CN106047102A - Conveying belt for production line - Google Patents

Conveying belt for production line Download PDF

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Publication number
CN106047102A
CN106047102A CN201610674577.XA CN201610674577A CN106047102A CN 106047102 A CN106047102 A CN 106047102A CN 201610674577 A CN201610674577 A CN 201610674577A CN 106047102 A CN106047102 A CN 106047102A
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antistatic coating
carbon fiber
layer
copper powder
copper
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Chinese (zh)
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不公告发明人
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Individual
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Priority to CN201610674577.XA priority Critical patent/CN106047102A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65G—TRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
    • B65G15/00—Conveyors having endless load-conveying surfaces, i.e. belts and like continuous members, to which tractive effort is transmitted by means other than endless driving elements of similar configuration
    • B65G15/30—Belts or like endless load-carriers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/06—Elements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/02—Ingredients treated with inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24—Electrically-conducting paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/085—Copper
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K

Abstract

The invention relates to a conveying belt for a production line, wherein the conveying belt includes a bottom layer, a laminated layer and a surface layer and also includes an antistatic coating layer; the conveyor belt is provided with the antistatic coating layer, the surface layer, the laminated layer and the bottom layer from top to bottom successively; the surface layer and the bottom layer are made of fabrics coated with PVC paste resin, and the fabric of the surface layer is doped with conductive fibers at least.

Description

A kind of conveyer belt for production line
Technical field
The application relates to conveyer belt field, particularly relates to a kind of conveyer belt for production line.
Background technology
Conveyer belt is widely used in conglomerate.Owing to general conveyer belt is isolation material, the friction when conveying The electrostatic produced is difficult to eliminate, and directly affects the application of product.
The most generally coat antistatic coating at conveyor belt surface, be allowed to form the conveyer belt possessing anti-static function, The sheet resistance of the Anti-static conveyor belt that offshore company produces is typically 108About Ω, and expensive, it is difficult to meet domestic visitor The needs at family.The Anti-static conveyor belt that domestic enterprise produces generally uses the mode adding conductive black to accelerate electrostatic leakage, with Avoiding a large amount of accumulations of electrostatic, the color of its Anti-static conveyor belt product is black or light/dark balance, and color is single, and use field is subject to To limiting.
Currently for antistatic coating, it is presented below as development trend: develop the addition type antistatic coating of high performance-price ratio, And reach preferable anti-static effect, be on the one hand exploitation high conductivity, low cost novel conductive fillers, to replace The precious metal materials such as silver, nickel, copper；On the other hand it is the electric conductivity improving addition type conductive filler, to keep the thing of original matrix Reason-chemical property, the most still facing a lot of problem for efficient conductive filler needs to solve.
Summary of the invention
It is desirable to provide a kind of conveyer belt for production line, to solve problem set forth above.
Embodiments of the invention provide a kind of conveyer belt for production line, including bottom, laminating layer and top layer, also Including antistatic coating, this conveyer belt is followed successively by antistatic coating, top layer, laminating layer and bottom from top to down；Wherein, top layer and Bottom is that the fabric of the fabric scribbling PVC paste resin, at least top layer is doped with conductive fiber.
The technical scheme that embodiments of the invention provide can include following beneficial effect:
The present invention is provided with antistatic coating on the top layer of conveyer belt, and its surface resistivity is relatively low, possesses good anti-quiet Electricity effect, thus solve problem set forth above.
Aspect and advantage that the application adds will part be given in the following description, and part will become from the following description Obtain substantially, or recognized by the practice of the application.It should be appreciated that above general description and details hereinafter only describe It is exemplary and explanatory, the application can not be limited.
Accompanying drawing explanation
The invention will be further described to utilize accompanying drawing, but the embodiment in accompanying drawing does not constitute any limit to the present invention System, for those of ordinary skill in the art, on the premise of not paying creative work, it is also possible to obtain according to the following drawings Other accompanying drawing.
