CN106048587A - High-decontamination water-based antirust agent for surface treatment of stone breaker and preparing method of antirust agent - Google Patents
High-decontamination water-based antirust agent for surface treatment of stone breaker and preparing method of antirust agent Download PDFInfo
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- CN106048587A CN106048587A CN201610599929.XA CN201610599929A CN106048587A CN 106048587 A CN106048587 A CN 106048587A CN 201610599929 A CN201610599929 A CN 201610599929A CN 106048587 A CN106048587 A CN 106048587A
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- antirust agent
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/20—Use of solutions containing silanes
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a high-decontamination water-based antirust agent for surface treatment of a stone breaker. The agent is made of raw materials including, by weight, 32 parts to 33 parts of phytic acid, 9 parts to 11 parts of polyaspartic acid, 8 parts to 9 parts of waste polystyrene foam plastic, 2 parts to 3 parts of succinic acid, 1 part to 2 parts of sodium carbonate, 1.1 parts to 1.3 parts of 3-amidogen-1,2,4-triazole, 3.4 parts to 3.6 parts of calcium gluconate, 1.7 parts to 1.9 parts of methyltriacetoxysilane, 4 parts to 6 parts of seaweed extracts, 2 parts to 4 parts of calcite powder, 4.4 parts to 4.6 parts of polyethylene glycol, 5.4 parts to 5.6 parts of polyvinyl alcohol and the balance deionized water. Phytic acid and polyaspartic acid serve as main components, polyethylene glycol and polyvinyl alcohol serve as polymer film-forming agents, modified waste polystyrene foam plastic is added to serve as a waterproof agent, meanwhile, other additives are added, the antirust agent prepared through the formula is optimized and is good in antirust effect, and the antirust agent is high in decontamination, capable of being stored for a long time, safe and environment-friendly and integrates rust prevention, sterilization, mould proof and cleaning.
Description
Technical field
The present invention relates to antirust agent technical field, particularly relate to the strong lithotrite surface of a kind of soil release performance and process with water base anti-
Rust agent and preparation method thereof.
Background technology
Metal erosion can result in the maintenance cost of machinery equipment to be increased, and changes the most in advance, and the corrosion of metal parts is then
Reduce the accuracy and sensitivity of equipment, affect the use of equipment, even cause scrapping of equipment.For lithotrite, its
The corrosion of non-Painted metal surfaces and metallic element is the most common during storing, using, so must take corresponding
Safeguard procedures.For a long time, for reducing the serious corrosion of lithotrite equipment, extension device and parts seal the cycle up for safekeeping, adopt
By various methods, antirust agent is exactly one of method therein.
Antirust agent is the synthesis penetrating agent of a kind of super grade high efficiency, it can strongly penetrate into rust, erosion, in greasy dirt thus
Easily dispose the rusty stain on screw, bolt and erosion, there is infiltration rust cleaning, loosen lubrication, resistance burn into protection metal
Etc. performance, and can form and store one layer of lubricating film on parts surface, dampness and other chemical analysis many can be suppressed to make
The corrosion become.For avoiding because production and environmental problem, the rust prevention during manufacture of current iron and steel that difficulty causes greatly removed by antirust oil
Use water-based antirust more.Industrial widely used water-based antirust usually contains nitrite, phosphate or chromate, this
Class antirust agent toxicity is relatively strong, and discharge of wastewater easily causes body eutrophication, uses and discharges the most severely limited.Environment-friendly type
The development of water-based antirust is by domestic and international extensive concern.
With phytic acid, poly-aspartate as main component in " development of a kind of nontoxic water-based antirust and performance thereof " literary composition, add
Add sodium molybdate and sodium benzoate as auxiliary agent, filter out Polyethylene Glycol and polyvinyl alcohol as macromolecule film former, preparation one
Novel non-toxic water-based antirust without nitrite, result shows that phytic acid and poly-aspartate have preferable complex role, helps
The existence of agent and macromolecule film former can effectively strengthen the corrosion resistance of rust-preventing film, and carries out antirust effect with nitrous acid salt form antirust agent
, there is certain gap, but it be without noxious substance, is worth of widely use in fruit contrast.But it is antirust for the tradition of preparation in literary composition
For agent, during developing due to it, it is primarily upon the performance of its rustless property, often ignores environmental protection adaptability, multi-functional
And the serviceability under extreme condition, generally there are poor heat stability, weatherability difference and sun-proof ultraviolet radiation preventing difference etc.
Problem, thus limit the lifting of antirust agent overall performance, also limit the range of application of antirust agent.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that the lithotrite surface that a kind of soil release performance is strong processes
With water-based antirust and preparation method thereof.
