CN106048395A - Liquid metal flow promoter - Google Patents
Liquid metal flow promoter Download PDFInfo
- Publication number
- CN106048395A CN106048395A CN201610542335.5A CN201610542335A CN106048395A CN 106048395 A CN106048395 A CN 106048395A CN 201610542335 A CN201610542335 A CN 201610542335A CN 106048395 A CN106048395 A CN 106048395A
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- CN
- China
- Prior art keywords
- accelerator
- liquid metal
- ferrosilicon
- rare
- ferromanganese
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/08—Making cast-iron alloys
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
- C21C1/10—Making spheroidal graphite cast-iron
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C37/00—Cast-iron alloys
- C22C37/04—Cast-iron alloys containing spheroidal graphite
Abstract
The invention relates to a liquid metal flow promoter which is characterized by being composed of the following components in percentages by mass: 55-63% of ferrosilicon, 16-22% of ferromanganese, 3-5% of ferronickel, 0.5-2% of bismuth, 10-18% of a silicon-zirconium inoculant and 1-4% of a rare-earth nodularizer. The promoter provided by the invention can effectively improve the flowability of a liquid metal in low temperature smelting and reduce formation of flaws such as pores, defects and looseness in a production process, so that the performance indexes of a casting are greatly improved, and the yield of enterprise production is improved; and meanwhile, the adding amount is small, the using efficiency is high, the using cost is low, and the economical benefit of the enterprise is increased.
Description
Technical field
The present invention relates to metal smelt technical field, particularly to a kind of liquid metal flows accelerator.
Background technology
The mobility of metal refers to the fluid ability of motlten metal, and the quality of metal fluidity, generally with " helical flow
Property sample " length weigh, metal liquid is poured in spiral type sample casting mold, under identical pouring condition, alloy
Mobility is the best, and the sample watered out is the longest.Different types of metal liquid, has different mobility, the stream of metal liquid
Dynamic property is good, and mold-filling capacity is the strongest, is readily available the foundry goods that size is accurate, profile is complete and clear-cut, if Liquid-metal flow
Property bad, will appear from following casting defect: (1) water less than with cold shut, water less than refer to foundry goods incomplete or may profile imperfect,
Or possibility foundry goods is complete, but corner is round and bright, and this defect often occurs at the position away from cast gate and thin-walled, and cold shut is
Referring to penetrate on foundry goods or do not penetrate through, a class defect in rounded shape gap, edge, cold shut occurs at thin-walled more, metal stream converges
At conjunction, Quench position etc.;(2) pore and field trash, the poor fluidity of metal liquid, then viscosity is big, the gas in motlten metal
Floating with field trash inconvenience and discharge, easily forming pore, field trash one class casting defect, pore refers to inner surface relatively light
Sliding, generally circular in cross section, oval hole, the most do not expose cast(ing) surface, field trash refers to exist in foundry goods or on surface
The particle class defect different from parent metal composition, common are sand, slag, oxide, sulfide etc..
As can be seen here, the quality of metal fluidity governs the yield rate of foundry enterprise, and wherein, chemical composition is impact gold
Belong to this quality factor of liquid fluidity, a kind of improve the accelerator of the mobility of liquid metal in melting accordingly, it would be desirable to develop.
Summary of the invention
For solving the problem of above-mentioned existence, it is an object of the invention to provide and plant containing a kind of liquid metal flows promotion
Agent.Described accelerator can be effectively improved the mobility of liquid metal in low smelting heat, reduce pore in production process, incompleteness,
The formation of the defect such as loose, is substantially improved the property indices of foundry goods, improves the yields that enterprise produces, the amount being simultaneously introduced
Few, service efficiency is high, and use cost is low, increases the economic well-being of workers and staff of enterprise.
For reaching above-mentioned purpose, the technical scheme is that
A kind of liquid metal flows accelerator, described accelerator is by ferrosilicon, ferromanganese, ferronickel, bismuth, silicon zirconium inovulant and rare earth
Nodulizer forms, and the mass percent of each component is: ferrosilicon: 55-63%, ferromanganese: 16-22%, ferronickel: 3-5%, bismuth: 0.5-2%,
Silicon zirconium inovulant: 10-18%, rare-earth nodularizer: 1-4%.
Further, in described accelerator, the mass percent of each component is: ferrosilicon: 62%, ferromanganese: 20%, ferronickel: 4%,
Bismuth: 1%, silicon zirconium inovulant: 11%, rare-earth nodularizer: 2%.
Preferably, any one during described ferrosilicon selects FeSi75-A or FeSi75-B or FeSi75-C.
Preferably, any one during described ferromanganese selects FeMn64 or FeMn68.
Preferably, any one during FeNi20 or FeNi30 selected by described ferronickel.
Preferably, described rare-earth nodularizer is rare earth ferrosilicomagnesium nodulizer FeSiMg8Re7 or FeSiMg10Re7.
Preferably, the 3-5% that addition is total melting weight when described accelerator uses.
