CN106042440B - A kind of nutrient raw material shaped device and its method of work for landscape rehabilitation - Google Patents

Abstract

The invention discloses a kind of nutrient raw material shaped device and its method of work for landscape rehabilitation, including reduction stage, heating tube, compression section, blanking storehouse, supporting leg, motor, control system；Stalk enters device from reduction stage upper end, and control system controlled motor rotates, and stalk, to lower landing, enters compression section, compression section enters the final discharger in blanking storehouse after the straw extrusion after heating is molded after reduction stage is broken after heated pipe heating.A kind of nutrient raw material shaped device and its method of work for landscape rehabilitation of the present invention, crop waste stalk is handled, environment-friendly high-efficiency, light structure is flexible and convenient to use, and power consumption is low, simple and practical.

Description

A kind of nutrient raw material shaped device and its method of work for landscape rehabilitation

Technical field

The invention belongs to garden landscape convalescence device field, and in particular to a kind of nutrient raw material for landscape rehabilitation is molded Device and its method of work.

Background technology

The history of the existing last 100 yearses of development of landscape rehabilitation equipment.Early stage in 20th century, western developed country are had started in garden Using machinery in the heavy operation of woods greening, handling machinery and agricultural machinery mainly are used at that time, such as uses automobile and lifting Machine transports and handling material, the consolidation before being planted with tractor and plough etc. etc..After the 1950s, various gardens Woods greening special-purpose machinery starts to be born one after another, and such as planting machine, lawn mower, orchard tractor, Landscape Greening Machines start Into fast-developing period.After the 1980s, in European and American developed countries, with the further development of economy, people's people's livelihood The gentle housing condition of running water further improves, and small-sized Landscape Greening Machines initially enter family with equipment, turn into the indispensability of family Equipment, particularly turf machinery have been popularized with equipment in the middle class family of the states such as the U.S., Canada.To 20th century End, all over the world construction and maintenance of most of city from public lawn to Yard-greenbelt all realize do mechanization operation.

The development of state's Study of Platycladus orientalis-Robinia pseudoacacia rehabilitation equipment originates in later stage the 1970s, has initially entered the 1990s soon Fast developing period, its outstanding feature, in addition to graden machine factory, forestry machinery factory production landscape rehabilitation equipment, a collection of strength Stronger universal machine works, machine tool plant also begin to produce the Landscape Greening Machines of different cultivars, the small-sized Landscape Greening Machines in part Have started to export to foreign countries.The import of advanced landscape rehabilitation equipment significantly rises.The one of the states such as Britain, Germany, Sweden, Japan The Landscape Greening Machines of a little major companies enter domestic market one after another, and the company for selling domestic and international landscape rehabilitation equipment emerges in multitude, Scale also expands day by day, and has preliminarily formed national selling network.The proportion of do mechanization operation in large-scale landscape engineering Significantly improve, a collection of mechanized construction troop has occurred.Landscape Greening Machines initially enter the garden of enterprises and institutions and lived Residence cell.But as a whole:The kind of state's Study of Platycladus orientalis-Robinia pseudoacacia rehabilitation equipment is also relatively simple, and performance, quality and manufacture level are all also Relatively backward, there is a big difference compared with developed countries, domestic Landscape Greening Machines be turned into industry than escheat very little, with hair Compared up to national all-round mechanization degree, gap is fairly obvious.It is generally domestic at present still in the development of landscape rehabilitation equipment Primary stage.

At present, landscape convalescence device in China's also has very big gap, user in many aspects of design with external Design to product has many discontented.

Occur people, machine non-matching phenomenon from the perspective of industrial design, in man-computer relation, user needs croucs The position of de-regulation cutter, acid, pain and sense of fatigue, which occurs, using the arm and waist, the leg that make people for a long time makes the operation of people comfortable Degree is greatly reduced；The noise of landscape convalescence device is excessive, the use of user is not only influenceed, to the resident, pedestrian et al. of surrounding Group causes deleterious effect, and user psychologically also has conflict, irritated mood；Hay mover is mixed using both gasoline, diesels Compound discharges CO as the energy₂, hydronitrogen, pollution is not only caused to surrounding environment, at the same time also day accumulate the moon The tired healthy human body for corroding user；The problem of these are existing various is constantly affecting the body of user The heart is experienced, and the not only use operation to user brings inconvenience, psychologically also result in bad influence.