The present invention is achieved by the following technical solutions:
The lithotrite surface process water-based antirust that a kind of soil release performance is strong, is prepared by the raw materials in: phytic acid 32-
33, poly-aspartate 9-11, waste polystyrene foam plastic 8-9, succinic acid 2-3, sodium carbonate 1-2,3-amino-1,2,4-tri-nitrogen
Azoles 1.1-1.3, calcium gluconate 3.4-3.6, methyl triacetoxysilane 1.7-1.9, Thallus Laminariae (Thallus Eckloniae) extract 4-6, calcite in powder
2-4, Polyethylene Glycol 4.4-4.6, polyvinyl alcohol 5.4-5.6, deionized water surplus.
The manufacture method of the lithotrite surface process water-based antirust that described a kind of soil release performance is strong, including following step
Rapid:
(1) waste polystyrene foam plastic cleaned, dry, pulverize, join in the dehydrated alcohol of gross weight 1.5-2 times, limit
Edged stirs so that it is be completely dissolved, and adds 3-amino-1, and 2,4-triazoles are sufficiently stirred for making oil phase liquid, put into 40-50 DEG C of water
In bath, constant temperature fully dissolves 1-2 hour, is warming up to 55-65 DEG C of quick stirring 20-30 minute；
(2) Thallus Laminariae (Thallus Eckloniae) extract is put into and the deionized water of 2/3 mass is warming up to 60-80 DEG C of constant temperature stirring 20-30 minute, add
Enter phytic acid, methyl triacetoxysilane ultrasonic disperse 15-20 minute, stand to obtain modified phytic acid；
(3) poly-aspartate, calcite in powder, succinic acid and balance deionized water are mixed, use high pressure homogenizer to process 2-3
Hour, it is spray-dried to obtain modified polyaspartic acid；
(4) step (2), (3) reaction mass are loaded in the reactor with agitator, control rotating speed 60-80 rev/min, stirring
10-15 minute, add step (1) and 30-40 minute stirring while adding of other residual components, discharging.
The invention have the advantage that the present invention with phytic acid, poly-aspartate as main component, with Polyethylene Glycol and polyvinyl alcohol
Forming one layer of fine and close thin film for macromolecule film former in metal surface, adding modified waste polystyrene foam plastic is waterproof helping
Agent, add other auxiliary agents simultaneously, the antirust agent favorable rust preventing effect that preferably prepared by formula, and persistent；With prior art phase
Than the present invention phytic acid is carried out silane coupler modified after ,-the Si-OH-generated after-the P-OH-of phytate molecule and silane hydrolyzate
Reaction generates-P-O-Si-key, the chelate of the hydrogenation of six carbocyclic with chair conformation that can be stable with metal generation, is attached to metal
Surface, corrosion resistance and pollution resistance strengthen, and the product stability of chelating is splendid, even if the most also can stably deposit
?；Also being modified poly-aspartate processing, improve the compounding effect with phytic acid, weather resistance strengthens；Raw material of the present invention
Wide material sources, preparation method is simple, and low production cost can be stingless to human body skin with long-term storage and non-toxic and safe environmental protection
Swash injury, integrate antirust, sterilization, mildew-resistant and cleaning.
Detailed description of the invention
The lithotrite surface process water-based antirust that a kind of soil release performance is strong, is prepared by the raw materials in: phytic acid
32, poly-aspartate 9, waste polystyrene foam plastic 8, succinic acid 2, sodium carbonate 1,3-amino-1,2,4-triazoles 1.1, Portugal
Grape Calciofon 3.4, methyl triacetoxysilane 1.7, Thallus Laminariae (Thallus Eckloniae) extract 4, calcite in powder 2, Polyethylene Glycol 4.4, polyvinyl alcohol
5.4, deionized water surplus.
The manufacture method of the lithotrite surface process water-based antirust that described a kind of soil release performance is strong, including following step
Rapid:
(1) waste polystyrene foam plastic cleaned, dry, pulverize, join in the dehydrated alcohol of gross weight 1.5-2 times, limit
Edged stirs so that it is be completely dissolved, and adds 3-amino-1, and 2,4-triazoles are sufficiently stirred for making oil phase liquid, put into 40-50 DEG C of water
In bath, constant temperature fully dissolves 1-2 hour, is warming up to 55-65 DEG C of quick stirring 20-30 minute；
(2) Thallus Laminariae (Thallus Eckloniae) extract is put into and the deionized water of 2/3 mass is warming up to 60-80 DEG C of constant temperature stirring 20-30 minute, add
Enter phytic acid, methyl triacetoxysilane ultrasonic disperse 15-20 minute, stand to obtain modified phytic acid；
(3) poly-aspartate, calcite in powder, succinic acid and balance deionized water are mixed, use high pressure homogenizer to process 2-3
Hour, it is spray-dried to obtain modified polyaspartic acid；
(4) step (2), (3) reaction mass are loaded in the reactor with agitator, control rotating speed 60-80 rev/min, stirring
10-15 minute, add step (1) and 30-40 minute stirring while adding of other residual components, discharging.
