CN106049188A - Environment-friendly cigarette package lined paper - Google Patents

Environment-friendly cigarette package lined paper Download PDF

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Publication number
CN106049188A
CN106049188A CN201610420008.2A CN201610420008A CN106049188A CN 106049188 A CN106049188 A CN 106049188A CN 201610420008 A CN201610420008 A CN 201610420008A CN 106049188 A CN106049188 A CN 106049188A
Authority
CN
China
Prior art keywords
paper
mass percentage
methyl
cigarette package
barrier layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610420008.2A
Other languages
Chinese (zh)
Other versions
CN106049188B (en
Inventor
郑毅生
郑敏生
李耀辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANTOU XINDA COLOR PRINTING PACKAGING MATERIALS CO Ltd
Original Assignee
SHANTOU XINDA COLOR PRINTING PACKAGING MATERIALS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANTOU XINDA COLOR PRINTING PACKAGING MATERIALS CO Ltd filed Critical SHANTOU XINDA COLOR PRINTING PACKAGING MATERIALS CO Ltd
Priority to CN201610420008.2A priority Critical patent/CN106049188B/en
Publication of CN106049188A publication Critical patent/CN106049188A/en
Application granted granted Critical
Publication of CN106049188B publication Critical patent/CN106049188B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10—Packing paper
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/18—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising waxes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Paper (AREA)
  • Wrappers (AREA)

Abstract

The invention relates to packaging paper in the tobacco industry, in particular to lined paper for packaging cigarettes. The lined paper comprises raw paper and a blocking layer. The raw paper and the blocking layer are composited by the coating of an adhesive. The blocking layer is formed by, by mass percentage, 10-20% of polycaprolactone, 5-15% of polyhydroxyalkanoate, 5-10% of polyvinyl alcohol, 0.3-0.8% of emulsifying wax, 1-8% of montmorillonite, 1-8% of zinc stearate, and the balance water. The adhesive comprises, by mass percentage, 10-25% of methyl acrylate, 10-25% of methyl methacrylate, 1-8% of methacrylic acid, 1-8% of methyl acetate, 1-8% of methyl tin mercaptide, 1-5% of bentonite, 1-3% of flexibilizer, and the balance water. The blocking layer guarantees blocking performance of the lined paper for the cigarettes on the conditions that metallic materials such as aluminum foil are not used, and the requirements for damp prevention and fragrance retention of the packaging paper for the cigarettes can be met.

