CN106011368A - Slag blocking ball for converter - Google Patents

Slag blocking ball for converter Download PDF

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Publication number
CN106011368A
CN106011368A CN201610600307.4A CN201610600307A CN106011368A CN 106011368 A CN106011368 A CN 106011368A CN 201610600307 A CN201610600307 A CN 201610600307A CN 106011368 A CN106011368 A CN 106011368A
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CN
China
Prior art keywords
ball
slag
skimming
gas
pushing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610600307.4A
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Chinese (zh)
Other versions
CN106011368B (en
Inventor
刘洪银
刘超
杨波
刘炳俊
袁鹏举
亓伟伟
郝帅
孙建卫
杨旭
王孝科
江洪广
路峰
王奉县
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Iron and Steel Group Co Ltd SISG
Original Assignee
Shandong Iron and Steel Group Co Ltd SISG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shandong Iron and Steel Group Co Ltd SISG filed Critical Shandong Iron and Steel Group Co Ltd SISG
Priority to CN201610600307.4A priority Critical patent/CN106011368B/en
Publication of CN106011368A publication Critical patent/CN106011368A/en
Application granted granted Critical
Publication of CN106011368B publication Critical patent/CN106011368B/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • C21C5/42Constructional features of converters
    • C21C5/46Details or accessories

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)

Abstract

The invention discloses a slag blocking ball for a converter. The slag blocking ball comprises a ball matrix (1) and a handle (3), wherein the handle is connected with the ball matrix; the surface of the ball matrix (1) is coated with a gas generating layer (2), which is 10cm to 20cm thick, in an enwrapping manner. According to the slag blocking ball for the converter, by adopting a method of coating the surface of the ball matrix of the slag blocking ball with a circle of substance which can generate gas at a high temperature, the effects of decreasing the occurrence rate of the stranding phenomenon of the slag blocking ball and suppressing the phenomenon that slag is entrapped by a tapping vortex are achieved.

