CN106054482B - A kind of array substrate and preparation method thereof and display device - Google Patents

A kind of array substrate and preparation method thereof and display device Download PDF

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Publication number
CN106054482B
CN106054482B CN201610682390.4A CN201610682390A CN106054482B CN 106054482 B CN106054482 B CN 106054482B CN 201610682390 A CN201610682390 A CN 201610682390A CN 106054482 B CN106054482 B CN 106054482B
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Prior art keywords
alignment mark
black matrix
array substrate
preparation
matrix film
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CN106054482A (en
Inventor
江亮亮
唐文浩
戴珂
尹傛俊
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BOE Technology Group Co Ltd
Hefei Xinsheng Optoelectronics Technology Co Ltd
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BOE Technology Group Co Ltd
Hefei Xinsheng Optoelectronics Technology Co Ltd
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    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/136Liquid crystal cells structurally associated with a semi-conducting layer or substrate, e.g. cells forming part of an integrated circuit
    • G02F1/1362Active matrix addressed cells
    • G02F1/136209Light shielding layers, e.g. black matrix, incorporated in the active matrix substrate, e.g. structurally associated with the switching element
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/136Liquid crystal cells structurally associated with a semi-conducting layer or substrate, e.g. cells forming part of an integrated circuit
    • G02F1/1362Active matrix addressed cells
    • G02F1/136286Wiring, e.g. gate line, drain line
    • G02F1/136295Materials; Compositions; Manufacture processes

Abstract

The present invention provides a kind of array substrate and preparation method thereof and display device.The preparation method of the array substrate includes: to have the region of alignment mark to form alignment mark coating in the formation of corresponding substrate using patterning processes;The region other than alignment mark forms black matrix film on substrate;Alignment mark coating is removed by exposing, to expose alignment mark;Technique is patterned to black matrix film, to form the figure of black matrix;Wherein, the exposure wavelength of alignment mark coating is different from the exposure wavelength of black matrix film.The black matrix film that the preparation method of the array substrate can be avoided higher optical density (optical density is usually >=4.0) is interfered caused by the identification of alignment mark, crawl and positioning in exposure process, enable black matrix film in exposure by alignment mark exactitude position, to not only increase the exposure accuracy of black matrix, and improve the exposure quality and performance of array substrate.

