CN106046719A - Antistatic type PBS (Poly Butylene Succinate) wood-plastic composite wire rod for 3D (Three Dimensional) printer - Google Patents
Antistatic type PBS (Poly Butylene Succinate) wood-plastic composite wire rod for 3D (Three Dimensional) printer Download PDFInfo
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- CN106046719A CN106046719A CN201610612822.4A CN201610612822A CN106046719A CN 106046719 A CN106046719 A CN 106046719A CN 201610612822 A CN201610612822 A CN 201610612822A CN 106046719 A CN106046719 A CN 106046719A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B13/00—Conditioning or physical treatment of the material to be shaped
- B29B13/06—Conditioning or physical treatment of the material to be shaped by drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/05—Filamentary, e.g. strands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92009—Measured parameter
- B29C2948/92085—Velocity
- B29C2948/92095—Angular velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92009—Measured parameter
- B29C2948/92209—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an antistatic type PBS (Poly Butylene Succinate) wood-plastic composite wire rod for a 3D (Three Dimensional) printer. The antistatic type PBS wood-plastic composite wire rod is prepared from the following raw materials in parts by weight: 65 to 75 parts of PBS, 20 to 30 parts of wood powder, 0.1 to 0.5 part of a chain extender, 0.1 to 0.5 part of a cross-linking agent, 0.1 to 2 parts of a nucleating agent, 0.2 to 1 part of an antioxigen, 0.2 to 2 parts of a lubricant, 0.5 to 2 parts of multi-wall carbon nanotube/ZnO composite powder and 5 to 15 parts of a composite antistatic agent. The PBS wood-plastic composite wire rod has a good antistatic effect; an antistatic product produced by the PBS wood-plastic composite wire rod is suitable for a special engineering purpose; the PBS wood-plastic composite wire rod also has a relatively low printing temperature and relatively good stretching strength and flexibility, has a low shrinkage rate, can prevent a warping problem after printing, and is suitable for a plurality of types of 3D molding technologies; the PBS wood-plastic composite wire rod is low in price, has low carbon, is environment-friendly, and can be completely circularly recycled; the PBS wood-plastic composite wire rod has a natural intimate feeling of wood, can generate a wood aroma in a printing process, and has a wide application prospect in the field of 3D printing.
Description
Technical field
The present invention relates to field of compound material, a kind of anti-static type is for the PBS/ wood plastics composite line of 3D printer
Material.
Background technology
3D printing technique is also known as a kind of emerging technology of increasing material manufacturing technology, actually rapid shaping field, and it is one
Kind based on mathematical model file, use powdery metal or plastics etc. can jointing material, come by the way of successively printing
The technology of constructed object.Ultimate principle is layered manufacturing, successively increases material and generates the technology of 3D solid.At present, 3D beats
Print technology is applied primarily to product prototype, Making mold and the field such as artistic creation, jewelry-making, substitutes these tradition and depends on
The retrofit technique relied.It addition, 3D printing technique is gradually applied to the necks such as medical science, biological engineering, building, clothing, aviation
Territory, has opened up wide space for innovation.
Poly butylene succinate (PBS), also referred to as polybutylene succinate or poly-succinic acid fourth diester, its fusing point is 105
DEG C, crystallization temperature is at about 61 DEG C, and relative crystallinity is 40 ~ 60%, is a kind of hemicrystalline with complete biodegradable ability
Resin, has good processing characteristics.At present, can be applicable to table ware, various household supplies articles for use, agricultural materials, bio-medical high score
The aspects such as sub-material, food and medicine packaging material, but pure PBS directly applies to 3D and prints the problem that there is thermal contraction, its
Toughness and hot strength also need to be improved further.
Summary of the invention
In order to solve above-mentioned the deficiencies in the prior art, the invention provides a kind of anti-static type PBS/ for 3D printer
Wood plastics composite wire rod, has good anti-static effect, utilizes its anti-static product produced to be applicable to special engineering purposes, also
Having relatively low print temperature, preferable hot strength and pliability, have low-shrinkage simultaneously, after preventing from printing, warpage is asked
Topic, it is adaptable to multiple 3D forming technique, and cheap, low-carbon environment-friendly, very can recycle by circulation and stress, there is timber
Natural friendliness, print time can produce natural wood aromatic odor, 3D print field have broad application prospects.