Description

A kind of environmental protection cigarette package lining paper
Technical field
The present invention relates to the wrapping paper field of tobacco business, the specifically internal lining paper of cigarette in packet.
Background technology
Existing internal lining paper is generally divided into common transfevent internal lining paper and radium-shine transfer internal lining paper, common transfevent internal lining paper Tobacco bale formability poor, easily there is the situation of aluminum；And radium-shine transfer internal lining paper after thin film is peeled off easily paper peel off The most only cause that flaw point occurs, if not or ink is the thickest for the ink used and paper adhesion, the ink at indentation line The obvious slight crack easily formed with aluminium lamination fracture, and aluminized paper easy fold and rake angle of producing in transportation, or because of Its flatness is affected because stacking.
Summary of the invention
It is an object of the invention to provide a kind of processing technology simple, there is high obstructing performance, printing word pattern effect Good cigarette pack internal lining paper.
For reaching above-mentioned purpose, the present invention adopts the following technical scheme that
A kind of environmental protection cigarette package lining paper, carries out multiple including body paper and barrier layer, body paper and barrier layer by adhesive coating Closing, described barrier layer is made up of the component of following mass percentage content: polyvinyl alcohol 5-10%；Polycaprolactone 10-20%；Poly- Hydroxyalkanoate 5-15%；Emulsifing wax 0.3-0.8%；Montmorillonite 1-8%；Zinc stearate 1-8%；Surplus is water.
As preferred scheme, described barrier layer is made up of the component of following mass percentage content: polyvinyl alcohol 5%； Polycaprolactone 13%；PHA 8%；Emulsifing wax 0.5%；Montmorillonite 1%；Zinc stearate 2%；Surplus is water.
In such scheme, described adhesive includes the component of following mass percentage content: 10～the acrylic acid of 25% The sulfur of the methyl acetate of the methacrylic acid of the methyl methacrylate of methyl ester, 10～25%, 1～8%, 1～8%, 1～8% Alcohol methyl stannum, 1～the bentonite of 5%, the toughener of 1-3%, surplus is water.
As preferred scheme, described adhesive includes the component of following mass percentage content: the acrylic acid of 15% Methyl ester, the methyl methacrylate of 10%, the methacrylic acid of 4%, the methyl acetate of 4%, the thiol methyl tin of 3%, 2% Bentonite, the toughener of 1%, surplus is water.
Further, described body paper has coating layer.
It is an advantage of the current invention that:
The barrier layer used in the present invention, in the case of without metal materials such as aluminium foils, it is ensured that the obstruct of tobacco lining paper Performance, it is possible to meet the requirement that cigarette packaging paper is moistureproof and guarantor is fragrant, it also avoid the appearance of aluminum situation；Printing on body paper Word, clear patterns are glossy, by good for body paper direct combination rear using effect on barrier layer, and oxygen transit dose, steam Transmitance, abrasion resistance and folding strength etc. all meet use requirement.The raw material non-degradable component content used is low, beneficially environment Protection.
Accompanying drawing illustrates:
Accompanying drawing 1 is present configuration schematic diagram.
Detailed description of the invention:
Embodiment one:
A kind of environmental protection cigarette package lining paper, is entered by adhesive coating including body paper 2 and barrier layer 3, body paper 2 and barrier layer 3 Row is compound, and body paper 2 has coating layer 1, and barrier layer 3 is made up of the component of following mass percentage content: polyvinyl alcohol 6%；Poly- Caprolactone 10%；PHA 10%；Emulsifing wax 0.8%；Montmorillonite 7%；Zinc stearate 6%；Surplus is water.
Adhesive includes the component of following mass percentage content: the acrylic acid methyl ester. of 22%, the methacrylic acid of 23% Methyl ester, the methacrylic acid of 7%, the methyl acetate of 8%, the thiol methyl tin of 8%, the bentonite of 4%, the toughener of 2%, remaining Amount is water.
Embodiment two:
The barrier layer 3 of package lining paper is made up of the component of following mass percentage content: polyvinyl alcohol 5%；Polycaprolactone 13%； PHA 8%；Emulsifing wax 0.5%；Montmorillonite 1%；Zinc stearate 2%；Surplus is water.
Adhesive includes the component of following mass percentage content: the acrylic acid methyl ester. of 15%, the methacrylic acid of 10% Methyl ester, the methacrylic acid of 4%, the methyl acetate of 4%, the thiol methyl tin of 3%, the bentonite of 2%, the toughener of 1%, remaining Amount is water.
Embodiment three:
The obstruct of package lining paper 3 layers is made up of the component of following mass percentage content: polyvinyl alcohol 8%；Polycaprolactone 19%； PHA 5%；Emulsifing wax 0.3%；Montmorillonite 1%；Zinc stearate 1%；Surplus is water.
Adhesive includes the component of following mass percentage content: the acrylic acid methyl ester. of 13%, the methacrylic acid of 13% Methyl ester, the methacrylic acid of 11%, the methyl acetate of 1%, the thiol methyl tin of 2%, the bentonite of 2%, the toughener of 1%, Surplus is water.
Embodiment one tests data such as following table:
Embodiment two tests data such as following table:
Embodiment three tests data such as following table:

Claims (5)