The content of the invention

In order to solve the above-mentioned technical problem, the invention provides a kind of nutrient raw material shaped device for landscape rehabilitation, Including reduction stage 1, heating tube 2, compression section 3, blanking storehouse 4, supporting leg 5, motor 6, control system 7；In the bottom of blanking storehouse 4 The heart is provided with motor 6, and the bottom of blanking storehouse 4 is surrounded by supporting leg 5, and the front side sidewall of blanking storehouse 4 is provided with control system 7, on blanking storehouse 4 Portion is provided with compression section 3；The top of compression section 3 is heating tube 2；The top of heating tube 2 is reduction stage 1, and the heating tube 2 is Helical structure made of stainless steel tube.

Further, the reduction stage 1, including central shaft 1-1, upper strata rotate sawtooth 1-2, fixed sawtooth 1-3, and lower floor turns Dynamic sawtooth 1-4；The central shaft 1-1 is arranged vertically at the inner hub location of reduction stage 1, and central shaft 1-1 lower ends extend vertically through The center of feed bin 4 is simultaneously connected with motor 6；It is horizontal loops that the upper strata, which rotates sawtooth 1-2 centers, and upper strata, which is rotated on the outside of sawtooth 1-2, is Three fan-shaped flakes of the side wall with sawtooth, fan-shaped flake horizontal homogeneous are distributed on the outside of horizontal loops, and it is horizontal that upper strata rotates sawtooth 1-2 Ring inner side and central shaft 1-1 outer wall vertical seamless weldings；It is horizontal circular ring on the outside of the fixed sawtooth 1-3, in fixed sawtooth 1-3 Side is the level on the outside of fixed sawtooth 1-3 along equally distributed rectangular tab of four side walls with sawtooth in horizontal circular ring center of circle direction Annulus outer wall seamless welding vertical with the inwall of reduction stage 1, fixed sawtooth 1-3 upper ends rotate the distance of sawtooth 1-2 lower ends with upper strata For 5mm~10mm；It is horizontal loops that the lower floor, which rotates sawtooth 1-4 centers, and lower floor rotates and sawed on the outside of sawtooth 1-4 for three side wall bands The fan-shaped flake of tooth, fan-shaped flake horizontal homogeneous are distributed on the outside of horizontal loops, and lower floor rotates on the inside of sawtooth 1-4 horizontal loops and center Axle 1-1 outer wall vertical seamless weldings, the distance that lower floor rotates sawtooth 1-4 upper ends to fixed sawtooth 1-3 lower ends is 5mm~10mm.

Further, the compression section 3, including fixed support plate 3-1, compress spiral 3-2, relief hole 3-3, TEMP Device 3-4；The fixed support plate 3-1 is located at the upper end of compression section 3, and fixed support plate 3-1 is centrally through horizontally disposed ball axle Hold it is vertical with central shaft 1-1 be socketed, be horizontal circular ring and seamless welding vertical with the inwall of compression section 3 on the outside of fixed support plate 3-1, Fixed support plate 3-1 outer annulars are connected with center ball bearing by four horizontally disposed Investigation of Reinforcing Rectangular Steel Beam vertical weldings；Institute State compression spiral 3-2 to be arranged vertically inside compression section 3, be the horizontal sheet spiral being rotated down, pressure on the outside of compression spiral 3-2 Contracting spiral 3-2 centers are up-narrow and down-wide truncated cone-shaped central tube, run through in the middle part of compression spiral 3-2 central tubes and are fixedly welded on center On axle 1-1 outer walls；The relief hole 3-3 is located at the side wall lower ends of compression section 3, and relief hole 3-3 is the circle through the side wall of compression section 3 Through hole, relief hole 3-3 quantity are no less than 10；The temperature sensor 3-4 is located in the upper end side wall of compression section 3, TEMP Device 3-4 seamless weldings vertical with the inwall of compression section 3, temperature sensor 3-4 are connected with control system 7 by wire.

Further, the blanking storehouse 4 is molded by high polymer material pressing mold, the composition of blanking storehouse 4 in parts by weight Composition and manufacturing process are as follows：

1st step, 600~800 parts of the ultra-pure water that electrical conductivity is the μ S/cm of 1.10 μ S/cm~1.40 is added in a kettle, open Agitator in dynamic reactor, rotating speed is 40rpm~60rpm, starts heat pump, reactor temperature is risen to 55 DEG C~60 ℃；Sequentially add 8~12 parts of γ-chloro ethyl acetoacetate, 8~12 parts of 3- (to methanesulfonylphenYl) serine ethyl ester, right 8~12 parts of nitrobenzene sulphonyl yl acetate, to being completely dissolved, regulation pH value is 4.5~6.5, and agitator speed is adjusted to for stirring 90rpm~100rpm, temperature are 70 DEG C~80 DEG C, esterification 2~6 hours；