Description

A kind of coverter pig skimming ball
Technical field
The invention belongs to technical field of ferrous metallurgy, in particular it relates to a kind of coverter pig skimming ball.
Background technology
Multipair follow-up liquid steel refining is crossed in converter slag and steel product quality all adversely affects, can cause rephosphorization of molten steel, The phenomenons such as refine white slag slagging is slow, inclusion content in melting steel is too much.The slag stopping method that converter current is put during steel has cunning Dynamic tapping hole pushing off the slag, throwing skimming ball pushing off the slag, throwing slag retaining cone pushing off the slag, throwing scum rod pushing off the slag, pneumatic dreg blocking etc., The most most widely used slag stopping method is slip tapping hole pushing off the slag and throws skimming ball pushing off the slag, slip tapping hole pushing off the slag Being applied in big-and-middle-sized converter, slip tapping hole pushing off the slag uses infrared ray identification slag technology, when detecting under beam During slag, and when exceeding the slag inclusion percentage ratio set by system, now provided slide plate closing motion by computer system Signal, is driven by hydraulic system and closes slip tapping hole, although under the minimizing that slip tapping hole pushing off the slag technology can be bigger The quantity of slag, but the eddy current slag in tapping process cannot be suppressed, in order to improve tap, in latter stage of tapping, although bright Know that molten steel eddy current can be involved in vessel slag slag in ladle, but also need to wait molten steel to turn off slip tapping hole after trying one's best out to the greatest extent; Skimming ball, floating plug density in the middle of molten steel and slag, molten steel close to when going out to the greatest extent, skimming ball, floating plug quilt Pour in tapping hole, produce pushing off the slag effect, owing to skimming ball, floating plug are the most stranded, often can not be by accurately Being flushed in tapping hole, pushing off the slag hit rate is low, and about 80%, and skimming ball, floating plug also cannot suppress tapping process In eddy current slag phenomenon.The method of interference eddy current slag is by installing near the furnace bottom position of tapping hole at present The gas blowing devices such as air brick blowing gas or carry out Gas injection in Gas injection pipeline is stretched into converter in stove, Play suppression eddy current or the effect that slag is blown open, but more complicated equipment need to be installed, and equipment is installed and safeguarded Costly.
Summary of the invention
It is an object of the invention to, it is provided that a kind of coverter pig skimming ball, at slag ball matrix surface coating one circle energy The method at high temperature producing the material of gas, can play reduction skimming ball stranded phenomenon incidence rate, suppression tapping whirlpool The effect of stream slag phenomenon.
For reaching above-mentioned purpose, present invention employs following technical scheme:
A kind of coverter pig skimming ball, described skimming ball includes ball matrix 1 and the handle 3 being connected with ball matrix, described The gas genetic horizon 2 that ball matrix 1 surface-coated parcel 10-20cm is thick.
Preferably, described gas genetic horizon 2 is 90% gas generating material and 10% binding agent system by mass percent Become.
It is further preferred that described gas generating material is one or more in calcium carbonate, magnesium carbonate and brium carbonate.
It is further preferred that by mass percentage, described gas generating material includes calcium carbonate 30-40%, carbon Acid magnesium 30-40% and brium carbonate 10-30%.
Preferably, described binding agent is the usual binders used for refractory material such as aluminous cement or aluminic acid silicon cement.
In the present invention, the mixture coating of gas generating material and binding agent is with on ball matrix, and coating thickness is 1-50cm, Coat and be placed on compacting in fetal membrane, can use after demoulding maintenance.
Put steel when closing on end 1-2 minute, artificial or throw skimming ball of the present invention with Slag pushing-off vehicle and enter converter tapping Near Kou, under tapping temperature, it is coated in the CaCO of ball matrix surface3、MgCO3、BaCO3Occur the most 1. The most 3. formula decomposition reaction:
CaCO3=CaO+CO2↑ ①
MgCO3=MgO+CO2↑ ②
BaCO3=BaO+CO2↑ ③
The most 3. the CO of releasing is reacted2Gas rise, drive steel stream rise, formed gush phenomenon, gush phenomenon with Tapping vortex phenomenon cancels each other, and has suppression eddy current and the effect that slag is blown open, and the gas of releasing can give skimming ball Kinetic energy is provided, the incidence rate that skimming ball is stranded can be reduced, improve skimming ball pushing off the slag success rate.
In tapping process, skimming ball of the present invention can coordinate slide plate slag-blocking system to use to suppress eddy current, also Can be used alone, i.e. pushing off the slag suppresses again eddy current.
In order to eliminate skimming ball pushing off the slag, slide plate pushing off the slag and the deficiency of interference eddy-current technique method of blowing, the present invention provides A kind of method at slag ball matrix surface coating gas generating material, both can use cheap skimming ball to carry out Pushing off the slag can provide the most again foam caused by reduction, plays the effect of interference tapping eddy current.
Advantages of the present invention
1, gas generating material releases a large amount of gases, provides kinetic energy to skimming ball, eliminates stranded phenomenon, improves Skimming ball accurately arrives the success rate of tapping hole.
2, gas generating material releases a large amount of gases, drives steel stream to rise, forms gush phenomenon, play suppression Eddy current and the effect that slag is blown open, reduce the lower quantity of slag.
3, compared to complicated furnace bottom gas blowing device or furnace gas injection tube duct device, at skimming ball table Topcoating covers the method low price of gas generating material, and simple and practical, equipment investment is little.
Accompanying drawing explanation
Fig. 1 is the coverter pig skimming ball structure sectional view of the present invention.
Detailed description of the invention
With the drawings and specific embodiments, the present invention is further detailed explanation below.
Embodiment 1
As it is shown in figure 1, a kind of coverter pig skimming ball, described skimming ball includes ball matrix 1 and is connected with ball matrix Handle 3, the gas genetic horizon 2 that described ball matrix 1 surface-coated parcel 1-50cm is thick.
Forming gas genetic horizon at ball matrix surface coating one circle gas generant, gas genetic horizon is by CaCO3、 MgCO3、BaCO3, aluminous cement 30%:30%:30%:10% mixing coating in proportion form, ball base diameter 30cm, gas generating material coating thickness 10cm.Utilize described skimming ball and slide plate pushing off the slag technology with the use of carrying out Pushing off the slag, tap critical end 1 minute time, utilize pushing off the slag dolly to throw pushing off the slag bead of the present invention and enter tapping hole Near, under the condition of high temperature, skimming ball produces gas, has the effect of suppression tapping eddy current.Production practices show, with It is used alone slide plate pushing off the slag technology to compare, uses skimming ball and the slide plate pushing off the slag technology of surface-coated gas generating material Carry out associating pushing off the slag, can averagely reduce the lower quantity of slag about 20% of tapping.
Embodiment 2
As it is shown in figure 1, a kind of coverter pig skimming ball, described skimming ball includes ball matrix 1 and is connected with ball matrix Handle 3, the gas genetic horizon 2 that described ball matrix 1 surface-coated parcel 1-50cm is thick.
Forming gas genetic horizon at ball matrix surface coating one circle gas generant, gas genetic horizon is by CaCO3、 MgCO3、BaCO3, the 30%:40%:20%:10% mixing coating in proportion of aluminic acid silicon cement form, ball base diameter 35cm, gas generating material coating thickness 15cm.Utilize skimming ball of the present invention to carry out pushing off the slag, face in tapping When boundary terminates 1 minute, utilize pushing off the slag dolly to throw described pushing off the slag bead and enter near tapping hole, under the condition of high temperature, Producing gas, have the effect of suppression eddy current, the gas of generation provides kinetic energy to skimming ball, can eliminate stranded phenomenon. Production practices show, compared with former skimming ball, use the skimming ball of surface-coated gas generating material can improve pushing off the slag Success rate 10%, reduces the lower quantity of slag about 30% of tapping.
Embodiment 3
As it is shown in figure 1, a kind of coverter pig skimming ball, described skimming ball includes ball matrix 1 and is connected with ball matrix Handle 3, the gas genetic horizon 2 that described ball matrix 1 surface-coated parcel 1-50cm is thick.
Forming gas genetic horizon at ball matrix surface coating one circle gas generant, gas genetic horizon is by CaCO3、 MgCO3、BaCO3, the 40%:40%:10%:10% mixing coating in proportion of aluminic acid silicon cement form, ball base diameter 40cm, gas generating material coating thickness 20cm.Utilize skimming ball of the present invention to carry out pushing off the slag, face in tapping When boundary terminates 1 minute, utilize pushing off the slag dolly to throw described pushing off the slag bead and enter near tapping hole, under the condition of high temperature, Producing gas, have the effect of suppression eddy current, the gas of generation provides kinetic energy to skimming ball, can eliminate stranded phenomenon. Production practices show, compared with former skimming ball, use the skimming ball of surface-coated gas generating material can improve pushing off the slag Success rate 10%, reduces the lower quantity of slag about 40% of tapping.
It should be noted last that, above example is only in order to illustrate technical scheme and unrestricted.Although With reference to embodiment, the present invention is described in detail, it will be apparent to an ordinarily skilled person in the art that the present invention Technical scheme modify or equivalent, without departure from the spirit and scope of technical solution of the present invention, it is equal Should contain in the middle of scope of the presently claimed invention.

