CN106024233A - Crystal magnetic material and preparation method and application thereof - Google Patents

Crystal magnetic material and preparation method and application thereof Download PDF

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Publication number
CN106024233A
CN106024233A CN201610015583.4A CN201610015583A CN106024233A CN 106024233 A CN106024233 A CN 106024233A CN 201610015583 A CN201610015583 A CN 201610015583A CN 106024233 A CN106024233 A CN 106024233A
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China
Prior art keywords
parts
stone
magnetic material
crystal magnetic
fibre
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Pending
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CN201610015583.4A
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Chinese (zh)
Inventor
翁桂华
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Shanghai Business Network Technology Co Ltd
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Shanghai Business Network Technology Co Ltd
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Priority to CN201610015583.4A priority Critical patent/CN106024233A/en
Publication of CN106024233A publication Critical patent/CN106024233A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/04Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
    • D01F6/06Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Artificial Filaments (AREA)

Abstract

The invention discloses a crystal magnetic material and a preparation method and applications thereof. The raw materials of the crystal magnetic material comprise components in the following parts by weight: 20-30 parts of medical stones, 10-20 parts of agate stones, 15-25 parts of tourmaline stones, 3-5 parts of muyu stones, 5-10 parts of stone needle, 5-8 parts of kallaite, 1-5 parts of graystones, 1-5 parts of too stones, 5-10 parts of sugilite, 1-2 parts of rhodochrosite, 2-8 parts of amber, 10-20 parts of pearls, and 10-20 parts of coral. Fibers containing the crystal magnetic material are high in strength, and a cloth can be used for bedding articles, clothing and shoes and other products, and use or wearing is comfortable and beautiful. The crystal magnetic material has high energy and can promote blood circulation, and has life cultivation and health preservation functions, and market prospect is good.