Description

A kind of array substrate and preparation method thereof and display device
Technical field
The present invention relates to field of display technology, and in particular, to a kind of array substrate and preparation method thereof and display device.
Background technique
In the field thin film transistor liquid crystal display TFT-LCD, generally pass through sealant (Sealant) for color film CF substrate It is combined together with array Array substrate.It is usually black in one layer of color film CF substrate side preparation in traditional liquid crystal display panel Matrix (BM, Black Matrix) blocks the gap between each sub-pixels for separating each sub-pixels, prevent colour mixture and Light leakage;And the technology of color film CF substrate or black matrix BM preparation on array Array substrate is called COA (CF On Array, CF substrate are attached at Array substrate) or BOA (BM On Array, BM are attached at Array substrate), COA and BOA can To solve the problems, such as that BM lightproof area caused by array substrate, the dislocation of color membrane substrates pairing and Array light-leaking area are unmatched, Pixel aperture ratio and panel transmitance are promoted, is particularly useful for flexible displays.
But due to black matrix BM optical density OD with higher, after being coated with BM photoresist glue directly on Array substrate, exposure The exposure light that equipment is often used can not penetrate BM layers, so that black matrix mask plate BM Mask can be interfered right on Array substrate Identification, crawl and the positioning of alignment mark Mark, so that black matrix mask plate BM Mask can not be carried out accurately with Array substrate Contraposition causes exposure machine that can only rely on the physical mechanical pair of equipment itself and Array substrate and black matrix mask plate BM Mask Position, and can not be corrected and be adjusted in advance referring to above-mentioned alignment mark Mark, the exposure accuracy of BM is greatly reduced, battle array is caused Black matrix figure BM Pattern total spacing TP (Total Pitch) error on column substrate is big, i.e. BM Pattern exposure Actual value and design value deviation CD Bias are larger, eventually lead to array substrate entirety film surface quality and dysfunction.
Summary of the invention
The present invention is directed to the above-mentioned technical problems in the prior art, provide a kind of array substrate and preparation method thereof and Display device.The black matrix film that the preparation method of the array substrate can be avoided higher optical density (optical density is usually >=4.0) exists It is interfered caused by the identification of alignment mark, crawl and positioning in exposure process, enables black matrix film in exposure by right Position label exactitude position, to not only increase the exposure accuracy of black matrix, and improve array substrate exposure quality and Performance.
The present invention provides a kind of preparation method of array substrate, comprising: step S1: using patterning processes in corresponding substrate The region for being formed with alignment mark forms alignment mark coating;
Step S2: the region other than the alignment mark forms black matrix film over the substrate;
Step S3: the alignment mark coating is removed by exposure, to expose the alignment mark;
Step S4: technique is patterned to the black matrix film, to form the figure of black matrix;
Wherein, the exposure wavelength of the alignment mark coating is different from the exposure wavelength of the black matrix film.
Preferably, the alignment mark coating uses near-infrared light-sensitive material.
Preferably, the near-infrared light-sensitive material includes the polymer containing adjacent nitro benzyl, containing adjacent nitro benzyl The monomer of the bromo- umbelliferone polymer of monomer, 4- or the bromo- umbelliferone of 4-.
Preferably, 3-5 times with a thickness of the black matrix film thickness of the alignment mark coating.
Preferably, the black matrix film with a thickness of 0.9-1.2um, the alignment mark coating with a thickness of 2.7- 6um。
Preferably, the alignment mark coating is exposed using near infrared light, using UV light to the black matrix Film is exposed.
Preferably, to the alignment mark coating exposure finish, and to the black matrix film be patterned technique it Before further include: the substrate is cleaned, to remove the remaining alignment mark coating in the alignment mark region, is made The alignment mark is exposed;
The substrate is dried.
Preferably, described technique is patterned to the black matrix film to include:
The alignment mark is identified and positioned;
The position of the mask plate of the figure of the black matrix is used to form according to alignment mark adjustment;
It is exposed exposure light to the black matrix film through the mask plate.
Preferably, the alignment mark coating is formed using mask plate technique or printing technology.
Preferably, over the substrate formed black matrix before further include: over the substrate formed grid, active layer, Source-drain electrode and pixel electrode;
The alignment mark uses material identical with the grid or the source-drain electrode, and is formed simultaneously.
Preferably, the alignment mark is formed in the edge region of the substrate, the shape packet of the alignment mark Include " ten " font, circle, rectangular or bar shaped.
The present invention also provides a kind of array substrate, the array substrate is prepared using the preparation method of above-mentioned array substrate It forms.
The present invention also provides a kind of display devices, including above-mentioned array substrate.
Beneficial effects of the present invention: the preparation method of array substrate provided by the present invention passes through the shape in corresponding substrate It is respectively formed alignment mark coating and black matrix film at the region other than the region and alignment mark for having alignment mark, and first will Alignment mark coating is by exposure removal, then the figure for using patterning processes to form black matrix, due to alignment mark coating It is different with the exposure wavelength of black matrix film, so the two will not be interfered and be influenced between each other in exposure, so as to Avoid the black matrix film of higher optical density (optical density usually >=4.0) in exposure process to the identification of alignment mark, crawl and It is interfered caused by positioning, enables black matrix film in exposure by alignment mark exactitude position, and then not only increase black square The exposure accuracy of battle array, and improve the exposure quality and performance of array substrate.
