CN106012502A - Nano enhanced basalt-aramid blended asbeston - Google Patents
Nano enhanced basalt-aramid blended asbeston Download PDFInfo
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- CN106012502A CN106012502A CN201610475869.0A CN201610475869A CN106012502A CN 106012502 A CN106012502 A CN 106012502A CN 201610475869 A CN201610475869 A CN 201610475869A CN 106012502 A CN106012502 A CN 106012502A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
- D02G3/045—Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/55—Epoxy resins
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
- D06M2101/36—Aromatic polyamides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2101/00—Inorganic fibres
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
- D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/16—Physical properties antistatic; conductive
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses nano enhanced basalt-aramid blended asbeston. The nano enhanced basalt-aramid blended asbeston is prepared from, by weight, 50-55 parts of poly-m-phenylene isophthalamide staple fibers, 45-50 parts of continuous basalt fibers, 8-10 parts of 100-mesh crystalline flake graphite, a proper amount of 20 wt% sodium hydroxide solution, a proper amount of 20 wt% salpeter solution, 0.5-0.6 part of sodium carboxymethylcellulose, 12-15 parts of newly-prepared 10 wt% silver ammonia solution, a proper amount of absolute ethyl alcohol, 6-7.5 parts of acetaldehyde, 8-10 parts of water-borne epoxy resin, 1.5-2 parts of hexamethylenetetramine, a proper amount of deionized water, 0.8-1 part of silane coupling agent kh570, 6-7 parts of nanosilicon dioxide, 0.8-1 part of stearic acid polyoxyethylene ester, 9-10 parts of waterborne polyurethane and 1.2-1.4 parts of cationic etherified starch. The nano enhanced basalt-aramid blended asbeston is suitable for ventilation and fire prevention for chemical engineering, metallurgy, military industry and the like and is also suitable for manufacturing protective articles and the like.
Description
Technical field
The present invention relates to flameproof fabric technical field, particularly relate to a kind of nanometer and strengthen basalt aramid fiber blending flameproof fabric.
Background technology
Fire is one of very important threat of modern architecture, and for the loss reduced when fire occurs the safety ensureing masses, various fire proofing materials have been widely used among the living environment of people.Basalt fibre, it is after basalt building stones melt at 1450 DEG C～1500 DEG C, continuous fiber by platinum-rhodium alloy bushing high speed pulling, basalt fibre flameproof fabric is to weave with the 7-9 μm continuous basalt fiber spun yarn of GBF, wherein there are plain and satin etc., due to its noninflammability, high temperature resistant, discharge without toxic gas, thermal insulation is good, without molten or drippage, intensity height, without advantages such as thermal contraction phenomenons, through high temperature resistant, the coating process of nonhazardous.It is used as the fire proofing material that inflammable protective garment liner, fire-retardant, thermal insulation fabric, flameproof fabric and fire screen are optimal.But the density of basalt fibre is big, and fiber weakness is big so that it is the folding of fiber to be avoided during producing, transporting and use.
During actual fabrication, for ensureing that basalt fiber cloth has more preferable serviceability, also basalt fibre and other fibers can be carried out blending, the material made can not only meet industrial use, protective garment fabric etc. can also be used as, in " fire-retardant fire protection fiber and the research of fabric " literary composition, have studied the fabric that multiple blend fibre is made, wherein use aramid fiber, basalt fibre to carry out blend fabric and make fire-entry suit top layer, moderate cost, tenacity of fibre is good, has certain fire-proof and thermal-insulation effect.But due in the working environment of the industries such as petrochemical industry, electrostatic is also possible to become incendiary source, cause fire, thus antistatic performance be flameproof fabric preparation in it is also contemplated that factor, this is accomplished by that basalt fibre flameproof fabric is carried out a series of process modification and has reached optimal using effect.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of nanometer strengthens basalt aramid fiber blending flameproof fabric.
The present invention is achieved by the following technical solutions:
A kind of nanometer strengthens basalt aramid fiber blending flameproof fabric, it is made up of the raw material of following weight portion: meta-aramid chopped fiber 50-55, continuous basalt fiber 45-50, 100 mesh crystalline flake graphite 8-10, concentration is that the sodium hydroxide solution of 20wt% is appropriate, concentration is that the salpeter solution of 20wt% is appropriate, sodium carboxymethyl cellulose 0.5-0.6, the concentration now joined is the silver ammino solution 12-15 of 10wt%, dehydrated alcohol is appropriate, acetaldehyde 6-7.5, aqueous epoxy resins 8-10, hexamethylenetetramine 1.5-2, deionized water is appropriate, silane coupler kh5700.8-1, nano silicon 6-7, stearic acid polyoxyethylene ester 0.8-1, aqueous polyurethane 9-10, cation etherification starch 1.2-1.4.
