CN106001395A - Coating for hub forming mold and preparation method thereof - Google Patents

Coating for hub forming mold and preparation method thereof Download PDF

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Publication number
CN106001395A
CN106001395A CN201610465900.2A CN201610465900A CN106001395A CN 106001395 A CN106001395 A CN 106001395A CN 201610465900 A CN201610465900 A CN 201610465900A CN 106001395 A CN106001395 A CN 106001395A
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CN
China
Prior art keywords
consumption
preparation
weight portion
coating
mixed liquor
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Pending
Application number
CN201610465900.2A
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Chinese (zh)
Inventor
倪勤松
王军
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WUHU YELLOW SWALLOW INDUSTRY Co Ltd
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WUHU YELLOW SWALLOW INDUSTRY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by WUHU YELLOW SWALLOW INDUSTRY Co Ltd filed Critical WUHU YELLOW SWALLOW INDUSTRY Co Ltd
Priority to CN201610465900.2A priority Critical patent/CN106001395A/en
Publication of CN106001395A publication Critical patent/CN106001395A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C3/00Selection of compositions for coating the surfaces of moulds, cores, or patterns

Abstract

The invention discloses coating for a hub forming mold and a preparation method thereof. The preparation method of the coating comprises the steps that sodium alginate, sodium carboxymethyl cellulose, aluminum phosphate, soluble silicate, phenol formaldehyde resin and water are stirred and mixed, so that mixed liquor M is formed; after being subjected to still standing for 2-4 hours, the mixed liquor M is added with refractory powder and stirred, and then mixed liquor N is obtained; and the mixed liquor N is put in a sealed environment to be subjected to aging treatment, and the coating for the hub forming mold is obtained. The problems that the defects of pores, sand holes and the like of a casting occur due to the fact that the volatility of traditional coating is high, meanwhile, the strength of the traditional coating is low, and a formed coating layer is prone to being cracked are solved.

