CN104499157A - Anti-bacterial fabric - Google Patents

Anti-bacterial fabric Download PDF

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Publication number
CN104499157A
CN104499157A CN201410801223.8A CN201410801223A CN104499157A CN 104499157 A CN104499157 A CN 104499157A CN 201410801223 A CN201410801223 A CN 201410801223A CN 104499157 A CN104499157 A CN 104499157A
Authority
CN
China
Prior art keywords
bamboo
nano
antibacterial
warp thread
charcoal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410801223.8A
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Chinese (zh)
Inventor
黄征神
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHANGSHU OUMEMGNA HOME TEXTILE Co Ltd
Original Assignee
CHANGSHU OUMEMGNA HOME TEXTILE Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHANGSHU OUMEMGNA HOME TEXTILE Co Ltd filed Critical CHANGSHU OUMEMGNA HOME TEXTILE Co Ltd
Priority to CN201410801223.8A priority Critical patent/CN104499157A/en
Publication of CN104499157A publication Critical patent/CN104499157A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D13/00Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
    • D03D13/008Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft characterised by weave density or surface weight
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/56Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads elastic
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Artificial Filaments (AREA)

Abstract

The invention discloses an anti-bacterial fabric. The anti-bacterial fabric is crosswise woven by use of warp yarns, weft yarns and wool yarns; at least one of the warp yarns, the weft yarns and the wool yarns is made of nano-antibacterial bamboo carbon fibers; the nano-antibacterial bamboo carbon fibers contain 0.0005-0.0020% of nano silver microparticles, 7-19% of bamboo carbon microparticles and the balance of viscose in percentage by mass. The anti-bacterial fabric is capable of overcoming the shortcomings of the prior art, and has the advantages of excellent wearability, good manufacturing property, outstanding anti-bacterial effect and the like.