1. an environmental protection cigarette package lining paper, is carried out by adhesive coating including body paper and barrier layer, body paper and barrier layer Compound, it is characterised in that described barrier layer is made up of the component of following mass percentage content:
Polycaprolactone 10-20%；
PHA 5-15%；
Polyvinyl alcohol 5-10%；
Emulsifing wax 0.3-0.8%；
Montmorillonite 1-8%；
Zinc stearate 1-8%；
Surplus is water.
A kind of environmental protection cigarette package lining paper the most according to claim 1, it is characterised in that: described barrier layer is by following The component of mass percentage content is constituted:
Polycaprolactone 13%；
PHA 8%；
Polyvinyl alcohol 5%；
Emulsifing wax 0.5%；
Montmorillonite 1%；
Zinc stearate 2%；
Surplus is water.
A kind of environmental protection cigarette package lining paper the most according to claim 1, it is characterised in that described adhesive include with The component of lower mass percentage content: 10～the methyl methacrylate of the acrylic acid methyl ester. of 25%, 10～25%, 1～8% The bentonite of the thiol methyl tin of the methyl acetate of methacrylic acid, 1～8%, 1～8%, 1～5%, the toughener of 1-3%, Surplus is water.
A kind of environmental protection cigarette package lining paper the most according to claim 1, it is characterised in that described adhesive include with The component of lower mass percentage content: the acrylic acid methyl ester. of 15%, the methyl methacrylate of 10%, the methacrylic acid of 4%, The methyl acetate of 4%, the thiol methyl tin of 3%, the bentonite of 2%, the toughener of 1%, surplus is water.
5. according to a kind of environmental protection cigarette package lining paper described in any one in claim 1-4, it is characterised in that described There is on body paper coating layer.
CN201610420008.2A 2016-06-15 2016-06-15 A kind of environmental protection cigarette package lining paper Active CN106049188B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610420008.2A CN106049188B (en) 2016-06-15 2016-06-15 A kind of environmental protection cigarette package lining paper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610420008.2A CN106049188B (en) 2016-06-15 2016-06-15 A kind of environmental protection cigarette package lining paper

Publications (2)

Publication Number Publication Date
CN106049188A true CN106049188A (en) 2016-10-26
CN106049188B CN106049188B (en) 2018-08-17

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107217545A (en) * 2017-05-15 2017-09-29 无锡市锡佳印刷包装有限公司 Environmental protection type packing paper
CN107287978A (en) * 2017-05-12 2017-10-24 无锡市锡佳印刷包装有限公司 A kind of antifog high-strength composite wrapping paper

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070184220A1 (en) * 2006-02-06 2007-08-09 Cleveland Christopher S Biodegradable paper-based laminate with oxygen and moisture barrier properties and method for making biodegradable paper-based laminate
CN101481565A (en) * 2008-01-07 2009-07-15 刘建林 Aqueous high isolation coating solution and boiling resistant high isolation coating obtained thereby
CN102134818A (en) * 2010-12-14 2011-07-27 汕头市信达彩印包装材料有限公司 Method for producing laser hologram lining paper for cigarette packaging
CN102943416A (en) * 2012-10-17 2013-02-27 云南瑞升烟草技术（集团）有限公司 Easily-degradable cigarette lining paper having high barrier property
CN103981773A (en) * 2014-04-18 2014-08-13 江苏金恒新型包装材料有限公司 Novel environmentally-friendly lining paper for cigarettes

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070184220A1 (en) * 2006-02-06 2007-08-09 Cleveland Christopher S Biodegradable paper-based laminate with oxygen and moisture barrier properties and method for making biodegradable paper-based laminate
CN101481565A (en) * 2008-01-07 2009-07-15 刘建林 Aqueous high isolation coating solution and boiling resistant high isolation coating obtained thereby
CN102134818A (en) * 2010-12-14 2011-07-27 汕头市信达彩印包装材料有限公司 Method for producing laser hologram lining paper for cigarette packaging
CN102943416A (en) * 2012-10-17 2013-02-27 云南瑞升烟草技术（集团）有限公司 Easily-degradable cigarette lining paper having high barrier property
CN103981773A (en) * 2014-04-18 2014-08-13 江苏金恒新型包装材料有限公司 Novel environmentally-friendly lining paper for cigarettes

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107287978A (en) * 2017-05-12 2017-10-24 无锡市锡佳印刷包装有限公司 A kind of antifog high-strength composite wrapping paper
CN107217545A (en) * 2017-05-15 2017-09-29 无锡市锡佳印刷包装有限公司 Environmental protection type packing paper

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Inventor after: Zheng Yisheng

Inventor after: Zheng Minsheng

Inventor before: Zheng Yisheng

Inventor before: Zheng Minsheng

Inventor before: Li Yaohui

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