Claims (5)

1. a coverter pig skimming ball, described skimming ball includes ball matrix (1) and the handle being connected with ball matrix (3), it is characterised in that the gas genetic horizon (2) that described ball matrix (1) surface-coated parcel 10-20cm is thick.
A kind of coverter pig skimming ball the most according to claim 1, it is characterised in that described gas genetic horizon (2) It is 90% gas generating material by mass percent and 10% binding agent is made.
A kind of coverter pig skimming ball the most according to claim 2, it is characterised in that described gas generating material For one or more in calcium carbonate, magnesium carbonate and brium carbonate.
A kind of coverter pig skimming ball the most according to claim 3, it is characterised in that by mass percentage, Described gas generating material includes calcium carbonate 30-40%, magnesium carbonate 30-40% and brium carbonate 10-30%.
A kind of coverter pig skimming ball the most according to claim 2, it is characterised in that described binding agent is aluminic acid Calcium cement or aluminic acid silicon cement.
CN201610600307.4A 2016-07-27 2016-07-27 A kind of coverter pig skimming ball Active CN106011368B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201610600307.4A CN106011368B (en) 2016-07-27 2016-07-27 A kind of coverter pig skimming ball

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CN106011368B CN106011368B (en) 2018-02-16

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117845011A (en) * 2023-12-22 2024-04-09 鞍钢股份有限公司 Converter tapping slag blocking device and method

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5831021A (en) * 1981-08-19 1983-02-23 Kawasaki Steel Corp Slag outflow preventing method in case of charging
CN2522427Y (en) * 2002-02-01 2002-11-27 宁开敏 Ball-shape dregs baffle device
CN2887885Y (en) * 2006-04-30 2007-04-11 周平 Full homogeneous skimming ball for making steel in converter
CN201406448Y (en) * 2009-05-19 2010-02-17 武汉武钢北湖冶金材料有限公司 Homogenous slag-stopping ball used for tapping hole of converter
CN202954062U (en) * 2012-11-30 2013-05-29 鞍钢股份有限公司 Slag stopper
CN103691924A (en) * 2013-12-17 2014-04-02 谢驰中 Slag blocking body capable of avoiding casting slag inclusion and manufacturing method thereof
CN204111796U (en) * 2014-09-02 2015-01-21 辽宁科技大学 A kind of slag-blocking apparatus of coverter pig
CN105215342A (en) * 2015-09-30 2016-01-06 江苏永钢集团有限公司 A kind of for preventing the skimming ball of large bag vortex slag
CN205893313U (en) * 2016-07-27 2017-01-18 山东钢铁股份有限公司 Converter is with keeping off slag ball

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5831021A (en) * 1981-08-19 1983-02-23 Kawasaki Steel Corp Slag outflow preventing method in case of charging
CN2522427Y (en) * 2002-02-01 2002-11-27 宁开敏 Ball-shape dregs baffle device
CN2887885Y (en) * 2006-04-30 2007-04-11 周平 Full homogeneous skimming ball for making steel in converter
CN201406448Y (en) * 2009-05-19 2010-02-17 武汉武钢北湖冶金材料有限公司 Homogenous slag-stopping ball used for tapping hole of converter
CN202954062U (en) * 2012-11-30 2013-05-29 鞍钢股份有限公司 Slag stopper
CN103691924A (en) * 2013-12-17 2014-04-02 谢驰中 Slag blocking body capable of avoiding casting slag inclusion and manufacturing method thereof
CN204111796U (en) * 2014-09-02 2015-01-21 辽宁科技大学 A kind of slag-blocking apparatus of coverter pig
CN105215342A (en) * 2015-09-30 2016-01-06 江苏永钢集团有限公司 A kind of for preventing the skimming ball of large bag vortex slag
CN205893313U (en) * 2016-07-27 2017-01-18 山东钢铁股份有限公司 Converter is with keeping off slag ball

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117845011A (en) * 2023-12-22 2024-04-09 鞍钢股份有限公司 Converter tapping slag blocking device and method

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