Ferrosilicon is with coke, steel cuttings, quartz or Silicon stone as raw material, and the ferro-silicium made with electric furnace smelting, ferrosilicon is at ferrum
Alloy industry is used as to produce the reducing agent of low carbon ferroalloy.Ferrosilicon adds the inovulant that can make spheroidal graphite cast-iron in cast iron, and energy
Stop carbide to be formed, promote precipitation and the nodularization of graphite, improve cast iron.Element silicon can promote carbon contained in the pig iron to divide
From for graphite-like, can deoxygenate, moreover it is possible to reduce the core of foundry goods, the mobility of molten pig iron can be improved, reduce the amount of contraction of foundry goods,
But siliceous too much, also can make that the pig iron is hardening to become fragile.
Ferromanganese can be used as deoxidizer and alloy addition in steel-making, can improve the casting character of the pig iron and cut performance,
Manganese can also form Manganese monosulfide. with objectionable impurities sulfur, enters slag.
Ferronickel as alloying element additive, can improve bending strength and the hardness of steel, in cast iron in steel industry
Can make its even structure, density improves.
Bismuth adds the Low temperature impact toughness that can improve iron and steel, the beneficially refinement of graphitization form with equal in steel industry
Homogenize, improve stability.
Silicon zirconium inovulant obtains tremendous development in recent years.As silicon system inovulant, silicon content height pregnant effect is good, and section is equal
Even property is good, and thickness case hardness difference is little.Another important element zirconium, reacts the nitride generated and reduces dissolved nitrogen, stop ferrum with nitrogen
Water reversible suction nitrogen, suppresses inoculation fade.Carbide that zirconium a small amount of in molten iron is formed, nitride, as graphite crystallization core, rise
To the most graphited effect.
The beneficial effects of the present invention is:
(1) a kind of liquid metal flows accelerator that the present invention provides, each component proportions use, it is possible to be effectively improved
The mobility of liquid metal in low smelting heat, reduces pore in production process, incompleteness, the formation of the defect such as loose, is substantially improved
The property indices of foundry goods, improves the yields that enterprise produces;
(2) a kind of liquid metal flows accelerator that the present invention provides, the amount needing to add in fusion process is few, uses
Efficiency is high, and use cost is low, increases the economic well-being of workers and staff of enterprise.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, the most detailed below in conjunction with embodiment
Describe in detail bright.
Embodiment 1
A kind of liquid metal flows accelerator, described accelerator is by ferrosilicon, ferromanganese, ferronickel, bismuth, silicon zirconium inovulant and rare earth
Nodulizer forms, and the mass percent of each component is: ferrosilicon: 55%, ferromanganese: 17%, ferronickel: 5%, bismuth: 1%, silicon zirconium inovulant:
18%, rare-earth nodularizer: 4%.
Preferably, described ferrosilicon selects FeSi75-A, and described ferromanganese selects FeMn64, and described ferronickel selects FeNi20, institute
Stating rare-earth nodularizer is rare earth ferrosilicomagnesium nodulizer FeSiMg8Re7.
When described accelerator uses addition is total melting weight 3%.
Embodiment 2
A kind of liquid metal flows accelerator, described accelerator is by ferrosilicon, ferromanganese, ferronickel, bismuth, silicon zirconium inovulant and rare earth
Nodulizer forms, and the mass percent of each component is: ferrosilicon: 57%, ferromanganese: 22%, ferronickel: 3%, bismuth: 0.5%, silicon zirconium inovulant:
14%, rare-earth nodularizer: 3.5%.
Preferably, described ferrosilicon selects FeSi75-A, and described ferromanganese selects FeMn68, and described ferronickel selects FeNi20, institute
Stating rare-earth nodularizer is rare earth ferrosilicomagnesium nodulizer FeSiMg10Re7.
When described accelerator uses addition is total melting weight 4%.
Embodiment 3
A kind of liquid metal flows accelerator, described accelerator is by ferrosilicon, ferromanganese, ferronickel, bismuth, silicon zirconium inovulant and rare earth
Nodulizer forms, and the mass percent of each component is: ferrosilicon: 62%, ferromanganese: 20%, ferronickel: 4%, bismuth: 1%, silicon zirconium inovulant:
11%, rare-earth nodularizer: 2%.
Preferably, described ferrosilicon selects FeSi75-B, and described ferromanganese selects FeMn68, and described ferronickel selects FeNi20, institute
Stating rare-earth nodularizer is rare earth ferrosilicomagnesium nodulizer FeSiMg8Re7.
Preferably, addition is total melting weight 5% when described accelerator uses.
Embodiment 4
A kind of liquid metal flows accelerator, described accelerator is by ferrosilicon, ferromanganese, ferronickel, bismuth, silicon zirconium inovulant and rare earth
Nodulizer forms, and the mass percent of each component is: ferrosilicon: 63%, ferromanganese: 16%, ferronickel: 5%, bismuth: 2%, silicon zirconium inovulant:
13%, rare-earth nodularizer: 1%.
Preferably, described ferrosilicon selects FeSi75-C, and described ferromanganese selects FeMn64, and described ferronickel selects FeNi30, institute
Stating rare-earth nodularizer is rare earth ferrosilicomagnesium nodulizer FeSiMg8Re7.
