CN106017571A - Electrolytic cell measuring robot system - Google Patents
Electrolytic cell measuring robot system Download PDFInfo
- Publication number
- CN106017571A CN106017571A CN201610559328.6A CN201610559328A CN106017571A CN 106017571 A CN106017571 A CN 106017571A CN 201610559328 A CN201610559328 A CN 201610559328A CN 106017571 A CN106017571 A CN 106017571A
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- CN
- China
- Prior art keywords
- robot
- sensor
- measurement
- guide rail
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01D—MEASURING NOT SPECIALLY ADAPTED FOR A SPECIFIC VARIABLE; ARRANGEMENTS FOR MEASURING TWO OR MORE VARIABLES NOT COVERED IN A SINGLE OTHER SUBCLASS; TARIFF METERING APPARATUS; MEASURING OR TESTING NOT OTHERWISE PROVIDED FOR
- G01D21/00—Measuring or testing not otherwise provided for
- G01D21/02—Measuring two or more variables by means not covered by a single other subclass
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/06—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
- C25C1/10—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese of chromium or manganese
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/06—Operating or servicing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
The invention discloses an electrolytic cell measuring robot system comprising a guide rail, a measuring robot arranged on the guide rail and walking along the guide rail, a temperature sensor, a manganese ion concentration sensor, a PH sensor, an electrical conductivity sensor, and a robot room arranged at the end of the guide rail. When the system is working, the measuring robot moves along the guide rail to a preset measuring point, and a lifting drive device sends the sensors down to an electrolytic cell to automatically measure the parameters of electrolyte. Measurement is quick and highly accurate, and a strong data support is provided for the improvement of the yield of electrolytic manganese. After measurement at one measuring point ends, the measuring robot can spray water and wash the sensors through a water pump and a high-pressure spray nozzle to clear the electrolyte on the sensors, so the accuracy of next measurement is improved. After completion of measurement, the measuring robot can be maintained in the robot room, such as being cleaned, charged and filled with water. Therefore, smooth measurement is guaranteed, and the service life of equipment is prolonged.
Description
Technical field
The present invention relates to electrolytic manganese technical field, particularly to a kind of electrolysis bath robot measurement system
System.
Background technology
Electrolytic manganese process is with the sulfate of manganese or chloride as electrolyte, adds certain support
Electrolyte and additive, apply certain electric current in diaphragm cell, makes on minus plate
Obtain sheet metal manganese.Electrolytic process there occurs and react as follows:
The catholyte of manganese separates out, liberation of hydrogen side reaction: Mn2++ 2e-=Mn ↓
2H++2e-=H2↑
The anode electrolysis reaction of manganese: Mn2++2H2O-2e-=MnO2↓+4H+
2H2O-4e-=O2↑+4H+
For above-mentioned complex reaction system, to need strictly to control electrolysis by electrolytic production of metals manganese
Condition, such as electric current density, tank liquor Fe content, pH value, temperature, ammonium sulfate concentrations, dioxy
Change selenium addition etc..Electrolyte keeps certain manganese ion concentration manganese needed for supply negative electrode
Amount is to ensure that one of primary condition of being normally carried out of electrolysis.Manganese ion concentration is the highest or the lowest the most not
It is beneficial to being normally carried out of manganese deposition.If the Mn in catholyte2+Excessive concentration, can cause Gao Meng
The precipitation of double salt, destroys electrolytic process, and easily produces Mn (OH)2Precipitation, causes producing
Product are impure；If Mn2+Concentration is too low, it is clear that the dilution of manganese can occur, and can be due to sternly
The concentration polarization effect of weight and reduce current efficiency, the deposition velocity of Mn reduces, and is susceptible to
Flake.
Therefore, in electrolytic manganese process, the parameters of electrolyte is detected electrolytic manganese production
It is controlled significant.
Summary of the invention
In view of this, it is an object of the invention to provide a kind of electrolysis bath measurement robot system, with
Realize Mn in electrolysis bath2+The information such as concentration are measured fast and accurately.
