CN105987793A - Highly acidic solution leakage sensing device - Google Patents
Highly acidic solution leakage sensing device Download PDFInfo
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- CN105987793A CN105987793A CN201510041831.8A CN201510041831A CN105987793A CN 105987793 A CN105987793 A CN 105987793A CN 201510041831 A CN201510041831 A CN 201510041831A CN 105987793 A CN105987793 A CN 105987793A
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Abstract
The invention relates to a highly acidic solution leakage sensing device, and particularly provides a highly acidic solution leakage sensing device for detecting the leakage of highly acidic and toxic chemical solutions, such as sulfonic acid, hydrochloric acid, nitric acid, hydrofluoric acid and the like. The device comprises a band-based film layer made of film materials, and an electric lead formed on the band-based film layer along the length direction. The band-based film layer is made of synthetic resin materials. The electric lead is composed of 40 to 90% of a conductive carbon dispersion liquid by weight, and 10 to 60% of a synthetic resin binder by weight, wherein the conductive carbon dispersion liquid and the synthetic resin binder are mixed and printed to form the electric lead.
Description
Technical field
The present invention relates to a kind of strongly acidic solution leakage sensing device, the strongly acidic solution leakage sensing device of particularly a kind of leakage situation for detecting the highly acid toxic chemical solution such as sulfonic acid, hydrochloric acid, nitric acid, hydrofluoric acid and leakage solution type.
Background technology
The applicant has applied for multinomial relevant banding leakage sensor patent, and obtains mandate (patent No.: 10-0909242,100827385).Described banding leakage sensor may be disposed at the place easily leaking and leaks for sensing.
As depicted in figs. 1 and 2, described leakage sensor 100 includes from the bottom to top lower adhesion layer the 120th, basal film layer 110 and the upper protective film layer 130 that lamination is arranged successively.
Described lower adhesion layer 120, in viscose glue banding, sticks to the position leaking；Described basal film layer 110 is used for being formed thereon conductor wire the 111st, 112, and in order to enable to form conductor wire the 111st, 112 with mode of printing, described basal film layer 110 is made up of the film of PET, PE, PTFE, PVC or other Te Folong series material.
Described conductor wire is the 111st, 112 in banding, and they are in a certain distance apart from one another, be set in parallel in the upper surface of basal film layer 110 along its length.The 111st, described conductor wire 112 is formed by electrically conductive ink or silver (Silver) compound printing.
Described upper protective film layer 130 lamination is arranged at the top of basal film layer 110, is used for protecting conductor wire the 111st, 112 to protect it from external damage.Described upper protective film layer 130 is also made up of PET, PE, PTFE, PVC or other Te Folong series material as basal film layer, and is being provided with sensing bore 131 in a certain distance apart from one another with conductor wire the 111st, 112 corresponding positions.
Therefore, when there is drainage, the water spilling can be flowed at conductor wire by the sensing bore 131 at the place of leaking, and makes two conductor wires be energized under the effect of water.Now, remote controllers are according to its "on" position, i.e. form the state of Guan Bi circuit, detected whether to leak, and sent associated alarm.
But, although this film-type leakage sensor 100 can be used for detecting the highly acid toxic chemical solution such as water and sulfonic acid, hydrochloric acid, nitric acid, the hydrofluoric acid with electric conductivity, but, 111st, 112 can dissolve in strongly acidic solution due to basal film layer 110 and conductor wire, accordingly, it is difficult to sense strongly acidic solution leakage phenomenon exactly.
Simultaneously as conductor wire the 111st, 112 dissolution velocity very fast, be difficult to accurately measure conductor wire the 111st, 112 increased resistance value, therefore, it is impossible to identify the species of leakage strongly acidic solution.
Content of the invention
It is an object of the invention to overcome above-mentioned deficiency, a kind of basal film layer is provided to be made up of the film material insoluble in strongly acidic solution, the material that conductor wire is made resistance value change by producing reaction to strongly acidic solution is constituted, thus can detect the strongly acidic solution leakage sensing device of strongly acidic solution leakage exactly.
