CN106007500A - Rigid-flexible protecting mortar for nuclear power plants - Google Patents

Rigid-flexible protecting mortar for nuclear power plants Download PDF

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Publication number
CN106007500A
CN106007500A CN201610329488.1A CN201610329488A CN106007500A CN 106007500 A CN106007500 A CN 106007500A CN 201610329488 A CN201610329488 A CN 201610329488A CN 106007500 A CN106007500 A CN 106007500A
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China
Prior art keywords
parts
powder
nuclear power
mortar
hard
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CN201610329488.1A
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CN106007500B (en
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刘连良
丁逊
刘益辉
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Yiyang Jinyu Building Material Technology Co Ltd
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Yiyang Jinyu Building Material Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00862Uses not provided for elsewhere in C04B2111/00 for nuclear applications, e.g. ray-absorbing concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses rigid-flexible protecting mortar for nuclear power plants and a preparation method of the rigid-flexible protecting mortar and belongs to the technical field of anti-radiation mortar. The rigid-flexible protecting mortar is prepared from the following components in parts by weight: 5-15 parts of cement, 6-10 parts of mineral powder, 30-50 parts of river sand, 3-5 parts of dispersed latex powder, 6-10 parts of wood fiber powder, 8-12 parts of nano-lead particles and 4-8 parts of epoxy resin powder. The invention aims at providing the rigid-flexible protecting mortar for the nuclear power plants and the preparation method of the rigid-flexible protecting mortar. The rigid-flexible protecting mortar has the characteristics of being long in service life, good in rigid-flexible property, high-temperature structure stability, and anti-radiation property, corrosion-resistant, wear-resistant and capable of avoiding layering, segregation and sagging and preventing nuclear leakage, thereby improving the security level of the nuclear power plants.