Display device provided by the present invention is improved by using the array substrate that above-mentioned preparation method is prepared The preparation quality of the display device, to improve the display quality and performance of the display device.
Detailed description of the invention
Fig. 1 is the schematic diagram that alignment mark coating and black matrix film are formed on the substrate in the embodiment of the present invention 1;
Fig. 2 be array substrate preparation method in the cross-sectional view and top view of alignment mark coating is formed on the substrate;
Fig. 3 be array substrate preparation method in the cross-sectional view and top view of black matrix film is formed on the substrate;
Fig. 4 is the cross-sectional view and top view that are exposed to alignment mark coating in the preparation method of array substrate;
Fig. 5 be array substrate preparation method in alignment mark coating is exposed after expose alignment mark section view Figure and top view;
Fig. 6 is the cross-sectional view and top view that are exposed to black matrix film in the preparation method of array substrate;
Fig. 7 be array substrate preparation method in black matrix film is exposed after formed black matrix figure cross-sectional view And top view.
Description of symbols therein:
1. substrate;2. alignment mark;3. alignment mark coating;4. black matrix film;5. black matrix mask plate;6. black matrix Figure;7. functional film layer.
Specific embodiment
To make those skilled in the art more fully understand technical solution of the present invention, with reference to the accompanying drawing and it is embodied Mode is described in further detail a kind of array substrate provided by the present invention and preparation method thereof and display device.
Embodiment 1:
The present embodiment provides a kind of preparation methods of array substrate, as shown in Fig. 1-Fig. 7, comprising: step S1: using composition Technique has the region of alignment mark 2 to form alignment mark coating 3 in the formation of corresponding substrate 1.Step S2: right on substrate 1 Region other than the label 2 of position forms black matrix film 4.Step S3: alignment mark coating 3 is removed by exposing, to expose Alignment mark 2.Step S4: being patterned technique to black matrix film 4, to form the figure 6 of black matrix.Wherein, alignment mark covers The exposure wavelength of cap rock 3 is different from the exposure wavelength of black matrix film 4.
The preparation method by the formation in corresponding substrate 1 have alignment mark 2 region and alignment mark 2 other than region It is respectively formed alignment mark coating 3 and black matrix film 4, and first by alignment mark coating 3 by exposure removal, then uses structure Figure technique forms the figure 6 of black matrix, since alignment mark coating 3 is different with the exposure wavelength of black matrix film 4, so the two It will not interfere and influence between each other in exposure, so as to avoid higher optical density (optical density is usually >=4.0) Black matrix film 4 is interfered caused by the identification, crawl and positioning of alignment mark 2 in exposure process, is exposing black matrix film 4 When can be by 2 exactitude position of alignment mark, and then not only increase the exposure accuracy of black matrix, and improve array substrate Exposure quality and performance.
It should be noted that the patterning processes for forming alignment mark coating 3 are mask plate technique, including exposure and imaging Technique;Alternatively, the patterning processes for forming alignment mark coating 3 are printing technology.Wherein to the patterning processes packet of black matrix film 4 Include the exposure and imaging technique to black matrix film 4.
In the present embodiment, alignment mark coating 3 uses near-infrared light-sensitive material.Due to being used in exposure machine to near-infrared The exposure wavelength that light-sensitive material is decomposed is generally focused within the scope of 740-750nm, and for black matrix material in exposure machine Expect that the exposure wavelength decomposed is generally focused on 350-450nm, so alignment mark coating 3 and black matrix film 4 are exposing When will not interfere and influence between each other.Near-infrared light-sensitive material can be formed a film by coating processes and printing technology, so It can be realized by overexposure to its photodegradation or degradation, preparation and treatment process are simple.
Wherein, near-infrared light-sensitive material includes the polymer containing adjacent nitro benzyl, the monomer containing adjacent nitro benzyl, 4- The monomer of bromo- umbelliferone polymer or the bromo- umbelliferone of 4-.Certainly, near-infrared light-sensitive material is also possible to it His material.
It should be noted that alignment mark coating 3 can also use other materials, as long as exposure wavelength and black matrix film 4 exposure wavelength is different.
In the present embodiment, 3-5 times with a thickness of 4 thickness of black matrix film of alignment mark coating 3.So set, right In the film forming procedure of position label coating 3 and black matrix film 4, it can prevent black matrix film 4 from covering alignment mark coating 3, To avoid in the subsequent exposure process to two film layers, black matrix film 4 causes to block shadow to the exposure of alignment mark coating 3 It rings.
In the present embodiment, black matrix film 4 with a thickness of 0.9-1.2um, alignment mark coating 3 with a thickness of 2.7-6um. Wherein, black matrix film 4 with a thickness of its conventional film forming thickness, when preparation, first formed using mask plate technique or printing technology Alignment mark coating 3 (as shown in Figure 2) is then coated with to form black matrix film 4 (as shown in Figure 3), alignment mark coating 3 3-5 times in 4 thickness of black matrix film of thickness control.In addition, length and width of the alignment mark coating 3 in corresponding 2 region of alignment mark Dimension control is in grade, and the thickness and precision control of alignment mark coating 3 is in the micron-scale.
In the present embodiment, step S1: the formation using patterning processes in corresponding substrate 1 has the region of alignment mark 2 to be formed Alignment mark coating 3 includes: firstly, alignment mark coating 3 passes through coating or printing-filming;Alignment mark coating 3 at When film finishes, alignment mark coating 3 is dried.In addition, when the film forming of black matrix film 4 finishes in step s 2, to black square Battle array film 4 is dried.The drying condition of above-mentioned drying is 90 DEG C or so, is dried about 90 seconds.First to the register guide after film forming Note coating 3 is dried, and alignment mark coating 3 can be made to shape substantially, prevents from covering in the alignment mark of near liquid state Other regional diffusions on substrate 1 of cap rock 3.The black matrix film 4 after film forming is dried afterwards, alignment mark is covered so as to subsequent Cap rock 3 and black matrix film 4 are exposed.