The technical problem to be solved is achieved by the following technical programs:
A kind of anti-static type is for the PBS/ wood plastics composite wire rod of 3D printer, and it is made up of the raw material of following weight portion meter:
PBS65 ~ 75 part, wood powder 20 ~ 30 parts, chain extender 0.1 ~ 0.5 part, cross-linking agent 0.1 ~ 0.5 part, nucleator 0.1 ~ 2 part, antioxidant
0.2 ~ 1 part, lubricant 0.2 ~ 2 part, multi-walled carbon nano-tubes/ZnO composite powder 0.5 ~ 2 part, compounded antistatic agent 5 ~ 15 parts.
In the present invention, described compounded antistatic agent by stannum oxide, titanium oxide and polyether ester by weight (1 ~ 4): (3 ~
5): (1 ~ 4) forms.
In the present invention, described multi-walled carbon nano-tubes is 1:(1 ~ 20 with the weight ratio of ZnO).Described multi-walled carbon nano-tubes with
The weight ratio of ZnO is 1:8.Described ZnO is flower-shaped nano ZnO material.
In the present invention, described wood powder selects the aspen fibers by using silicon of 300 mesh, pine cellulosic, rice husk, agricultural crop straw at least
A kind of.
There is advantages that composite wire of the present invention has good anti-static effect, utilize it to produce
Anti-static product be applicable to special engineering purposes；In advance multi-walled carbon nano-tubes is processed, then flower-shaped ZnO powder is inhaled
Attached form composite powder on multi-walled carbon nanotubes；Obtain scientific matching by test of many times again, be combined with PBS, wood powder and prepare
Can be used for the composite wire of 3D printer, it, compared with traditional polylactic acid (PLA) wire rod, has relatively low print temperature, relatively
Good hot strength and pliability, have low-shrinkage simultaneously, warpage issues after preventing from printing, it is adaptable to multiple 3D molding skill
Art, and composite wire is cheap, low-carbon environment-friendly, can very circulation and stress recycling, have timber natural friendliness,
Natural wood aromatic odor can be produced during printing, print field at 3D and have broad application prospects.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be described in detail.
Embodiment 1
A kind of anti-static type is for the PBS/ wood plastics composite wire rod of 3D printer, and it is made up of the raw material of following weight portion meter:
PBS70 part, wood powder 20 parts, chain extender 0.2 part, cross-linking agent 0.3 part, nucleator 0.5 part, 1 part of antioxidant, lubricant 1 part, many walls
CNT/ZnO composite powder 1.2 parts, compounded antistatic agent 10 parts；Described compounded antistatic agent by stannum oxide, titanium oxide and
Polyether ester forms by weight 2:3:2；Described multi-walled carbon nano-tubes/ZnO composite powder is by multi-walled carbon nano-tubes and flower-like nanometer
ZnO forms by weight 1:2.
This PBS composite material and preparation method thereof is as follows:
(1) preparation of flower-like nanometer ZnO: the sodium hydroxide of the Zinc diacetate dihydrate and 1.96g that weigh 0.76783g is respectively placed in
In beaker A, B and with forming clear solution with 10ml deionized water dissolving respectively, beaker A is placed in psychrolusia (5 DEG C) and even
Speed stirring, the most at the uniform velocity instills the sodium hydroxide solution in beaker B beaker A, carries out in three times, is spaced 5min, obtain uniformly,
Stable precursor solution, the precursor solution measuring 32.5ml with graduated cylinder is transferred in autoclave and seals, at 180 DEG C
Lower reaction 4 hours, question response still is cooled to room temperature, by product deionized water and dehydrated alcohol cyclic washing, filters extremely
Filtrate pH=7, is then dried at 60 DEG C, it is thus achieved that flower-like nanometer ZnO powder.
(2) pretreatment of multi-walled carbon nano-tubes: add concentrated sulphuric acid and the mixed acid of concentrated nitric acid in multi-walled carbon nano-tubes, many
The w/v of wall carbon nano tube and mixed acid is 1:135g/ml, takes out after soaking 5h, with distilled water wash, and uses vacuum
Pumping is filtered, and sucking filtration to filtrate is neutrality, is then put into by multi-walled carbon nano-tubes and dries in baking oven to constant weight, standby.