Described a kind of nanometer strengthens basalt aramid fiber blending flameproof fabric, is made up of step in detail below:
(1) 100 mesh crystalline flake graphites are boiled 10-12 minute in the sodium hydroxide solution that concentration is 20wt%, it is washed with deionized to neutrality to add in the salpeter solution that concentration is 20wt% and boils 10-12 minute, continue washing to be vacuum dried 8-10 hour at 60-70 DEG C to neutrality, after cooling, the crystalline flake graphite of pretreatment is mixed with sodium carboxymethyl cellulose, add in the deionized water of total amount 2-2.5 times amount, stir, obtain crystalline flake graphite suspension stand-by；Acetaldehyde is dissolved in the dehydrated alcohol of 2-2.5 times amount, obtains acetaldehyde solution stand-by；Crystalline flake graphite suspension is heated to 60-65 DEG C, it is simultaneously added dropwise the silver ammino solution that concentration is 10wt% and acetaldehyde solution now joined, reaction is stirred until reactant color is not in change with the speed of 300-400 rev/min, take out solid, with being washed with deionized water after absolute ethanol washing to neutrality, finally dry, obtain silver-plated crystalline graphite powder；
(2) by epoxy emulsion, hexamethylenetetramine mixing, add in the deionized water of total amount 10-12 times amount, it is subsequently adding silver-plated crystalline graphite powder, with 300-400 turn/speed of part stirs 30-40 minute and forms dipping sizing agent, again meta-aramid chopped fiber is immersed, it is dried at 75-85 DEG C after taking-up, obtains silvering graphite cladding aramid fiber；
(3) silvering graphite cladding aramid fiber step (2) obtained mixes with basalt fibre, through comb and parallel cotton fibers prior to spinning, drafting, rove, spun yarn, obtains scribbled, finally scribbled is woven into net, obtains flameproof fabric base fabric；
(4) deionized water adding 2-3 times amount in nano silicon carries out ball milling to disperse 90-120 minute to form dispersion liquid, be subsequently adding.This nanoparticle is added silane coupler kh570, is heated to 80-90 DEG C, after stirring 2.5-3 hour with the speed of 1000-1200 rev/min, be cooled to room temperature, filter, wash, dry after reheat the deionized water of 10-12 times amount to obtain silica dispersions stand-by；Mix with silica dispersions after aqueous polyurethane is diluted 4-5 times with deionized water, add remaining residual components, stir 60-80 minute with the speed of 400-500 rev/min, obtain coating paste；
(5) the flameproof fabric scrim surfaces coating paste brushing that step (4) obtains obtained in step (3), by doctor blade, dry 90-120 minute at 90-100 DEG C, obtains the present invention.
The invention have the advantage that the present invention passes through chemical reaction flake graphite's surface is silver-plated, then silver-plated crystalline flake graphite is coated on aramid fiber surface by the method for dipping, not only improve the mechanical performance of fiber, spinnability, make aramid fiber anti-flammability, antistatic property be greatly promoted simultaneously；Again aramid fiber is become cloth with basalt fibre blending woven, the flameproof fabric medium density made, can not only fire-retardant fireproof, simultaneously antistatic, acid and alkali-resistance, have excellence surface property, mechanical property.
The compositions such as nano silicon are added in the preparation of coating paste by the present invention, through the product that this slurry coats, the most do not damage the structure of itself, are greatly improved again the mechanical property of fiber；The Product Process that the present invention makes is easy to Industry Control, is suitable for large-scale production, is not only suitable for the ventilating fire preventions such as chemical industry, metallurgy, military project, is also adaptable for manufacturing protective articles etc..
Detailed description of the invention
A kind of nanometer strengthens basalt aramid fiber blending flameproof fabric, it is made up of the raw material of following weight portion (kilogram): meta-aramid chopped fiber 50, continuous basalt fiber 45, 100 mesh crystalline flake graphites 8, concentration is that the sodium hydroxide solution of 20wt% is appropriate, concentration is that the salpeter solution of 20wt% is appropriate, sodium carboxymethyl cellulose 0.5, the concentration now joined is the silver ammino solution 12 of 10wt%, dehydrated alcohol is appropriate, acetaldehyde 6, aqueous epoxy resins 8, hexamethylenetetramine 1.5, deionized water is appropriate, silane coupler kh5700.8, nano silicon 6, stearic acid polyoxyethylene ester 0.8, aqueous polyurethane 9, cation etherification starch 1.2.