Description

A kind of hard and soft protection mortar for nuclear power station
Technical field
The invention belongs to anti-radiation mortar technical field, a kind of hard and soft for nuclear power station is prevented Protect mortar.
Background technology
Nuclear power is the energy of a kind of cleaning, highly efficient and relatively safety.Nuclear power station generation nuclear leakage accident, Refer to that the radioactive substance in nuclear reactor leaks, cause environmental pollution and make the public by radiation hazradial bundle. Therefore, grasp knowledge of some reply nuclear leakage to provide against any misfortune or necessary.The feelings that nuclear leakage is general Condition shows radioprotective to the impact of personnel, also referred to as radioactive substance, and radioactive substance is with ripple or microgranule A kind of energy that form is launched just makes radioprotective, nuclear explosion and nuclear accident have radioprotective.It has a, b With tri-kinds of forms of radiation of y.As long as a radiation just can be blocked with a piece of paper, but in suction body, harm is big;b Radiation is high-velocity electrons, and after skin is stained with, burn is obvious;Y radiation is similar with X-ray, can penetrate human body And building, damage effect distance is remote.
It is many that universe, nature can produce radioactive material, but harm is the biggest, only nuclear blast Personnel could be caused injures and deaths by fried or nuclear power plant accident leakage radioactive substance on a large scale.Radioactivity Material can be sucked by breathing, and skin wound and digestive tract are absorbed into internal, causes interior radiation, y spoke Penetrate and can penetrate certain distance and be absorbed by organisms, make personnel be injured by external exposure.Interior external exposure is formed and puts The symptom penetrating disease has: fatigue, giddy, insomnia, skin rubefaction, ulcer, hemorrhage, alopecia, white blood Sick, vomit, diarrhoea etc..The most also can increase cancer, distortion, heritability pathological changes incidence rate, impact The health of several generations.Generally, the emittance that health accepts is the most, and its radiation sickness symptom is the most serious, Carcinogenic, teratogenesis risk is the biggest.
Existing anti-nuclear radiation mortar be by cement-based gelling material, heavy aggregate, containing light element aggregate and Additives etc. form, the anti-material of core of the most complementary construction after stirring with water.But existing anti-core Radiation mortar there is problems in that 1, alpha ray shield poor performance, and radioactive substance is directly through body of wall pair Biology works the mischief;2, water resistance is poor, perishable, and the time one can produce nuclear leakage;3, no Tool flexibility, easy to crack;4, the phenomenons such as layering, isolation and sagging are easily produced.It it is more than the anti-spoke of nuclear power Penetrate mortar technical staff's urgent problem.
Summary of the invention
It is an object of the invention to for problem above, it is provided that a kind of hard and soft for nuclear power station protects sand Slurry, service life is long, has hard and soft characteristic, has a good hard and soft characteristic, not stratified, do not isolate, Under sagging, its condition of high temperature, structural stability is not good, be provided simultaneously with the features such as corrosion-resistant, wear-resistant, Shielding property is good, prevents nuclear leakage, improves the safe class of nuclear power station.
For realizing object above, the technical solution used in the present invention is: a kind of hard and soft for nuclear power station Property protection mortar, is grouped into by the one-tenth of following parts by weight: cement 5~15 parts, breeze 6~10 parts, River sand 30~50 parts, dispersed latex powder 3~5 parts, wood fiber powder 6~10 parts, nanometer lead granule 8~ 12 parts, epoxy powder 4~8 parts.
Preferably, a kind of hard and soft protection mortar for nuclear power station, by the composition of following parts by weight Composition: cement 5 parts, breeze 6 parts, river sand 30 parts, dispersed latex powder 3 parts, wood fiber powder 6 Part, nanometer lead granule 8 parts, epoxy powder 4 parts.
Preferably, a kind of hard and soft protection mortar for nuclear power station, by the composition of following parts by weight Composition: cement 10 parts, breeze 8 parts, river sand 40 parts, dispersed latex powder 4 parts, wood fiber powder 8 Part, nanometer lead granule 10 parts, epoxy powder 6 parts.
Preferably, a kind of hard and soft protection mortar for nuclear power station, by the composition of following parts by weight Composition: cement 15 parts, breeze 10 parts, river sand 50 parts, dispersed latex powder 5 parts, wood fiber powder 10 parts, nanometer lead granule 12 parts, epoxy powder 8 parts.
Preferably, described wood fibre powder particles is 10~20 mesh.
Preferably, described epoxy powder granule is 20~40 mesh.
Preferably, described nanometer lead granule is hollow ball structure.
Preferably, described dispersed latex powder is high polymer polyacrylamide.
The preparation method of a kind of hard and soft protection mortar for nuclear power station, comprises the following steps: by water Mud, breeze, river sand carry out physical property with nanometer lead granule and mix, add dispersed latex powder, stirring 10~ 15 minutes, add wood fiber powder and epoxy powder, continue stirring 10~15 minutes, obtain just Flexible protective mortar.
1, beneficial effects of the present invention: use the nanometer lead particulate component of hollow ball shape, there is anti-spoke Penetrating effect, its density is high, light weight, Stability Analysis of Structures, and high-temperature stable is corrosion-resistant, wear-resistant, energy Enough having more preferable dispersion effect, the mortar quality obtained is more uniform, has rigidity, is difficult to split.
