CN105368290A - Nanometer flame-retardant coating and preparation process thereof - Google Patents

Nanometer flame-retardant coating and preparation process thereof Download PDF

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Publication number
CN105368290A
CN105368290A CN201510982357.9A CN201510982357A CN105368290A CN 105368290 A CN105368290 A CN 105368290A CN 201510982357 A CN201510982357 A CN 201510982357A CN 105368290 A CN105368290 A CN 105368290A
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retardant coating
reactor
flame retardant
parts
nano
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CN105368290B (en
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张学明
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Zhongjiwei Chongqing New Material Technology Research Institute Co ltd
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Chongqing Ka Le Stone Science And Technology Ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/544—Silicon-containing compounds containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/67—Particle size smaller than 100 nm
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a nanometer flame-retardant coating which comprises the following components in parts by weight according to the formula: 30-35 parts of waterborne polyurethane, 5-10 parts of nanosilicon dioxide, 30-35 parts of methylbenzene, 15-20 parts of deionized water, 3-6 parts of n-butyl alcohol, 3-6 parts of isocyanate, 1.0-1.5 parts of a silane coupling agent, 0.3-0.5 part of a stabilizer and 0.3-0.8 part of an antifoaming agent; meanwhile, the invention further discloses a preparation process of the nanometer flame-retardant coating. According to the nanometer flame-retardant coating and the preparation process thereof, provided by the invention, the silane coupling agent is adopted for performing modified treatment on nanosilicon dioxide, and modified nanosilicon dioxide is uniformly dispersed in the flame-retardant coating, so that the flame-retardant coating has excellent fireproof performance of nano particles, solves the durability problem of the conventional flame retardant coating, is non-toxic, harmless, excellent in environment friendliness, and good in decorative effect.