Another object of the present invention is to provide one to set upper and lower resistance limit value based on basic resistance value, by measuring the time that resistance value changes in the range of resistance limit value, identify that the strongly acidic solution of the strongly acidic solution species of leakage leaks sensing device.
To achieve these goals, this invention takes following technical scheme:
The strongly acidic solution leakage sensing device of the present invention includes the basal film layer of film material, at the above conductor wire being formed along its length of described basal film layer, described basal film layer is formed by synthetic resin material, and described conductor wire is mixed by conductive carbon dispersion liquid 40～90 percentage by weight and synthetic resin adhesive 10～60 percentage by weight and formed with mode of printing printing.
When described conductive carbon dispersion liquid 40～90 percentage by weight is converted into 100 percentage by weight, described conductive carbon dispersion liquid is mixed by neutral range of solvents 80～98 weight percent when non-ionic surfactant Series Dispersant 1～10 percentage by weight that activated carbon or CNT or Graphene or carbon powder 1～20 percentage by weight, pH value are 6.5～7.5.
When described adhesive 10～60 percentage by weight is converted into 100 percentage by weight, described adhesive is mixed by acrylic acid resin or PE or PU or PC or epoxy resin 40～60 percentage by weight and volatile solvent 40～60 percentage by weight.
The strongly acidic solution leakage sensing device of the present invention includes the basal film layer of film material, at the above conductor wire being formed along its length of described basal film layer, described basal film layer is formed by synthetic resin material, and the above of described conductor wire is formed with the coat being mixed by coating 90～99 percentage by weight and curing agent 1～10 percentage by weight.
Described curing agent is isocyanates or melamine.
The strongly acidic solution leakage sensing device of the present invention includes the basal film layer of film material, the above conductor wire being formed along its length at described basal film layer, described basal film layer is formed by synthetic resin material, the above of described conductor wire is formed by coating, alkyd resin, PE, PET, PC, aldehyde resin (POM), polymethyl methacrylate (PMMA), polyamide (PA), ionomer, polyarylate, polyester, egonol, polyester elastomer (PEE), any one in phenolic resin (PF) forms coat, or polymer composite is formed coat.
The strongly acidic solution leakage sensing device of the present invention is by the basal film layer of film material, at the above conductor wire being formed along its length of described basal film layer with formed by the material that can dissolve or corrode in strongly acidic solution and the coat for covering described conductor wire constitutes strongly acidic solution sensor, it is connected with controller, for generating alarm according to the situation that resistance value changes in time while conductor wire supplies remote sensing power supply on described strongly acidic solution sensor.
The material that the strongly acidic solution leakage sensing device of the present invention can be dissolved by the basal film layer of film material, utilization in strongly acidic solution or corrode is formed at the conductor wire above basal film layer along its length and constitutes strongly acidic solution sensor, it is connected with controller, for generating alarm according to the situation that resistance value changes in time while described conductor wire supplies remote sensing power supply on described strongly acidic solution sensor.
The strongly acidic solution leakage sensing device of the present invention is by separated by a distance side by side and 2 strands of conductor wires arranging and utilization are dissolved in strongly acidic solution or the material that corrodes is coated on the clad outside described conductor wire and constitutes strongly acidic solution sensor, it is connected with controller, for generating alarm according to the situation that resistance value changes in time while described conductor wire supplies remote sensing power supply on described strongly acidic solution sensor.
It is set with the reference resistor value of described strongly acidic solution sensor in described controller, described reference resistor value "+" direction and "-" direction setting have upper limit resistance value and the lower resistance value of alarm set value.