(3) preparation of multi-walled carbon nano-tubes/nano-ZnO composite powder: pretreated multi-walled carbon nano-tubes is added
In 100ml deionized water, prepare carbon after disperseing 200min under 800kW ultrasonic vibration and 1300r/min centrifugal speed stir and receive
Mitron dispersion liquid；Flower-like nanometer ZnO powder is added in 100ml ethanol, in the centrifugal speed of 1300kW ultrasonic vibration and 1500r/min
Nano-ZnO dispersion solution is prepared after the lower dispersion 100min of degree stirring；Ultrasonic lower toward addition nanometer in carbon nano tube dispersion liquid at 300kW
ZnO dispersion liquid, ultrasonic 90min, then sucking filtration, drying, prepare multi-walled carbon nano-tubes/nano-ZnO composite powder.
(4) preparation of PBS/ wood plastics composite wire rod: PBS, wood powder are dried in 80 DEG C of vacuum drying ovens 8h；After weighing
Each component be placed in high-speed kneading machine, keep rotating speed 5000rpm/min, high-speed stirred 60min；Mixed material joins
Double screw extruder charge door, double screw extruder parameter is: 121 DEG C of a district, two 125 DEG C of districts, three 135 DEG C of districts, 4th district
135 DEG C, five 130 DEG C of districts, rotating speed is 82rpm/min, extruding pelletization；Institute's pelletize adds by single screw extrusion machine extrusion after drying
Work becomes filament, extruder temperature to be set as 95 DEG C of a district, two 115 DEG C of districts, three 135 DEG C of districts, four 120 DEG C of districts, obtains extrusion line
Material, i.e. PBS/ wood plastics composite wire rod.
Wire rod carries out 3D printing test, print temperature 145 DEG C, and print procedure is smooth, prints product surface smooth well-balanced,
Appearance looks elegant, dimensionally stable and non-warpage, antistatic performance is good, has the timber fragrance of uniqueness.
Embodiment 2
Based on embodiment 1, the difference is that only: described multi-walled carbon nano-tubes/ZnO composite powder is by multi-walled carbon nano-tubes and flower
Shape nano-ZnO forms by weight 1:8.Prepared PBS/ wood plastics composite wire rod is carried out 3D printing test, print temperature 145
DEG C, print procedure is smooth, prints product surface smooth well-balanced, appearance looks elegant, dimensionally stable and non-warpage, has excellent anti-quiet
Electrical property, has the timber fragrance of uniqueness.
Embodiment 3
Based on embodiment 1, the difference is that only: described multi-walled carbon nano-tubes/ZnO composite powder is by multi-walled carbon nano-tubes and flower
Shape nano-ZnO forms by weight 1:15.Prepared PBS/ wood plastics composite wire rod is carried out 3D printing test, print temperature 145
DEG C, print procedure is smooth, prints product surface smooth well-balanced, and appearance looks elegant, dimensionally stable and non-warpage, antistatic performance is good
Good, there is the timber fragrance of uniqueness.
Embodiment 4
Based on embodiment 2, the difference is that only: described compounded antistatic agent is by stannum oxide, titanium oxide and polyether ester by weight
Form than 1:3:1.Prepared PBS/ wood plastics composite wire rod is carried out 3D printing test, print temperature 145 DEG C, print procedure stream
Freely, printing product surface smooth well-balanced, appearance looks elegant, dimensionally stable and non-warpage, antistatic performance is good, has the wood of uniqueness
Material fragrance.
Embodiment 5
Based on embodiment 2, the difference is that only: described compounded antistatic agent is by stannum oxide, titanium oxide and polyether ester by weight
Form than 4:3:4.Prepared PBS/ wood plastics composite wire rod is carried out 3D printing test, print temperature 145 DEG C, print procedure stream
Freely, printing product surface smooth well-balanced, appearance looks elegant, dimensionally stable and non-warpage, antistatic performance is good, has the wood of uniqueness
Material fragrance.
Embodiment 6
Based on embodiment 2, the difference is that only: described compounded antistatic agent is by stannum oxide, titanium oxide and polyether ester by weight
Form than 2:5:1.Prepared PBS/ wood plastics composite wire rod is carried out 3D printing test, print temperature 145 DEG C, print procedure stream
Freely, printing product surface smooth well-balanced, appearance looks elegant, dimensionally stable and non-warpage, antistatic performance is good, has the wood of uniqueness
Material fragrance.
Comparative example 1
Based on embodiment 1, the difference is that only: only add multi-walled carbon nano-tubes, be not added with nano-ZnO.By prepared PBS/
Wood plastics composite wire rod carries out 3D printing test, print temperature 145 DEG C, and print procedure is smooth, prints product surface smooth well-balanced, outward
Seeing attractive in appearance, dimensionally stable and non-warpage, antistatic performance is good, has the timber fragrance of uniqueness.