Electrolysis bath measurement robot system of the present invention, including being arranged between adjacent two row electrolysis baths
Guide rail, be arranged on guide rail and along guide rail walking robot measurement, temperature sensor,
Manganese ion concentration sensor, pH value sensor, conductivity sensor and be arranged on guide rail
The robot room of end,
Described robot measurement includes the slide unit coordinated with slide, be fixed on slide unit and
Two ends are suspended in the crossbeam above electrolysis bath and the lifting drive being arranged on crossbeam；
Described temperature sensor, manganese ion concentration sensor, pH value sensor and conductance
Rate sensor is arranged on lifting drive；
Described robot measurement also include gather sensor detection information ZigBee acquisition station,
The water tank that is arranged on slide unit, to the high pressure nozzle of sensor water spray, Water in Water Tanks is inputted
The water pump of high pressure nozzle and the shell being arranged on slide unit；
Described robot is little is provided with water injector that cleaning robot is carried out, right within doors
Charger that robot is charged, water tank is carried out the priming apparatus of moisturizing.
Further, described guide rail is rack guide rail, and the bottom of described slide unit is provided with and tooth bar
The gear that guide rail coordinates, slide unit is additionally provided with the servomotor driving pinion rotation.
Further, described lifting drive is cylinder, linear electric motors or motor-driven rolling
Ballscrew.
Beneficial effects of the present invention:
1, electrolysis bath measurement robot system of the present invention, control robot measurement along guide rail move to
The measurement point preset, then lifting drive is by temperature sensor, manganese ion concentration sensing
Device, pH value sensor, conductivity sensor are fed down in electrolysis bath, and sensor is to electrolysis
The temperature of liquid, manganese ion concentration, pH value and conductivity measure, transmitting measured values
To ZigBee acquisition station, detection signal is uploaded to main frame by ZigBee acquisition station again, thus
Achieving the automatic measurement to electrolyte parameters, measuring speed is fast, and measurement accuracy is high,
Can be for improving the data support that electrolytic manganese yield provides strong.
2, electrolysis bath measurement robot system of the present invention, after a measurement point measurement terminates, surveys
Amount robot can carry out hydroblasting by water pump and high pressure nozzle to sensor, it is thus possible to remove
Viscous electrolyte on a sensor, can improve the accuracy next time measured.
3, electrolysis bath measurement robot system of the present invention, after all of measurement point is measured,
Robot measurement returns to robot cabin, at the little water injector that can pass through within doors of robot to machine
People is carried out, to remove the electrolyte residual in robot and ammonium sulfate crystallization；Can pass through
Robot is charged by charging device, to ensure the electricity consumption measured its next time；Priming apparatus can be passed through
Water tank is added water, to ensure sensor group be rinsed when next time measures；So that surveying
Amount system can well be safeguarded, improves measurement accuracy, extension device life-span.
Accompanying drawing explanation
Fig. 1 is the structural representation of electrolysis bath measurement robot system；
Fig. 2 is the structural representation after removing robot shells of the electrolysis bath measurement robot system
Figure；
Fig. 3 is the structural representation of robot cabin；
Description of reference numerals:
1-electrolysis bath, 2-guide rail, 3-temperature sensor, 4-manganese ion concentration sensor,
5-PH value sensor, 6-conductivity sensor, 7-robot room, 8-slide unit, 9-crossbeam,
10-lifting drive, 11-ZigBee acquisition station, 12-water tank, 13-high pressure nozzle,
14-water pump, 15-shell, 16-water injector, 17-charger, 18-priming apparatus, 19-
Gear, 20-servomotor.
Detailed description of the invention
The invention will be further described with embodiment below in conjunction with the accompanying drawings.