After this antirust agent film forming, average CuSO4The drop time reaches 93s, and salt water resistance soaks 37h, the 36h of resistance to neutral salt spray, anti-
Become rusty respond well.
Claims (2)
1. the lithotrite surface process water-based antirust that a soil release performance is strong, it is characterised in that by the raw material of following weight portion
Make: phytic acid 32-33, poly-aspartate 9-11, waste polystyrene foam plastic 8-9, succinic acid 2-3, sodium carbonate 1-2,3-ammonia
Base-1,2,4-triazole 1.1-1.3, calcium gluconate 3.4-3.6, methyl triacetoxysilane 1.7-1.9, Thallus Laminariae (Thallus Eckloniae) extract
4-6, calcite in powder 2-4, Polyethylene Glycol 4.4-4.6, polyvinyl alcohol 5.4-5.6, deionized water surplus.
The manufacture method of the lithotrite surface process water-based antirust that a kind of soil release performance the most according to claim 1 is strong,
It is characterized in that comprising the following steps:
(1) waste polystyrene foam plastic cleaned, dry, pulverize, join in the dehydrated alcohol of gross weight 1.5-2 times, limit
Edged stirs so that it is be completely dissolved, and adds 3-amino-1, and 2,4-triazoles are sufficiently stirred for making oil phase liquid, put into 40-50 DEG C of water
In bath, constant temperature fully dissolves 1-2 hour, is warming up to 55-65 DEG C of quick stirring 20-30 minute；
(2) Thallus Laminariae (Thallus Eckloniae) extract is put into and the deionized water of 2/3 mass is warming up to 60-80 DEG C of constant temperature stirring 20-30 minute, add
Enter phytic acid, methyl triacetoxysilane ultrasonic disperse 15-20 minute, stand to obtain modified phytic acid；
(3) poly-aspartate, calcite in powder, succinic acid and balance deionized water are mixed, use high pressure homogenizer to process 2-3
Hour, it is spray-dried to obtain modified polyaspartic acid；
(4) step (2), (3) reaction mass are loaded in the reactor with agitator, control rotating speed 60-80 rev/min, stirring
10-15 minute, add step (1) and 30-40 minute stirring while adding of other residual components, discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610599929.XA CN106048587A (en) | 2016-07-28 | 2016-07-28 | High-decontamination water-based antirust agent for surface treatment of stone breaker and preparing method of antirust agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610599929.XA CN106048587A (en) | 2016-07-28 | 2016-07-28 | High-decontamination water-based antirust agent for surface treatment of stone breaker and preparing method of antirust agent |
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| Publication Number | Publication Date |
|---|---|
| CN106048587A true CN106048587A (en) | 2016-10-26 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610599929.XA Pending CN106048587A (en) | 2016-07-28 | 2016-07-28 | High-decontamination water-based antirust agent for surface treatment of stone breaker and preparing method of antirust agent |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002698A (en) * | 2010-11-29 | 2011-04-06 | 湘潭大学 | Anti-rust treating agent for nickel-plated battery steel shell and using method thereof |
| CN104892667A (en) * | 2015-06-16 | 2015-09-09 | 青岛格瑞烯金属防护科技有限公司 | Preparation method of phytic acid polymer and application of phytic acid polymer in field of metal surface pretreatment |
-
2016
- 2016-07-28 CN CN201610599929.XA patent/CN106048587A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002698A (en) * | 2010-11-29 | 2011-04-06 | 湘潭大学 | Anti-rust treating agent for nickel-plated battery steel shell and using method thereof |
| CN104892667A (en) * | 2015-06-16 | 2015-09-09 | 青岛格瑞烯金属防护科技有限公司 | Preparation method of phytic acid polymer and application of phytic acid polymer in field of metal surface pretreatment |
Non-Patent Citations (1)
| Title |
|---|
| 钟雪丽等: "《一种无毒水基防锈剂的研制及其性能》", 《表面技术》 * |
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Application publication date: 20161026 |