CN106047178A - Infusing paint containing nano molybdenum disilicide and used for clutch facing material - Google Patents

Infusing paint containing nano molybdenum disilicide and used for clutch facing material Download PDF

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Publication number
CN106047178A
CN106047178A CN201610562942.8A CN201610562942A CN106047178A CN 106047178 A CN106047178 A CN 106047178A CN 201610562942 A CN201610562942 A CN 201610562942A CN 106047178 A CN106047178 A CN 106047178A
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China
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parts
molybdenum disilicide
nano
paint
coating
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CN201610562942.8A
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Chinese (zh)
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张和庆
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Individual
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Individual
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Priority to CN201610562942.8A priority Critical patent/CN106047178A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00Coating compositions based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Operated Clutches (AREA)
  • Braking Arrangements (AREA)

Abstract

The invention relates to infusing paint containing nano molybdenum disilicide and used for a clutch facing material. The paint is characterized by comprising the following components in parts by mass: 80-90 parts of nano liquid resin, 10-20 parts of nano cellulose crystal whiskers, 10-15 parts of sodium polystyrenesulfonate, 5-8 parts of nano molybdenum disilicide, 3-5 parts of feldspar powder, 2-3 parts of sodium bentonite, 1-1.5 parts of molybdenum disulfide, 2-3 parts of yttrium oxide, 2-3 parts of calcium oxide and 1-2 parts of a calcium-zinc stabilizer. The paint is prepared by sequentially mixing and stirring the components. The paint is simple in process and applicable to manufacturing and use of automobile clutch facings, internal structure stability can be effectively ensured, and the use performance can be improved.