Described conductor wire is formed side by side by the first conductor wire and the second conductor wire, and described first conductor wire and the second conductor wire are mixed with adhesive by activated carbon or carbon black or CNT (CNT) or Graphene (graphene)；When described first conductor wire is made up of electric conductors such as silver compound, sheet metal electrically conductive inks, described second conductor wire is then mixed with adhesive by activated carbon or carbon black or CNT (CNT) or Graphene (graphene).
Described conductor wire passes through to form adhesive agent at basal film layer, and sprays conductive powder at described adhesive agent and formed.
Spraying (sputtering) technique is utilized to form described conductor wire.
Due to the fact that and utilize the material that resistance value changes under the effect of strongly acidic solution to form basal film layer and conductor wire, therefore, when being arranged at described basal film layer and conductor wire on the equipment storing or transporting highly acid toxicant, can accurately sense Acid constituents；Owing in banding, therefore, being not only easy to be arranged on pipeline etc., and cheap for manufacturing cost, there is stronger price competitiveness.
Additionally, also can sound the alarm according to strongly acidic solution species, therefore, quickly and accurately corresponding measure can be taked to various leakage solution.
Brief description
Fig. 1 is the STRUCTURE DECOMPOSITION schematic diagram of existing leakage sensor.
Fig. 2 is the structure section figure of existing leakage sensor.
Fig. 3 is the structural representation of strongly acidic solution of the present invention leakage sensing device embodiment one.
Fig. 4 is that conductor wire resistance value leaks, with strongly acidic solution, the schematic diagram changing.
Structural representation when Fig. 5 a is to be connected with controller in strongly acidic solution of the present invention leakage sensing device embodiment one.
Electrical block diagram when Fig. 5 b is to be connected with controller in strongly acidic solution of the present invention leakage sensing device embodiment one.
Fig. 6 is the structural representation of strongly acidic solution of the present invention leakage sensing device embodiment two.
Structural representation when Fig. 7 a is to be connected with controller in strongly acidic solution of the present invention leakage sensing device embodiment two.
Electrical block diagram when Fig. 7 b is to be connected with controller in strongly acidic solution of the present invention leakage sensing device embodiment two.
Fig. 8 is that controller sends the state diagram of alarm according to the resistance value changing with the strongly acidic solution species of leakage.
Fig. 9 is the another kind of structural representation of strongly acidic solution sensor.
Figure 10 and Figure 11 is to form conductor wire schematic diagram.
In figure: 210: basal film layer；211st, 212: conductor wire；220: lower adhesion layer；230: upper protective film layer；231: sensing bore；240: coat；300: controller；400: top connector；500: terminator terminating junctor.
Detailed description of the invention
The present invention is described in detail below in conjunction with the accompanying drawings.
The basic structure of the strongly acidic solution sensor 200 of the embodiment of the present invention one is identical with the structure shown in Fig. 1 and Fig. 2, therefore, this emphasis to basal film layer the 210th, conductor wire as shown in Figure 3 211st, 212 and the composition of upper protective film layer 230 illustrate.
It is known that when poisonous strongly acidic solution leaks in soil or air, it may occur that water pollution, soil pollution, air pollution etc., not only can destroy material, and can have a strong impact on health.Accordingly, it would be desirable to a kind of quickly acid solution leak detection technology of economy.
To this end, present invention basal film to be ensured layer the 210th, conductor wire the 211st, 212 and upper protective film layer 230 at highly acid toxic chemical solution such as sulfonic acid, hydrochloric acid, nitric acid, hydrofluoric acid, i.e. acid solution does not dissolves.
Basal film layer 210 of the present invention is by PC, PP, PE, PET, PI, PIFE(Teflon) etc. synthetic resin constitute, its thickness is 50～300.
The 211st, described conductor wire 212 is had the linear conductive carbon dispersion liquid of conduction and acrylic acid resin or PE or PU by activated carbon, CNT (CNT:Carbon Nano Tube), Graphene (Graphene), carbon black (Carbon black) etc. or the adhesive such as PC or epoxy resin mixes and forms.40～90 weight percent conductive carbon dispersion liquids and 10～60 weight percent binder mix and form electric conductive carbon printing ink, described electric conductive carbon printing ink can be printed on basal film layer 210 by various mode of printings such as intaglio printing, silk screen printing, air brushing, to form conductor wire the 211st, 212.
