CN106007739A - Andalusite-based refractory brick for gas generator - Google Patents
Andalusite-based refractory brick for gas generator Download PDFInfo
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- CN106007739A CN106007739A CN201610307419.0A CN201610307419A CN106007739A CN 106007739 A CN106007739 A CN 106007739A CN 201610307419 A CN201610307419 A CN 201610307419A CN 106007739 A CN106007739 A CN 106007739A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/66—Monolithic refractories or refractory mortars, including those whether or not containing clay
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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- C—CHEMISTRY; METALLURGY
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
- C04B2235/3222—Aluminates other than alumino-silicates, e.g. spinel (MgAl2O4)
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3241—Chromium oxides, chromates, or oxide-forming salts thereof
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
Abstract
The invention relates to the field of gas generators, in particular to an andalusite-based refractory brick for a gas generator. The refractory brick is prepared from 35% of andalusite, 20% of bauxite, 20% of clay, 10% of saw dust, 5% of tabular corundum, 2% of silica powder, 2% of aluminum micro powder, 1% of cyanite, 0.5% of calcium aluminate, 2% of an additive and 1.5% of a coagulation accelerator. The preparing process of the refractory brick comprises the following first step of smashing, the second step of mixing, the third step of aging, the fourth step of sintering, the fifth step of heat preserving, the sixth step of forming and the seventh step of curing. The refractory brick is easy to prepare, controllable in cost and good in high-temperature resisting performance; besides, due to the large dosage of andalusite and the inherent characteristics of andalusite, the refractory brick can be higher in heat shock resistance, slag resistance and anti-corrosion resistance compared with traditional refractory bricks.
Description
Technical field
The present invention relates to gas generator field, a kind of gas generator refractory brick based on andalusite.
Background technology
Gas generator is the production that coal is converted into imflammable gas coal gas (being mainly composed of CO, H2, CH4 etc.)
Equipment, part gas generator uses refractory brick to pile up and forms.Its operation principle is: sieved by the coal meeting gasifying process index
After choosing, firing machine join in gas stove, blast self-produced steam with air gas mixture as gasifying agent from furnace bottom.Coal exists
Through physics, chemical reaction in stove, generating imflammable gas, gas in upper segment is through cyclone oil remover, electric trapper filtered tar. hypomere
Coal gas, through cyclone dust extractor dust out, is transported to user after mixing and uses.
Refractory brick is called for short firebrick.The refractory material being fired into refractory clay or other refractory raw materials.Faint yellow or band brown.Energy
The high temperature of resistance to 1580 DEG C 1770 DEG C.Also firebrick it is.There is the refractory material of definite shape and size.By process of preparing
Division can be divided into burnt brick, unburned brick, fused cast refractories (molten-cast brick), refratory insulating brick;Standard type can be divided into by shape and size
Brick, common brick, special shaped brick etc..Can be used as building kiln and the high temperature construction material of various Thermal Equipment and structural material, and
At high temperature it is amenable to various physicochemical change and mechanism.Such as chamotte brick, high-alumina brick, silica brick, magnesia brick etc..
Andalusite (Andalusite) is a kind of aluminium silicate mineral, and it is manufacture refractory material and porcelain in spark plug former
Material.Industrial utilize andalusite, mainly take its resistant to elevated temperatures characteristic.After andalusite is heated to 1350 DEG C at ambient pressure, open
Begin to change into the acicular mullite parallel with mother crystal.Mullite crystal is the form that aluminosilicate is the most stable under high temperature action,
Its theoretical yield is 87.64%.
Andalusite, during thermal conversion becomes mullite, can form good mullite network, volumetric expansion about 4%.This
A kind of irreversible crystal transformation, Once transformed, then there is higher fire resistance, refractoriness up to more than 1800 DEG C, and
Resistance to suddenly cold and hot, mechanical strength is big, and heat shock resistance power is strong, and resistance to slag is strong, and loading inversion point is high, and it is steady to have high chemistry
Qualitative (not even being dissolved in Fluohydric acid .) and extremely strong resistance to chemical corrosion.
Summary of the invention
For the problems of the prior art, present invention is primarily targeted at, promote the fire resistant quality of existing refractory brick, improve resistance to
Firebrick service life, so that refractory brick has more the value in industry.
The object of the invention to solve the technical problems realizes by the following technical solutions.The one proposed according to the present invention
Gas generator refractory brick based on andalusite, its formula consists of: andalusite 30%-50%, bauxite 20%-35%, clay
15%-25%, wood flour 10%-20%, plate diamond spar 5%-10%, silicon powder 1%-6%, alumina powder 1%-6%, kyanite 1%-5%,
Calcium aluminate 0.5%-2%, additive 1%-5%, coagulant 0.5%-2%.