Description

A kind of crystal magnetic material and its preparation method and application
Technical field
The present invention relates to field of textiles, be specifically related to a kind of crystal magnetic material and its preparation method and application.
Background technology
Along with the development of magnetic therapy technology Yu sanitary health career, the clothes decoration with magnetic therapy functions has been subject to To the attention of society, on market, various magnetic therapy articles for use go on the family of the people common people mutually, and magnetic textile is particularly subject to To welcoming.Japan, Britain the most once did the report about magnetic fibre, and had certain magnetic field by this kind of The magnetic fibre woven into fabric of intensity, makes clothing, the most comfortable and easy to wear, and have antiinflammatory, detumescence, Blood pressure lowering, improving the effectiveness such as blood viscosity and microcirculation. magnetic fibre is a kind of new functional fiber material, It can be divided into magnetic textile fabric and non-textile fiber.Magnetic textile fabric is that one has textile fabric concurrently Characteristic and the material of magnetic.
The method that preparation magnetic textile fabric mainly uses co-blended spinning at present, is generally less than particle diameter The magnetic material microgranule of 1 μm is mixed in melt or the spinning solution of fibre-forming polymer, through melt-spun or wet spinning system Become magnetic fibre.The intensity of gained magnetic fibre depends primarily on amount and the particle diameter adding magnetic particle.
But currently used magnetic material only has Fe3O4, ferrum, cobalt, nickel etc. the most several, greatly Constrain the development of magnetic textile fabric.
Summary of the invention
The technical problem to be solved can use to overcome current magnetic textile fabric The shortcoming of magnetic material limitednumber, and provide a kind of crystal magnetic material and its preparation method and application. Containing the fibre strength height of the crystal magnetic material that the present invention provides, cloth can be used for bedding, clothing The products such as shoes and hats, use or comfortable and easy to wear, attractive in appearance and possess high-energy, can blood circulation promoting, There is health-caring function, good market prospects.
The invention provides a kind of crystal magnetic material, its raw material includes the component of following portions by weight: wheat Meal stone 20~30 parts, Agate 10~20 parts, tourmaline stone 15~25 parts, Muyu-Stone 3~5 parts, stone needle 5~10 parts, turquoise 5~8 parts, Black Warrior stone 1~5 parts, great void stone 1~5 parts, relax all come 5~10 parts, Manganese spar 1~2 parts, succinum 2~8 parts, Margarita 10~20 parts and Corallium Japonicum Kishinouye 10~20 parts.
In the present invention, described Maifanitum is the Maifanitum that this area is conventionally referred, its main chemical compositions The most inorganic aluminosilicate;It generally comprises SiO2、Al2O3、Fe2O3、FeO、MgO、CaO、 K2O、Na2O、TiO2、P2O5And MnO.
In the present invention, described Agate is the Agate that this area is conventionally referred, generally refers to have stricture of vagina The calcedony of band structure, mainly includes silicon dioxide.
In the present invention, described tourmaline stone is the tourmaline stone that this area is conventionally referred, is also called electrically Stone, generally borosilicate crystalline solid, and aluminum, ferrum, magnesium, sodium, lithium and potassium element can be comprised.
In the present invention, described Muyu-Stone is the Muyu-Stone that this area is conventionally referred, and its mineral composition is general For limonite, Fe2O3Content from 20% to 78%, also comprise phosphate, metasilicate and Strontium, molybdenum, lithium, zinc and selenium element.
In the present invention, described stone needle is the stone needle that this area is conventionally referred, and its main component is generally carbon Acid calcium, other compositions include calcium oxide, silicon oxide, sodium oxide and aluminum, ferrum, strontium, magnesium, phosphorus, chromium, Manganese, nickel, copper and yttrium.
In the present invention, described turquoise is the turquoise described in the routine of this area, generally comprises copper and aluminum Phosphate mineral aggregation, its Theoretical molecular formula is CuAl6(PO4)4(OH)8·5H2O。
In the present invention, described basalt is the basalt described in the routine of this area, and its Main Ingredients and Appearance is general Including silicon dioxide, aluminium sesquioxide, ferrum oxide, calcium oxide, magnesium oxide, potassium oxide and sodium oxide.
In the present invention, described great void stone is the great void stone described in the routine of this area.
In the present invention, described relaxing all comes and all carrys out stone for relaxing described in the routine of this area, is also called ferrosilicon lithium Sodium stone, sugilite, Su Jishi, its Main Ingredients and Appearance generally comprise silicon oxide and potassium, sodium, ferrum and Elemental lithium.
In the present invention, described manganese spar is the carbonic acid of the manganese spar described in the routine of this area, generally manganese Salt mineral, composition is MnCO3, also comprise ferrum, calcium and zinc element.
In the present invention, described succinum is the succinum described in the routine of this area, and its chemical molecular formula is generally C10H16O, additionally comprises hydrogen sulfide and aluminum, magnesium, calcium and element silicon.
In the present invention, described Margarita is the Margarita that this area is conventionally referred, and its inorganic constituents includes carbonic acid Calcium, magnesium carbonate, silicon oxide, calcium phosphate, Al2O3And Fe2O3;Its organic principle includes aminoacid, cattle Sulfonic acid, vitamin and peptides.
In the present invention, described Corallium Japonicum Kishinouye is the Corallium Japonicum Kishinouye described in the routine of this area, and it mainly includes CaCO3, Exist with crystallite calcite aggregated form.
Present invention also offers the preparation method of above-mentioned crystal magnetic material, by described raw material mixed grinding, ?.
Wherein, the method for described grinding and condition can refer to the grinding that this area routine uses method and Condition;Described grinding preferably uses grinder to carry out.
Present invention also offers the application in preparing magnetic fibre of the above-mentioned crystal magnetic material.