2nd step, take 8~12 parts of acetparaminosalol-methyl o-anisate, 4-tert-Butylphenylacetic acid methyl esters 8~12 Part crushes, and powder diameter is 50~80 mesh；It is well mixed to add 15~30 parts of nanoscale boric acid rhodium, is laid in pallet, tiles Thickness is 5mm~10mm, uses the alpha ray irradiation that dosage is 0.35MeV~1.50MeV for 1.2kGy~3.2kGy, energy 10min~15min；

3rd step, the mixed-powder handled through the 2nd step are dissolved in 8~12 parts of gavaculine ethyl ester, add reactor, Agitator speed is 90rpm~100rpm, and temperature is 100 DEG C~110 DEG C, start vavuum pump make the vacuum of reactor reach- 0.01MPa~-0.03MPa, keeps this state response 2~6 hours；Pressure release is simultaneously passed through ammonia, makes the reacting kettle inner pressure be 0.01MPa~0.03MPa, insulation stand 2~6 hours；Agitator speed is promoted to 150rpm~160rpm, simultaneous reactions afterwards Kettle pressure release is to 0MPa；Sequentially add 8~12 parts of m-dibutylamino benzoic acid, N- pi-allyl-N- m-aminophenyl Methyl-aminos After 8~12 parts of t-butyl formate is completely dissolved, adds 8~12 parts of crosslinking agent and be stirred so that the hydrophilic parent of reactor solution Oily equilibrium valve is 6.5~7.5, and insulation stands 2~6 hours；

4th step, when agitator speed is 100rpm~110rpm, sequentially add and face different 8~12 parts of toluene hydrogen acid ether (hydrogen acid ester), 5- 8~12 parts of 8~12 parts of amino isophthalic acid dimethyl ester and monochloroacetic acid phenyl ester, reactor pressure is lifted, is reached 1.50MPa~3.50MPa, temperature are 150 DEG C~160 DEG C, polymerisation 2~6 hours；By reacting kettle inner pressure after the completion of reaction 0MPa is down to, 30 DEG C~33 DEG C is cooled to, discharging, enters molding press and can be prepared by blanking storehouse 4；

Crosslinking agent meta-chlorocarbanilate between the chloro- 2- butynyls-N- of 4-；

The particle diameter of the nanoscale boric acid rhodium is 30nm~60nm.

Further, the invention also discloses a kind of method of work of the nutrient raw material shaped device for landscape rehabilitation, Including herein below：

1st step, stalk enter device from the upper end of reduction stage 1, and the controlled motor 6 of control system 7 rotates, and stalk is in reduction stage 1 Broken backward lower landing, heated pipe 2 enter compression section 3 after heating, compression section 3 enters after the straw extrusion after heating is molded 4 final discharger of blanking storehouse；

2nd step, when the temperature that temperature sensor 3-4 is measured be less than 110 DEG C when, temperature sensor 3-4 sends a signal to control System 7 processed, control system 7 control heating tube to accelerate heat conduction oil flow rate, when the temperature that temperature sensor 3-4 is measured is higher than 130 DEG C When, temperature sensor 3-4 sends a signal to control system 7, and control system 7 controls heating tube to reduce heat conduction oil flow rate.

A kind of nutrient raw material shaped device and its method of work for landscape rehabilitation disclosed in patent of the present invention, its advantage It is：

(1) device will be used to handle crop waste stalk, environment-friendly high-efficiency；

(2) apparatus structure is light and handy, flexible and convenient to use；

(3) device energy-wasting is low, simple and practical.

A kind of nutrient raw material shaped device and its method of work for landscape rehabilitation of the present invention, handle crops Waste straw, environment-friendly high-efficiency, light structure is flexible and convenient to use, and power consumption is low, simple and practical.

Brief description of the drawings

Fig. 1 is a kind of heretofore described nutrient raw material shaped device schematic diagram for landscape rehabilitation.

Fig. 2 is reduction stage schematic diagram in the present invention.

Fig. 3 is compression section schematic diagram in the present invention.

Fig. 4 is the statistical chart that decline feed bin material residual intensity of the present invention changes with usage time.