When mixing acrylic acid resin as adhesive, and adhesive 10～60 percentage by weight being converted into 100 percentage by weight, its blending ingredients is the volatile solvent of the acrylic acid resin of 40～60 percentage by weights and 40～60 percentage by weights.Wherein, acrylic acid resin not only has anti-highly acid, and has powerful adhesive force when being printed on basal film layer 210, and described volatile solvent then can improve volatility during printing, makes printing process be more prone to.
If additionally, using PE or PU or PC or epoxy resin etc. as adhesive use when, it is also possible to the volatile solvent of PE or PU or PC of 40～60 percentage by weights or epoxy resin and 40～60 percentage by weights mixes.
When conductive carbon dispersion liquid 40～90 percentage by weight is converted into 100 percentage by weight, in 100 percentage by weights, activated carbon or CNT or Graphene or carbon black powder 1～20 percentage by weight, ethyl cellosolve solution 80～98 weight percent form paste after when non-ionic surfactant Series Dispersant 1～10 percentage by weight mixes.Wherein, CNT, Graphene or carbon black powder have electric conductivity, and ethyl cellosolve and non-ionic surfactant Series Dispersant, for stablizing the structure of conductive carbon, make particle dispersion more uniform.
Additionally, also the alcohol Series P H values such as IP available A, water, ethanol or methyl alcohol are the neutral range of solvents replacement ethyl cellosolve solution of 6.5～7.5.
As described above, conductive carbon dispersion liquid can be used, and form conductor wire the 211st, 212 by the various ways such as intaglio printing, now, conductor wire the 211st, 212 thickness be 2～20.
Described upper protective film layer 230 is made up of synthetic resin materials such as the PC with anti-strongly acidic solution characteristic, PP, PE, PI, PET, Teflons, and thickness is 50～300, and corresponding conductor wire the 211st, 212 position be provided with sensing bore 231.
When there is leakage in strongly acidic solution, strongly acidic solution is flowed into by the sensing bore 231 that leak occurs, with constitute conductor wire the 211st, 212 adhesive react, and As time goes on described adhesive generation bulging, make the arrangement generation avalanche of conductive carbon ion, as shown in Figure 4.
Thus, conductor wire the 211st, 212 resistance value increase, remote controllers by receive described conductor wire the 211st, 212 increased resistance value, it may be judged whether have strongly acidic solution to leak.
At this moment, the 211st, described conductor wire 212 can be made up of various ways, as shown in table 1.
Table 1:
When the first conductor wire 211 and the second conductor wire 212 are mixed with adhesive by activated carbon or carbon black or CNT (CNT) or Graphene (graphene), sensing bore 231 is set in the position corresponding with described first conductor wire and the second conductor wire.
But, when the first conductor wire 211 is made up of electric conductors such as silver compound, sheet metal electrically conductive inks, when second conductor wire 212 is then mixed with adhesive by activated carbon or carbon black or CNT (CNT) or Graphene (graphene), only sensing bore 231 is set in the position corresponding with the second conductor wire 212.
This is because need when the first conductor wire 211 is formed by the more weak material of resistance to strongly acidic solution ability to be protected.
Fig. 5 is the schematic diagram for confirming whole systems that whether strongly acidic solution leak.As shown in Figure 5 a, the two ends of strongly acidic solution sensor 200 are connected with top connector 400 and terminator terminating junctor 500, described top connector 400 is connected with controller 300, and described terminator terminating junctor 500 then connects conductor wire the 211st, 212 in the termination of strongly acidic solution sensor 200.