Wherein, the described method preparing magnetic fibre can be commonly used in the art to prepare magnetic fibre Method, preferably blending method, generally described crystal magnetic material is mixed into the molten of fibre-forming polymer In body or spinning solution, make magnetic fibre through melt-spun or wet spinning.
On the basis of meeting common sense in the field, above-mentioned each optimum condition, can combination in any, i.e. get Ben Fa Bright each preferred embodiments.
Agents useful for same of the present invention and raw material are the most commercially.
The crystal magnetic material that the present invention provides is made up of multiple high energy body, coordinates the efficient bio-active factor, The high-energy health material being composited is magnetized through high and new technology means.There is powerful energy field, magnetic And extremely strong penetrating power, use core process technology, by crystal magnetic material at the production ring of fiber Joint is mixed into viscose glue, processes magnetic material cloth, and then produce various functional home textile articles for use and clothes making Product.
The most progressive effect of the present invention is: the invention provides a kind of new applicable preparation magnetic weaving The crystal magnetic material of fiber, containing the fibre strength height of the crystal magnetic material that the present invention provides, cloth Material can be used for the product such as bedding, clothes, shoes and hats, uses or comfortable and easy to wear, attractive in appearance and possess height Energy, can blood circulation promoting, there is health-caring function, good market prospects.
Detailed description of the invention
Further illustrate the present invention below by the mode of embodiment, but the most therefore limit the present invention to Among described scope of embodiments.The experimental technique of unreceipted actual conditions in the following example, according to often Rule method and condition, or select according to catalogue.
The main component of the raw material used in embodiments of the invention is as follows:
Maifanitum: main chemical compositions is inorganic aluminosilicate;Including SiO2、Al2O3、Fe2O3、 FeO、MgO、CaO、K2O、Na2O、TiO2、P2O5And MnO.
Agate: be mainly composed of silicon dioxide.
Tourmaline stone: for borosilicate crystalline solid, and comprise aluminum, ferrum, magnesium, sodium, lithium and potassium element.
Muyu-Stone: mineral composition is limonite, Fe2O3Content be 78%, also comprise phosphate, partially Silicate and strontium, molybdenum, lithium, zinc and selenium element.
Stone needle: it is mainly composed of calcium carbonate, other compositions include calcium oxide, silicon oxide, sodium oxide with And aluminum, strontium, ferrum, magnesium, phosphorus, chromium, manganese, nickel, copper and yttrium.
Turquoise: be mainly composed of the phosphate mineral aggregation of copper and aluminum.
Basalt: its Main Ingredients and Appearance includes silicon dioxide, aluminium sesquioxide, ferrum oxide, calcium oxide, oxygen Change magnesium, potassium oxide and sodium oxide.
Relax and all come: Main Ingredients and Appearance includes silicon oxide and potassium, sodium, ferrum and elemental lithium.
Manganese spar: for the carbonate mineral of manganese, composition is MnCO3, also comprise ferrum, calcium and zinc element.
Succinum: its chemical molecular formula is C10H16O, additionally comprise hydrogen sulfide and aluminum, magnesium, calcium and Element silicon.
Margarita: its inorganic constituents includes calcium carbonate, magnesium carbonate, silicon oxide, calcium phosphate, Al2O3And Fe2O3; Its organic principle includes aminoacid, taurine, vitamin and peptides.
Corallium Japonicum Kishinouye: its Main Ingredients and Appearance includes CaCO3, exist with crystallite calcite aggregated form.
Embodiment 1
A kind of crystal magnetic material, its raw material includes the component of following portions by weight: Maifanitum 20 parts, Agate 10 parts, 25 parts of tourmaline stone, Muyu-Stone 5 parts, stone needle 10 parts, turquoise 5 parts, profound Military 1 part of stone, 1 part of great void stone, relax all come 10 parts, manganese spar 2 parts, succinum 2 parts, Margarita 20 parts With 20 parts of Corallium Japonicum Kishinouye.
Use grinder to grind after being mixed by above-mentioned raw materials, collect the raw material powder after grinding.
Embodiment 2
A kind of crystal magnetic material, its raw material includes the component of following portions by weight: Maifanitum 30 parts, Agate 20 parts, 15 parts of tourmaline stone, Muyu-Stone 3 parts, stone needle 5 parts, turquoise 8 parts, the Black Warrior 5 parts of stone, 5 parts of great void stone, relax all come 5 parts, manganese spar 1 part, succinum 8 parts, Margarita 10 parts and 10 parts of Corallium Japonicum Kishinouye.
Use grinder to grind after being mixed by above-mentioned raw materials, collect the raw material powder after grinding.
Embodiment 3
A kind of crystal magnetic material, its raw material includes the component of following portions by weight: Maifanitum 25 parts, Agate 15 parts, 20 parts of tourmaline stone, Muyu-Stone 4 parts, stone needle 8 parts, turquoise 7 parts, the Black Warrior 3 parts of stone, 4 parts of great void stone, relax all come 7 parts, manganese spar 1 part, succinum 5 parts, Margarita 15 parts and 15 parts of Corallium Japonicum Kishinouye.
Use grinder to grind after being mixed by above-mentioned raw materials, collect the raw material powder after grinding.
Embodiment 4
The raw material powder obtained in embodiment 1 is added in melt polypropylene, is sufficiently mixed, wherein, raw material The mass ratio of powder and melt polypropylene is 1:4, is woven into magnetic fibre through spinning-drawing machine.
The magnetic fibre obtained has higher intensity and bigger and stable magnetic field.
Embodiment 5
The raw material powder obtained in embodiment 2 is added in melt polypropylene, is sufficiently mixed, wherein, raw material The mass ratio of powder and melt polypropylene is 1:1, is woven into magnetic fibre through spinning-drawing machine.
The magnetic fibre obtained has higher intensity and bigger and stable magnetic field.
Embodiment 6
The raw material powder obtained in embodiment 3 is added in melt polypropylene, is sufficiently mixed, wherein, raw material The mass ratio of powder and melt polypropylene is 1:9, is woven into magnetic fibre through spinning-drawing machine.
The magnetic fibre obtained has higher intensity and bigger and stable magnetic field.

