CN106045358A - Method for improving compatibility and bonding performance of waste rubber particles and cement - Google Patents

Method for improving compatibility and bonding performance of waste rubber particles and cement Download PDF

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Publication number
CN106045358A
CN106045358A CN201610373527.8A CN201610373527A CN106045358A CN 106045358 A CN106045358 A CN 106045358A CN 201610373527 A CN201610373527 A CN 201610373527A CN 106045358 A CN106045358 A CN 106045358A
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Prior art keywords
waste
cement
powder
rubber particle
rubber
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CN201610373527.8A
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Inventor
杨蝉聪
詹忠
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SICHUAN GOLDMILL ENVIRONMENTAL PROTECTION NEW MATERIALS Co Ltd
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SICHUAN GOLDMILL ENVIRONMENTAL PROTECTION NEW MATERIALS Co Ltd
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Priority to CN201610373527.8A priority Critical patent/CN106045358A/en
Publication of CN106045358A publication Critical patent/CN106045358A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • C04B40/0042Powdery mixtures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02Agglomerated materials, e.g. artificial aggregates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/10Clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/08Diatomaceous earth
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/18Waste materials; Refuse organic
    • C04B18/20Waste materials; Refuse organic from macromolecular compounds
    • C04B18/22Rubber, e.g. ground waste tires
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/50Flexible or elastic materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/50Flexible or elastic materials
    • C04B2111/503Elastic materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The invention discloses a method for improving the compatibility and bonding performance of waste rubber particles and cement, and belongs to the field of building materials. The method aims at solving the problems of poor compatibility and poor bonding performance of waste rubber particles and a cement base. In the method, inorganic inert powder is embedded in waste rubber particles, and the inorganic inert powder material and the rubber particles can be mixed in any proportion according to application needs; by embedding the inorganic inert powder in the rubber powder through a physical method, the bonding strength of rubber cement base powder and cement paste can be significantly improved, the density of the rubber cement base powder can be improved at the same time, and the rubber cement base powder can be uniformly distributed in concrete.