Fig. 1 is the structural representation of conveyer belt of the present invention.
Fig. 2 is the preparation flow figure of antistatic coating of the present invention.
Detailed description of the invention
Here will illustrate exemplary embodiment in detail, its example represents in the accompanying drawings.Explained below relates to During accompanying drawing, unless otherwise indicated, the same numbers in different accompanying drawings represents same or analogous key element.Following exemplary embodiment Described in embodiment do not represent all embodiments consistent with the present invention.On the contrary, they are only with the most appended The example of the apparatus and method that some aspects that described in detail in claims, the present invention are consistent.
Electrostatic coatings is a kind of functional coating, and it can conduct electric charge and can get rid of stored charge, say, that electrostatic The existing antistatic property of coating, has again the barrier propterty of coating itself.The U.S. is the earliest in the conducting resinl patent that 1948 announce Disclosed electrically-conducting paint；In early days, mainly based on silver system and carbon system anti-static coatings.
Along with the R and D of antistatic coating, Related product is more and more abundanter, its building industry, electron trade, Furniture industry, aviation and military field application are wide.At present, antistatic coating is divided into Intrinsical and addition type, and Intrinsical resists Electrostatic coatings is to be film forming matter by the polymer itself with electric conductivity, but, it is high that preparation cost prepared by this kind of coating, and application is relatively Few；Addition type antistatic coating is to add certain conductive filler in nonconducting resin itself to realize static conductive function, its Being formed conductive network in resin by conductive filler, embody electric conductivity, current conductive filler mainly has: carbon-based material, metal mold Powder, metal-oxide, conducting nanoparticles and antistatic additive etc..
Currently for antistatic coating, it is presented below as development trend: develop the addition type antistatic coating of high performance-price ratio, And reach preferable anti-static effect, be on the one hand exploitation high conductivity, low cost novel conductive fillers, to replace The precious metal materials such as silver, nickel, copper；On the other hand it is the electric conductivity improving addition type conductive filler, to keep the thing of original matrix Reason-chemical property, the most still facing a lot of problem for efficient conductive filler needs to solve.
Application scenarios one:
Fig. 1 shows a kind of conveyer belt for production line that embodiments herein relates to, including bottom 1, laminating layer 2 With top layer 3, also including antistatic coating 4, this conveyer belt is followed successively by antistatic coating 4, top layer 3, laminating layer 2 and the end from top to down Layer 1；Wherein, top layer 3 and bottom 1 are the fabric scribbling PVC paste resin, and at least the fabric on top layer 3 is doped with conductive fiber.
The present invention is provided with antistatic coating on the top layer of conveyer belt, and its surface resistivity is relatively low, possesses good anti-quiet Electricity effect.
Preferably, described antistatic coating is formed by antistatic coating coating, and described antistatic coating uses unsaturation tree Fat is base material, containing cis-butenedioic anhydride in described unsaturated-resin, and phthalic anhydride, disodiumedetate poly-400, propylene glycol, ethylene glycol, fourth Enediol, NaOH, dibutyl tin laurate, MEHQ.
In antistatic coating involved by the application, unsaturated-resin is base material, is that the aqueous of a kind of ultraviolet light polymerization is coated with Material, described unsaturated-resin side base contains the highly polar groups such as ether, hydroxyl, carboxyl, can produce conductive ion, become macromolecule Electrolyte, the surface resistivity of described unsaturated-resin is 5.2 × 109Ω/cm2。
Preferably, described antistatic coating uses copper powder and copper carbon fiber to be filler, described copper powder and described coppered carbon Fiber quality is than for 3:4, and described copper powder size is 200 mesh, and described copper carbon fiber copper film thickness is 130nm.
In the antistatic coating of the application, copper powder uniformly mixes with copper carbon fiber, is internally formed two dimension conduction at coating Network, reduces the surface resistivity of antistatic coating further.