Description

Wheel hub mould coating and preparation method thereof
Technical field
The present invention relates to coating preparation field, in particular it relates to wheel hub mould coating and preparation side thereof Method.
Background technology
Along with the development in epoch, require day by day to improve to the matter of the product of casting quality, traditional sand casting Can not meet Production requirement, new special casts, high with its precision, resistant to damage is good, low cost Etc. advantage, being increasingly widely used, representative therein is exactly permanent mold casting, its because processing performance is high, Technological process is easy, surface finish of casting advantages of higher gains great popularity, but the one of permanent mold casting is big A difficult problem is how to improve its metal type dies life-span, and therefore, the research and development of metal mold heat-resisting paint have weight Want meaning.Traditional coating volatility is high, will result in foundry goods and produces the defect such as pore, sand holes, is coated with meanwhile The intensity of material is relatively low, and the coating of formation is easy to crack.
Summary of the invention
It is an object of the invention to provide a kind of wheel hub mould coating and preparation method thereof, solve tradition Coating volatility is high, will result in foundry goods and produces the defect such as pore, sand holes, and meanwhile, the intensity of coating is relatively low, The coating problem easy to crack formed.
To achieve these goals, the invention provides the preparation method of a kind of wheel hub mould coating, Wherein, described preparation method includes:
(1) by sodium alginate, sodium carboxymethyl cellulose, aluminum phosphate, waterglass, phenolic resin and water Stirring mixing, forms mixed liquor M;
(2) add refractory powder after described mixed liquor M being stood 2-4h, after stirring, obtain mixed liquor N;
(3) mixed liquor N is placed in sealed environment carries out ripening, obtain wheel hub mould and be coated with Material;Wherein, relative to the water of 100 weight portions, the consumption of described sodium alginate is 5-15 weight portion, The consumption of described sodium carboxymethyl cellulose is 2-7 weight portion, and the consumption of described aluminum phosphate is 3-10 weight portion, The consumption of described waterglass is 4-12 weight portion, and the consumption of described phenolic resin is 10-20 weight portion, institute The consumption stating refractory powder is 1-5 weight portion.
Present invention also offers a kind of wheel hub mould coating, described wheel hub mould coating is by above-mentioned Preparation method prepare.
By technique scheme, the invention provides a kind of wheel hub mould coating and preparation side thereof Method, wherein, described preparation method includes: by sodium alginate, sodium carboxymethyl cellulose, aluminum phosphate, water Glass, phenolic resin and water stirring mixing, form mixed liquor M;Described mixed liquor M is stood 2-4h Rear addition refractory powder, obtains mixed liquor N after stirring;Mixed liquor N is placed in sealed environment carry out old Change processes, and obtains wheel hub mould coating, by the synergism between each raw material so that prepared Coating possesses relatively low volatility, and the coating of formation is the most easy to crack to come off, and the intensity of coating is high.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the detailed description of the invention of the present invention is described in detail.It should be appreciated that this place is retouched The detailed description of the invention stated is merely to illustrate and explains the present invention, is not limited to the present invention.
The invention provides the preparation method of a kind of wheel hub mould coating, wherein, described preparation method Including: sodium alginate, sodium carboxymethyl cellulose, aluminum phosphate, waterglass, phenolic resin and water are stirred Mixing, forms mixed liquor M;Refractory powder is added, after stirring after described mixed liquor M is stood 2-4h Obtain mixed liquor N;Mixed liquor N is placed in sealed environment and carries out ripening, obtain wheel hub shaping mould Tool coating, wherein, relative to the water of 100 weight portions, the consumption of described sodium alginate is 5-15 weight Part, the consumption of described sodium carboxymethyl cellulose is 2-7 weight portion, and the consumption of described aluminum phosphate is 3-10 weight Amount part, the consumption of described waterglass is 4-12 weight portion, and the consumption of described phenolic resin is 10-20 weight Part, the consumption of described refractory powder is 1-5 weight portion.
So that the coating prepared possesses relatively low volatility and higher intensity, in the one of the present invention In preferred embodiment, relative to the water of 100 weight portions, the consumption of described sodium alginate is 8-12 Weight portion, the consumption of described sodium carboxymethyl cellulose is 3-5 weight portion, and the consumption of described aluminum phosphate is 5-7 Weight portion, the consumption of described waterglass is 6-10 weight portion, and the consumption of described phenolic resin is 14-16 weight Amount part, the consumption of described refractory powder is 2-3 weight portion.
The present invention one preferred embodiment in, in order to improve the refractory ability of coating further, Described refractory powder is one or more in clay, silicon oxide and aluminium oxide, it is preferred that described fire-resistant The particle diameter of powder is 2-8mm.
In order to improve the performance of sodium alginate further, the present invention one preferred embodiment in, The time stating ripening is 24-36h.