Fig. 5 b is a kind of embodiment circuit diagram.The material that the second conductor wire 212 in this circuit diagram is made resistance value change by reacting strongly acidic solution is formed, and the first conductor wire 211 is formed by electric conductor.When strongly acidic solution leaks, and being flowed into by sensing bore 231, when contacting with the second conductor wire 212, the resistance value of described second conductor wire 212 changes.According to this resistance change situation, remote controllers 300 confirm whether strongly acidic solution leaks.
Fig. 6 is the schematic diagram of the embodiment of the present invention two.As shown in Figure 6; the strongly acidic solution sensor 200 of the present invention lower adhesion layer the 220th, the basal film layer 210 that lamination is arranged successively from the bottom to top and upper protective film layer 230, described basal film layer 210 is provided with the conductor wire being separated by side by side and putting the 211st, 212 along its length.In order to cover conductor wire the 211st, 212 top, utilizing coating, alkyd resin, PE, PET, PC, aldehyde resin (POM), the soluble or easy resin material corroding in strong acid such as polymethyl methacrylate (PMMA), polyamide (PA), ionomer, polyarylate, polyester elastomer (PEE), phenolic resin (PF) forms coat 240.Described coat 240 is dissolved in strongly acidic solution, but water insoluble, and it can be formed by bar type coating (Bar coating), the slit coating mode such as (slot die), intaglio plate coating.
Described coat 240 can be formed by multiple polymer composites, and the 211st, conductor wire 212 can be formed by conductive materials such as ink, silver compound, sheet metal or thin plates.
Therefore, when water is flowed into by sensing bore 231, the 211st, conductor wire 212 cannot be energized under the waterproof action of coat 240.But, when strongly acidic solution flows into, coat 240 occurs to dissolve or be etched, resistance value is made to change, so that the conductor wire being formed by conductive material the 211st, 212 energising, cause resistance value to change, can detect whether strongly acidic solution leaks according to resistance change situation.
Now, the thickness of coat 240 is 2～20.
Described coat 240 is preferably mixed by coating 90～99 percentage by weight and curing agent 1～10 percentage by weight, and described curing agent can use isocyanates or melamine.
Strongly acidic solution includes sulfonic acid, hydrochloric acid, nitric acid, hydrofluoric acid etc., of a great variety.Conductor wire as above 211st, 212 energising make the structure that resistance value changes, the resistance change situation detection leak condition that can only occur according to leaking with strongly acidic solution, and be difficult to confirm the species of the strongly acidic solution of leakage.
The present invention can confirm to occur the species of the strongly acidic solution of leakage according to time dependent resistance value.
Described controller 300 receives increased resistance value or conductor wire the 211st, 212 increased resistance value occurring because of energising of the conductor wire 212 described in embodiment one and embodiment two, and confirm the resistance value changing in time, according to the species of its result identification strongly acidic solution.
Structural representation when Fig. 7 a is to be connected with controller in strongly acidic solution of the present invention leakage sensing device embodiment two, electrical block diagram when Fig. 7 b is to be connected with controller in strongly acidic solution of the present invention leakage sensing device embodiment two.As shown in Fig. 7 a, 7b, the two ends of strongly acidic solution sensor 200 are connected with top connector 400 and terminator terminating junctor 500, described top connector 400 is connected with controller 300, and described terminator terminating junctor 500 then connects conductor wire the 211st, 212 in the termination of strongly acidic solution sensor 200.
The running status chart of the controller 300 according to the resistance change situation identification strongly acidic solution species between two conductor wires the 211st, 212 when Fig. 8 is the coat 240 being formed such as embodiment two for explanation.Described controller 300 is set with the reference resistor value of the sensor length based on strongly acidic solution sensor 200, on the basis of described reference resistor value, be set with "+" compensate (offset) value and "-" offset, to compensate the change of the self-resistance value causing because of factors such as outside temperature, humidity, electric noise, physical contacts.
Described offset can be adjusted according to the installation environment of strongly acidic solution sensor 200.