Preferably, such as Fig. 2, the making step of described antistatic coating is as follows:
Step one, Treatment of Carbon:
Carbon fiber is cut into 2～5mm, is then immersed in 10h in acetone soln, then with deionized water to carbon fiber Clean 3～5 times；At room temperature, the carbon fiber after cleaning is immersed in concentrated nitric acid, takes out, then use deionized water after 1h Repeatedly clean, next put into oscillation cleaning 1h in supersonic cleaning machine, at 100 DEG C, be dried 2h；Dried carbon fiber is put into In magnetic control sputtering device, 10-4It is deposited with one layer of copper film at carbon fiber surface under Pa base vacuum, obtains copper carbon fiber；
Step 2, process copper powder:
50ml dehydrated alcohol concentrated hydrochloric acid solution is formulated in clean container, then weighs 25g copper powder and put in container, By solution stirring 1h, it is purified, then rinse 3 times with ether and dehydrated alcohol, until by-product HCl and CuCl2 Clean from Copper Powder Surface, then copper powder is placed in vacuum drying oven, take out standby after being dried 12h；
Step 3, prepares unsaturated-resin:
Take cis-butenedioic anhydride 0.44mol, phthalic anhydride 0.06mol, poly-400 0.145mol of disodiumedetate, propylene glycol 0.12mol, ethylene glycol 0.18mol, butylene glycol 0.05mol, add 0.3mol NaOH, 0.1% catalyst dibutyltin cinnamic acid two fourth Ji Xi, the polymerization inhibitor MEHQ mixing of 5/10000ths, fill this blend in the 250ml there-necked flask of band water knockout drum, It is placed in conduction oil, electric stirring, 160 DEG C of nitrogen atmospheres react 60min；It is warmed up to 180 DEG C, melt polymerization in nitrogen atmosphere 120min, then it is warming up to 195 DEG C, in nitrogen atmosphere, melt polymerization is 60 to acid number, is cooled to 100 DEG C and pours out, obtains after cooling The transparent unsaturated-resin of buff；
Step 4, prepares antistatic coating:
First weigh unsaturated-resin 100ml, add 5g copper powder and copper carbon fiber, be sufficiently mixed, add 3% silicon Alkane coupling agent, by mixture mechanical agitation, obtains antistatic coating.
Preferably, the antistatic coating prepared being coated in target object surface, coating thickness is 1～3 μm, then will It irradiates under distance ultraviolet source 10cm and makes curing of coatings.
Show it is further preferred that antistatic coating involved by the application to be carried out antistatic test, when copper powder adds Amount mass ratio is 6～18%, when copper powder and copper carbon fiber mass ratio are 3:4, and the surface resistivity of described antistatic coating It is 0.6～2.2 × 107Ω/cm2；After 60 days, aging resistance test shows, surface resistivity variable quantity is less than 5%.
Application scenarios two:
Fig. 1 shows a kind of conveyer belt for production line that embodiments herein relates to, including bottom 1, laminating layer 2 With top layer 3, also including antistatic coating 4, this conveyer belt is followed successively by antistatic coating 4, top layer 3, laminating layer 2 and the end from top to down Layer 1；Wherein, top layer 3 and bottom 1 are the fabric scribbling PVC paste resin, and at least the fabric on top layer 3 is doped with conductive fiber.
The present invention is provided with antistatic coating on the top layer of conveyer belt, and its surface resistivity is relatively low, possesses good anti-quiet Electricity effect.
Preferably, described antistatic coating is formed by antistatic coating coating, and described antistatic coating uses unsaturation tree Fat is base material, containing cis-butenedioic anhydride in described unsaturated-resin, and phthalic anhydride, disodiumedetate poly-400, propylene glycol, ethylene glycol, fourth Enediol, NaOH, dibutyl tin laurate, MEHQ.