Description

A kind of nano flame retardant coating and preparation technology thereof
Technical field
The present invention relates to a kind of anti-flaming dope, particularly relate to a kind of nano flame retardant coating and preparation technology thereof.
Background technology
The meaning of anti-flaming dope is, has during the condition of a fire and fire can be avoided to occur, the protection security of the lives and property; Event of fire, can slow down spreading of fire to greatest extent, for firefighter provides the quality time, make loss drop to bottom line.Along with the development in application of paints field expands, also more and more urgent to the demand of anti-flaming dope.
Timber has comfortable pleasant texture and beautiful texture, be the important materials of building and upholstery at present, but timber is inflammable, easily causes fire, jeopardizes the safety of life and property of the mankind.In order to improve the security that timber uses, fire-retardant finish must be carried out to timber, adopting anti-flaming dope to be a kind of simple and easy to do method.Due to the favor that steel construction has short construction period, environmental pollution is little, shock resistance good, quality is light, intensity advantages of higher is more and more subject to people, particularly in large span, super high rise building and structures, obtain increasingly extensive application, therefore steel construction will play its uniqueness and irreplaceable effect in the construction work in future.But steel construction is directly exposed burns under thermal-flame, less than 20min, steel construction will soon lose its supporting capacity, does not reach the fire protection requirement in building code far away, therefore adopts anti-flaming dope to be very necessary to steel construction.
Nanotechnology is that 20 th century later grow up, and becomes one of 21 century three large dominant technology.Nanoparticle is of a size of 1 ~ 100nm, because nanoparticle is that nanometer scale makes it have much unusual physics and chemistry character, as quantum size effect, small-size effect, surface effects and macro quanta tunnel effect.Nanoparticle is added to fire endurance, cohesive strength, the weather resistance that anti-flaming dope in anti-flaming dope, can be improved, increase the anti-microbial property of coating simultaneously, make coating have stronger Practical Performance.Silicon-dioxide (SiO2) is inorganics, there is uninflammability, by its nanometer, add after modification again in anti-flaming dope, the mechanical property of body, thermal characteristics, being separated by property of gas and the energy of resistance to dissolubility can be improved, the compactness of coating is higher simultaneously, the combustion heat can be reduced to unburn partial feedback and degradation production to the diffusion of flame region, inhibit the speed that volatile matter produces, serve the effect of good heat insulation and oxygen barrier, thus delay the burning of coating, there is good flame retardant effect.
Summary of the invention
For above shortcomings in prior art, the invention provides a kind of thermal conductivity low, fire endurance is high, and has the nano flame retardant coating of fine decorative effect.
Meanwhile, present invention also offers a kind of preparation technology of nano flame retardant coating.
In order to solve the problems of the technologies described above, present invention employs following technical scheme:
A kind of nano flame retardant coating, this coating comprises following formula (weight part): aqueous polyurethane 30 ~ 35; Nano silicon 5 ~ 10; Toluene 30 ~ 35; Deionized water 15 ~ 20; Propyl carbinol 3 ~ 6; Isocyanic ester 3 ~ 6; Silane coupling agent 1.0 ~ 1.5; Stablizer 0.3 ~ 0.5; Defoamer 0.3 ~ 0.8.
As a preferred embodiment of the present invention, described silane coupling agent is hexamethyldisilazane (HMDZ) or coupling agent KH-550 [(C 2h 5o 3) 3si (CH 2) 3nH 2].
As another kind of preferred version of the present invention, described nano silicon median size is 28nm, and specific surface area is 600m 2/ g.
Prepare a technique for above-mentioned nano flame retardant coating, this technique comprises the steps:
1) by weight joining in toluene by nano silicon, after supersound process 55 ~ 65min, unit for uniform suspension is obtained;
2) silane coupling agent is joined in suspension, supersound process 28 ~ 32min, react 115 ~ 125min in 78 ~ 82 DEG C of constant temperature water baths after, obtain modified manometer silicon dioxide;
3) by weight adding aqueous polyurethane, deionized water in reactor, the speed of 790 ~ 810r/min stirs 58 ~ 62min;
4) add propyl carbinol by weight, then in reactor, add isocyanic ester while stirring, the speed of 490 ~ 510r/min stirs 28 ~ 32min;
5) by weight joining in reactor by modified manometer silicon dioxide, the speed of 490 ~ 510r/min stirs 28 ~ 32min;
6) by weight adding stablizer and defoamer in reactor, after the speed stirring 58 ~ 62min of 90 ~ 110r/min, nano flame retardant coating is obtained.
Technique effect of the present invention is: this nano flame retardant paint coating thickness is only 40 ~ 50um, and its thermal conductivity is lower than 0.025W/mk, and fire endurance is not less than 60min, has good decorative effect simultaneously.
Embodiment
A kind of nano flame retardant coating, this coating comprises following formula (weight part): aqueous polyurethane 30 ~ 35; Nano silicon 5 ~ 10; Toluene 30 ~ 35; Deionized water 15 ~ 20; Propyl carbinol 3 ~ 6; Isocyanic ester 3 ~ 6; Silane coupling agent 1.0 ~ 1.5; Stablizer 0.3 ~ 0.5; Defoamer 0.3 ~ 0.8.
Silane coupling agent is hexamethyldisilazane (HMDZ) or coupling agent KH-550 [(C 2h 5o 3) 3si (CH 2) 3nH 2], nano silicon median size is 28nm, and specific surface area is 600m 2/ g, stablizer can adopt photostabilizer 292, and defoamer can adopt silicone antifoam agent AT-882DN.
Embodiment 1
A preparation technology for nano flame retardant coating, this technique comprises the steps:
1) take toluene 30kg in reaction vessel, add 5kg nano silicon, through ultrasonication 55min, obtain unit for uniform suspension;