Described controller 300 be set be positioned at reference resistor value "+" alarm set value (High Limit) in direction, i.e. upper limit resistance value and the alarm set value (Low Limit) being positioned at resistance value "-" direction, i.e. lower resistance value.Can adjust sensing sensitivity by the scope regulating alarm set value.
It when strongly acidic solution occurs leakage, is gradually lowered and enters the time in range of set value by the resistance value between mensuration conductor wire the 211st, 212, identify the species of strongly acidic solution.
For example, when chemical solution A leakage, when contacting with coat 240, coat 240 dissolves or is etched, and makes resistance value change.At this moment, the time in the range of controller 300 measures the resistance value entrance alarm set value starting to change to change from resistance value, and according to the species of its minute identification strongly acidic solution.
For chemical solution B, chemical solution C and chemical solution D, compared with chemical solution A, in the range of resistance value utilizes relatively short period of time just to enter alarm set value after starting change, described controller 300 is identified the strongly acidic solution species of leakage by measuring this kind of time.
When the increased resistance value of various chemical solutions is consistent with alarm set value (High Limit), send alarm at this positioner 300, continue the change of induced electricity resistance afterwards.A certain specified chemical solution is such as chemical solution D, and resistance value changes makes it exceed alarm set value (Low
Limit), when, controller 300 is beyond alarm set value (Low
Limit) position sends alarm.
Various strongly acidic solution time dependent resistance value data are stored in described controller 300, therefore, start to change to the time in the range of increased resistance value enters alarm set value by measuring from resistance value, send to should the chemical solution i.e. alarm of strongly acidic solution species of time.
For embodiment one, when under the effect of acid solution, the resistance value of conductor wire 212 increases, elapsed time is longer, and resistance value is bigger.
I.e., according to embodiments of the present invention one and embodiment two, when conductor wire the 211st, 212 resistance value be decreased or increased when, the strongly acidic solution species of leakage according to resistance value degree over time, can be identified.
In addition, strongly acidic solution of the present invention leakage sensing device can substitute described banding pattern strongly acidic solution sensor 200 with cable type sensors.As it is shown in figure 9, the 610th, cable sensor 600 by two strands of conductor wires 620 is separated by side by side and puts, the clad 630 being made up of the material being dissolved in strongly acidic solution outside it, can be coated.
Described clad 630, as the coat 240 of the present invention, can be formed by coating after CNT (Carbon Nano Tube) dispersion liquid 60～90 percentage by weight and acrylic acid resin 10～40 percentage by weight containing volatile solvent mixing.
Described clad 630 can be formed by the material dissolved under the effect of strongly acidic solution or corrode.
Therefore, when strongly acidic solution is contacted with described clad 630, described clad 630 dissolves, and makes resistance value change, and conductor wire the 610th, the resistance value between 620 also changes therewith.
Other principles are described above.
In addition, when conductor wire the 211st, 212 formed by activated carbon or carbon black or CNT (CNT) or Graphene (Graphene) when, mode of printing can be used, also can by prepare to be formed on basal film layer 210 conductor wire the 211st, 212 position sticking two-faced adhesive tape or coating adhesive formed after adhesive agent 211-1,212-1, spread powdered carbon black or CNT (CNT) or Graphene (Graphene) and formed, as shown in Figure 10.
That is, by conductive powder is sprinkling upon adhesive agent 211-1,212-1 upper formation conductor wire the 211st, 212.
Therefore, only could adhere to electrical conductivity Carbon black or CNT (CNT) or Graphene (Graphene) in the place being formed with adhesive agent 211-1,212-1 and form conductor wire.
Additionally, utilize spraying (suttering) method also can form conductor wire the 211st, 212.Described spraying method is to arrange to have the metal of electric conductivity and basal film layer 210 of the present invention in vacuum chamber, now, described basal film layer 210 will overlap in addition to the position of conductor wire to be formed upper protective film 213, as shown in figure 11.