In figure 1 above~Fig. 3, reduction stage 1, central shaft 1-1, upper strata rotates sawtooth 1-2, fixed sawtooth 1-3, lower floor's rotation Sawtooth 1-4, heating tube 2, compression section 3, fixed support plate 3-1, spiral 3-2 is compressed, relief hole 3-3, temperature sensor 3-4, is fallen Feed bin 4, supporting leg 5, motor 6, control system 7.

Embodiment

With reference to the accompanying drawings and examples to a kind of nutrient raw material shaped device for landscape rehabilitation provided by the invention And its method of work is further described.

As shown in figure 1, it is a kind of nutrient raw material shaped device schematic diagram for landscape rehabilitation provided by the invention.From figure In find out, including reduction stage 1, heating tube 2, compression section 3, blanking storehouse 4, supporting leg 5, motor 6, control system 7；Stalk is from broken 1 upper end of section enters device, and the controlled motor 6 of control system 7 rotates, and stalk is after reduction stage 1 is broken to lower landing, heated pipe 2 Enter compression section 3 after heating, compression section 3 enters 4 final discharger of blanking storehouse after the straw extrusion after heating is molded.

As shown in Fig. 2 it is heretofore described reduction stage schematic diagram.Find out from Fig. 2 or Fig. 1, the reduction stage 1, Including central shaft 1-1, upper strata rotates sawtooth 1-2, fixed sawtooth 1-3, and lower floor rotates sawtooth 1-4；The vertical cloth of central shaft 1-1 Put in the inner hub location of reduction stage 1, central shaft 1-1 lower ends extend vertically through the center of blanking storehouse 4 and are connected with motor 6；On described It is horizontal loops that layer, which rotates sawtooth 1-2 centers, and it is three fan-shaped flakes of the side wall with sawtooth that upper strata, which is rotated on the outside of sawtooth 1-2, fan-shaped Wafer level is evenly distributed on the outside of horizontal loops, and upper strata rotates seamless with central shaft 1-1 outer wall verticals on the inside of sawtooth 1-2 horizontal loops Welding；It is horizontal circular ring on the outside of the fixed sawtooth 1-3, is uniformly to divide along horizontal circular ring center of circle direction on the inside of fixed sawtooth 1-3 Four rectangular tabs of the side wall with sawtooth of cloth, it is vertical seamless to fix horizontal circular ring outer wall and the inwall of reduction stage 1 on the outside of sawtooth 1-3 Welding, the distance that fixed sawtooth 1-3 upper ends rotate sawtooth 1-2 lower ends with upper strata is 5mm~10mm；The lower floor rotates sawtooth 1- 4 centers are horizontal loops, and it is three fan-shaped flakes of the side wall with sawtooth that lower floor, which is rotated on the outside of sawtooth 1-4, fan-shaped flake horizontal homogeneous It is distributed on the outside of horizontal loops, lower floor rotates to be turned on the inside of sawtooth 1-4 horizontal loops with central shaft 1-1 outer wall vertical seamless weldings, lower floor The distance of dynamic sawtooth 1-4 upper ends to fixed sawtooth 1-3 lower ends is 5mm~10mm.

As shown in figure 3, it is heretofore described compression section schematic diagram.Find out from Fig. 3, Fig. 2 or Fig. 1, the compression Section 3, including fixed support plate 3-1, compress spiral 3-2, relief hole 3-3, temperature sensor 3-4；The fixed support plate 3-1 positions In the upper end of compression section 3, fixed support plate 3-1 is socketed centrally through horizontally disposed ball bearing is vertical with central shaft 1-1, fixed It is horizontal circular ring and seamless welding vertical with the inwall of compression section 3 on the outside of support plate 3-1, fixed support plate 3-1 outer annulars are with Heart ball bearing is connected by four horizontally disposed Investigation of Reinforcing Rectangular Steel Beam vertical weldings；The compression spiral 3-2 is arranged vertically at pressure It is the horizontal sheet spiral being rotated down on the outside of compression spiral 3-2, compression spiral 3-2 centers are up-narrow and down-wide inside contracting section 3 Truncated cone-shaped central tube, compression spiral 3-2 central tubes middle part, which is run through, to be fixedly welded on central shaft 1-1 outer walls；The relief hole 3-3 Positioned at the side wall lower ends of compression section 3, relief hole 3-3 is the manhole through the side wall of compression section 3, and relief hole 3-3 quantity is no less than 10；The temperature sensor 3-4 is located in the upper end side wall of compression section 3, temperature sensor 3-4 nothings vertical with the inwall of compression section 3 Seam welding, temperature sensor 3-4 are connected with control system 7 by wire.