It should be noted that can also be dried again after alignment mark coating 3 and black matrix film 4 all form a film It is dry.
In the present embodiment, in step S3 after black matrix film forming, first alignment mark coating 3 is exposed (such as Fig. 4 institute Show).Specifically: alignment mark coating 3 is exposed using near infrared light, in exposure machine, is pre-designed a near-infrared Light lamp tube, control fluorescent tube are 2mm apart from 1 surface distance of substrate, and illumination wavelength range concentrates on 740-750nm, and light exposure is 20mW/cm2, time for exposure are 30 minutes;The quick material membrane of near-infrared carries out photodegradation or degradation under the irradiation of near infrared light, absolutely Major part is removed.It is finished to the exposure of alignment mark coating 3, and black matrix film 4 is patterned before technique further include: Substrate 1 is cleaned, to remove the remaining alignment mark coating 3 in 2 region of alignment mark, alignment mark 2 is exposed; Then substrate 1 is dried.In the step, the residue of the photosensitive material membrane of near-infrared is removed by cleaning process, and is dried, To expose the alignment mark 2 (as shown in Figure 5) being entirely covered.Then it executes step S4: work is patterned to black matrix film 4 Skill.The patterning processes include the subsequent exposure and imaging technique to black matrix film 4.Black matrix film 4 is exposed using UV light. It specifically includes: alignment mark 2 is identified and positioned, in exposure machine, utilize the e light (wave in 500-600nm wave-length coverage Long 546nm) and d light (wavelength 578nm) alignment mark 2 is positioned and is identified, adjust aligning accuracy;According to alignment mark 2 adjustment are used to form the position of the black matrix mask plate 5 of the figure of black matrix, i.e., carry out space and property to black matrix mask plate 5 Shape adjustment;It is exposed exposure light to black matrix film 4 through black matrix mask plate 5, makes to concentrate on UV in exposure machine I light (wavelength 365nm), h light (wavelength 405nm), the g light (wavelength 436nm) in light area are irradiated through black matrix mask plate 5 Black matrix film 4 (as shown in Figure 6), the corresponding photochemical reaction of inducing catalysis form the figure 6 of specific black matrix (such as Fig. 7 institute Show).
The preparation process of above-mentioned black matrix, it can be ensured that after exposing to alignment mark coating 3, alignment mark 2 can Be exposed, so as to it is subsequent black matrix film 4 is exposed when carry out black matrix mask plate 5 align, it is higher so as to avoid The black matrix film 4 of optical density (optical density is usually >=4.0) makes the identification, crawl and positioning of alignment mark 2 in exposure process At interference, so that black matrix film 4, by 2 exactitude position of alignment mark, and then is not only increased black matrix in exposure Exposure accuracy, and improve the exposure quality and performance of array substrate.
It in the present embodiment, is formed before black matrix on substrate 1 further include: grid, active layer, source are formed on substrate 1 Drain electrode and pixel electrode;Alignment mark 2 uses material identical with grid or source-drain electrode, and is formed simultaneously.It should be noted that Usual alignment mark 2 uses light-proof material, and is formed simultaneously with first film layer being formed on substrate 1.Such as alignment mark 2 Identical material is used with grid, and is formed simultaneously.By alignment mark 2 when can so make to be subsequently formed each film layer on substrate 1 Carry out the figure contraposition of subsequent each film layer.I.e. black matrix is formed in array substrate (i.e. BOA, BM on Array), array base On plate before forming black matrix, it is initially formed conventional arrangement of each functional film layer 7 in array substrate.BOA is able to solve array Black matrix shading and the unmatched problem of array substrate light-leaking area caused by substrate and color membrane substrates misplace, promote pixel openings Rate and panel transmitance, are particularly useful for curved-surface display.
In the present embodiment, alignment mark 2 is formed in the edge region of substrate 1, and the shape of alignment mark 2 includes " ten " Font, circle, rectangular or bar shaped.Certainly, alignment mark 2 is also possible to other shapes.
Based on the preparation method of above-mentioned array substrate, the present embodiment also provides a kind of above-mentioned preparation method of use and is prepared Array substrate.
Embodiment 1 the utility model has the advantages that the preparation method of array substrate provided in embodiment 1, by corresponding substrate Formation there is the region of alignment mark and the region other than alignment mark to be respectively formed alignment mark coating and black matrix film, and First by alignment mark coating by exposure removal, then using the figure of patterning processes formation black matrix, since alignment mark covers Cap rock is different with the exposure wavelength of black matrix film, so the two will not be interfered and be influenced between each other in exposure, thus Can be avoided the black matrix film of higher optical density (optical density usually >=4.0) in exposure process to the identification of alignment mark, grab Interference caused by taking and positioning enables black matrix film in exposure by alignment mark exactitude position, and then not only increases The exposure accuracy of black matrix, and improve the exposure quality and performance of array substrate.
Embodiment 2:
The present embodiment provides a kind of display devices, including the array substrate in embodiment 1.
By using the array substrate in embodiment 1, the preparation quality of the display device can be improved, to improve this The display quality and performance of display device.
Display device provided by the present invention can appoint for liquid crystal display panel, LCD TV, display, mobile phone, navigator etc. What products or components having a display function.
It is understood that the principle that embodiment of above is intended to be merely illustrative of the present and the exemplary implementation that uses Mode, however the present invention is not limited thereto.For those skilled in the art, essence of the invention is not being departed from In the case where mind and essence, various changes and modifications can be made therein, these variations and modifications are also considered as protection scope of the present invention.