The present invention one preferred embodiment in, in order to improve the intensity of coating further, described The viscosity of epoxy resin is 1500-2500mPa s.
Present invention also offers a kind of wheel hub mould coating, described wheel hub mould coating is by above-mentioned Preparation method prepare.
Hereinafter will be described the present invention by embodiment.In following example, sodium alginate is The commercially available product that Qingdao excellent rope chemistry Science and Technology Ltd. provides, epoxy resin is that money wide industrial chemicals in Wuxi has The commercially available product that limit company provides.
Embodiment 1
By 8g sodium alginate, 3g sodium carboxymethyl cellulose, 5g aluminum phosphate, 6g waterglass, 14g phenolic aldehyde Resin and the stirring mixing of 100g water, form mixed liquor M;Add after described mixed liquor M is stood 2h 2g refractory powder (particle diameter is 2mm), obtains mixed liquor N after stirring;Mixed liquor N is placed in sealing ring Border carries out ripening (time is 24h), obtains wheel hub mould coating A1.
Embodiment 2
By 12g sodium alginate, 5g sodium carboxymethyl cellulose, 7g aluminum phosphate, 10g waterglass, 16g phenol Urea formaldehyde and the stirring mixing of 100g water, form mixed liquor M;Add after described mixed liquor M is stood 4h Enter refractory powder (particle diameter is 8mm), after stirring, obtain mixed liquor N;Mixed liquor N is placed in sealing ring Border carries out ripening (time is 36h), obtains wheel hub mould coating A2.
Embodiment 3
By 10g sodium alginate, 4g sodium carboxymethyl cellulose, 6g aluminum phosphate, 8g waterglass, 15g phenol Urea formaldehyde and the stirring mixing of 100g water, form mixed liquor M;Add after described mixed liquor M is stood 3h Enter refractory powder (particle diameter is 5mm), after stirring, obtain mixed liquor N;Mixed liquor N is placed in sealing ring Border carries out ripening (time is 30h), obtains wheel hub mould coating A3.
Embodiment 4
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of water is 100g, described Sargassum The consumption of acid sodium is 5g, and the consumption of described sodium carboxymethyl cellulose is 2g, and the consumption of described aluminum phosphate is 3g, the consumption of described waterglass is 4g, and the consumption of described phenolic resin is 10g, described refractory powder Consumption is 1g, obtains wheel hub mould coating A4.
Embodiment 5
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of water is 100g, described Sargassum The consumption of acid sodium is 15g, and the consumption of described sodium carboxymethyl cellulose is 7g, and the consumption of described aluminum phosphate is 10g, the consumption of described waterglass is 12g, and the consumption of described phenolic resin is 20g, described refractory powder Consumption be 5g, obtain wheel hub mould coating A5.
Comparative example 1
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of water is 100g, described Sargassum The consumption of acid sodium is 3g, and the consumption of described sodium carboxymethyl cellulose is 1g, and the consumption of described aluminum phosphate is 2g, the consumption of described waterglass is 2g, and the consumption of described phenolic resin is 6g, described refractory powder Consumption is 0.5g, obtains wheel hub mould coating D1.
Comparative example 2
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of water is 100g, described Sargassum The consumption of acid sodium is 20g, and the consumption of described sodium carboxymethyl cellulose is 10g, the consumption of described aluminum phosphate For 12g, the consumption of described waterglass is 15g, and the consumption of described phenolic resin is 22g, described refractory powder The consumption of material is 7g, obtains wheel hub mould coating D2.
Test case 1
Hub mold is heated to 200 DEG C, then the coating A1-A5, D1 and the D2 that stir is divided It is not sprayed on mould (THICKNESS CONTROL is between 0.25mm~0.30mm), mould is placed on instrument, Setting the number of turns (10 circle) rotated, start instrument and measure, the quality passing through scraped coating is many Few, it is judged that the power of coating intensity.
Table 1
Embodiment is numbered The amount of gas evolution from the coating (ml/g) Scrape the quality (g) of coating
A1 1.2 0.4
A2 1.1 0.5
A3 0.9 0.3
A4 1.5 1.1
A5 1.8 0.9
D1 3.5 1.9
D2 3.6 1.8
By above table data it can be seen that the coating A1-A5's prepared within the scope of the present invention sends out Less than coating D1 and D2 prepared outside the scope of the invention, tolerance to illustrate that the volatility of A1-A5 is low, Not easily causing foundry goods and produce the defect such as pore, sand holes, after strength test, A1-A5 scrapes the matter of coating Amount D1 and D2 to be less than, illustrates that the intensity of A1-A5 is higher than D1 and D2, meanwhile, in the present invention The coating A1-A3 prepared in the range of You Xuan possesses the most excellent performance.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited to above-mentioned reality Execute the detail in mode, in the technology concept of the present invention, can be to the technical side of the present invention Case carries out multiple simple variant, and these simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technology described in above-mentioned detailed description of the invention is special Levy, in the case of reconcilable, can be combined by any suitable means, in order to avoid need not The repetition wanted, various possible compound modes are illustrated by the present invention the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as its Without prejudice to the thought of the present invention, it should be considered as content disclosed in this invention equally.