Preferably, its formula consists of: andalusite 35%, bauxite 20%, clay 20%, wood flour 10%, plate diamond spar 5%,
Silicon powder 2%, alumina powder 2%, kyanite 1%, calcium aluminate 0.5%, additive 2%, coagulant 1.5%.
Preferably, described additive is Cr2O3, and described coagulant is sodium aluminate.
A kind of gas generator refractory brick based on andalusite of the present invention, its preparation process comprises the following steps:
(1) pulverize: the components in certain proportion in above-mentioned formula is configured, use double-roll crusher above-mentioned formula will to remove andalusite and wood
Material outside bits mixes and pulverizes, and then wears into mixed-powder with ball mill and sieves, and mixed-powder fineness is 205 mesh,
Wood flour Raymond machine is levigate and sieves, and wood flour fineness is less than 1mm, and andalusite double-roll crusher is individually pulverized and enters ball mill
Pulverizing powder also sieves, and andalusite fineness of powder is 86 mesh;
(2) batch mixing: use Secondary mixing, above-mentioned mixed-powder, wood flour and andalusite powder are together placed in blender,
Mixing time is 2-3min for the first time, and rotating speed is 80-120r/min, is subsequently adding the water of 10%-12% and is allowed to be mixed into plastic
Shape, mixing time is 4-5min for the second time, and rotating speed is 150-210r/min;
(3) ageing mixture: ageing mixture is carried out in ageing mixture storehouse, the ageing mixture time is 10h, and ageing mixture equipment uses reversible moving formula distributing device;
(4) sintering: firing temperature uses 1400-1600 DEG C;
(5) insulation: temperature retention time is 4-6h;
(6) molding: molding uses semi-hard plastic double-stage vacuum extruding machine, and briquetting pressure is 10MPa, a size of 240mm × 115mm
× 90mm or 390mm × 190mm × 190mm;
(7) maintenance: at room temperature maintenance 48h.
Preferably, firing temperature uses 1450-1500 DEG C, and optimum temperature is 1500 DEG C.
By technique scheme, the refractory brick of the present invention at least has the advantage that
The refractory brick of the present invention is simple to manufacture, and cost is controlled, and resistance to elevated temperatures is excellent, and making in a large number due to andalusite of the present invention
With, and the inherent character of andalusite itself so that the thermal-shock resistance of refractory brick of the present invention, resistance to slag, corrosion resistance relatively pass
System refractory brick is the highest.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below in conjunction with tool
Body embodiment, is expanded on further the present invention.
Embodiment 1
A kind of gas generator refractory brick based on andalusite of the present invention, its formula consists of: andalusite 35%, aluminum
Alumina 20%, clay 20%, wood flour 10%, plate diamond spar 5%, silicon powder 2%, alumina powder 2%, kyanite 1%, aluminic acid
Calcium 0.5%, additive 2%, coagulant 1.5%.
Preferably, described additive is Cr2O3, and described coagulant is sodium aluminate.
A kind of gas generator refractory brick based on andalusite of the present invention, its preparation process comprises the following steps:
(1) pulverize: the components in certain proportion in above-mentioned formula is configured, use double-roll crusher above-mentioned formula will to remove andalusite and wood
Material outside bits mixes and pulverizes, and then wears into mixed-powder with ball mill and sieves, and mixed-powder fineness is 205 mesh,
Wood flour Raymond machine is levigate and sieves, and wood flour fineness is less than 1mm, and andalusite double-roll crusher is individually pulverized and enters ball mill
Pulverizing powder also sieves, and andalusite fineness of powder is 86 mesh;
(2) batch mixing: use Secondary mixing, above-mentioned mixed-powder, wood flour and andalusite powder are together placed in blender,
Mixing time is 2-3min for the first time, and rotating speed is 80-120r/min, is subsequently adding the water of 10%-12% and is allowed to be mixed into plastic
Shape, mixing time is 4-5min for the second time, and rotating speed is 150-210r/min;
(3) ageing mixture: ageing mixture is carried out in ageing mixture storehouse, the ageing mixture time is 10h, and ageing mixture equipment uses reversible moving formula distributing device;
(4) sintering: firing temperature uses 1400-1600 DEG C;
(5) insulation: temperature retention time is 4-6h;
(6) molding: molding uses semi-hard plastic double-stage vacuum extruding machine, and briquetting pressure is 10MPa, a size of 240mm × 115mm
× 90mm or 390mm × 190mm × 190mm;
(7) maintenance: at room temperature maintenance 48h.