It is of the present invention a kind of for the nutrient raw material shaped device of landscape rehabilitation and its course of work of method of work It is：

1st step, stalk enter device from the upper end of reduction stage 1, and the controlled motor 6 of control system 7 rotates, and stalk is in reduction stage 1 Broken backward lower landing, heated pipe 2 enter compression section 3 after heating, compression section 3 enters after the straw extrusion after heating is molded 4 final discharger of blanking storehouse；

2nd step, when the temperature that temperature sensor 3-4 is measured be less than 110 DEG C when, temperature sensor 3-4 sends a signal to control System 7 processed, control system 7 control heating tube to accelerate heat conduction oil flow rate, when the temperature that temperature sensor 3-4 is measured is higher than 130 DEG C When, temperature sensor 3-4 sends a signal to control system 7, and control system 7 controls heating tube to reduce heat conduction oil flow rate.

A kind of nutrient raw material shaped device and its method of work for landscape rehabilitation of the present invention, handle crops Waste straw, environment-friendly high-efficiency, light structure is flexible and convenient to use, and power consumption is low, simple and practical.

It is the embodiment of the manufacturing process in blanking storehouse 4 of the present invention below, embodiment is to further illustrate this hair Bright content, but should not be construed as limiting the invention.Without departing from the spirit and substance of the case in the present invention, to the present invention The modification and replacement that method, step or condition are made, belong to the scope of the present invention.

Unless otherwise specified, the conventional meanses that technological means used in embodiment is well known to those skilled in the art.

Embodiment 1

Blanking storehouse 4 of the present invention is manufactured according to following steps, and is counted in parts by weight：

1st step, 600 parts of the ultra-pure water that electrical conductivity is 1.10 μ S/cm is added in a kettle, start in reactor and stir Device, rotating speed 40rpm, start heat pump, reactor temperature is risen to 55 DEG C；Sequentially add γ-chloroacetyl acetic acid second 8 parts of ester, 8 parts of 3- (to methanesulfonylphenYl) serine ethyl ester, 8 parts of p-Nitrophenyl sulfonyl acetate, stirring to being completely dissolved, It is 4.5 to adjust pH value, agitator speed is adjusted into 90rpm, temperature is 70 DEG C, esterification 2 hours；

2nd step, take 8 parts of 8 parts of acetparaminosalol-methyl o-anisate, 4-tert-Butylphenylacetic acid methyl esters crushing, powder Last particle diameter is 50 mesh；It is well mixed to add 15 parts of nanoscale boric acid rhodium, is laid in pallet, tiling thickness is 5mm, using dosage The alpha ray for being 0.35MeV for 1.2kGy, energy irradiates 10min；

3rd step, the mixed-powder handled through the 2nd step are dissolved in 8 parts of gavaculine ethyl ester, add reactor, stirring Device rotating speed is 90rpm, and temperature is 100 DEG C, and starting vavuum pump makes the vacuum of reactor reach -0.01MPa, keeps this state anti- Answer 2 hours；Pressure release is simultaneously passed through ammonia, and it is 0.01MPa to make reacting kettle inner pressure, and insulation stands 2 hours；Agitator speed carries afterwards Rise to 150rpm, simultaneous reactions kettle pressure release to 0MPa；Sequentially add between 8 parts of m-dibutylamino benzoic acid, N- pi-allyls-N- After aminobenzene methyl -8 parts of t-butyl carbamate is completely dissolved, adds 8 parts of crosslinking agent and be stirred so that reactor solution Hydrophilic lipophilic balance is 6.5, and insulation stands 2 hours；

4th step, when agitator speed is 100rpm, sequentially add and face different 8 parts of toluene hydrogen acid ether (hydrogen acid ester), 5- amino isophthalic diformazans 8 parts of 8 parts of dimethyl phthalate and monochloroacetic acid phenyl ester, reactor pressure is lifted, reach 1.50MPa, temperature is 150 DEG C, polymerization Reaction 2 hours；Reacting kettle inner pressure is down to 0MPa after the completion of reaction, 30 DEG C is cooled to, discharging, enters molding press and can be prepared by Feed bin 4；

Crosslinking agent meta-chlorocarbanilate between the chloro- 2- butynyls-N- of 4-；

The particle diameter of the nanoscale boric acid rhodium is 30nm.