Comparative example 2
Based on embodiment 1, the difference is that only: multi-walled carbon nano-tubes is not anticipated.Prepared PBS/ wood is moulded
Composite wire carries out 3D printing test, print temperature 145 DEG C, and print procedure is smooth, prints product surface smooth well-balanced, and outward appearance is beautiful
Seeing, dimensionally stable and non-warpage, antistatic performance is good, has the timber fragrance of uniqueness.
Comparative example 3
Based on embodiment 1, the difference is that only: change multi-walled carbon nano-tubes into SWCN.By prepared PBS/ wood
Moulding composite wire and carry out 3D printing test, print temperature 145 DEG C, print procedure is smooth, prints product surface smooth well-balanced, outward appearance
Attractive in appearance, dimensionally stable and non-warpage, antistatic performance is good, has the timber fragrance of uniqueness.
Comparative example 4
Based on embodiment 1, the difference is that only: without multi-walled carbon nano-tubes/ZnO composite powder.By prepared PBS/ wood
Moulding composite wire and carry out 3D printing test, print temperature 145 DEG C, print procedure is smooth, prints product surface smooth well-balanced, outward appearance
Attractive in appearance, dimensionally stable and non-warpage, antistatic performance is general, has the timber fragrance of uniqueness.
Comparative example 5
Based on embodiment 1, the difference is that only: described compounded antistatic agent is by stannum oxide and polyethers fat 2:2 group by weight
Become.Prepared PBS/ wood plastics composite wire rod carries out 3D printing test, print temperature 145 DEG C, and print procedure is smooth, prints goods
Smooth surface is well-balanced, appearance looks elegant, dimensionally stable and non-warpage, and antistatic performance is poor, has the timber fragrance of uniqueness.
Comparative example 6
Based on embodiment 1, the difference is that only: described compounded antistatic agent is by stannum oxide and titanium oxide 2:3 group by weight
Become.Prepared PBS/ wood plastics composite wire rod carries out 3D printing test, print temperature 145 DEG C, and print procedure is smooth, prints goods
Smooth surface is well-balanced, appearance looks elegant, dimensionally stable and non-warpage, and antistatic performance is poor, has the timber fragrance of uniqueness.
Comparative example 7
Based on embodiment 1, the difference is that only: described compounded antistatic agent is by titanium oxide and polyethers fat 3:2 group by weight
Become.Prepared PBS/ wood plastics composite wire rod carries out 3D printing test, print temperature 145 DEG C, and print procedure is smooth, prints goods
Smooth surface is well-balanced, appearance looks elegant, dimensionally stable and non-warpage, and antistatic performance is poor, has the timber fragrance of uniqueness.
Comparative example 8
Based on embodiment 1, the difference is that only: without described compounded antistatic agent.By prepared PBS/ wood plastics composite line
Material carries out 3D printing test, print temperature 145 DEG C, and print procedure is smooth, prints product surface smooth well-balanced, appearance looks elegant, chi
Very little stable and not warpage, has the timber fragrance of uniqueness.
PBS composite is made injection batten, and carries out tensile property test (GB/T1040.2-2006), curved respectively
Qu Qiangdu (GB/T1446-2006) and impact property test (GB/T1943-2008) and sheet resistance test, and test result is shown in
Following table.
Embodiment described above only have expressed embodiments of the present invention, and it describes more concrete and detailed, but can not
Therefore the restriction to the scope of the claims of the present invention it is interpreted as, as long as using the skill that the form of equivalent or equivalent transformation is obtained
Art scheme, all should fall within the scope and spirit of the invention.
Claims (6)
1. anti-static type is for a PBS/ wood plastics composite wire rod for 3D printer, and it is made up of the raw material of following weight portion meter:
PBS65 ~ 75 part, wood powder 20 ~ 30 parts, chain extender 0.1 ~ 0.5 part, cross-linking agent 0.1 ~ 0.5 part, nucleator 0.1 ~ 2 part, antioxidant
0.2 ~ 1 part, lubricant 0.2 ~ 2 part, multi-walled carbon nano-tubes/ZnO composite powder 0.5 ~ 2 part, compounded antistatic agent 5 ~ 15 parts；Described
Compounded antistatic agent by stannum oxide, titanium oxide and polyether ester by weight (1 ~ 4): (3 ~ 5): (1 ~ 4) forms.