Description

A kind of clutch surface sheet stock containing nanometer molybdenum disilicide soaks coating processed
Technical field
The present invention relates to Clutch Technology, a kind of clutch surface sheet stock leaching system containing nanometer molybdenum disilicide is coated with Material.
Background technology
Traditional automobile clutch surface containing nanometer molybdenum disilicide uses riveted type, and dough sheet is riveted on steel disc, bothersome Taking a lot of work, rivet affects dough sheet service life and uses safety.Existing structure without riveted type, such as Patent No. A kind of clutch surface containing nanometer molybdenum disilicide disclosed in 201210157147.2, with steel after the employing unordered mixing of multiple material Sheet sulfuration connects, and the internal structure of its mixing compacting is unstable, affects serviceability.
Summary of the invention
For above-mentioned deficiency without riveted type structure in prior art, the invention provides a kind of technique simple, be suitable to vapour The car clutch surface manufacture containing nanometer molybdenum disilicide uses, and can effectively guarantee that internal structure is stable, improve containing of serviceability The clutch surface sheet stock of nanometer molybdenum disilicide is with soaking coating processed.
The technical solution used in the present invention is: a kind of clutch surface sheet stock containing nanometer molybdenum disilicide soaks coating processed, institute State coating by mass fraction proportioning: liquid nano resin 80-90 part, nano-cellulose whisker 10-20 part, kayexalate 10-15 part, nanometer molybdenum disilicide 5-8 part, feldspar powder 3-5 part, sodium bentonite 2-3 part, molybdenum bisuphide 1-1.5 part, yittrium oxide 2-3 part, calcium oxide 2-3 part, calcium zinc stabilizer 1-2 part, the successively coating of mix and blend.
The clutch surface assembly containing nanometer molybdenum disilicide of the present invention does not damage engine flywheel face and platen face, dough sheet Without boring, it is not necessary to riveting, service life is long, and its processing technology is simple, prepare in order recombination line, Compound Fabric, coiling lines and Round shape dough sheet material, effectively guarantees that its internal structure is stable, is conducive to improving usage safety performance and the stability of dough sheet assembly, prolongs Its service life long.Use liquid nano resin, nano-cellulose whisker, nanometer molybdenum disilicide, feldspar powder, sodium bentonite, Molybdenum bisuphide, yittrium oxide are blended prepares Wear-resistant, high-temperature resistant coating, is conducive to improving the frictional behaviour of dough sheet structure, extends and use the longevity Life.
Detailed description of the invention
The invention will be further described below.
Embodiment one
A kind of clutch surface sheet stock containing nanometer molybdenum disilicide soaks coating processed and presses mass fraction proportioning: liquid nano resin 80 Part, nano-cellulose whisker 10 parts, kayexalate 10 parts, nanometer molybdenum disilicide 5 parts, feldspar powder 3 parts, Na-bentonite 2 parts of soil, molybdenum bisuphide 1 part, yittrium oxide 2 parts, calcium oxide 2 parts, calcium zinc stabilizer 1 part, the successively coating of mix and blend.
A kind of clutch surface assembly manufacture method containing nanometer molybdenum disilicide, comprises the following steps:
A. raw material is chosen: FKF compound mineral fiber 22Kg, ceramic fibre 8Kg, aromatic polyamide fibre 15Kg, polyacrylonitrile Fiber 15Kg, resistance to high mill brass wire 5Kg, sepiolite fibre 20Kg and nylon wire 15Kg are woven into the high-strength complex zygonema of 4mm, This line is made into 100Kg, 1 meter of wide Compound Fabric again;
B. by above-mentioned 1 meter of wide Compound Fabric coating above-mentioned coating, air-dry to tack-free;
C. with cutter, 1 meter of wide Compound Fabric is cut into every wide for 10mm dough sheet materials, use wrapping machine to be coiled into round shape dough sheet Material;
D. round shape dough sheet material is put into lower mold, put into steel disc, steel disc positive and negative brushing FH11-128 rubber cement;
E. on steel disc, place into round shape dough sheet material, pressing mold;
F. electric heating warming is to 175 DEG C, opens press, pressure to 30MPa, and insulation, pressurize depanning in 40 minutes, sulfidization molding must be without riveting Connect the examination automobile clutch surface containing nanometer molybdenum disilicide.
Embodiment two
A kind of clutch surface sheet stock containing nanometer molybdenum disilicide soaks coating processed and presses mass fraction proportioning: liquid nano resin 90 Part, nano-cellulose whisker 20 parts, kayexalate 15 parts, nanometer molybdenum disilicide 8 parts, feldspar powder 5 parts, Na-bentonite 3 parts of soil, molybdenum bisuphide 1.5 parts, yittrium oxide 3 parts, calcium oxide 3 parts, calcium zinc stabilizer 2 parts, the successively coating of mix and blend.
A kind of clutch surface assembly manufacture method containing nanometer molybdenum disilicide, comprises the following steps:
A. raw material is chosen: FKF compound mineral fiber 22Kg, ceramic fibre 8Kg, aromatic polyamide fibre 15Kg, polyacrylonitrile Fiber 15Kg, resistance to high mill brass wire 5Kg, sepiolite fibre 20Kg and nylon wire 15Kg are woven into the high-strength complex zygonema of 4mm, This line is made into 100Kg, 1 meter of wide Compound Fabric again;
B. by above-mentioned 1 meter of wide Compound Fabric coating above-mentioned coating, air-dry to tack-free;
C. with cutter, 1 meter of wide Compound Fabric is cut into every wide for 10mm dough sheet materials, use wrapping machine to be coiled into round shape dough sheet Material;
D. round shape dough sheet material is put into lower mold, put into steel disc, steel disc positive and negative brushing FH11-128 rubber cement;
E. on steel disc, place into round shape dough sheet material, pressing mold;
F. electric heating warming is to 180 DEG C, opens press, pressure to 35MPa, and insulation, pressurize depanning in 45 minutes, sulfidization molding must be without riveting Connect the examination automobile clutch surface containing nanometer molybdenum disilicide.
Embodiment three
A kind of clutch surface sheet stock containing nanometer molybdenum disilicide soaks coating processed and presses mass fraction proportioning: liquid nano resin 85 Part, nano-cellulose whisker 15 parts, kayexalate 12 parts, nanometer molybdenum disilicide 6 parts, feldspar powder 4 parts, Na-bentonite 2.5 parts of soil, molybdenum bisuphide 1.2 parts, yittrium oxide 2.3 parts, calcium oxide 2.5 parts, calcium zinc stabilizer 1.5 parts, successively mix and blend Coating.
A kind of clutch surface assembly manufacture method containing nanometer molybdenum disilicide, comprises the following steps:
A. raw material is chosen: FKF compound mineral fiber 22Kg, ceramic fibre 8Kg, aromatic polyamide fibre 15Kg, polyacrylonitrile Fiber 15Kg, resistance to high mill brass wire 5Kg, sepiolite fibre 20Kg and nylon wire 15Kg are woven into the high-strength complex zygonema of 4mm, This line is made into 100Kg, 1 meter of wide Compound Fabric again;
B. by above-mentioned 1 meter of wide Compound Fabric coating above-mentioned coating, air-dry to tack-free;
C. with cutter, 1 meter of wide Compound Fabric is cut into every wide for 10mm dough sheet materials, use wrapping machine to be coiled into round shape dough sheet Material;
D. round shape dough sheet material is put into lower mold, put into steel disc, steel disc positive and negative brushing FH11-128 rubber cement;
E. on steel disc, place into round shape dough sheet material, pressing mold;
F. electric heating warming is to 178 DEG C, opens press, pressure to 32MPa, and insulation, pressurize depanning in 44 minutes, sulfidization molding must be without riveting Connect the examination automobile clutch surface containing nanometer molybdenum disilicide.