Preferably, firing temperature uses 1450-1500 DEG C, and optimum temperature is 1500 DEG C.
The ultimate principle of the present invention, principal character and advantage have more than been shown and described.Skilled person will appreciate that of the industry,
The present invention is not restricted to the described embodiments, the principle that the present invention is simply described of the description in above-mentioned embodiment and description,
Without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, and these changes and improvements all fall
Enter in the scope of protection of present invention.Claimed scope is defined by appending claims and equivalent thereof.
Claims (5)
1. a gas generator refractory brick based on andalusite, it is characterised in that: its formula consists of: andalusite 30%-50%,
Bauxite 20%-35%, clay 15%-25%, wood flour 10%-20%, plate diamond spar 5%-10%, silicon powder 1%-6%, aluminium oxide are micro-
Powder 1%-6%, kyanite 1%-5%, calcium aluminate 0.5%-2%, additive 1%-5%, coagulant 0.5%-2%.
A kind of gas generator refractory brick based on andalusite the most according to claim 1, it is characterised in that: its formula
Consist of: andalusite 35%, bauxite 20%, clay 20%, wood flour 10%, plate diamond spar 5%, silicon powder 2%, aluminium oxide are micro-
Powder 2%, kyanite 1%, calcium aluminate 0.5%, additive 2%, coagulant 1.5%.
A kind of gas generator refractory brick based on andalusite the most according to claim 1, it is characterised in that: described
Additive is Cr2O3, and described coagulant is sodium aluminate.
A kind of gas generator refractory brick based on andalusite the most according to claim 1 and 2, it is characterised in that: system
Standby process comprises the following steps:
(1) pulverize: the components in certain proportion in above-mentioned formula is configured, use double-roll crusher above-mentioned formula will to remove andalusite and wood
Material outside bits mixes and pulverizes, and then wears into mixed-powder with ball mill and sieves, and mixed-powder fineness is 205 mesh,
Wood flour Raymond machine is levigate and sieves, and wood flour fineness is less than 1mm, and andalusite double-roll crusher is individually pulverized and enters ball mill
Pulverizing powder also sieves, and andalusite fineness of powder is 86 mesh;
(2) batch mixing: use Secondary mixing, above-mentioned mixed-powder, wood flour and andalusite powder are together placed in blender,
Mixing time is 2-3min for the first time, and rotating speed is 80-120r/min, is subsequently adding the water of 10%-12% and is allowed to be mixed into plastic
Shape, mixing time is 4-5min for the second time, and rotating speed is 150-210r/min;
(3) ageing mixture: ageing mixture is carried out in ageing mixture storehouse, the ageing mixture time is 10h, and ageing mixture equipment uses reversible moving formula distributing device;
(4) sintering: firing temperature uses 1400-1600 DEG C;
(5) insulation: temperature retention time is 4-6h;
(6) molding: molding uses semi-hard plastic double-stage vacuum extruding machine, and briquetting pressure is 10MPa, a size of 240mm × 115mm
× 90mm or 390mm × 190mm × 190mm;
(7) maintenance: at room temperature maintenance 48h.
A kind of gas generator refractory brick based on andalusite the most according to claim 4, it is characterised in that: burn till temperature
Degree uses 1450-1500 DEG C, and optimum temperature is 1500 DEG C.
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CN201610307419.0A CN106007739A (en) | 2016-05-11 | 2016-05-11 | Andalusite-based refractory brick for gas generator |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101045635A (en) * | 2007-03-22 | 2007-10-03 | 武汉科技大学 | Ceramic Al203SiC refractory and preparation method thereof |
CN104446568A (en) * | 2014-12-15 | 2015-03-25 | 山东鲁阳股份有限公司 | Fireproof insulating brick and preparation method thereof |
CN105367096A (en) * | 2015-11-25 | 2016-03-02 | 南京联合荣大工程材料有限责任公司 | Refractory raw material and blast furnace press-in material containing same |
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2016
- 2016-05-11 CN CN201610307419.0A patent/CN106007739A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101045635A (en) * | 2007-03-22 | 2007-10-03 | 武汉科技大学 | Ceramic Al203SiC refractory and preparation method thereof |
CN104446568A (en) * | 2014-12-15 | 2015-03-25 | 山东鲁阳股份有限公司 | Fireproof insulating brick and preparation method thereof |
CN105367096A (en) * | 2015-11-25 | 2016-03-02 | 南京联合荣大工程材料有限责任公司 | Refractory raw material and blast furnace press-in material containing same |
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