The present embodiment electrolysis bath measurement robot system, including being arranged on adjacent two row electrolysis baths 1
Between guide rail 2, be arranged on guide rail and along guide rail walking robot measurement, temperature pass
Sensor 3, manganese ion concentration sensor 4, pH value sensor 5, conductivity sensor 6, with
And it is arranged on the robot room 7 of rail end,
Described robot measurement includes the slide unit 8 coordinated with slide, is fixed on slide unit
And two ends are suspended in the crossbeam 9 above electrolysis bath and the lifting drive 10 being arranged on crossbeam；
Described temperature sensor, manganese ion concentration sensor, pH value sensor and conductance
Rate sensor is arranged on lifting drive；
Described robot measurement also includes the ZigBee acquisition station gathering sensor detection information
11, the water tank 12 that is arranged on slide unit, to the high pressure nozzle 13 of sensor water spray, by water tank
The middle water input water pump 14 of high pressure nozzle and the shell 15 being arranged on slide unit；
Described robot is little be provided with within doors water injector 16 that cleaning robot is carried out,
The charger 17 that robot is charged, the priming apparatus 18 that water tank is carried out moisturizing.
The present embodiment electrolysis bath measurement robot system, controls robot measurement along leading by PLC
Rail moves to default measurement point, and then lifting drive is by dense to temperature sensor, manganese ion
Degree sensor, pH value sensor, conductivity sensor are fed down in electrolysis bath, sensor
Temperature, manganese ion concentration, pH value and the conductivity of electrolyte is measured, measures
Value is transferred to ZigBee acquisition station, and detection signal is uploaded to main frame by ZigBee acquisition station again,
It is achieved thereby that the automatic measurement to electrolyte parameters, measuring speed is fast, measures accurately
Property high, can be for improving the data support that electrolytic manganese yield provides strong.
And this electrolysis bath measurement robot system, after a measurement point measurement terminates, measures
Robot can carry out hydroblasting by water pump and high pressure nozzle to sensor, it is thus possible to remove viscous
Electrolyte on a sensor, can improve the accuracy next time measured.
And this electrolysis bath measurement robot system, after all of measurement point is measured, survey
Amount robot returns to robot cabin, at the little water injector that can pass through within doors of robot to robot
It is carried out, to remove the electrolyte residual in robot and ammonium sulfate crystallization；Can be by filling
Robot is charged by electric installation, to ensure the electricity consumption measured its next time；Can be by priming apparatus pair
Water tank adds water, to ensure to be rinsed sensor group when next time measures；So that measuring
System can well be safeguarded, improves measurement accuracy, extension device life-span.
In the present embodiment, described guide rail 2 is rack guide rail, and the bottom of described slide unit is provided with
The gear 19 coordinated with rack guide rail, slide unit is additionally provided with the servo electricity driving pinion rotation
Machine 20.Driven by servomotor gear is used to move at rack guide rail so that robot measurement
Moving displacement precision is high, easy to control, can accurately arrive the measurement point of setting.
In the present embodiment, described lifting drive 7 is linear electric motors, controls simple and convenient,
Lifting drive 7 can be also cylinder, motor-driven ball the most in different embodiments
Other forms such as leading screw.
Finally illustrating, above example is only in order to illustrate technical scheme rather than limit
System, although the present invention being described in detail with reference to preferred embodiment, the common skill of this area
Art personnel should be appreciated that and can modify technical scheme or equivalent,
Without deviating from objective and the scope of technical solution of the present invention, it all should contain the right in the present invention
In the middle of claimed range.
Claims (3)
1. an electrolysis bath measurement robot system, it is characterised in that: include being arranged on adjacent
Guide rail between two row electrolysis baths, be arranged on guide rail and along guide rail walking robot measurement,
Temperature sensor, manganese ion concentration sensor, pH value sensor, conductivity sensor, with
And it is arranged on the robot room of rail end,
Described robot measurement includes the slide unit coordinated with slide, be fixed on slide unit and
Two ends are suspended in the crossbeam above electrolysis bath and the lifting drive being arranged on crossbeam；
Described temperature sensor, manganese ion concentration sensor, pH value sensor and conductance
Rate sensor is arranged on lifting drive；
Described robot measurement also include gather sensor detection information ZigBee acquisition station,
The water tank that is arranged on slide unit, to the high pressure nozzle of sensor water spray, Water in Water Tanks is inputted
The water pump of high pressure nozzle and the shell being arranged on slide unit；
Described robot is little is provided with water injector that cleaning robot is carried out, right within doors
Charger that robot is charged, water tank is carried out the priming apparatus of moisturizing.