Claims (7)

1. a crystal magnetic material, it is characterised in that its raw material includes the component of following portions by weight: Maifanitum 20~30 parts, Agate 10~20 parts, tourmaline stone 15~25 parts, Muyu-Stone 3~5 parts, stone acupuncture needle Stone 5~10 parts, turquoise 5~8 parts, Black Warrior stone 1~5 parts, great void stone 1~5 parts, relaxing all comes 5~10 Part, manganese spar 1~2 parts, succinum 2~8 parts, Margarita 10~20 parts and Corallium Japonicum Kishinouye 10~20 parts.
2. the preparation method of crystal magnetic material as claimed in claim 1, it is characterised in that by described Raw material mixed grinding,.
3. preparation method as claimed in claim 2, it is characterised in that described grinding uses grinds Machine is carried out.
4. crystal magnetic material application in preparing magnetic fibre as claimed in claim 1.
Apply the most as claimed in claim 4, it is characterised in that the described method preparing magnetic fibre For blending method.
Apply the most as claimed in claim 5, it is characterised in that described blending method is by described Crystal magnetic material is mixed in melt or the spinning solution of fibre-forming polymer, makes magnetic through melt-spun or wet spinning Fiber.
Apply the most as claimed in claim 6, it is characterised in that described crystal magnetic material and institute The melt of the fibre-forming polymer stated or the mass ratio of spinning solution are 1:1~1:9.
CN201610015583.4A 2016-01-11 2016-01-11 Crystal magnetic material and preparation method and application thereof Pending CN106024233A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108385192A (en) * 2018-02-24 2018-08-10 中科纺织研究院(青岛)有限公司 A kind of stone needle nylon fibre
CN111714382A (en) * 2019-09-16 2020-09-29 上海茂奎电子商务有限公司 Magnetic crystal composition, preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101058942A (en) * 2007-06-08 2007-10-24 武汉大学 Method of preparing magnetic nano composite fibre
CN102400238A (en) * 2011-09-01 2012-04-04 丁一 Element-negative-ion-releasing sterilizing mite-preventing electromagnetic-wave-preventing fire-retarding nano-grade fabric used in vehicles
CN104847064A (en) * 2015-04-28 2015-08-19 福建省南安市荣达建材有限公司 Health-care ceramic tile and manufacturing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101058942A (en) * 2007-06-08 2007-10-24 武汉大学 Method of preparing magnetic nano composite fibre
CN102400238A (en) * 2011-09-01 2012-04-04 丁一 Element-negative-ion-releasing sterilizing mite-preventing electromagnetic-wave-preventing fire-retarding nano-grade fabric used in vehicles
CN104847064A (en) * 2015-04-28 2015-08-19 福建省南安市荣达建材有限公司 Health-care ceramic tile and manufacturing method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108385192A (en) * 2018-02-24 2018-08-10 中科纺织研究院(青岛)有限公司 A kind of stone needle nylon fibre
CN111714382A (en) * 2019-09-16 2020-09-29 上海茂奎电子商务有限公司 Magnetic crystal composition, preparation method and application thereof

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