2) taking silane coupling agent 1kg joins in suspension, and supersound process 28min, react 115min in 78 DEG C of constant temperature water baths after, obtains modified manometer silicon dioxide;
3) in reactor, add 20kg deionized water, then take 35kg aqueous polyurethane and join in reactor, stir 58min with the speed of 790r/min;
4) taking propyl carbinol 3kg joins in reactor, then in reactor, adds isocyanic ester while stirring, and the quality of isocyanic ester is the speed stirring 28min of 5kg, 490r/min;
5) join in reactor by modified manometer silicon dioxide, the speed of 490r/min stirs 28min;
6) in reactor, add 0.4kg stablizer and 0.6kg defoamer, after the speed stirring 58min of 90r/min, obtain nano flame retardant coating.
This nano flame retardant paint coating thickness is only 43um after testing, and its thermal conductivity is 0.025W/mk, and fire endurance is not less than 62min, has good decorative effect simultaneously.
Embodiment 2
A preparation technology for nano flame retardant coating, this technique comprises the steps:
1) take toluene 31kg in reaction vessel, add 6kg nano silicon, through ultrasonication 60min, obtain unit for uniform suspension;
2) taking silane coupling agent 1.1kg joins in suspension, and supersound process 29min, react 117min in 80 DEG C of constant temperature water baths after, obtains modified manometer silicon dioxide;
3) in reactor, add 19kg deionized water, then take 34kg aqueous polyurethane and join in reactor, stir 59min with the speed of 795r/min;
4) taking propyl carbinol 4kg joins in reactor, then in reactor, adds isocyanic ester while stirring, and the quality of isocyanic ester is the speed stirring 29min of 6kg, 495r/min;
5) join in reactor by modified manometer silicon dioxide, the speed of 500r/min stirs 30min;
6) in reactor, add 0.3kg stablizer and 0.7kg defoamer, after the speed stirring 60min of 100r/min, obtain nano flame retardant coating.
This nano flame retardant paint coating thickness is only 41um after testing, and its thermal conductivity is 0.022W/mk, and fire endurance is not less than 65min, has good decorative effect simultaneously.
Embodiment 3
A preparation technology for nano flame retardant coating, this technique comprises the steps:
1) take toluene 32kg in reaction vessel, add 7kg nano silicon, through ultrasonication 64min, obtain unit for uniform suspension;
2) taking silane coupling agent 1.2kg joins in suspension, and supersound process 30min, react 120min in 79 DEG C of constant temperature water baths after, obtains modified manometer silicon dioxide;
3) in reactor, add 18kg deionized water, then take 33kg aqueous polyurethane and join in reactor, stir 60min with the speed of 800r/min;
4) taking propyl carbinol 5kg joins in reactor, then in reactor, adds isocyanic ester while stirring, and the quality of isocyanic ester is the speed stirring 30min of 4kg, 500r/min;
5) join in reactor by modified manometer silicon dioxide, the speed of 500r/min stirs 30min;
6) in reactor, add 0.3kg stablizer and 0.8kg defoamer, after the speed stirring 62min of 95r/min, obtain nano flame retardant coating.
This nano flame retardant paint coating thickness is only 46um after testing, and its thermal conductivity is 0.021W/mk, and fire endurance is not less than 68min, has good decorative effect simultaneously.
Embodiment 4
A preparation technology for nano flame retardant coating, this technique comprises the steps:
1) take toluene 33kg in reaction vessel, add 9kg nano silicon, through ultrasonication 62min, obtain unit for uniform suspension;
2) taking silane coupling agent 1.3kg joins in suspension, and supersound process 31min, react 123min in 81 DEG C of constant temperature water baths after, obtains modified manometer silicon dioxide;
3) in reactor, add 17kg deionized water, then take 32kg aqueous polyurethane and join in reactor, stir 61min with the speed of 805r/min;
4) taking propyl carbinol 5.3kg joins in reactor, then in reactor, adds isocyanic ester while stirring, and the quality of isocyanic ester is the speed stirring 31min of 3kg, 505r/min;
5) join in reactor by modified manometer silicon dioxide, the speed of 500r/min stirs 30min;
6) in reactor, add 0.5kg stablizer and 0.4kg defoamer, after the speed stirring 61min of 110r/min, obtain nano flame retardant coating.
This nano flame retardant paint coating thickness is only 49um after testing, and its thermal conductivity is 0.020W/mk, and fire endurance is not less than 71min, has good decorative effect simultaneously.
Embodiment 5
A preparation technology for nano flame retardant coating, this technique comprises the steps:
1) take toluene 35kg in reaction vessel, add 10kg nano silicon, through ultrasonication 65min, obtain unit for uniform suspension;
2) taking silane coupling agent 1.5kg joins in suspension, and supersound process 32min, react 125min in 82 DEG C of constant temperature water baths after, obtains modified manometer silicon dioxide;
3) in reactor, add 15kg deionized water, then take 30kg aqueous polyurethane and join in reactor, stir 62min with the speed of 810r/min;
4) taking propyl carbinol 6kg joins in reactor, then in reactor, adds isocyanic ester while stirring, and the quality of isocyanic ester is the speed stirring 32min of 3.8kg, 510r/min;
5) join in reactor by modified manometer silicon dioxide, the speed of 500r/min stirs 30min;
6) in reactor, add 0.4kg stablizer and 0.3kg defoamer, after the speed stirring 59min of 105r/min, obtain nano flame retardant coating.
This nano flame retardant paint coating thickness is only 47um after testing, and its thermal conductivity is 0.022W/mk, and fire endurance is not less than 67min, has good decorative effect simultaneously.
What finally illustrate is, above embodiment is only in order to illustrate technical scheme of the present invention and unrestricted, although with reference to preferred embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that, can modify to technical scheme of the present invention or equivalent replacement, and not departing from aim and the scope of technical solution of the present invention, it all should be encompassed in the middle of right of the present invention.