In antistatic coating involved by the application, unsaturated-resin is base material, is that the aqueous of a kind of ultraviolet light polymerization is coated with Material, described unsaturated-resin side base contains the highly polar groups such as ether, hydroxyl, carboxyl, can produce conductive ion, become macromolecule Electrolyte, the surface resistivity of described unsaturated-resin is 5.2 × 109Ω/cm2。
Preferably, described antistatic coating uses copper powder and copper carbon fiber to be filler, described copper powder and described coppered carbon Fiber quality is than for 3:4, and described copper powder size is 200 mesh, and described copper carbon fiber copper film thickness is 130nm.
In the antistatic coating of the application, copper powder uniformly mixes with copper carbon fiber, is internally formed two dimension conduction at coating Network, reduces the surface resistivity of antistatic coating further.
Preferably, such as Fig. 2, the making step of described antistatic coating is as follows:
Step one, Treatment of Carbon:
Carbon fiber is cut into 2～5mm, is then immersed in 10h in acetone soln, then with deionized water to carbon fiber Clean 3～5 times；At room temperature, the carbon fiber after cleaning is immersed in concentrated nitric acid, takes out, then use deionized water after 1h Repeatedly clean, next put into oscillation cleaning 1h in supersonic cleaning machine, at 100 DEG C, be dried 2h；Dried carbon fiber is put into In magnetic control sputtering device, 10-4It is deposited with one layer of copper film at carbon fiber surface under Pa base vacuum, obtains copper carbon fiber；
Step 2, process copper powder:
50ml dehydrated alcohol concentrated hydrochloric acid solution is formulated in clean container, then weighs 25g copper powder and put in container, By solution stirring 1h, it is purified, then rinse 3 times with ether and dehydrated alcohol, until by-product HCl and CuCl2 Clean from Copper Powder Surface, then copper powder is placed in vacuum drying oven, take out standby after being dried 12h；
Step 3, prepares unsaturated-resin:
Take cis-butenedioic anhydride 0.44mol, phthalic anhydride 0.06mol, poly-400 0.145mol of disodiumedetate, propylene glycol 0.12mol, ethylene glycol 0.18mol, butylene glycol 0.05mol, add 0.3mol NaOH, 0.1% catalyst dibutyltin cinnamic acid two fourth Ji Xi, the polymerization inhibitor MEHQ mixing of 5/10000ths, fill this blend in the 250ml there-necked flask of band water knockout drum, It is placed in conduction oil, electric stirring, 160 DEG C of nitrogen atmospheres react 60min；It is warmed up to 180 DEG C, melt polymerization in nitrogen atmosphere 120min, then it is warming up to 195 DEG C, in nitrogen atmosphere, melt polymerization is 60 to acid number, is cooled to 100 DEG C and pours out, obtains after cooling The transparent unsaturated-resin of buff；
Step 4, prepares antistatic coating:
First weigh unsaturated-resin 100ml, add 5g copper powder and copper carbon fiber, be sufficiently mixed, add 3% silicon Alkane coupling agent, by mixture mechanical agitation, obtains antistatic coating.
Preferably, the antistatic coating prepared being coated in target object surface, coating thickness is 1～3 μm, then will It irradiates under distance ultraviolet source 10cm and makes curing of coatings.
Show it is further preferred that antistatic coating involved by the application to be carried out antistatic test, when copper powder adds Amount mass ratio is 6%, and when copper powder and copper carbon fiber mass ratio are 3:4, the surface resistivity of described antistatic coating is 0.6 ×107Ω/cm2；After 60 days, aging resistance test shows, surface resistivity variable quantity is less than 5%.
Application scenarios three:
Fig. 1 shows a kind of conveyer belt for production line that embodiments herein relates to, including bottom 1, laminating layer 2 With top layer 3, also including antistatic coating 4, this conveyer belt is followed successively by antistatic coating 4, top layer 3, laminating layer 2 and the end from top to down Layer 1；Wherein, top layer 3 and bottom 1 are the fabric scribbling PVC paste resin, and at least the fabric on top layer 3 is doped with conductive fiber.
The present invention is provided with antistatic coating on the top layer of conveyer belt, and its surface resistivity is relatively low, possesses good anti-quiet Electricity effect.