Embodiment 2

Blanking storehouse 4 of the present invention is manufactured according to following steps, and is counted in parts by weight：

1st step, 800 parts of the ultra-pure water that electrical conductivity is 1.40 μ S/cm is added in a kettle, start in reactor and stir Device, rotating speed 60rpm, start heat pump, reactor temperature is risen to 60 DEG C；Sequentially add γ-chloroacetyl acetic acid second 12 parts of ester, 12 parts of 3- (to methanesulfonylphenYl) serine ethyl ester, 12 parts of p-Nitrophenyl sulfonyl acetate, stir to completely molten Solution, regulation pH value are 6.5, agitator speed are adjusted into 100rpm, temperature is 80 DEG C, esterification 6 hours；

2nd step, 12 parts of 12 parts of acetparaminosalol-methyl o-anisate, 4-tert-Butylphenylacetic acid methyl esters crushing are taken, Powder diameter is 80 mesh；It is well mixed to add 30 parts of nanoscale boric acid rhodium, is laid in pallet, tiling thickness is 10mm, is used The alpha ray irradiation 15min that dosage is 3.2kGy, energy is 1.50MeV；

3rd step, the mixed-powder handled through the 2nd step are dissolved in 12 parts of gavaculine ethyl ester, add reactor, stirring Device rotating speed is 100rpm, and temperature is 110 DEG C, and starting vavuum pump makes the vacuum of reactor reach -0.03MPa, keeps this state Reaction 6 hours；Pressure release is simultaneously passed through ammonia, and it is 0.03MPa to make reacting kettle inner pressure, and insulation stands 6 hours；Agitator speed afterwards It is promoted to 160rpm, simultaneous reactions kettle pressure release to 0MPa；Sequentially add 12 parts of m-dibutylamino benzoic acid, N- pi-allyls- After 12 parts of the N- m-aminophenyl Methyl-carbamic acids tert-butyl ester is completely dissolved, adds 12 parts of crosslinking agent and be stirred so that reactor The hydrophilic lipophilic balance of solution is 7.5, and insulation stands 6 hours；

4th step, when agitator speed is 110rpm, sequentially add and face different 12 parts of toluene hydrogen acid ether (hydrogen acid ester), 5- amino isophthalic two 12 parts of 12 parts of formic acid dimethyl ester and monochloroacetic acid phenyl ester, reactor pressure being lifted, reach 3.50MPa, temperature is 160 DEG C, Polymerisation 6 hours；Reacting kettle inner pressure is down to 0MPa after the completion of reaction, is cooled to 33 DEG C, discharging, entering molding press can make Obtain blanking storehouse 4；

Crosslinking agent meta-chlorocarbanilate between the chloro- 2- butynyls-N- of 4-；

The particle diameter of the nanoscale boric acid rhodium is 60nm.

Embodiment 3

Blanking storehouse 4 of the present invention is manufactured according to following steps, and is counted in parts by weight：

1st step, 700 parts of the ultra-pure water that electrical conductivity is 1.20 μ S/cm is added in a kettle, start in reactor and stir Device, rotating speed 50rpm, start heat pump, reactor temperature is risen to 57 DEG C；Sequentially add γ-chloroacetyl acetic acid second 10 parts of ester, 10 parts of 3- (to methanesulfonylphenYl) serine ethyl ester, 10 parts of p-Nitrophenyl sulfonyl acetate, stir to completely molten Solution, regulation pH value are 5.5, agitator speed are adjusted into 95rpm, temperature is 75 DEG C, esterification 4 hours；

2nd step, 10 parts of 10 parts of acetparaminosalol-methyl o-anisate, 4-tert-Butylphenylacetic acid methyl esters crushing are taken, Powder diameter is 60 mesh；It is well mixed to add 20 parts of nanoscale boric acid rhodium, is laid in pallet, tiling thickness is 8mm, using agent Measure the alpha ray for being 0.50MeV for 2.2kGy, energy and irradiate 12min；

3rd step, the mixed-powder handled through the 2nd step are dissolved in 10 parts of gavaculine ethyl ester, add reactor, stirring Device rotating speed is 95rpm, and temperature is 105 DEG C, and starting vavuum pump makes the vacuum of reactor reach -0.02MPa, keeps this state anti- Answer 4 hours；Pressure release is simultaneously passed through ammonia, and it is 0.02MPa to make reacting kettle inner pressure, and insulation stands 4 hours；Agitator speed carries afterwards Rise to 155rpm, simultaneous reactions kettle pressure release to 0MPa；Sequentially add 10 parts of m-dibutylamino benzoic acid, N- pi-allyls-N- After 10 parts of the m-aminophenyl Methyl-carbamic acid tert-butyl ester is completely dissolved, adds 10 parts of crosslinking agent and be stirred so that reactor is molten The hydrophilic lipophilic balance of liquid is 6.9, and insulation stands 4 hours；