Anti-static type the most according to claim 1 is for the PBS/ wood plastics composite wire rod of 3D printer, it is characterised in that institute
State compounded antistatic agent to be made up of by weight 2:3:2 stannum oxide, titanium oxide and polyether ester.
Anti-static type the most according to claim 1 is for the PBS/ wood plastics composite wire rod of 3D printer, it is characterised in that institute
The weight ratio stating multi-walled carbon nano-tubes and ZnO is 1:(1 ~ 20).
Anti-static type the most according to claim 3 is for the PBS/ wood plastics composite wire rod of 3D printer, it is characterised in that institute
The weight ratio stating multi-walled carbon nano-tubes and ZnO is 1:8.
5. be used for the PBS/ wood plastics composite wire rod of 3D printer according to the anti-static type described in claim 3 or 4, its feature exists
In, described ZnO is flower-shaped nano ZnO material.
Anti-static type the most according to claim 1 is for the PBS/ wood plastics composite wire rod of 3D printer, it is characterised in that institute
State wood powder select the aspen fibers by using silicon of 300 mesh, pine cellulosic, rice husk, agricultural crop straw at least one.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610612822.4A CN106046719A (en) | 2016-07-29 | 2016-07-29 | Antistatic type PBS (Poly Butylene Succinate) wood-plastic composite wire rod for 3D (Three Dimensional) printer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610612822.4A CN106046719A (en) | 2016-07-29 | 2016-07-29 | Antistatic type PBS (Poly Butylene Succinate) wood-plastic composite wire rod for 3D (Three Dimensional) printer |
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| Publication Number | Publication Date |
|---|---|
| CN106046719A true CN106046719A (en) | 2016-10-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610612822.4A Pending CN106046719A (en) | 2016-07-29 | 2016-07-29 | Antistatic type PBS (Poly Butylene Succinate) wood-plastic composite wire rod for 3D (Three Dimensional) printer |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108164931A (en) * | 2016-12-07 | 2018-06-15 | 黑龙江鑫达企业集团有限公司 | A kind of environment-friendly type 3D printing wood plastic composite |
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|---|---|---|---|---|
| CN104356618A (en) * | 2014-10-29 | 2015-02-18 | 衢州学院 | Biomass wood-plastic composite material for 3D (three-dimensional) printing and preparation method for biomass wood-plastic composite material |
| CN104962051A (en) * | 2015-06-23 | 2015-10-07 | 浙江农林大学 | Bamboo-plastic composite wire material for 3D printing and manufacturing method thereof |
| US20150344682A1 (en) * | 2012-11-19 | 2015-12-03 | Hewlett-Packard Development Company, Lp. | Compositions for three-dimensional (3d) printing |
| CN105176020A (en) * | 2015-10-19 | 2015-12-23 | 福建师范大学 | PBS (Poly Butylene Succinate)/carbon material composite wire for 3D (Three-dimensional) printing and preparation method thereof |
| CN105199339A (en) * | 2015-10-19 | 2015-12-30 | 福建师范大学 | PBS (poly butylenes succinate)/PBAT (poly butyleneadipate-co-terephthalate)/CNTs (Carbon Nanotubes) material for 3D printing and preparation method of PBS/PBAT/CNTs material |
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2016
- 2016-07-29 CN CN201610612822.4A patent/CN106046719A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150344682A1 (en) * | 2012-11-19 | 2015-12-03 | Hewlett-Packard Development Company, Lp. | Compositions for three-dimensional (3d) printing |
| CN104356618A (en) * | 2014-10-29 | 2015-02-18 | 衢州学院 | Biomass wood-plastic composite material for 3D (three-dimensional) printing and preparation method for biomass wood-plastic composite material |
| CN104962051A (en) * | 2015-06-23 | 2015-10-07 | 浙江农林大学 | Bamboo-plastic composite wire material for 3D printing and manufacturing method thereof |
| CN105176020A (en) * | 2015-10-19 | 2015-12-23 | 福建师范大学 | PBS (Poly Butylene Succinate)/carbon material composite wire for 3D (Three-dimensional) printing and preparation method thereof |
| CN105199339A (en) * | 2015-10-19 | 2015-12-30 | 福建师范大学 | PBS (poly butylenes succinate)/PBAT (poly butyleneadipate-co-terephthalate)/CNTs (Carbon Nanotubes) material for 3D printing and preparation method of PBS/PBAT/CNTs material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108164931A (en) * | 2016-12-07 | 2018-06-15 | 黑龙江鑫达企业集团有限公司 | A kind of environment-friendly type 3D printing wood plastic composite |
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