Claims (7)

1. the preparation method of a wheel hub mould coating, it is characterised in that described preparation method bag Include:
(1) by sodium alginate, sodium carboxymethyl cellulose, aluminum phosphate, waterglass, phenolic resin and water Stirring mixing, forms mixed liquor M;
(2) add refractory powder after described mixed liquor M being stood 2-4h, after stirring, obtain mixed liquor N;
(3) mixed liquor N is placed in sealed environment carries out ripening, obtain wheel hub mould and be coated with Material;Wherein, relative to the water of 100 weight portions, the consumption of described sodium alginate is 5-15 weight portion, The consumption of described sodium carboxymethyl cellulose is 2-7 weight portion, and the consumption of described aluminum phosphate is 3-10 weight portion, The consumption of described waterglass is 4-12 weight portion, and the consumption of described phenolic resin is 10-20 weight portion, institute The consumption stating refractory powder is 1-5 weight portion.
Preparation method the most according to claim 1, wherein, relative to the water of 100 weight portions, The consumption of described sodium alginate is 8-12 weight portion, and the consumption of described sodium carboxymethyl cellulose is 3-5 weight Part, the consumption of described aluminum phosphate is 5-7 weight portion, and the consumption of described waterglass is 6-10 weight portion, institute The consumption stating phenolic resin is 14-16 weight portion, and the consumption of described refractory powder is 2-3 weight portion.
Preparation method the most according to claim 1, wherein, described refractory powder is clay, oxygen One or more in SiClx and aluminium oxide.
Preparation method the most according to claim 1, wherein, the particle diameter of described refractory powder is 2-8mm。
Preparation method the most according to claim 1, wherein, the time of described ripening is 24-36h。
Preparation method the most according to claim 1, wherein, the viscosity of described epoxy resin is 1500-2500mPa·s。
7. a wheel hub mould coating, it is characterised in that described wheel hub mould coating is by weighing Profit requires in 1-6 that the preparation method described in any one prepares.
CN201610465900.2A 2016-06-24 2016-06-24 Coating for hub forming mold and preparation method thereof Pending CN106001395A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610465900.2A CN106001395A (en) 2016-06-24 2016-06-24 Coating for hub forming mold and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610465900.2A CN106001395A (en) 2016-06-24 2016-06-24 Coating for hub forming mold and preparation method thereof

Publications (1)

Publication Number Publication Date
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105001783A (en) * 2015-08-12 2015-10-28 江苏绿科生物技术有限公司 Preparation method of high-temperature-resistant coating
CN105033169A (en) * 2015-07-27 2015-11-11 芜湖黄燕实业有限公司 Anti-sedimentation release agent and preparation method thereof
CN105033172A (en) * 2015-07-27 2015-11-11 芜湖黄燕实业有限公司 Release agent used for aluminum alloy part die-casting die and preparation method thereof
CN105033170A (en) * 2015-07-27 2015-11-11 芜湖黄燕实业有限公司 Release agent used for aluminum alloy part die-casting die and preparation method thereof
CN105033171A (en) * 2015-07-27 2015-11-11 芜湖黄燕实业有限公司 Release agent used for aluminum alloy hub die-casting die and preparation method thereof
CN105110755A (en) * 2015-08-12 2015-12-02 江苏绿科生物技术有限公司 High-temperature-resistant coating
CN105170882A (en) * 2015-07-27 2015-12-23 芜湖黄燕实业有限公司 High-storability release agent and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105033169A (en) * 2015-07-27 2015-11-11 芜湖黄燕实业有限公司 Anti-sedimentation release agent and preparation method thereof
CN105033172A (en) * 2015-07-27 2015-11-11 芜湖黄燕实业有限公司 Release agent used for aluminum alloy part die-casting die and preparation method thereof
CN105033170A (en) * 2015-07-27 2015-11-11 芜湖黄燕实业有限公司 Release agent used for aluminum alloy part die-casting die and preparation method thereof
CN105033171A (en) * 2015-07-27 2015-11-11 芜湖黄燕实业有限公司 Release agent used for aluminum alloy hub die-casting die and preparation method thereof
CN105170882A (en) * 2015-07-27 2015-12-23 芜湖黄燕实业有限公司 High-storability release agent and preparation method thereof
CN105001783A (en) * 2015-08-12 2015-10-28 江苏绿科生物技术有限公司 Preparation method of high-temperature-resistant coating
CN105110755A (en) * 2015-08-12 2015-12-02 江苏绿科生物技术有限公司 High-temperature-resistant coating

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