2, utilizing dispersed latex powder, wood fiber powder and epoxy powder to obtain composition, regulation mortar sticks Knot degree, makes mortar possess flexibility;Dry powder and mortar is made to have superpower adhesive force, flexible.
Above material combination together, interacts, makes one high temperature resistance anti-radiation mortar of the present invention have Good hard and soft characteristic, not stratified, do not isolate, not under sagging, its condition of high temperature structural stability good, Being provided simultaneously with corrosion-resistant, the feature such as wear-resistant, shielding property is good, improves the peace of anti-radiation mortar Congruence level.
Detailed description of the invention
The most further the present invention is made explaination.
Embodiment 1:
A kind of hard and soft protection mortar for nuclear power station, is grouped into by the one-tenth of following parts by weight: water 5 parts of mud, breeze 6 parts, river sand 30 parts, dispersed latex powder 3 parts, wood fiber powder 6 parts, nanometer Lead granule 8 parts, epoxy powder 4 parts.
In the case of compare Jia, described wood fibre powder particles is 10~20 mesh.
In the case of compare Jia, described epoxy powder granule is 20~40 mesh.
In the case of compare Jia, described nanometer lead granule is hollow ball structure.
In the case of compare Jia, described dispersed latex powder is high polymer polyacrylamide.
The preparation method of a kind of hard and soft protection mortar for nuclear power station, comprises the following steps: by water Mud, breeze, river sand carry out physical property with nanometer lead granule and mix, and add dispersed latex powder, stir 10 Minute, add wood fiber powder and epoxy powder, continue stirring 10 minutes, obtain hard and soft and prevent Protect mortar.
Embodiment 2:
A kind of hard and soft protection mortar for nuclear power station, is grouped into by the one-tenth of following parts by weight: water 10 parts of mud, breeze 8 parts, river sand 40 parts, dispersed latex powder 4 parts, wood fiber powder 8 parts, receive Rice lead granule 10 parts, epoxy powder 6 parts.
In the case of compare Jia, described wood fibre powder particles is 10~20 mesh.
In the case of compare Jia, described epoxy powder granule is 20~40 mesh.
In the case of compare Jia, described nanometer lead granule is hollow ball structure.
In the case of compare Jia, described dispersed latex powder is high polymer polyacrylamide.
The preparation method of a kind of hard and soft protection mortar for nuclear power station, comprises the following steps: by water Mud, breeze, river sand carry out physical property with nanometer lead granule and mix, and add dispersed latex powder, stir 13 Minute, add wood fiber powder and epoxy powder, continue stirring 13 minutes, obtain hard and soft and prevent Protect mortar.
Embodiment 3:
A kind of hard and soft protection mortar for nuclear power station, is grouped into by the one-tenth of following parts by weight: water 15 parts of mud, breeze 10 parts, river sand 50 parts, dispersed latex powder 5 parts, wood fiber powder 10 parts, Nanometer lead granule 12 parts, epoxy powder 8 parts.
In the case of compare Jia, described wood fibre powder particles is 10~20 mesh.
In the case of compare Jia, described epoxy powder granule is 20~40 mesh.
In the case of compare Jia, described nanometer lead granule is hollow ball structure.
In the case of compare Jia, described dispersed latex powder is high polymer polyacrylamide.
The preparation method of a kind of hard and soft protection mortar for nuclear power station, comprises the following steps: by water Mud, breeze, river sand carry out physical property with nanometer lead granule and mix, and add dispersed latex powder, stir 15 Minute, add wood fiber powder and epoxy powder, continue stirring 15 minutes, obtain hard and soft and prevent Protect mortar.
A kind of hard and soft protection mortar for nuclear power station of the present invention adds water after mixing and stirring and i.e. can be used directly, It compared with prior art has the advantage that and utilizes nanometer lead particulate component, due to the density ratio of lead Relatively big, radiation-proof effect is good, stability is strong, and the nanometer lead of hollow ball-shape can have more preferable dispersion effect, The mortar quality obtained is more uniform, have the features such as corrosion-resistant, high-low temperature resistant, deformation rate are little, improves The cracking resistance of protection mortar, utilizes dispersed latex powder, wood fiber powder and epoxy resin powder simultaneously Last composition, regulates mortar degree of cohering, and makes mortar possess flexibility;Raw material is combined, interact, One high temperature resistance anti-radiation mortar of the present invention is made to have a good hard and soft characteristic, not stratified, do not isolate, no Under sagging, its condition of high temperature, structural stability is good, be provided simultaneously with the features such as corrosion-resistant, wear-resistant, anti- Radiance is good, improves the safe class of anti-radiation mortar.
It should be noted that in this article, term " include ", " comprising " or its any other Variant is intended to comprising of nonexcludability so that include the process of a series of key element, method, Which key element article or equipment not only include, but also include other key elements being not expressly set out, Or also include the key element intrinsic for this process, method, article or equipment.
Above a kind of hard and soft protection mortar for nuclear power station provided by the present invention is carried out in detail Introducing, principle and embodiment to the present invention are set forth herein, the explanation of above example It is only intended to help to understand method and the core concept thereof of the present invention;General simultaneously for this area Technical staff, according to the thought of the present invention, the most all can change Part, in sum, this specification content should not be construed as limitation of the present invention.