Described a kind of nanometer strengthens basalt aramid fiber blending flameproof fabric, is made up of step in detail below:
(1) 100 mesh crystalline flake graphites are boiled 10 minutes in the sodium hydroxide solution that concentration is 20wt%, it is washed with deionized to neutrality to add in the salpeter solution that concentration is 20wt% and boils 10 minutes, continue washing to be vacuum dried 8 hours at 60 DEG C to neutrality, after cooling, the crystalline flake graphite of pretreatment is mixed with sodium carboxymethyl cellulose, add in the deionized water of total amount 2 times amount, stir, obtain crystalline flake graphite suspension stand-by；Acetaldehyde is dissolved in the dehydrated alcohol of 2 times amount, obtains acetaldehyde solution stand-by；Crystalline flake graphite suspension is heated to 60 DEG C, it is simultaneously added dropwise the silver ammino solution that concentration is 10wt% and acetaldehyde solution now joined, reaction is stirred until reactant color is not in change with the speed of 300 revs/min, take out solid, with being washed with deionized water after absolute ethanol washing to neutrality, finally dry, obtain silver-plated crystalline graphite powder；
(2) by epoxy emulsion, hexamethylenetetramine mixing, add in the deionized water of total amount 10 times amount, it is subsequently adding silver-plated crystalline graphite powder, stir 30 minutes with the speed of 300 turns/part and form dipping sizing agent, again meta-aramid chopped fiber is immersed, it is dried at 75 DEG C after taking-up, obtains silvering graphite cladding aramid fiber；
(3) silvering graphite cladding aramid fiber step (2) obtained mixes with basalt fibre, through comb and parallel cotton fibers prior to spinning, drafting, rove, spun yarn, obtains scribbled, finally scribbled is woven into net, obtains flameproof fabric base fabric；
(4) deionized water adding 2 times amount in nano silicon carries out ball milling disperse 90 minutes to form dispersion liquid, be subsequently adding.This nanoparticle is added silane coupler kh570, is heated to 80 DEG C, after stirring 2.5 hours with the speed of 1000 revs/min, be cooled to room temperature, filter, wash, dry after reheat the deionized water of 10 times amount to obtain silica dispersions stand-by；Mix with silica dispersions after aqueous polyurethane is diluted 4 times with deionized water, add remaining residual components, stir 60 minutes with the speed of 400 revs/min, obtain coating paste；
(5) the flameproof fabric scrim surfaces coating paste brushing that step (4) obtains obtained in step (3), by doctor blade, is dried 90 minutes at 90 DEG C, obtains the present invention.
Through measuring fracture strength 12.4 MPa of flameproof fabric of the present invention, elongation at break 19.2%, limited oxygen index is more than 30, nonflammable.
Claims (2)
- null1. a nanometer strengthens basalt aramid fiber blending flameproof fabric，It is characterized in that，It is made up of the raw material of following weight portion: meta-aramid chopped fiber 50-55、Continuous basalt fiber 45-50、100 mesh crystalline flake graphite 8-10、Concentration is that the sodium hydroxide solution of 20wt% is appropriate、Concentration is that the salpeter solution of 20wt% is appropriate、Sodium carboxymethyl cellulose 0.5-0.6、The concentration now joined is the silver ammino solution 12-15 of 10wt%、Dehydrated alcohol is appropriate、Acetaldehyde 6-7.5、Aqueous epoxy resins 8-10、Hexamethylenetetramine 1.5-2、Deionized water is appropriate、Silane coupler kh5700.8-1、Nano silicon 6-7、Stearic acid polyoxyethylene ester 0.8-1、Aqueous polyurethane 9-10、Cation etherification starch 1.2-1.4.