Claims (1)

1. the clutch surface sheet stock containing nanometer molybdenum disilicide is with soaking coating processed, it is characterised in that: described coating is divided by quality Number proportioning: liquid nano resin 80-90 part, nano-cellulose whisker 10-20 part, kayexalate 10-15 part, nanometer two Molybdenum silicide 5-8 part, feldspar powder 3-5 part, sodium bentonite 2-3 part, molybdenum bisuphide 1-1.5 part, yittrium oxide 2-3 part, calcium oxide 2- 3 parts, calcium zinc stabilizer 1-2 part, the successively coating of mix and blend.
CN201610562942.8A 2016-07-18 2016-07-18 Infusing paint containing nano molybdenum disilicide and used for clutch facing material Pending CN106047178A (en)

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Application Number Priority Date Filing Date Title
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CN201610562942.8A CN106047178A (en) 2016-07-18 2016-07-18 Infusing paint containing nano molybdenum disilicide and used for clutch facing material

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107903753A (en) * 2017-12-07 2018-04-13 龚贤飞 A kind of nanometer molybdenum disilicide high-temperature resistant coating
CN107903741A (en) * 2017-12-07 2018-04-13 龚贤飞 A kind of heat resistant and wear resistant aqueous ceramic coating

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101759862A (en) * 2009-12-21 2010-06-30 中国计量学院 Method for preparing nanoparticle-modified friction material
CN102993635A (en) * 2012-12-03 2013-03-27 浙江科马摩擦材料股份有限公司 Method for preparing clutch facing through taking water soluble phenol-formaldehyde resin as adhesion agent
CN103030921A (en) * 2011-09-29 2013-04-10 浙江科马摩擦材料股份有限公司 Clutch facing without rubber winding and preparation method thereof
CN103320092A (en) * 2013-06-14 2013-09-25 陕西科技大学 Method for preparing wet friction material of nano silicon carbide modified carbon cloth
CN105114498A (en) * 2015-08-06 2015-12-02 杭州科瑞特摩擦材料有限公司 Poly-p-phenylene terephthamide composite fiber dry clutch facing and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101759862A (en) * 2009-12-21 2010-06-30 中国计量学院 Method for preparing nanoparticle-modified friction material
CN103030921A (en) * 2011-09-29 2013-04-10 浙江科马摩擦材料股份有限公司 Clutch facing without rubber winding and preparation method thereof
CN102993635A (en) * 2012-12-03 2013-03-27 浙江科马摩擦材料股份有限公司 Method for preparing clutch facing through taking water soluble phenol-formaldehyde resin as adhesion agent
CN103320092A (en) * 2013-06-14 2013-09-25 陕西科技大学 Method for preparing wet friction material of nano silicon carbide modified carbon cloth
CN105114498A (en) * 2015-08-06 2015-12-02 杭州科瑞特摩擦材料有限公司 Poly-p-phenylene terephthamide composite fiber dry clutch facing and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
张厚安等: "《二硅化钼及其复合材料的制备与性能》", 30 June 2007, 国防工业出版社 *
王丹等: ""热塑性树脂基纳米复合材料研究与应用"", 《生物质化学工程》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107903753A (en) * 2017-12-07 2018-04-13 龚贤飞 A kind of nanometer molybdenum disilicide high-temperature resistant coating
CN107903741A (en) * 2017-12-07 2018-04-13 龚贤飞 A kind of heat resistant and wear resistant aqueous ceramic coating

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