Claims (13)

1. a kind of preparation method of array substrate, comprising:
Step S1: the region of alignment mark forms alignment mark coating in the formation of corresponding substrate using patterning processes;
Step S2: the region other than the alignment mark forms black matrix film over the substrate;It is characterized by further comprising:
Step S3: the alignment mark coating is removed by exposure, to expose the alignment mark;
Step S4: technique is patterned to the black matrix film, to form the figure of black matrix;
Wherein, the exposure wavelength of the alignment mark coating is different from the exposure wavelength of the black matrix film.
2. the preparation method of array substrate according to claim 1, which is characterized in that the alignment mark coating uses Near-infrared light-sensitive material.
3. the preparation method of array substrate according to claim 2, which is characterized in that the near-infrared light-sensitive material includes The bromo- umbelliferone polymer of polymer containing adjacent nitro benzyl, the monomer containing adjacent nitro benzyl, 4- or the bromo- 7- of 4- The monomer of Hydroxycoumarin.
4. the preparation method of array substrate according to claim 1, which is characterized in that the thickness of the alignment mark coating Degree is 3-5 times of the black matrix film thickness.
5. the preparation method of array substrate according to claim 1, which is characterized in that the black matrix film with a thickness of 0.9-1.2um, the alignment mark coating with a thickness of 2.7-6um.
6. the preparation method of array substrate according to claim 2, which is characterized in that using near infrared light to the contraposition Label coating is exposed, and is exposed using UV light to the black matrix film.
7. the preparation method of array substrate according to claim 1, which is characterized in that the alignment mark coating Exposure finishes, and is patterned before technique to the black matrix film further include: cleans to the substrate, described in removal The remaining alignment mark coating in alignment mark region, is exposed the alignment mark;
The substrate is dried.
8. the preparation method of array substrate according to claim 1, which is characterized in that described to be carried out to the black matrix film Patterning processes include:
The alignment mark is identified and positioned;
The position of the mask plate of the figure of the black matrix is used to form according to alignment mark adjustment;
It is exposed exposure light to the black matrix film through the mask plate.
9. the preparation method of array substrate according to claim 1, which is characterized in that the alignment mark coating uses Mask plate technique or printing technology are formed.
10. the preparation method of array substrate according to claim 1, which is characterized in that form black square over the substrate Before battle array further include: form grid, active layer, source-drain electrode and pixel electrode over the substrate;
The alignment mark uses material identical with the grid or the source-drain electrode, and is formed simultaneously.
11. the preparation method of array substrate described in -10 any one according to claim 1, which is characterized in that the register guide Note is formed in the edge region of the substrate, and the shape of the alignment mark includes " ten " font, circle, rectangular or item Shape.
12. a kind of array substrate, which is characterized in that the array substrate is using the battle array as described in claim 1-11 any one The preparation method of column substrate is prepared.
13. a kind of display device, which is characterized in that including the array substrate described in claim 12.
CN201610682390.4A 2016-08-17 2016-08-17 A kind of array substrate and preparation method thereof and display device Active CN106054482B (en)

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CN107966865A (en) * 2017-12-18 2018-04-27 深圳市华星光电半导体显示技术有限公司 Production method, array base palte and the display panel of array base palte
CN110133928B (en) * 2019-05-15 2022-01-04 京东方科技集团股份有限公司 Array substrate, manufacturing method thereof and display panel
CN110211502A (en) * 2019-06-28 2019-09-06 云谷(固安)科技有限公司 The production method of array substrate and preparation method thereof and display panel

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CN102800566B (en) * 2012-07-16 2015-01-28 中国电子科技集团公司第五十五研究所 Method for protecting alignment mark through contact area lead wire process in semiconductor device
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