Claims (9)

1. the hard and soft protection mortar for nuclear power station, it is characterised in that by the one-tenth of following parts by weight It is grouped into: cement 5~15 parts, breeze 6~10 parts, river sand 30~50 parts, dispersed latex powder 3~5 Part, wood fiber powder 6~10 parts, nanometer lead granule 8~12 parts, epoxy powder 4~8 parts.
A kind of hard and soft protection mortar for nuclear power station the most according to claim 1, it is characterised in that It is grouped into by the one-tenth of following parts by weight: cement 5 parts, breeze 6 parts, river sand 30 parts, dispersed latex 3 parts of powder, wood fiber powder 6 parts, nanometer lead granule 8 parts, epoxy powder 4 parts.
A kind of hard and soft protection mortar for nuclear power station the most according to claim 1, it is characterised in that It is grouped into by the one-tenth of following parts by weight: cement 10 parts, breeze 8 parts, river sand 40 parts, dispersed latex 4 parts of powder, wood fiber powder 8 parts, nanometer lead granule 10 parts, epoxy powder 6 parts.
A kind of hard and soft protection mortar for nuclear power station the most according to claim 1, it is characterised in that It is grouped into by the one-tenth of following parts by weight: cement 15 parts, breeze 10 parts, river sand 50 parts, dispersion breast Rubber powder 5 parts, wood fiber powder 10 parts, nanometer lead granule 12 parts, epoxy powder 8 parts.
5. according to a kind of hard and soft protection mortar for nuclear power station described in any one in claim 1-4, It is characterized in that, described wood fibre powder particles is 10~20 mesh.
6. according to a kind of hard and soft protection mortar for nuclear power station described in any one in claim 1-4, It is characterized in that, described epoxy powder granule is 20~40 mesh.
7. according to a kind of hard and soft protection mortar for nuclear power station described in any one in claim 1-4, It is characterized in that, described nanometer lead granule is hollow ball structure.
8. according to a kind of hard and soft protection mortar for nuclear power station described in any one in claim 1-4, It is characterized in that, described dispersed latex powder is high polymer polyacrylamide.
9. according to a kind of hard and soft protection mortar for nuclear power station described in any one in claim 1-8 Preparation method, it is characterised in that comprise the following steps: by cement, breeze, river sand and nanometer lead Grain carries out physical property mixing, adds dispersed latex powder, stirs 10~15 minutes, adds wood fiber powder With epoxy powder, continue stirring 10~15 minutes, obtain hard and soft protection mortar.
CN201610329488.1A 2016-05-18 2016-05-18 A kind of hard and soft protection mortar for nuclear power station Active CN106007500B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106587769A (en) * 2016-12-05 2017-04-26 益阳金宙建材科技有限公司 Mortar used for quick leaking stoppage of nuclear power station accident cooling water pipe leakage
CN106782723A (en) * 2016-12-05 2017-05-31 益阳金宙建材科技有限公司 A kind of anti-radiation mortar for isolating nuclear leakage
CN109133764A (en) * 2018-08-22 2019-01-04 益阳金宙建材科技有限公司 A kind of fast dry type tunnel mortar and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN1510695A (en) * 2002-12-20 2004-07-07 张式琦 Materials for preventing ionizing radiation
KR20120024917A (en) * 2012-02-15 2012-03-14 한일원자력(주) Radioactive ray shield block
CN103377739A (en) * 2012-04-18 2013-10-30 苏州麦奇新型材料有限公司 Nuclear radiation proofing mortar
CN105482225A (en) * 2015-12-30 2016-04-13 上海师范大学 Nuclear radiation prevention rare earth composite material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1510695A (en) * 2002-12-20 2004-07-07 张式琦 Materials for preventing ionizing radiation
KR20120024917A (en) * 2012-02-15 2012-03-14 한일원자력(주) Radioactive ray shield block
CN103377739A (en) * 2012-04-18 2013-10-30 苏州麦奇新型材料有限公司 Nuclear radiation proofing mortar
CN105482225A (en) * 2015-12-30 2016-04-13 上海师范大学 Nuclear radiation prevention rare earth composite material and preparation method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106587769A (en) * 2016-12-05 2017-04-26 益阳金宙建材科技有限公司 Mortar used for quick leaking stoppage of nuclear power station accident cooling water pipe leakage
CN106782723A (en) * 2016-12-05 2017-05-31 益阳金宙建材科技有限公司 A kind of anti-radiation mortar for isolating nuclear leakage
CN106782723B (en) * 2016-12-05 2018-06-01 益阳金宙建材科技有限公司 A kind of anti-radiation mortar for being used to isolate nuclear leakage
CN106587769B (en) * 2016-12-05 2021-05-28 益阳金宙建材科技有限公司 Rapid leaking stoppage mortar for water leakage of emergency cooling water pipeline of nuclear power station
CN109133764A (en) * 2018-08-22 2019-01-04 益阳金宙建材科技有限公司 A kind of fast dry type tunnel mortar and preparation method thereof

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Denomination of invention: Rigid-flexible protecting mortar for nuclear power plants

Effective date of registration: 20180606

Granted publication date: 20171114

Pledgee: Taojiang branch of the Industrial Commercial Bank of China Ltd

Pledgor: Yiyang Jinyu Building Material Technology Co., Ltd.

Registration number: 2018430000034

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Date of cancellation: 20220412

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Pledgee: Taojiang branch of the Industrial Commercial Bank of China Ltd.

Pledgor: YIYANG JINYU BUILDING MATERIAL TECHNOLOGY Co.,Ltd.

Registration number: 2018430000034