Description

A kind of method strengthening waste and old rubber particle and cement compatibility cementability
The application is the divisional application of original application " a kind of waste rubber powder processing method for cement-based material ", former Shen Please the applying date: on February 14th, 2014, application number: 2014100517361.
Technical field
The present invention relates to building materials field, be specifically a kind of waste and old rubber particle and cement compatibility cementability of strengthening Method.
Background technology
Over nearly 30 years, the developed country such as the U.S., Canada, Japan, Korea S has contemplated that the waste tire rubber that will pulverize Grain is applied in cement-based material, and Zhu professor (being University Of Tianjin professor now) of Arizona State university is found by research, The cement-based material of mix 760cm3 at least can utilize rubber grain produced by 5 junked tires, and exists in August, 2006 In the construction process of one hundred houses east, Wu Xiang road two, Wuqing District, Tianjin mouth bridge, Rubber Concrete is used to carry out first Deck paving.In the use of so far 7 years, observe and do not find that pave-load layer cracks and cracking phenomena.For observed result, Analyze engineering and the economy of the Rubber Concrete being applied to deck paving.Result shows: deck paving is rubber collection One of material concrete application having the fine suitability and advantage, its durability obtains preliminary identification, is worth further research promotion, Therefore Latex cement sill can alleviate the environmental pollution that junked tire accumulation is caused to a great extent, has the biggest Environmental protection, social benefit.
Many research shows, after waste rubber grain is applied to cement-based material, the elasticity of cement-based material increases permissible Improve its shock resistance, freeze proof, cracking resistance, absorb sound, be incubated, the performance such as heat insulation, the most also have anti-skidding, eliminate the noise, anti salt spray corrosion, Anti-ground turns over the performances such as alkali, but due to the hydrophobicity of waste Crumb rubber, with the poor compatibility of cement-based material, easily causes layering, Make its intensity decline to a great extent, limit its application significantly.
The reduction of cement concrete strength can be slowed down by rubber particle surface modification, be applied to cement-based material at present Rubber particle surface method of modifying mainly have the means such as ultrasonic wave water washing, ozone or sulfur trioxide activation, NaOH solution cleaning Rubber powder surface is made to combine upper hydrophilic polar group, such as carboxyl, sulfonic group etc..The middle promulgated by the State Council of Publication No. CN101638465A Bright patent, discloses a kind of rubber particle surface method of modifying for cement-based material, and concrete technical scheme is: first by propylene Acid is configured to ethanol solution, then in the acrylic acid-ethanol solution described in being added by the Polyethylene Glycol that mean molecule quantity is 1000, spreads At rubber particle surface, then aqueous solution will be configured to as catalyst potassium peroxydisulfate, be sprinkling upon rubber particle surface.In blender It is sufficiently stirred for several minutes, then carries out reacting by heating 1 hour at 80 DEG C ~ 90 DEG C, obtain modified rubber powder.Although this patented technology The more convenient waste rubber grain surface modification that solves, but practice of construction is far smaller than cement mortar due to waste Crumb rubber density Density so that rubber powder easily floats on concrete surface, causes stirring layering, is unfavorable for construction.
Secondly, the method for modifying of the waste and old rubber particle used at present is mainly chemical surface modification, by by acid, alcohol Deng spray solution on rubber grain, by modes such as stirring, heating so that the surface of rubber grain has certain hydrophilic Property, but for rubber grain inside, it is still that hydrophobicity, does not infiltrates with inorganic matters such as cement mortars, causes rubber Grain and the poor compatibility of cement mortar;Simultaneously as the density of rubber grain is less than water and cement mortar, when rubber grain is added All in cement mortar, hydrophobicity and its density within rubber grain are less than cement mortar, cause rubber grain to rise, make Become lamination, have a strong impact on the quality of concrete.
Summary of the invention
It is an object of the invention to, for waste rubber grain surface modification cost height have again chemical material three waste discharge and The problems such as the construction inconvenience that cement slurry density and waste Crumb rubber density variation cause greatly, it is provided that the enhancing of a kind of lower cost is waste and old Rubber grain and the method for cement based compatibility cementability, this method makes Latex cement original washing powder the most cementing with cement based, with Time mate with the cement mortar of different densities according to Latex cement original washing powder density and to be easy to construction so that Latex cement original washing powder substantially according to Design requirement is uniformly distributed in cement concrete.
The technical solution used in the present invention is as follows:
The invention discloses a kind of method strengthening waste and old rubber particle and cement compatibility cementability, by waste old Embed inert inorganic powders in Li, comprise the steps:
1) inert inorganic powders material is mixed with waste rubber grain;
2) mixture step 1 obtained makes inert inorganic powders material embed waste Crumb rubber by physical method.
In the present invention, inert inorganic powders material described in step 1 refers to be not susceptible to the inorganic material of chemical reaction Powder, includes but not limited to kieselguhr, flyash, blanc fixe, Iron Ore Powder, quartz sand powder, agstone, Pulvis Talci, phosphorus ore Powder, asbestos breeze, graphite powder, silica flour etc.;Its particle diameter can be adjusted according to actual needs, in an instantiation, and institute State inert inorganic powders material and waste rubber grain particle diameter not less than 10 mesh, such as: 10 mesh, 20 mesh, 30 mesh, 40 mesh, 50 mesh and 60 mesh etc..
In the present invention, described inert inorganic powders material can mix by a certain percentage with waste rubber grain, at one In concrete example, inert inorganic powders material is 3%-70%:97%-30% with the weight ratio of waste rubber grain.Both ratios Can be adjusted according to the requirement of actual cement mortar proportioning, when cement slurry density is higher, inert inorganic powders material is with useless In the mixture of rubber grain, the comparision contents of waste rubber grain is high, when cement slurry density is relatively low, and inert inorganic powders material High with the comparision contents of inert inorganic powders material in the mixture of waste rubber grain.In the present invention, inert inorganic powders material Material shared part by weight in the mixture can be 5%, 10%, 20%, 30%, 40%, 50%, 60% or 70%, and waste rubber grain is mixed In compound, shared part by weight can be 95%, 90%, 80%, 70%, 60%, 50%, 40% or 30%.