Preferably, addition is total melting weight 4% when described accelerator uses.
Embodiment 5
A kind of liquid metal flows accelerator, described accelerator is by ferrosilicon, ferromanganese, ferronickel, bismuth, silicon zirconium inovulant and rare earth
Nodulizer forms, and the mass percent of each component is: ferrosilicon: 60%, ferromanganese: 20%, ferronickel: 4.5%, bismuth: 1.5%, and silicon zirconium breeds
Agent: 10%, rare-earth nodularizer: 4%.
Preferably, described ferrosilicon selects FeSi75-B, and described ferromanganese selects FeMn68, and described ferronickel selects FeNi20, institute
Stating rare-earth nodularizer is rare earth ferrosilicomagnesium nodulizer FeSiMg8Re7.
Preferably, addition is total melting weight 5% when described accelerator uses.
On Melt Flow Rate Measurer, the melt index of the accelerator casting pig of different embodiment is added in test, and in injection
Carry out spiral of Archimedes sample injection on machine, measure the helical length of its correspondence, the results are shown in Table 1.
Table 1. adds melt index and the helical length of embodiment 1-5 accelerator casting pig
Wherein, comparative example is the casting pig of the accelerator without embodiment 1-5, and remaining condition is the most identical.
Result shows, the accelerator adding embodiment 1-5 can be effectively improved the mobility of liquid metal in low smelting heat.
Meanwhile, reduce pore in production process, incompleteness, the formation of the defect such as loose, be substantially improved the property indices of foundry goods, improve
The yields that enterprise produces, the amount being simultaneously introduced is few, and service efficiency is high, and use cost is low, increases the economic well-being of workers and staff of enterprise.
It should be noted that above example is only in order to illustrate technical scheme and unrestricted.Although with reference to relatively
The present invention has been described in detail by good embodiment, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent, and without deviating from the scope of technical solution of the present invention, it all should contain the power in the present invention
In profit claimed range.
Claims (7)
1. a liquid metal flows accelerator, it is characterised in that described accelerator is by ferrosilicon, ferromanganese, ferronickel, bismuth, silicon zirconium
Inovulant and rare-earth nodularizer composition, the mass percent of each component is: ferrosilicon: 55-63%, ferromanganese: 16-22%, ferronickel: 3-
5%, bismuth: 0.5-2%, silicon zirconium inovulant: 10-18%, rare-earth nodularizer: 1-4%.
A kind of liquid metal flows accelerator the most according to claim 1, it is characterised in that in described accelerator each group
The mass percent divided is: ferrosilicon: 62%, ferromanganese: 20%, ferronickel: 4%, bismuth: 1%, silicon zirconium inovulant: 11%, rare-earth nodularizer:
2%。
A kind of liquid metal flows accelerator the most according to claim 1, it is characterised in that described ferrosilicon is selected
Any one in FeSi75-A or FeSi75-B or FeSi75-C.
A kind of liquid metal flows accelerator the most according to claim 1, it is characterised in that described ferromanganese is selected
Any one in FeMn64 or FeMn68.
A kind of liquid metal flows accelerator the most according to claim 1, it is characterised in that described ferronickel is selected
Any one in FeNi20 or FeNi30.
A kind of liquid metal flows accelerator the most according to claim 1, it is characterised in that described rare-earth nodularizer is
Rare earth ferrosilicomagnesium nodulizer FeSiMg8Re7 or FeSiMg10Re7.
A kind of liquid metal flows accelerator the most according to claim 1, it is characterised in that when described accelerator uses
The 3-5% that addition is total melting weight.
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103252476A (en) * | 2013-04-25 | 2013-08-21 | 吴江市液铸液压件铸造有限公司 | Casting method of thin section casting |
CN103882282A (en) * | 2014-03-28 | 2014-06-25 | 日月重工股份有限公司 | Molten iron of hundred-tonnage ferritic nodular cast iron casting and preparation method of molten iron |
CN104498816A (en) * | 2015-01-16 | 2015-04-08 | 河北兴盛机械有限公司 | Grey cast iron with excellent cutting property and production method thereof |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103252476A (en) * | 2013-04-25 | 2013-08-21 | 吴江市液铸液压件铸造有限公司 | Casting method of thin section casting |
CN103882282A (en) * | 2014-03-28 | 2014-06-25 | 日月重工股份有限公司 | Molten iron of hundred-tonnage ferritic nodular cast iron casting and preparation method of molten iron |
CN104498816A (en) * | 2015-01-16 | 2015-04-08 | 河北兴盛机械有限公司 | Grey cast iron with excellent cutting property and production method thereof |
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Effective date of registration: 20230602 Address after: Room 585, floor 5, building 1, Hutai fashion, No. 10, Nanhai Road, Liuhe Town, Taicang City, Suzhou City, Jiangsu Province 215400 Patentee after: Suzhou huienyuan medical device accessories Co.,Ltd. Address before: 215138 Shitian Road, Yangchenghu Town, Xiangcheng District, Suzhou City, Jiangsu Province Patentee before: JIANGSU JIEDI ROBOT Co.,Ltd. |