Described diaphragm 213 can be made up of synthetic resin adhesive tape.
Adding negative voltage on conducting metal, after adding positive voltage, injecting argon gas in vacuum chamber on basal film layer 210, the ion deposition at this moment spilling because ionization argon gas clashes with conducting metal is at basal film layer 210.
Depositing operation removes diaphragm 213 after terminating, just form conductor wire the 211st, 212.
Why use above-mentioned spraying method, be because when conductor wire the 211st, 212 formed by conductive materials such as electrically conductive ink, silver compound, sheet metal or thin plates when, its thickness is 5～10, there is bigger resistance value, if being coated coat 240 at an upper portion thereof, then conductor wire the 211st, 212 and the thickness of coat 240 will reach 30～50, additionally, being affected by conductor wire the 211st, 212 thickness, coat 240 is difficult to be stably adhered on basal film layer 210.
But, if use spraying method, conductor wire the 211st, 212 thickness be only 0.1～1, thickness diminishes, thus coat 240 can be made to be stably adhered on basal film layer 240.
Additionally, be formed at basal film layer 210 conductor wire the 211st, 212 not necessarily two above, available by activated carbon or carbon black or CNT
Or Graphene (Graphene) only forms a conductor wire with the material that adhesive mixes the above of basal film layer 210 (CNT).The two ends of one conductor wire can be connected to controller by conductive cable.
Claims (13)
1. a strongly acidic solution leakage sensing device, it is characterized in that: it includes the basal film layer of film material, at the above conductor wire being formed along its length of described basal film layer, described basal film layer is formed by synthetic resin material, and described conductor wire is mixed by conductive carbon dispersion liquid 40～90 percentage by weight and synthetic resin adhesive 10～60 percentage by weight and formed with mode of printing printing.
2. strongly acidic solution according to claim 1 leakage sensing device, it is characterized in that: when described conductive carbon dispersion liquid 40～90 percentage by weight is converted into 100 percentage by weight, described conductive carbon dispersion liquid is mixed by neutral range of solvents 80～98 weight percent when non-ionic surfactant Series Dispersant 1～10 percentage by weight that activated carbon or CNT or Graphene or carbon powder 1～20 percentage by weight, pH value are 6.5～7.5.
3. strongly acidic solution according to claim 1 leakage sensing device, it is characterized in that: when described adhesive 10～60 percentage by weight is converted into 100 percentage by weight, described adhesive is mixed by acrylic acid resin or PE or PU or PC or epoxy resin 40～60 percentage by weight and volatile solvent 40～60 percentage by weight.
4. a strongly acidic solution leakage sensing device, it is characterized in that: it includes the basal film layer of film material, at the above conductor wire being formed along its length of described basal film layer, described basal film layer is formed by synthetic resin material, and the above of described conductor wire is formed with the coat being mixed by coating 90～99 percentage by weight and curing agent 1～10 percentage by weight.
5. strongly acidic solution according to claim 4 leakage sensing device, it is characterised in that: described curing agent is isocyanates or melamine.
6. a strongly acidic solution leakage sensing device, it is characterized in that: it includes the basal film layer of film material, at the above conductor wire being formed along its length of described basal film layer, described basal film layer is formed by synthetic resin material, described conductor wire above is formed by coating, alkyd resin, PE, PET, PC, aldehyde resin (POM), polymethyl methacrylate (PMMA), polyamide (PA), ionomer, polyarylate,
Any one in polyester, egonol, polyester elastomer (PEE), phenolic resin (PF) forms coat, or is formed coat by polymer composite.
7. a strongly acidic solution leakage sensing device, it is characterized in that: by the basal film layer of film material, at the above conductor wire being formed along its length of described basal film layer with formed by the material that can dissolve or corrode in strongly acidic solution and the coat for covering described conductor wire constitutes strongly acidic solution sensor, it is connected with controller, for generating alarm according to the situation that resistance value changes in time while conductor wire supplies remote sensing power supply on described strongly acidic solution sensor.