Preferably, described antistatic coating is formed by antistatic coating coating, and described antistatic coating uses unsaturation tree Fat is base material, containing cis-butenedioic anhydride in described unsaturated-resin, and phthalic anhydride, disodiumedetate poly-400, propylene glycol, ethylene glycol, fourth Enediol, NaOH, dibutyl tin laurate,
MEHQ.
In antistatic coating involved by the application, unsaturated-resin is base material, is that the aqueous of a kind of ultraviolet light polymerization is coated with Material, described unsaturated-resin side base contains the highly polar groups such as ether, hydroxyl, carboxyl, can produce conductive ion, become macromolecule Electrolyte, the surface resistivity of described unsaturated-resin is 5.2 × 109Ω/cm2。
Preferably, described antistatic coating uses copper powder and copper carbon fiber to be filler, described copper powder and described coppered carbon Fiber quality is than for 3:4, and described copper powder size is 200 mesh, and described copper carbon fiber copper film thickness is 130nm.
In the antistatic coating of the application, copper powder uniformly mixes with copper carbon fiber, is internally formed two dimension conduction at coating Network, reduces the surface resistivity of antistatic coating further.
Preferably, such as Fig. 2, the making step of described antistatic coating is as follows:
Step one, Treatment of Carbon:
Carbon fiber is cut into 2～5mm, is then immersed in 10h in acetone soln, then with deionized water to carbon fiber Clean 3～5 times；At room temperature, the carbon fiber after cleaning is immersed in concentrated nitric acid, takes out, then use deionized water after 1h Repeatedly clean, next put into oscillation cleaning 1h in supersonic cleaning machine, at 100 DEG C, be dried 2h；Dried carbon fiber is put into In magnetic control sputtering device, 10-4It is deposited with one layer of copper film at carbon fiber surface under Pa base vacuum, obtains copper carbon fiber；
Step 2, process copper powder:
50ml dehydrated alcohol concentrated hydrochloric acid solution is formulated in clean container, then weighs 25g copper powder and put in container, By solution stirring 1h, it is purified, then rinse 3 times with ether and dehydrated alcohol, until by-product HCl and CuCl2 Clean from Copper Powder Surface, then copper powder is placed in vacuum drying oven, take out standby after being dried 12h；
Step 3, prepares unsaturated-resin:
Take cis-butenedioic anhydride 0.44mol, phthalic anhydride 0.06mol, poly-400 0.145mol of disodiumedetate, propylene glycol 0.12mol, ethylene glycol 0.18mol, butylene glycol 0.05mol, add 0.3mol NaOH, 0.1% catalyst dibutyltin cinnamic acid two fourth Ji Xi, the polymerization inhibitor MEHQ mixing of 5/10000ths, fill this blend in the 250ml there-necked flask of band water knockout drum, It is placed in conduction oil, electric stirring, 160 DEG C of nitrogen atmospheres react 60min；It is warmed up to 180 DEG C, melt polymerization in nitrogen atmosphere 120min, then it is warming up to 195 DEG C, in nitrogen atmosphere, melt polymerization is 60 to acid number, is cooled to 100 DEG C and pours out, obtains after cooling The transparent unsaturated-resin of buff；
Step 4, prepares antistatic coating:
First weigh unsaturated-resin 100ml, add 5g copper powder and copper carbon fiber, be sufficiently mixed, add 3% silicon Alkane coupling agent, by mixture mechanical agitation, obtains antistatic coating.
Preferably, the antistatic coating prepared being coated in target object surface, coating thickness is 1～3 μm, then will It irradiates under distance ultraviolet source 10cm and makes curing of coatings.
Show it is further preferred that antistatic coating involved by the application to be carried out antistatic test, when copper powder adds Amount mass ratio is 10%, and when copper powder and copper carbon fiber mass ratio are 3:4, the surface resistivity of described antistatic coating is 1.5×107Ω/cm2；After 60 days, aging resistance test shows, surface resistivity variable quantity is less than 5%.