Description

A kind of antibiotic facing material
Technical field
The present invention relates to field of textile, particularly relate to a kind of antibiotic facing material.
Background technology
Along with the raising of people's living standard, the requirement of people to clothes is more and more higher, the pursuit of consumer from is warming comfortable to emphasis, attractive in appearance, future development such as grade good for health, function textile also arises at the historic moment, as far back as the World War I time, people have just started the research to antibacterial fabric, to the modern times, the atypical pneumonia that at the beginning of the enteron aisle acute disease and 2003 that Japan in 1996 is caused by 0-157 pathogenic Escherichia coli in the whole country, China causes due to SARS virus, having to, they all cause huge injury to the healthy of the mankind, and people therefrom have also been obtained inspiration: because of concerning natural microorganism, the skin of the mankind is a kind of well nutrition supply persons, some resident bacterium on people's skin play a part protection skin and endanger from pathogenic bacteria, once the flora imbalance in microorganism, a small amount of pathogenic bacteria in them will amount reproduction, and pass through skin, respiratory tract, alimentary canal and genital tract mucosa work the mischief to human body.Antibacterial fabric, as a possible prevention and the product cutting off disease propagation source, will play vital effect in people's disease prevention and cure.
The exploitation method mainly of current antibacterial fabric is direct anti-bacterial fibre and carries out arrangement processing to antibiotic fabric.Carrying out anti-bacterial finish to fabric is by resin or be fixed on the fiber surface of fabric by suction-operated antiseptic, antibacterial action great majority are because antiseptic is formed from fiber surface stripping, some antiseptic can be combined with the functional group of fiber surface by chemical action, but its antibiotic property is also only present in the top layer of fiber, when after surface fibre comes off its come off after its antibiotic property can not supplement, so its antibacterial persistence is poor.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of antibiotic facing material, can overcome the deficiencies in the prior art, and described antibiotic facing material has the advantages such as wearability is excellent, textile process performance is good, antibacterial effect is outstanding.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is:
A kind of antibiotic facing material is provided, be made up of warp thread, weft yarn and wool yarn interlacing, having at least a kind of in described warp thread, weft yarn and wool yarn is nano-antibacterial bamboo-carbon fibre, it is the Silver nanoparticles of 0.005 ~ 0.020 ‰ and the bamboo-charcoal particles of 7 ~ 18% that described anti-bacterial bamboo charcoal nano-fiber contains mass fraction, and surplus is viscose.
In a preferred embodiment of the present invention, the particle diameter of the described nano-Ag particles in described anti-bacterial bamboo charcoal nano-fiber is less than 50nm, and the particle diameter of described bamboo-charcoal particles is less than 1 μm.
In a preferred embodiment of the present invention, be made up of warp thread, weft yarn and wool yarn interlacing, described warp thread is 75D/36F low elastic polyester filament, and weft yarn is 100D/46F low elastic polyester filament, and described wool yarn is nano-antibacterial bamboo-carbon fibre.
In a preferred embodiment of the present invention, the density of warp thread is 38 pieces/centimetre, and the density of weft yarn is 40 pieces/centimetre.
The invention has the beneficial effects as follows: a kind of antibiotic facing material of the present invention, nano-antibacterial bamboo-carbon fibre is included in described antibiotic facing material, containing mass fraction in described nano-antibacterial bamboo-carbon fibre is the Silver nanoparticles of 0.005 ~ 0.020 ‰ and the bamboo-charcoal particles of 7 ~ 18%, surplus is viscose, this kind of anti-bacterial fibre has lasting antibacterial effect, and has higher security.
Accompanying drawing explanation
Fig. 1 is the structural representation of a kind of antibiotic facing material of the present invention;
Fig. 2 is the sectional view along A-A direction in Fig. 1;
Wherein: 1, warp thread; 2, weft yarn; 3, wool yarn.
Detailed description of the invention
Below preferred embodiment of the present invention is described in detail, can be easier to make advantages and features of the invention be readily appreciated by one skilled in the art, thus more explicit defining is made to protection scope of the present invention.
Embodiment 1 prepares the nano-antibacterial bamboo-carbon fibre that fiber number is 1.58dtex:
1) preparation of bamboo-charcoal particles:
The bamboo wood of predry is put into retort, be heated to 450 DEG C ~ 500 DEG C and carry out carbonization reaction, then be heated to 1200 DEG C, maintain this temperature and calcining is carried out to the bamboo wood after carbonization reaction obtain bamboo charcoal, grind to form nano level bamboo-charcoal particles after cooling, the particle diameter of bamboo-charcoal particles is less than 1 μm;
2) preparation of cellulose rayon spinning liquid:
Take cellulose pulp as raw material, through dipping, squeezing, pulverize, experienced, yellow and dissolving step obtain cellulose rayon spinning liquid;
3) preparation of the blended viscose glue of nano-antibacterial bamboo charcoal:
