(e)ing of sealing element, battery, it has to reduce the content of active material, or be added Inhibitor, this has just limited to the raising of battery electrical property.The present invention utilizes the good gas permeability of polytetrafluoroethylene (PTFE), by inside battery The gas slowly generated discharges, and inside battery is made not generate gas accumulation.In this way reduce the stress of sealing ring, aging is existing As reducing.And air pressure inside greatly reduces, and not will produce battery explosion phenomenon, is conducive to the security performance of battery, also breaks The obstruction condition of the raising of battery electrical property.The present invention is to the degree of purity of raw material, box hat and conductive nail plated layer compact simultaneously Degree, production process cleannes, production equipment material and wearability require all to substantially reduce, and reduce cost, and bigger is created for enterprise Profit.
Description of the drawings
Fig. 1 is the sectional view of the alkaline battery of the present invention;
Fig. 2 is enlarged drawing at A in Fig. 1;
Fig. 3 is the sectional view of the lower seal of the present invention;
Fig. 4 is the stereogram of the lower seal of the present invention;
Fig. 5 is the sectional view of the upper sealing ring of the present invention;
Fig. 6 is the stereogram of the upper sealing ring of the present invention;
Fig. 7 is the breathable lamina of the present invention or the stereogram of breathable films;
Fig. 8 is the sectional view of the cathode bottom cover and conductive nail of the present invention;
Fig. 9 is the stereogram of the cathode bottom cover and conductive nail of the present invention.
Specific implementation mode
Below in conjunction with attached drawing embodiment, present invention is further described in detail.
Battery collector, including seal ring assembly 1, cathode bottom cover 2 and conductor nail 3, seal ring assembly 1 include inserting conductor The center column 4 and the peripheral part 6 that fits closely of 5 inner wall of battery case of nail 3 and between center column 4 and peripheral part 6 Interconnecting piece 7, air hole 8 is provided on interconnecting piece 7, and the centre or side of air hole 8 are provided with made of polytetrafluoroethylene (PTFE) thoroughly Gas thin slice or breathable films 9, breathable lamina or breathable films 9 prevent the alkalies of inside battery from being reserved outward from air hole 8.Thoroughly Gas thin slice or breathable films 9 attach and are fixed on the inner or outer side of air hole 8.Seal ring assembly 1 includes 11 He of lower seal Upper sealing ring 12, air hole 8 are made of the first air hole 81 of lower seal 11 and the second air hole 82 of upper sealing ring 12, the One air hole 81 and the alignment of the second air hole 82, breathable lamina or breathable films 9 are crushed on lower seal 11 and upper sealing ring 12 Between.Breathable films or breathable lamina can also be that expanded PTFE or ptfe composite are made.
Center column 4 is located in lower seal 11, and peripheral part 6 is located in lower seal 11.
The inner end of breathable lamina or breathable films 9 extends to the outer wall of center column 4, breathable lamina or breathable films 9 Outer end extends to the inner wall of peripheral part 6.Breathable lamina or breathable films 9 or expanded PTFE or polytetrafluoroethylene (PTFE) Composite material is made, and is in holey, has certain porosity.These small boring ratio hydrones of this material are small, compare gas Molecule is big, while being in irregular alignment, is the material of permeable watertight.
Alkaline battery includes the battery current collector of above structure.
The lower seal 11 of the present invention can be once molded by the thermoplastic macromolecule material with certain resilience Type is made.Breathable lamina or film 9 made of expanded PTFE or ptfe composite, centre bore omit for outer diameter More than the circular hole of the center column outer diameter of lower seal.It is first ventilative must to cover lower seal 11 for thin slice or 9 area of film Hole 81, thickness are set according to each battery and material property situation, are selected between 0.01 ㎜ to 3 ㎜, preferably 2 ㎜.
Polytetrafluoroethylene (PTFE) be plastics king, but its can not injection molding, the structure of thin slice or film 9 of the present invention is simple, adds The various facility of work mode, it is of low cost.The electrical insulating property of polytetrafluoroethylene (PTFE) is good, heatproof span is big, compression resilience is well very suitable It shares in battery seal is made.And it is with excellent chemical stability, corrosion resistance and good ageing resistance, (energy Long-term work at a temperature of+250 DEG C to -180 DEG C), this makes it be placed in inside battery also extremely difficult aging for a long time.Selected simultaneously Polytetrafluoroethylene film or piece permeable watertight, the gas that inside battery slowly generates is discharged, inside battery is made not generate Gas is accumulated.The stress of seal ring assembly reduces in this way, and aging phenomenon reduces.And air pressure inside greatly reduces, and not will produce Battery explosion phenomenon is conducive to security performance.
The round plate that upper sealing ring 12 includes and has the lug boss 121 of longitudinally through centre bore, is connected with lug boss 121 122, set on second air hole 82 through longitudinal direction opposite with lower seal 11 of round plate 122.11 newel of lower seal Body 4 is embedded into the centre bore of sealing ring 12, this makes the center column 4 of lower seal 11 add the active force of conductive nail 3 By force, sealing effect is more preferable.
The requirement of 12 material of upper sealing ring is wide in range, can be high molecular material or metal material.Its thickness is according to the intensity of material It is different and different.In general it is slightly better than the material of lower seal using rigidity, not only acts as sealing function, more plays certain Supporting role.
To keep sealing effect good, it is made in upper sealing ring 12, expanded PTFE or ptfe composite Breathable lamina 9, can further be sealed with the fluid sealant of alkali resistance between lower seal 11.
It is cathode bottom cover 2 on upper sealing ring 12, cathode bottom cover 2 is rotary body, can be one time punching molded by steel band, Including intermediate lands, periphery horizontal plane and the venthole for being set to boss side surfaces.Its center is connected with conductive nail 3.In collector In assembling process, conductive nail 3 is inserted into 11 centre bore of lower seal, and cathode bottom cover is embedded into outside sealing ring and lower seal In the caulking groove that circumference is constituted.
In battery forming process, each member in tight of above-mentioned collector is pressed in by groove slot top by bending edge curling seal Between box hat oral area bending part.On the outside of lower seal peripheral part alkaline-resisting fluid sealant is coated between box hat inner wall.