- The most according to claim 1, a kind of nanometer strengthens basalt aramid fiber blending flameproof fabric, it is characterised in that be made up of step in detail below:(1) 100 mesh crystalline flake graphites are boiled 10-12 minute in the sodium hydroxide solution that concentration is 20wt%, it is washed with deionized to neutrality to add in the salpeter solution that concentration is 20wt% and boils 10-12 minute, continue washing to be vacuum dried 8-10 hour at 60-70 DEG C to neutrality, after cooling, the crystalline flake graphite of pretreatment is mixed with sodium carboxymethyl cellulose, add in the deionized water of total amount 2-2.5 times amount, stir, obtain crystalline flake graphite suspension stand-by；Acetaldehyde is dissolved in the dehydrated alcohol of 2-2.5 times amount, obtains acetaldehyde solution stand-by；Crystalline flake graphite suspension is heated to 60-65 DEG C, it is simultaneously added dropwise the silver ammino solution that concentration is 10wt% and acetaldehyde solution now joined, reaction is stirred until reactant color is not in change with the speed of 300-400 rev/min, take out solid, with being washed with deionized water after absolute ethanol washing to neutrality, finally dry, obtain silver-plated crystalline graphite powder；(2) by epoxy emulsion, hexamethylenetetramine mixing, add in the deionized water of total amount 10-12 times amount, it is subsequently adding silver-plated crystalline graphite powder, with 300-400 turn/speed of part stirs 30-40 minute and forms dipping sizing agent, again meta-aramid chopped fiber is immersed, it is dried at 75-85 DEG C after taking-up, obtains silvering graphite cladding aramid fiber；(3) silvering graphite cladding aramid fiber step (2) obtained mixes with basalt fibre, through comb and parallel cotton fibers prior to spinning, drafting, rove, spun yarn, obtains scribbled, finally scribbled is woven into net, obtains flameproof fabric base fabric；(4) deionized water adding 2-3 times amount in nano silicon carries out ball milling to disperse 90-120 minute to form dispersion liquid, be subsequently adding；This nanoparticle is added silane coupler kh570, is heated to 80-90 DEG C, after stirring 2.5-3 hour with the speed of 1000-1200 rev/min, be cooled to room temperature, filter, wash, dry after reheat the deionized water of 10-12 times amount to obtain silica dispersions stand-by；Mix with silica dispersions after aqueous polyurethane is diluted 4-5 times with deionized water, add remaining residual components, stir 60-80 minute with the speed of 400-500 rev/min, obtain coating paste；(5) the flameproof fabric scrim surfaces coating paste brushing that step (4) obtains obtained in step (3), by doctor blade, dry 90-120 minute at 90-100 DEG C, obtains the present invention.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610475869.0A CN106012502A (en) | 2016-06-27 | 2016-06-27 | Nano enhanced basalt-aramid blended asbeston |
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| CN201610475869.0A CN106012502A (en) | 2016-06-27 | 2016-06-27 | Nano enhanced basalt-aramid blended asbeston |
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Cited By (5)
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| CN107460726A (en) * | 2017-08-18 | 2017-12-12 | 丹阳新星服饰有限公司 | A kind of preparation method of Antistatic Fabric |
| CN110241647A (en) * | 2019-06-21 | 2019-09-17 | 江西农业大学 | A kind of preparation method of high-strength transparence nano-cellulose paper |
| CN110256107A (en) * | 2019-07-18 | 2019-09-20 | 西华大学 | A kind of polyurethane foam insulation decorative integrated plate and preparation method thereof |
| CN111088691A (en) * | 2019-12-30 | 2020-05-01 | 江苏领瑞新材料科技有限公司 | Method of weak-polarization treatment technology for fiber surface |
| CN116178901A (en) * | 2023-03-17 | 2023-05-30 | 大连理工大学 | Preparation method of novel high-strength and high-brittleness 3D printing material for rock reconstruction |
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| CN105368290A (en) * | 2015-12-24 | 2016-03-02 | 重庆卡勒斯通科技有限公司 | Nanometer flame-retardant coating and preparation process thereof |
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| CN1919933A (en) * | 2006-09-01 | 2007-02-28 | 清华大学 | Method of preparing electric conductive adhesive by chemical plating silver on graphite powder surface |
| CN102851949A (en) * | 2012-09-28 | 2013-01-02 | 嘉兴市安瑞材料科技有限公司 | Flame retardant flexible ceiling film and method for preparing same |
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| CN205295595U (en) * | 2015-07-09 | 2016-06-08 | 上海兰邦工业纤维有限公司 | Aramid fiber covering yarn |
| CN105368290A (en) * | 2015-12-24 | 2016-03-02 | 重庆卡勒斯通科技有限公司 | Nanometer flame-retardant coating and preparation process thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107460726A (en) * | 2017-08-18 | 2017-12-12 | 丹阳新星服饰有限公司 | A kind of preparation method of Antistatic Fabric |
| CN110241647A (en) * | 2019-06-21 | 2019-09-17 | 江西农业大学 | A kind of preparation method of high-strength transparence nano-cellulose paper |
| CN110256107A (en) * | 2019-07-18 | 2019-09-20 | 西华大学 | A kind of polyurethane foam insulation decorative integrated plate and preparation method thereof |
| CN111088691A (en) * | 2019-12-30 | 2020-05-01 | 江苏领瑞新材料科技有限公司 | Method of weak-polarization treatment technology for fiber surface |
| CN116178901A (en) * | 2023-03-17 | 2023-05-30 | 大连理工大学 | Preparation method of novel high-strength and high-brittleness 3D printing material for rock reconstruction |
| CN116178901B (en) * | 2023-03-17 | 2023-08-18 | 大连理工大学 | Preparation method of high-strength and high-brittleness 3D printing material for rock reconstruction |
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Application publication date: 20161012 |