8. a strongly acidic solution leakage sensing device, it is characterized in that: the material can dissolved by the basal film layer of film material, utilization in strongly acidic solution or corrode is formed at the conductor wire above basal film layer along its length and constitutes strongly acidic solution sensor, it is connected with controller, for generating alarm according to the situation that resistance value changes in time while described conductor wire supplies remote sensing power supply on described strongly acidic solution sensor.
9. a strongly acidic solution leakage sensing device, it is characterized in that: by separated by a distance side by side and 2 strands of conductor wires arranging and utilization are dissolved in strongly acidic solution or the material that corrodes is coated on the clad outside described conductor wire and constitutes strongly acidic solution sensor, it is connected with controller, for generating alarm according to the situation that resistance value changes in time while described conductor wire supplies remote sensing power supply on described strongly acidic solution sensor.
10. the strongly acidic solution leakage sensing device according to according to any one of claim 7 to 9, it is characterized in that: in described controller, be set with the reference resistor value of described strongly acidic solution sensor, described reference resistor value "+" direction and "-" direction setting have upper limit resistance value and the lower resistance value of alarm set value.
The 11. strongly acidic solution leakage sensing devices according to according to any one of claim 4 to 9, it is characterized in that: described conductor wire is formed side by side by the first conductor wire and the second conductor wire, described first conductor wire and the second conductor wire are mixed with adhesive by activated carbon or carbon black or CNT (CNT) or Graphene (graphene)；When described first conductor wire is made up of electric conductors such as silver compound, sheet metal, electrically conductive inks, described second conductor wire is then mixed with adhesive by activated carbon or carbon black or CNT (CNT) or Graphene (graphene).
The 12. strongly acidic solution leakage sensing devices according to according to any one of claim 4 or 6 or 7 or 8, it is characterised in that: described conductor wire passes through to form adhesive agent at basal film layer, and sprays conductive powder at described adhesive agent and formed.
The 13. strongly acidic solution leakage sensing devices according to according to any one of claim 4 or 6 or 7 or 8, it is characterised in that: utilize spraying (sputtering) technique to form described conductor wire.
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| CN107063580A (en) * | 2017-01-22 | 2017-08-18 | 柳哲 | Diaphragm type organic liquid leakage detection system |
| CN114935434A (en) * | 2022-04-06 | 2022-08-23 | 中国电子科技集团公司第二十九研究所 | End connector, film type leakage detection device and leakage detection method |
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| US20070275296A1 (en) * | 2004-02-26 | 2007-11-29 | Origin Electric Company, Limited | Acid Liquid Leakage Sensor |
| CN101223437A (en) * | 2005-07-14 | 2008-07-16 | 尤妮佳股份有限公司 | Water content detection sensor |
| CN102016531A (en) * | 2008-04-24 | 2011-04-13 | 株式会社俞旻St | Leak sensor apparatus for sensing moisture |
| CN103328946A (en) * | 2011-08-05 | 2013-09-25 | 俞洪根 | Device for detecting an oil leak |
| WO2014119974A1 (en) * | 2013-02-04 | 2014-08-07 | (주)유민에쓰티 | Device for detecting leakage of acidic solution |
| CN104141883A (en) * | 2013-12-10 | 2014-11-12 | 唐山学院 | Control method and device for sulfuric acid leakage monitoring |
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| CN107063580A (en) * | 2017-01-22 | 2017-08-18 | 柳哲 | Diaphragm type organic liquid leakage detection system |
| CN107063580B (en) * | 2017-01-22 | 2023-11-10 | 柳哲 | Thin film type organic liquid leakage detection system |
| CN114935434A (en) * | 2022-04-06 | 2022-08-23 | 中国电子科技集团公司第二十九研究所 | End connector, film type leakage detection device and leakage detection method |
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