4th step, when agitator speed is 105rpm, sequentially add and face different 10 parts of toluene hydrogen acid ether (hydrogen acid ester), 5- amino isophthalic two 10 parts of 10 parts of formic acid dimethyl ester and monochloroacetic acid phenyl ester, reactor pressure being lifted, reach 2.50MPa, temperature is 155 DEG C, Polymerisation 4 hours；Reacting kettle inner pressure is down to 0MPa after the completion of reaction, is cooled to 32 DEG C, discharging, entering molding press can make Obtain blanking storehouse 4；

Crosslinking agent meta-chlorocarbanilate between the chloro- 2- butynyls-N- of 4-；

The particle diameter of the nanoscale boric acid rhodium is 50nm.

Reference examples

Reference examples are the blanking storehouse of certain commercially available brand.

Embodiment 4

Blanking storehouse described in the blanking storehouse 4 that embodiment 1~3 is prepared and reference examples carries out using effect contrast.It is right The two Unit Weight, corrosion resistant erosion degree, material compression strength are counted, as a result as shown in table 1.

As seen from Table 1, the index such as blanking storehouse 4 of the present invention, its Unit Weight, corrosion resistant erosion degree, material compression strength It is superior to the product of prior art production.

In addition, as shown in figure 4, it is the statistics that the material residual intensity of blanking storehouse 4 of the present invention changes with usage time. Find out in figure, blanking storehouse 4 used in embodiment 1~3, its material residual intensity is significantly better than existing production with usage time intensity of variation Product.

Claims (2)

1. a kind of nutrient raw material shaped device for landscape rehabilitation, including reduction stage（1）, heating tube（2）, compression section（3）, fall Feed bin（4）, supporting leg（5）, motor（6）, control system（7）；It is characterized in that：The blanking storehouse（4）Bottom centre is provided with electricity Machine（6）, blanking storehouse（4）Bottom is surrounded by supporting leg（5）, blanking storehouse（4）Front side sidewall is provided with control system（7）, blanking storehouse （4）Top is provided with compression section（3）；The compression section（3）Top is heating tube（2）；The heating tube（2）Top is reduction stage （1）, the heating tube（2）For helical structure made of stainless steel tube；

The reduction stage（1）, including central shaft（1-1）, upper strata rotates sawtooth（1-2）, fixed sawtooth（1-3）, lower floor, which rotates, saws Tooth（1-4）；Wherein described central shaft（1-1）It is arranged vertically at reduction stage（1）Inner hub location, central shaft（1-1）Hang down lower end Directly run through blanking storehouse（4）Center and and motor（6）It is connected；The upper strata rotates sawtooth（1-2）Center is horizontal loops, and upper strata rotates Sawtooth（1-2）Outside is three fan-shaped flakes of the side wall with sawtooth, and fan-shaped flake horizontal homogeneous is distributed on the outside of horizontal loops, upper strata Rotate sawtooth（1-2）Horizontal loops inner side and central shaft（1-1）Outer wall vertical seamless welding；The fixed sawtooth（1-3）Outside is Horizontal circular ring, fixed sawtooth（1-3）Inner side is along equally distributed rectangle of four side walls with sawtooth in horizontal circular ring center of circle direction Thin slice, fixed sawtooth（1-3）Outside horizontal circular ring outer wall and reduction stage（1）The vertical seamless welding of inwall, fixed sawtooth（1-3）On End rotates sawtooth with upper strata（1-2）The distance of lower end is 5mm~10mm；The lower floor rotates sawtooth（1-4）Center is horizontal loops, Lower floor rotates sawtooth（1-4）Outside is three fan-shaped flakes of the side wall with sawtooth, and fan-shaped flake horizontal homogeneous is distributed in horizontal loops Outside, lower floor rotate sawtooth（1-4）Horizontal loops inner side and central shaft（1-1）Outer wall vertical seamless welding, lower floor rotate sawtooth（1- 4）Upper end is to fixed sawtooth（1-3）The distance of lower end is 5mm~10mm；