The bamboo-charcoal particles obtained by step 1) and Silver nanoparticles join in alkaline solution, the particle diameter of the Nano Silver herein selected is less than 50nm, stir 30min at normal temperatures, then add stabilizing agent wherein, stir 30 minutes under rotating speed 50 turns/min, form preformed solution, the quality of described Silver nanoparticles is 0.008% of added bamboo-charcoal particles quality, the quality of described stabilizing agent is 0.05% of added bamboo-charcoal particles gross mass, and stabilizing agent is good with polyethylene glycol herein; By spinning front injecting systems, preformed solution is accounted for the ratio of 15% of finished fiber weight according to bamboo-charcoal particles wherein, join in blender by measuring pump, cellulose rayon spinning liquid joins in blender by viscose glue flowmeter simultaneously, is prepared into the blended viscose glue of nano-antibacterial bamboo charcoal after mixing;
4) spinning and post processing:
The blended viscose glue of nano-antibacterial bamboo charcoal prepared is introduced coagulating bath spinning moulding after filtering, under the condition of temperature 60 ± 2 DEG C, nano-antibacterial bamboo-carbon fibre is obtained through strand drawing-off and post-processing step, coagulating bath comprises following composition: sulfuric acid 80g/l, zinc sulfate 7.9g/l, sodium sulphate 346.8g/l, and the flow process of strand drawing-off is: drawing-off between shower nozzle drawing-off → dish → plasticizing-bath drawing-off; The process conditions of strand drawing-off are: shower nozzle drawing-off 20%, drawing-off 30% between dish, plasticizing-bath drawing-off 16%; Described post-processing step is refining, oven dry, cut-out, obtained finished product, and what refining adopted is endless tow refining, and what cut off employing is that dry method is cut off.
The fiber number of nano-antibacterial bamboo-carbon fibre obtained is thus 1.58dtex, and dry strength is 2.50 cN/dtex, and wet strength is 1.35cN/dtex, and percentage elongation is 18.8%, and residual sulfur content is 3.8mg/100g.
Embodiment 2 prepares the nano-antibacterial bamboo-carbon fibre that fiber number is 1.64dtex:
1) preparation of bamboo-charcoal particles:
The bamboo wood of predry is put into retort, be heated to 450 DEG C and carry out carbonization reaction, then be heated to 1200 DEG C, maintain this temperature and calcining is carried out to the bamboo wood after carbonization reaction obtain bamboo charcoal, grind to form nano level bamboo-charcoal particles after cooling, the particle diameter of bamboo-charcoal particles is less than 1 μm;
2) preparation of cellulose rayon spinning liquid:
Take cellulose pulp as raw material, through dipping, squeezing, pulverize, experienced, yellow and dissolving step obtain cellulose rayon spinning liquid;
3) preparation of the blended viscose glue of nano-antibacterial bamboo charcoal:
The bamboo-charcoal particles obtained by step 1) and Silver nanoparticles join in alkaline solution, the particle diameter of the Nano Silver herein selected is less than 50nm, stir 30min at normal temperatures, then add stabilizing agent wherein, stir 40 minutes under rotating speed 60 turns/min, form preformed solution, the quality of described Silver nanoparticles is 0.01% of added bamboo-charcoal particles quality, the quality of described stabilizing agent is 0.08% of added bamboo-charcoal particles gross mass, and stabilizing agent is good with polyethylene glycol herein; By spinning front injecting systems, preformed solution is accounted for the ratio of 12% of finished fiber weight according to bamboo-charcoal particles wherein, join in blender by measuring pump, cellulose rayon spinning liquid joins in blender by viscose glue flowmeter simultaneously, is prepared into the blended viscose glue of nano-antibacterial bamboo charcoal after mixing;
4) spinning and post processing:
The blended viscose glue of nano-antibacterial bamboo charcoal prepared is introduced coagulating bath spinning moulding after filtering, under the condition of temperature 60 ± 2 DEG C, nano-antibacterial bamboo-carbon fibre is obtained through strand drawing-off and post-processing step, coagulating bath comprises following composition: sulfuric acid 80g/l, zinc sulfate 7.9g/l, sodium sulphate 346.8g/l, and the flow process of strand drawing-off is: drawing-off between shower nozzle drawing-off → dish → plasticizing-bath drawing-off; The process conditions of strand drawing-off are: shower nozzle drawing-off 15%, drawing-off 35% between dish, plasticizing-bath drawing-off 15%; Described post-processing step is refining, oven dry, cut-out, obtained finished product, and what refining adopted is endless tow refining, and what cut off employing is that dry method is cut off.
The fiber number of nano-antibacterial bamboo-carbon fibre obtained is thus 1.64dtex, and dry strength is 2.20 cN/dtex, and wet strength is 1.13cN/dtex, and percentage elongation is 16.5%, and residual sulfur content is 3.0mg/100g.
Illustrated antibiotic facing material, can be that nano-antibacterial bamboo-carbon fibre can be made with low elastic polyester filament Co-knit, this antibiotic facing material is made up of warp thread 1, weft yarn 2 and wool yarn 3 interlacing, warp thread 1 is 75D/36F low elastic polyester filament, weft yarn 2 is 100D/46F low elastic polyester filaments, wool yarn 3 is the nano-antibacterial bamboo-carbon fibre shown in any embodiment of the present invention, and the density of warp thread 1 is 38 pieces/centimetre, and the density of weft yarn 2 is 40 pieces/centimetre.The fabric made has long-acting antibacterial action, and has higher security, and this fabric is economical and practical, comfortable and easy to wear.Certainly, also can be that at least one fiber in warp thread, weft yarn or wool yarn is nano-antibacterial bamboo-carbon fibre, specifically require depending on product purpose.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every utilize description of the present invention to do equivalent structure or equivalent flow process conversion; or be directly or indirectly used in other relevant technical fields, be all in like manner included in scope of patent protection of the present invention.