Claims (8)

1. battery current collector, including seal ring assembly, cathode bottom cover and conductor nail, seal ring assembly includes in inserting conductor nail The peripheral part that stem body and battery case inner wall fit closely and the interconnecting piece between center column and peripheral part, it is special It levies and is to be provided with air hole on the interconnecting piece, the centre of the air hole is provided with by expanded PTFE or gathers Breathable lamina or breathable films made of tetrafluoroethene composite material, breathable lamina or breathable films slowly generate inside battery Gas discharge, and the breathable lamina or breathable films prevent the alkalies of inside battery from being stayed outward from air hole Go out;The seal ring assembly includes upper sealing ring and lower seal, the air hole by lower seal the first air hole Formed with the second air hole of upper sealing ring, first air hole and the alignment of the second air hole, the breathable lamina or Breathable films are crushed between the upper sealing ring and lower seal.
2. battery current collector according to claim 1, it is characterised in that the center column is located in lower seal, institute The peripheral part stated is located in lower seal.
3. battery current collector according to claim 2, it is characterised in that the inner end of the breathable lamina or breathable films Extend to the outer wall of center column, the outer end of the breathable lamina or breathable films extends to the inner wall of peripheral part.
4. battery current collector according to claim 1, it is characterised in that the breathable lamina or breathable films is breathed freely Amount is 60-80L/ ㎡ .S.
5. battery current collector according to claim 1, it is characterised in that the thickness of the breathable lamina or breathable films For the ㎜ of 0.01 ㎜~3.
6. battery current collector according to claim 1, it is characterised in that the upper sealing ring includes having centre bore Lug boss and the round plate being connected with lug boss, multiple second air holes are distributed on the round plate.
7. battery current collector according to claim 1, it is characterised in that upper sealing ring, breathable lamina and the lower sealing It is further sealed with the fluid sealant of alkali resistance between circle.
8. alkaline battery, it is characterised in that including any battery current collectors of claim 1-7.
CN201610571591.7A 2016-07-18 2016-07-18 Battery current collector and alkaline battery Active CN106058120B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610571591.7A CN106058120B (en) 2016-07-18 2016-07-18 Battery current collector and alkaline battery

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Application Number Priority Date Filing Date Title
CN201610571591.7A CN106058120B (en) 2016-07-18 2016-07-18 Battery current collector and alkaline battery

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CN106058120A CN106058120A (en) 2016-10-26
CN106058120B true CN106058120B (en) 2018-08-31

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109509847A (en) * 2017-09-15 2019-03-22 惠州市竤泰科技有限公司 A kind of miniature lithium ion battery and its manufacturing method
WO2021079163A1 (en) * 2019-10-21 2021-04-29 W.L. Gore & Associates G.K. Battery with improved gas to moisture permeability ratio

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1310866A (en) * 1998-07-29 2001-08-29 杜拉塞尔公司 End cap assembly for an alkaline cell
CN201804924U (en) * 2010-09-24 2011-04-20 比亚迪股份有限公司 Alkaline cell sealing ring and alkaline cell using same
CN102299282A (en) * 2010-06-28 2011-12-28 黎永康 Explosion-proof device of power lithium battery top cover and manufacturing method thereof
JP2013097890A (en) * 2011-10-28 2013-05-20 Fujimori Kogyo Co Ltd Sealing member, method for manufacturing sealing member, and vessel for power storage device
CN205303567U (en) * 2015-12-04 2016-06-08 东莞乔登节能科技有限公司 Lithium cell blast resistant construction
CN205882039U (en) * 2016-07-18 2017-01-11 中银(宁波)电池有限公司 Battery collector body and alkaline battery

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005056742A (en) * 2003-08-06 2005-03-03 Matsushita Electric Ind Co Ltd Alkaline dry cell

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1310866A (en) * 1998-07-29 2001-08-29 杜拉塞尔公司 End cap assembly for an alkaline cell
CN102299282A (en) * 2010-06-28 2011-12-28 黎永康 Explosion-proof device of power lithium battery top cover and manufacturing method thereof
CN201804924U (en) * 2010-09-24 2011-04-20 比亚迪股份有限公司 Alkaline cell sealing ring and alkaline cell using same
JP2013097890A (en) * 2011-10-28 2013-05-20 Fujimori Kogyo Co Ltd Sealing member, method for manufacturing sealing member, and vessel for power storage device
CN205303567U (en) * 2015-12-04 2016-06-08 东莞乔登节能科技有限公司 Lithium cell blast resistant construction
CN205882039U (en) * 2016-07-18 2017-01-11 中银(宁波)电池有限公司 Battery collector body and alkaline battery

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