The compression section（3）, including：Fixed support plate（3-1）, compress spiral（3-2）, relief hole（3-3）, temperature sensor （3-4）；Wherein described fixed support plate（3-1）Positioned at compression section（3）Upper end, fixed support plate（3-1）Centrally through horizontal cloth The ball bearing and central shaft put（1-1）Vertical socket, fixed support plate（3-1）Outside is horizontal circular ring and and compression section（3） The vertical seamless welding of inwall, fixed support plate（3-1）Outer annular and center ball bearing pass through four horizontally disposed rectangles Girder steel vertical welding is connected；The compression spiral（3-2）It is arranged vertically at compression section（3）Inside, compress spiral（3-2）Outside is The sheet spiral that level is rotated down, compress spiral（3-2）Center is up-narrow and down-wide truncated cone-shaped central tube, compresses spiral（3- 2）Run through in the middle part of central tube and be fixedly welded on central shaft（1-1）On outer wall；The relief hole（3-3）Positioned at compression section（3）Side wall Lower end, relief hole（3-3）For through compression section（3）The manhole of side wall, relief hole（3-3）Quantity is no less than 10；It is described Temperature sensor（3-4）Positioned at compression section（3）In the side wall of upper end, temperature sensor（3-4）With compression section（3）Inwall is vertically seamless Welding, temperature sensor（3-4）With control system（7）Connected by wire.

A kind of 2. nutrient raw material shaped device for landscape rehabilitation according to claim 1, it is characterised in that：It is described fall Feed bin（4）It is molded by high polymer material pressing mold, blanking storehouse（4）Constituent and manufacturing process in parts by weight is as follows：

1st step, 600~800 parts of the ultra-pure water that electrical conductivity is the μ S/cm of 1.10 μ S/cm~1.40 is added in a kettle, start anti- Agitator in kettle is answered, rotating speed is 40rpm~60rpm, starts heat pump, reactor temperature is risen to 55 DEG C~60 DEG C；According to Secondary 8~12 parts of γ-chloro ethyl acetoacetate of addition, 8~12 parts of 3- (to methanesulfonylphenYl) serine ethyl ester, p-nitrophenyl 8~12 parts of sulfonyl acetic acid ester, to being completely dissolved, regulation pH value is 4.5~6.5 for stirring, by agitator speed be adjusted to 90rpm~ 100rpm, temperature are 70 DEG C~80 DEG C, esterification 2~6 hours；

2nd step, take 8~12 parts of 8~12 parts of acetparaminosalol-methyl o-anisate, 4-tert-Butylphenylacetic acid methyl esters powder Broken, powder diameter is 50~80 mesh；It is well mixed to add 15~30 parts of nanoscale boric acid rhodium, is laid in pallet, tile thickness For 5mm~10mm, the alpha ray that uses dosage to be 0.35MeV~1.50MeV for 1.2kGy~3.2kGy, energy irradiate 10min~ 15min；

3rd step, the mixed-powder handled through the 2nd step are dissolved in 8~12 parts of gavaculine ethyl ester, add reactor, stirring Device rotating speed is 90rpm~100rpm, and temperature is 100 DEG C~110 DEG C, start vavuum pump make the vacuum of reactor reach- 0.01MPa~-0.03MPa, keeps this state response 2~6 hours；Pressure release is simultaneously passed through ammonia, makes the reacting kettle inner pressure be 0.01MPa~0.03MPa, insulation stand 2~6 hours；Agitator speed is promoted to 150rpm~160rpm, simultaneous reactions afterwards Kettle pressure release is to 0MPa；Sequentially add 8~12 parts of m-dibutylamino benzoic acid, N- pi-allyl-N- m-aminophenyl Methyl-aminos After 8~12 parts of t-butyl formate is completely dissolved, adds 8~12 parts of crosslinking agent and be stirred so that the hydrophilic parent of reactor solution Oily equilibrium valve is 6.5~7.5, and insulation stands 2~6 hours；

4th step, when agitator speed is 100rpm~110rpm, sequentially add and face different 8~12 parts of toluene hydrogen acid ether (hydrogen acid ester), 5- amino 8~12 parts of 8~12 parts of DMIP and monochloroacetic acid phenyl ester, lift reactor pressure, reach 1.50MPa~ 3.50MPa, temperature are 150 DEG C~160 DEG C, polymerisation 2~6 hours；Reacting kettle inner pressure is down to 0MPa after the completion of reaction, 30 DEG C~33 DEG C are cooled to, discharging, enters molding press and can be prepared by blanking storehouse（4）；

Crosslinking agent meta-chlorocarbanilate between the chloro- 2- butynyls-N- of 4-；

The particle diameter of the nanoscale boric acid rhodium is 30nm~60nm.