Claims (4)

1. a nano flame retardant coating, is characterized in that, this coating comprises following formula (weight part): aqueous polyurethane 30 ~ 35; Nano silicon 5 ~ 10; Toluene 30 ~ 35; Deionized water 15 ~ 20; Propyl carbinol 3 ~ 6; Isocyanic ester 3 ~ 6; Silane coupling agent 1.0 ~ 1.5; Stablizer 0.3 ~ 0.5; Defoamer 0.3 ~ 0.8.
2. a kind of nano flame retardant coating according to claim 1, is characterized in that, described silane coupling agent is hexamethyldisilazane (HMDZ) or coupling agent KH-550 [(C 2h 5o 3) 3si (CH 2) 3nH 2].
3. a kind of nano flame retardant coating according to claim 1, is characterized in that, described nano silicon median size is 28nm, and specific surface area is 600m 2/ g.
4. prepare a technique for nano flame retardant coating according to claim 1, it is characterized in that, this technique comprises the steps:
1) by weight joining in toluene by nano silicon, after supersound process 55 ~ 65min, unit for uniform suspension is obtained;
2) silane coupling agent is joined in suspension, supersound process 28 ~ 32min, react 115 ~ 125min in 78 ~ 82 DEG C of constant temperature water baths after, obtain modified manometer silicon dioxide;
3) by weight adding aqueous polyurethane, deionized water in reactor, the speed of 790 ~ 810r/min stirs 58 ~ 62min;
4) add propyl carbinol by weight, then in reactor, add isocyanic ester while stirring, the speed of 490 ~ 510r/min stirs 28 ~ 32min;
5) by weight joining in reactor by modified manometer silicon dioxide, the speed of 490 ~ 510r/min stirs 28 ~ 32min;
6) by weight adding stablizer and defoamer in reactor, after the speed stirring 58 ~ 62min of 90 ~ 110r/min, nano flame retardant coating is obtained.
CN201510982357.9A 2015-12-24 2015-12-24 A kind of nano flame retardant coating and its preparation process Active CN105368290B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106012502A (en) * 2016-06-27 2016-10-12 安徽忆特斯阻燃科技有限公司 Nano enhanced basalt-aramid blended asbeston
CN116102912A (en) * 2023-03-17 2023-05-12 广州豫顺新材料有限公司 Nano silicon dioxide-based flame retardant and application thereof in polyurethane coating
CN118271957A (en) * 2024-05-07 2024-07-02 广州豫顺新材料科技有限公司 Nanometer silicon dioxide synergistic flame-retardant modified paint and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101215438A (en) * 2008-01-03 2008-07-09 海门市森达装饰材料有限公司 Anti-soiling aging-resisting stainless steel paint and preparation method thereof
CN104277699A (en) * 2014-10-29 2015-01-14 芜湖县双宝建材有限公司 High-strength modified waterborne polyurethane coating
CN104312411A (en) * 2014-10-20 2015-01-28 芜湖县双宝建材有限公司 Waterproof high-hardness waterborne polyurethane coating
CN105131820A (en) * 2015-09-21 2015-12-09 黄利锟 Polyurethane composite resin paint resistant to friction and dirt as well as preparation method of paint

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101215438A (en) * 2008-01-03 2008-07-09 海门市森达装饰材料有限公司 Anti-soiling aging-resisting stainless steel paint and preparation method thereof
CN104312411A (en) * 2014-10-20 2015-01-28 芜湖县双宝建材有限公司 Waterproof high-hardness waterborne polyurethane coating
CN104277699A (en) * 2014-10-29 2015-01-14 芜湖县双宝建材有限公司 High-strength modified waterborne polyurethane coating
CN105131820A (en) * 2015-09-21 2015-12-09 黄利锟 Polyurethane composite resin paint resistant to friction and dirt as well as preparation method of paint

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张书华等: "《高性能电缆材料及其应用技术》", 30 November 2015, 上海交通大学出版社 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106012502A (en) * 2016-06-27 2016-10-12 安徽忆特斯阻燃科技有限公司 Nano enhanced basalt-aramid blended asbeston
CN116102912A (en) * 2023-03-17 2023-05-12 广州豫顺新材料有限公司 Nano silicon dioxide-based flame retardant and application thereof in polyurethane coating
CN116102912B (en) * 2023-03-17 2024-01-30 广州豫顺新材料有限公司 Nano silicon dioxide-based flame retardant and application thereof in polyurethane coating
CN118271957A (en) * 2024-05-07 2024-07-02 广州豫顺新材料科技有限公司 Nanometer silicon dioxide synergistic flame-retardant modified paint and preparation method thereof

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