Physical method described in step 2 of the present invention can be to include but not limited to that mechanical force rolls, screw extrusion, high speed are cut Cut, airflow milling head-on collision, the method such as ultrasonic blending process.By the method for physics so that in described inert inorganic powders material One or more be embedded in waste Crumb rubber, this embedding can be to have fully embedded into, it is also possible to is to be partially submerged into.By this side The rubber powder mixture that method obtains has three kinds of physical forms: the rubber powder that a. inorganic inert dusty material is not embedded into, b. is inorganic Inert powder material embeds rubber powder and forms complex, c. inorganic inert dusty material individualism granule.
By step 1 and the process of 2, the blend that inorganic inert dusty material and the rubber powder obtained is inlayed is referred to as rubber Cement original washing powder, it has with cement good cementing, thus it is strong with cement slurry interface viscose glue to increase substantially Latex cement original washing powder Degree, simultaneously because inorganic inert powder embeds in rubber powder, the density increasing Latex cement original washing powder makes rubber powder be not easy Upwards isolate layering, uniformly divide according to the Latex cement original washing powder obtained by regulation rubber grain and inorganic inert dusty material ratio It is dispersed in cement concrete.
The beneficial effects of the present invention is:
1, inorganic inert dusty material and rubber grain can need mix with arbitrary proportion according to application, close according to cement based The Latex cement original washing powder of degree preparation corresponding density, to reach Latex cement original washing powder and cement based and uniformly to mix, it is to avoid is layered;
2, rubber powder is embedded by physical method by inorganic inert dusty material, it is possible to dramatically increase Latex cement original washing powder and cement Slurry bonding strength, increases Latex cement original washing powder density, it is simple to Latex cement original washing powder is uniformly distributed in concrete simultaneously.
Accompanying drawing explanation
Fig. 1 is the inorganic inert dusty material microstructure with rubber powder embedding monomer altogether of the present invention;
Fig. 2 is the microstructure of the Latex cement original washing powder of the present invention;
Fig. 3 is Latex cement original washing powder and the contrast of General Purpose Rubber powder hydrophilic of the present invention, is Latex cement base in left sample cup in figure Powder (60 mesh), is General Purpose Rubber powder (60 mesh) in right sample cup;
Fig. 4 is the rupture strength test result of the embodiment of the present invention 1 rubber concrete;
Fig. 5 is the intensity test result of the embodiment of the present invention 1 rubber concrete;
Fig. 6 is oleo stock Behavior of Hardened Cement Paste (left) and 3% robber cement mudstone (right) the damage-form comparison diagram of the embodiment of the present invention 2;
Fig. 7 is blank sample Behavior of Hardened Cement Paste (left) and the elastic modelling quantity comparison diagram of 6% Latex cement (right) of the embodiment of the present invention 2.
Detailed description of the invention
Below in conjunction with the accompanying drawings, the present invention is described in detail.
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with drawings and Examples, right The present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, and It is not used in the restriction present invention.
Specific embodiment 1: the goods of rubber concrete
18000g 40 mesh waste Crumb rubber (90%) and 2000g 40 mesh kieselguhr (10%) is stirred 5 minutes by agitator, preparation Become mixing just material;Mixing just material makes Latex cement original washing powder by grinding the machine of squeezing.According to JGJ55-2000 and JTG F30-2003 Test method prepares rubber concrete module.(see Table 1)
The every material usage of table 1 concrete
The anti-folding of embodiment 1 rubber concrete, intensity test result are shown in Fig. 3 and Fig. 4.
From anti-folding, the intensity test result of contrast it will be seen that when Latex cement original washing powder mix ratio is 5%, resist Folding intensity is higher than the cement concrete not adding Latex cement original washing powder;When Latex cement original washing powder mix ratio is 5%, 10% and 15%, Comprcssive strength is higher than the cement concrete not adding Latex cement original washing powder.Bonding between this explanation rubber particle and cement mortar is very Good, when the concrete stress that Latex cement is constituted, anisotropy during rubber particle stress has decomposed power;When Latex cement base When powder mix ratio is bigger, flexible support point increases, and intensity reduces.
Specific embodiment 2: the goods of elastic cement slurry stone
40 kg 40 mesh waste Crumb rubber (80%) and 10 kg 40 mesh kieselguhr (20%) are stirred 5 minutes by agitator, preparation Become mixing just material;Mixing just material makes Latex cement original washing powder by grinding the machine of squeezing.Add in cement mortar according to weight ratio 4%, 6% and 8% Add Latex cement original washing powder, prepare robber cement mudstone.
Table 2 robber cement mudstone system mechanical property
Table 3 Latex cement system comprehensive mechanical property
By Behavior of Hardened Cement Paste Mechanical Property Analysis it is found that improve the increasing being mainly manifested in Poisson's ratio that Behavior of Hardened Cement Paste is elastic Add, the reduction of elastic modelling quantity.Dynamic survey by the Behavior of Hardened Cement Paste elastic modelling quantity of the Latex cement original washing powder dosage of the different dosage of contrast Examination finds, conventional cement slurries elastic modelling quantity is only 12.6GPa, and when Latex cement original washing powder dosage reaches 6%, elastic modelling quantity improves For 17.3GPa, intensity aspect conventional cement slurries intensity is 21MPa, and the cement mortar of the rubber powder mixture that dosage reaches 6% is strong Degree brings up to 31 MPa.
Specific embodiment 3 secretes the application of page 1 well scene
Basic condition is introduced, casing programme:
Design is total for amount 37.7 m3, actual for amount 38 m3.
Cementing quality
Cementing quality basic condition is introduced: sealing layer position: 2588-3707m, surveys artificial bottom of a well: 3644m.
Conclusion:
(1) the modified effect of Latex cement original washing powder is obvious, it is possible to as oil well cement additive, it is possible to improve the bullet of cement mortar Mould, but the reduction certain to comprcssive strength, but rupture strength can be significantly improved;
(2) being shown experimentally that, Latex cement original washing powder dosage should control between 3%-6%, more than 85 DEG C of suggestion usage quantities It is about 3 ~ 5% to be advisable;
(3) Latex cement original washing powder-mortar architecture has preferable dilatancy, and anti-gas channeling is functional;
(4) secrete page 1 well effect of field application to show: Latex cement original washing powder can effectively ensure that one, the sealing quality of second interface.
Comprehensive Assessment: good mechanical property, elastic and toughness is obviously improved;Key property is good, meets horizontal well solid Well demand, acceptance rate: 90%.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention Any amendment, equivalent and the improvement etc. made within god and principle, should be included within the scope of the present invention.