Electrolysis bath measurement robot system the most according to claim 1, it is characterised in that:
Described guide rail is rack guide rail, and the bottom of described slide unit is provided with the tooth coordinated with rack guide rail
Wheel, slide unit is additionally provided with the servomotor driving pinion rotation.
Electrolysis bath measurement robot system the most according to claim 1, it is characterised in that:
Described lifting drive is cylinder, linear electric motors or motor-driven ball screw.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610559328.6A CN106017571A (en) | 2016-07-15 | 2016-07-15 | Electrolytic cell measuring robot system |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610559328.6A CN106017571A (en) | 2016-07-15 | 2016-07-15 | Electrolytic cell measuring robot system |
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| Publication Number | Publication Date |
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| CN106017571A true CN106017571A (en) | 2016-10-12 |
Family
ID=57119199
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610559328.6A Pending CN106017571A (en) | 2016-07-15 | 2016-07-15 | Electrolytic cell measuring robot system |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109187855A (en) * | 2018-08-13 | 2019-01-11 | 大同新成新材料股份有限公司 | A kind of device and method detecting concentration of electrolyte |
| CN109212126A (en) * | 2017-06-29 | 2019-01-15 | 宁夏软件工程院有限公司 | A kind of electrolyte polyion ingredient on-line measurement device |
Citations (7)
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|---|---|---|---|---|
| CN1211733A (en) * | 1998-03-09 | 1999-03-24 | 金山公夫 | Electrolyte solution concentration measurer |
| CN201217698Y (en) * | 2008-05-22 | 2009-04-08 | 武汉长海电气科技开发有限公司 | Wireless monitoring system for parameters of electrolyzer |
| US20110177403A1 (en) * | 2009-06-08 | 2011-07-21 | Toyota Jidosha Kabushiki Kaisha | Hydrogen concentration measurement device and fuel cell system |
| CN102251260A (en) * | 2010-12-17 | 2011-11-23 | 高伟 | Continuous test controlling and adjusting device for aluminium electrolysis cell |
| CN203265168U (en) * | 2013-05-22 | 2013-11-06 | 北京中农宸熙科技有限公司 | Dissolved oxygen sensor probe cleaning device |
| CN105170545A (en) * | 2015-07-16 | 2015-12-23 | 江苏大学 | Cleaning method and device for sensor probe for PH value detection |
| CN105463514A (en) * | 2015-06-12 | 2016-04-06 | 贵阳铝镁设计研究院有限公司 | Automatic inspection method and device for aluminum electrolysis cell condition |
-
2016
- 2016-07-15 CN CN201610559328.6A patent/CN106017571A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1211733A (en) * | 1998-03-09 | 1999-03-24 | 金山公夫 | Electrolyte solution concentration measurer |
| CN201217698Y (en) * | 2008-05-22 | 2009-04-08 | 武汉长海电气科技开发有限公司 | Wireless monitoring system for parameters of electrolyzer |
| US20110177403A1 (en) * | 2009-06-08 | 2011-07-21 | Toyota Jidosha Kabushiki Kaisha | Hydrogen concentration measurement device and fuel cell system |
| CN102251260A (en) * | 2010-12-17 | 2011-11-23 | 高伟 | Continuous test controlling and adjusting device for aluminium electrolysis cell |
| CN203265168U (en) * | 2013-05-22 | 2013-11-06 | 北京中农宸熙科技有限公司 | Dissolved oxygen sensor probe cleaning device |
| CN105463514A (en) * | 2015-06-12 | 2016-04-06 | 贵阳铝镁设计研究院有限公司 | Automatic inspection method and device for aluminum electrolysis cell condition |
| CN105170545A (en) * | 2015-07-16 | 2015-12-23 | 江苏大学 | Cleaning method and device for sensor probe for PH value detection |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109212126A (en) * | 2017-06-29 | 2019-01-15 | 宁夏软件工程院有限公司 | A kind of electrolyte polyion ingredient on-line measurement device |
| CN109187855A (en) * | 2018-08-13 | 2019-01-11 | 大同新成新材料股份有限公司 | A kind of device and method detecting concentration of electrolyte |
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Application publication date: 20161012 |