Application scenarios four:
Fig. 1 shows a kind of conveyer belt for production line that embodiments herein relates to, including bottom 1, laminating layer 2 With top layer 3, also including antistatic coating 4, this conveyer belt is followed successively by antistatic coating 4, top layer 3, laminating layer 2 and the end from top to down Layer 1；Wherein, top layer 3 and bottom 1 are the fabric scribbling PVC paste resin, and at least the fabric on top layer 3 is doped with conductive fiber.
The present invention is provided with antistatic coating on the top layer of conveyer belt, and its surface resistivity is relatively low, possesses good anti-quiet Electricity effect.
Preferably, described antistatic coating is formed by antistatic coating coating, and described antistatic coating uses unsaturation tree Fat is base material, containing cis-butenedioic anhydride in described unsaturated-resin, and phthalic anhydride, disodiumedetate poly-400, propylene glycol, ethylene glycol, fourth Enediol, NaOH, dibutyl tin laurate, MEHQ.
In antistatic coating involved by the application, unsaturated-resin is base material, is that the aqueous of a kind of ultraviolet light polymerization is coated with Material, described unsaturated-resin side base contains the highly polar groups such as ether, hydroxyl, carboxyl, can produce conductive ion, become macromolecule Electrolyte, the surface resistivity of described unsaturated-resin is 5.2 × 109Ω/cm2。
Preferably, described antistatic coating uses copper powder and copper carbon fiber to be filler, described copper powder and described coppered carbon Fiber quality is than for 3:4, and described copper powder size is 200 mesh, and described copper carbon fiber copper film thickness is 130nm.
In the antistatic coating of the application, copper powder uniformly mixes with copper carbon fiber, is internally formed two dimension conduction at coating Network, reduces the surface resistivity of antistatic coating further.
Preferably, such as Fig. 2, the making step of described antistatic coating is as follows:
Step one, Treatment of Carbon:
Carbon fiber is cut into 2～5mm, is then immersed in 10h in acetone soln, then with deionized water to carbon fiber Clean 3～5 times；At room temperature, the carbon fiber after cleaning is immersed in concentrated nitric acid, takes out, then use deionized water after 1h Repeatedly clean, next put into oscillation cleaning 1h in supersonic cleaning machine, at 100 DEG C, be dried 2h；Dried carbon fiber is put into In magnetic control sputtering device, 10-4It is deposited with one layer of copper film at carbon fiber surface under Pa base vacuum, obtains copper carbon fiber；
Step 2, process copper powder:
50ml dehydrated alcohol concentrated hydrochloric acid solution is formulated in clean container, then weighs 25g copper powder and put in container, By solution stirring 1h, it is purified, then rinse 3 times with ether and dehydrated alcohol, until by-product HCl and CuCl2 Clean from Copper Powder Surface, then copper powder is placed in vacuum drying oven, take out standby after being dried 12h；
Step 3, prepares unsaturated-resin:
Take cis-butenedioic anhydride 0.44mol, phthalic anhydride 0.06mol, poly-400 0.145mol of disodiumedetate, propylene glycol 0.12mol, ethylene glycol 0.18mol, butylene glycol 0.05mol, add 0.3mol NaOH, 0.1% catalyst dibutyltin cinnamic acid two fourth Ji Xi, the polymerization inhibitor MEHQ mixing of 5/10000ths, fill this blend in the 250ml there-necked flask of band water knockout drum, It is placed in conduction oil, electric stirring, 160 DEG C of nitrogen atmospheres react 60min；It is warmed up to 180 DEG C, melt polymerization in nitrogen atmosphere 120min, then it is warming up to 195 DEG C, in nitrogen atmosphere, melt polymerization is 60 to acid number, is cooled to 100 DEG C and pours out, obtains after cooling The transparent unsaturated-resin of buff；
Step 4, prepares antistatic coating:
First weigh unsaturated-resin 100ml, add 5g copper powder and copper carbon fiber, be sufficiently mixed, add 3% silicon Alkane coupling agent, by mixture mechanical agitation, obtains antistatic coating.