Claims (8)

1. the method strengthening waste and old rubber particle and cement compatibility cementability, it is characterised in that to waste and old rubber particle Middle embedding inert inorganic powders.
2. the method strengthening waste and old rubber particle and cement compatibility cementability as claimed in claim 1, it is characterised in that institute The step stating embedding inert inorganic powders is as follows:
Step 1: inert inorganic powders material is mixed with waste rubber grain;
Step 2: mixture step 1 obtained makes inert inorganic powders material embed waste Crumb rubber by physical method.
3. the method strengthening waste and old rubber particle and cement compatibility cementability as claimed in claim 2, it is characterised in that its The inert inorganic powders material of middle step 1 selected from kieselguhr, flyash, blanc fixe, Iron Ore Powder, quartz sand powder, agstone, One or more in Pulvis Talci, ground phosphate rock, asbestos breeze, graphite powder, silica flour.
4. the method strengthening waste and old rubber particle and cement compatibility cementability as claimed in claim 2, it is characterised in that institute The inert inorganic powders particle diameter stated is not less than 10 mesh.
5. the method for the cement compatibility strengthening waste and old rubber particle as described in claim 2, it is characterised in that inertia without Machine powder is 3%-70% with the weight ratio of inert inorganic powders in the mixture of waste rubber grain.
6. the method for the cement compatibility strengthening waste and old rubber particle as described in claim 2, it is characterised in that described Embedding grammar rolls selected from mechanical force, screw extrusion, high speed shear, airflow milling clash, ultrasonic blending processes.
7. the method for the cement compatibility strengthening waste and old rubber particle as described in claim 2, it is characterised in that described lazy Property inorganic powder is for having fully embedded in waste and old rubber particle.
8. the method for the cement compatibility strengthening waste and old rubber particle as described in claim 2, it is characterised in that described lazy Property inorganic powder is for being partially embedded in waste and old rubber particle.
CN201610373527.8A 2014-02-14 2014-02-14 Method for improving compatibility and bonding performance of waste rubber particles and cement Pending CN106045358A (en)

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CN201410051736.1A CN103819109B (en) 2014-02-14 2014-02-14 A kind of waste rubber powder processing method for cement-based material
CN201610373527.8A CN106045358A (en) 2014-02-14 2014-02-14 Method for improving compatibility and bonding performance of waste rubber particles and cement

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CN201610373528.2A Pending CN106007540A (en) 2014-02-14 2014-02-14 Production method of compression and bending resistant rubber concrete product
CN201610373527.8A Pending CN106045358A (en) 2014-02-14 2014-02-14 Method for improving compatibility and bonding performance of waste rubber particles and cement
CN201410051736.1A Active CN103819109B (en) 2014-02-14 2014-02-14 A kind of waste rubber powder processing method for cement-based material
CN201610374409.9A Pending CN106045397A (en) 2014-02-14 2014-02-14 Anti-compression anti-fracture rubber cement product
CN201610374408.4A Pending CN106007437A (en) 2014-02-14 2014-02-14 Rubber and cement matrix powder
CN201610373529.7A Pending CN106045356A (en) 2014-02-14 2014-02-14 Preparation method of high-strength anti-fracture cement paste stone products

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CN201610374409.9A Pending CN106045397A (en) 2014-02-14 2014-02-14 Anti-compression anti-fracture rubber cement product
CN201610374408.4A Pending CN106007437A (en) 2014-02-14 2014-02-14 Rubber and cement matrix powder
CN201610373529.7A Pending CN106045356A (en) 2014-02-14 2014-02-14 Preparation method of high-strength anti-fracture cement paste stone products

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CN111423141A (en) * 2020-04-29 2020-07-17 中交第三航务工程局有限公司 Modification method of rubber concrete and application thereof
CN115140961A (en) * 2021-03-31 2022-10-04 中国石油化工股份有限公司 Elastic particles for cement paste, elastic cement paste, and preparation method and application of elastic particles

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CN105753415B (en) * 2016-05-21 2018-10-26 夏百庆 A method of preparing cement mortar using waste rubber, bone meal
CN106082742A (en) * 2016-06-16 2016-11-09 四川金摩尔环保新材料有限责任公司 A kind of cement original washing powder and in the application of cement concrete and application in highway construction thereof
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