Claims (4)

1. an antibiotic facing material, it is characterized in that, be made up of warp thread, weft yarn and wool yarn interlacing, having at least a kind of in described warp thread, weft yarn and wool yarn is nano-antibacterial bamboo-carbon fibre, it is the Silver nanoparticles of 0.005 ~ 0.020 ‰ and the bamboo-charcoal particles of 7 ~ 18% that described anti-bacterial bamboo charcoal nano-fiber contains mass fraction, and surplus is viscose.
2. antibiotic facing material according to claim 1, is characterized in that, the particle diameter of the described nano-Ag particles in described anti-bacterial bamboo charcoal nano-fiber is less than 50nm, and the particle diameter of described bamboo-charcoal particles is less than 1 μm.
3. antibiotic facing material according to claim 1, is characterized in that, is to be made up of warp thread, weft yarn and wool yarn interlacing, and described warp thread is 75D/36F low elastic polyester filament, and weft yarn is 100D/46F low elastic polyester filament, and described wool yarn is nano-antibacterial bamboo-carbon fibre.
4. antibiotic facing material according to claim 3, is characterized in that, the density of warp thread is 38 pieces/centimetre, and the density of weft yarn is 40 pieces/centimetre.
CN201410801223.8A 2014-12-22 2014-12-22 Anti-bacterial fabric Pending CN104499157A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410801223.8A CN104499157A (en) 2014-12-22 2014-12-22 Anti-bacterial fabric

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410801223.8A CN104499157A (en) 2014-12-22 2014-12-22 Anti-bacterial fabric

Publications (1)

Publication Number Publication Date
CN104499157A true CN104499157A (en) 2015-04-08

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104928826A (en) * 2015-06-01 2015-09-23 句容市申兔工艺针织厂 Anti-radiation antibacterial deodorizing fabric and preparation method thereof
CN105926137A (en) * 2016-07-14 2016-09-07 南通中兴多元复合钢管有限公司 Antibacterial health care fabric
CN108251943A (en) * 2018-01-09 2018-07-06 嘉兴涌锦服饰有限公司 A kind of preparation method of antibacterial blended yarn weaved fabric

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101070632A (en) * 2007-04-24 2007-11-14 孙仲毅 Nano silver-bamboo-charcoal dispersing liquid and method for preparing nano silver-bamboo-charcoal fiber
CN101440534A (en) * 2007-11-21 2009-05-27 上海中大科技发展有限公司 Nano bamboo charcoal anti-bacterial fiber and production method thereof
CN102758292A (en) * 2011-04-27 2012-10-31 南通绿芭蕉纺织品有限公司 Anti-bacterial fabric
CN102758288A (en) * 2011-04-27 2012-10-31 南通绿芭蕉纺织品有限公司 Double-layer heat storage anti-bacterial fabric
CN103668710A (en) * 2013-12-19 2014-03-26 苏州丽绣纺织有限公司 Anti-microbial velvet fabric
TW201435170A (en) * 2013-03-15 2014-09-16 Long-Chi Cai Charcoal yarn knitted fabrics

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101070632A (en) * 2007-04-24 2007-11-14 孙仲毅 Nano silver-bamboo-charcoal dispersing liquid and method for preparing nano silver-bamboo-charcoal fiber
CN101440534A (en) * 2007-11-21 2009-05-27 上海中大科技发展有限公司 Nano bamboo charcoal anti-bacterial fiber and production method thereof
CN102758292A (en) * 2011-04-27 2012-10-31 南通绿芭蕉纺织品有限公司 Anti-bacterial fabric
CN102758288A (en) * 2011-04-27 2012-10-31 南通绿芭蕉纺织品有限公司 Double-layer heat storage anti-bacterial fabric
TW201435170A (en) * 2013-03-15 2014-09-16 Long-Chi Cai Charcoal yarn knitted fabrics
CN103668710A (en) * 2013-12-19 2014-03-26 苏州丽绣纺织有限公司 Anti-microbial velvet fabric

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104928826A (en) * 2015-06-01 2015-09-23 句容市申兔工艺针织厂 Anti-radiation antibacterial deodorizing fabric and preparation method thereof
CN105926137A (en) * 2016-07-14 2016-09-07 南通中兴多元复合钢管有限公司 Antibacterial health care fabric
CN108251943A (en) * 2018-01-09 2018-07-06 嘉兴涌锦服饰有限公司 A kind of preparation method of antibacterial blended yarn weaved fabric

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Application publication date: 20150408