Preferably, the antistatic coating prepared being coated in target object surface, coating thickness is 1～3 μm, then will It irradiates under distance ultraviolet source 10cm and makes curing of coatings.
Show it is further preferred that antistatic coating involved by the application to be carried out antistatic test, when copper powder adds Amount mass ratio is 15%, and when copper powder and copper carbon fiber mass ratio are 3:4, the surface resistivity of described antistatic coating is 1.8×107Ω/cm2；After 60 days, aging resistance test shows, surface resistivity variable quantity is less than 5%.
Application scenarios five:
Fig. 1 shows a kind of conveyer belt for production line that embodiments herein relates to, including bottom 1, laminating layer 2 With top layer 3, also including antistatic coating 4, this conveyer belt is followed successively by antistatic coating 4, top layer 3, laminating layer 2 and the end from top to down Layer 1；Wherein, top layer 3 and bottom 1 are the fabric scribbling PVC paste resin, and at least the fabric on top layer 3 is doped with conductive fiber.
The present invention is provided with antistatic coating on the top layer of conveyer belt, and its surface resistivity is relatively low, possesses good anti-quiet Electricity effect.
Preferably, described antistatic coating is formed by antistatic coating coating, and described antistatic coating uses unsaturation tree Fat is base material, containing cis-butenedioic anhydride in described unsaturated-resin, and phthalic anhydride, disodiumedetate poly-400, propylene glycol, ethylene glycol, fourth Enediol, NaOH, dibutyl tin laurate, MEHQ.
In antistatic coating involved by the application, unsaturated-resin is base material, is that the aqueous of a kind of ultraviolet light polymerization is coated with Material, described unsaturated-resin side base contains the highly polar groups such as ether, hydroxyl, carboxyl, can produce conductive ion, become macromolecule Electrolyte, the surface resistivity of described unsaturated-resin is 5.2 × 109Ω/cm2。
Preferably, described antistatic coating uses copper powder and copper carbon fiber to be filler, described copper powder and described coppered carbon Fiber quality is than for 3:4, and described copper powder size is 200 mesh, and described copper carbon fiber copper film thickness is 130nm.
In the antistatic coating of the application, copper powder uniformly mixes with copper carbon fiber, is internally formed two dimension conduction at coating Network, reduces the surface resistivity of antistatic coating further.
Preferably, such as Fig. 2, the making step of described antistatic coating is as follows:
Step one, Treatment of Carbon:
Carbon fiber is cut into 2～5mm, is then immersed in 10h in acetone soln, then with deionized water to carbon fiber Clean 3～5 times；At room temperature, the carbon fiber after cleaning is immersed in concentrated nitric acid, takes out, then use deionized water after 1h Repeatedly clean, next put into oscillation cleaning 1h in supersonic cleaning machine, at 100 DEG C, be dried 2h；Dried carbon fiber is put into In magnetic control sputtering device, 10-4It is deposited with one layer of copper film at carbon fiber surface under Pa base vacuum, obtains copper carbon fiber；
Step 2, process copper powder:
50ml dehydrated alcohol concentrated hydrochloric acid solution is formulated in clean container, then weighs 25g copper powder and put in container, By solution stirring 1h, it is purified, then rinse 3 times with ether and dehydrated alcohol, until by-product HCl and CuCl2 Clean from Copper Powder Surface, then copper powder is placed in vacuum drying oven, take out standby after being dried 12h；
Step 3, prepares unsaturated-resin:
Take cis-butenedioic anhydride 0.44mol, phthalic anhydride 0.06mol, poly-400 0.145mol of disodiumedetate, propylene glycol 0.12mol, ethylene glycol 0.18mol, butylene glycol 0.05mol, add 0.3mol NaOH, 0.1% catalyst dibutyltin cinnamic acid two fourth Ji Xi, the polymerization inhibitor MEHQ mixing of 5/10000ths, fill this blend in the 250ml there-necked flask of band water knockout drum, It is placed in conduction oil, electric stirring, 160 DEG C of nitrogen atmospheres react 60min；It is warmed up to 180 DEG C, melt polymerization in nitrogen atmosphere 120min, then it is warming up to 195 DEG C, in nitrogen atmosphere, melt polymerization is 60 to acid number, is cooled to 100 DEG C and pours out, obtains after cooling The transparent unsaturated-resin of buff；
Step 4, prepares antistatic coating:
First weigh unsaturated-resin 100ml, add 5g copper powder and copper carbon fiber, be sufficiently mixed, add 3% silicon Alkane coupling agent, by mixture mechanical agitation, obtains antistatic coating.
Preferably, the antistatic coating prepared being coated in target object surface, coating thickness is 1～3 μm, then will It irradiates under distance ultraviolet source 10cm and makes curing of coatings.
Show it is further preferred that antistatic coating involved by the application to be carried out antistatic test, when copper powder adds Amount mass ratio is 18%, and when copper powder and copper carbon fiber mass ratio are 3:4, the surface resistivity of described antistatic coating is 2.2×107Ω/cm2；After 60 days, aging resistance test shows, surface resistivity variable quantity is less than 5%.
Those skilled in the art, after considering description and putting into practice invention disclosed herein, will readily occur to its of the present invention Its embodiment.The application is intended to any modification, purposes or the adaptations of the present invention, these modification, purposes or Person's adaptations is followed the general principle of the present invention and includes the undocumented common knowledge in the art of the application Or conventional techniques means.Description and embodiments is considered only as exemplary, and true scope and spirit of the invention are by following Claim is pointed out.
It should be appreciated that the invention is not limited in precision architecture described above and illustrated in the accompanying drawings, and And various modifications and changes can carried out without departing from the scope.The scope of the present invention is only limited by appended claim.

Claims (3)

1. for a conveyer belt for production line, including bottom, laminating layer and top layer, it is characterised in that also include that antistatic is coated with Layer, this conveyer belt is followed successively by antistatic coating, top layer, laminating layer and bottom from top to down；Wherein, top layer and bottom are for scribbling The fabric of the fabric of PVC paste resin, at least top layer is doped with conductive fiber.
Conveyer belt the most according to claim 1, it is characterised in that described antistatic coating coats 1～3 with antistatic coating μm is formed, and described antistatic coating is with unsaturated-resin as base material, with copper powder and copper carbon fiber as filler.
Conveyer belt the most according to claim 2, it is characterised in that described copper powder and described copper carbon fiber mass ratio are 3: 4, described copper powder size is 200 mesh, and described copper carbon fiber copper film thickness is 130nm.
CN201610674577.XA 2016-08-16 2016-08-16 Conveying belt for production line Pending CN106047102A (en)

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Publication number Priority date Publication date Assignee Title
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CN102126598A (en) * 2011-01-10 2011-07-20 南京东润带业有限公司 Antistatic poly vinyl chloride (PVC) conveyer belt
CA2851164A1 (en) * 2011-10-19 2013-04-25 Basf Se Use of antistats in interior coating materials
CN104448676A (en) * 2014-12-29 2015-03-25 安徽瑞研新材料技术研究院有限公司 Metal macromolecule alloy shielding material and machining process thereof

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EP1373420A1 (en) * 2001-03-05 2004-01-02 Georg Gros Water-based coating mixture, method for application of corrosion protection layer with said mixture, substrates coated thus and use thereof
CN102126598A (en) * 2011-01-10 2011-07-20 南京东润带业有限公司 Antistatic poly vinyl chloride (PVC) conveyer belt
CA2851164A1 (en) * 2011-10-19 2013-04-25 Basf Se Use of antistats in interior coating materials
CN104448676A (en) * 2014-12-29 2015-03-25 安徽瑞研新材料技术研究院有限公司 Metal macromolecule alloy shielding material and machining process thereof

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Application publication date: 20161026