CN105987509A - Hot water storage tank unit - Google Patents

Hot water storage tank unit Download PDF

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Publication number
CN105987509A
CN105987509A CN201510082229.9A CN201510082229A CN105987509A CN 105987509 A CN105987509 A CN 105987509A CN 201510082229 A CN201510082229 A CN 201510082229A CN 105987509 A CN105987509 A CN 105987509A
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CN
China
Prior art keywords
heat
water pot
heat accumulation
accumulation water
foaming
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Granted
Application number
CN201510082229.9A
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Chinese (zh)
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CN105987509B (en
Inventor
伏木隆之
岛崎幸治
渡边宏太朗
四至本知秀
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Hitachi Global Life Solutions Inc
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Hitachi Appliances Inc
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Publication of CN105987509A publication Critical patent/CN105987509A/en
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Publication of CN105987509B publication Critical patent/CN105987509B/en
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  • Thermal Insulation (AREA)

Abstract

The invention provides a hot water storage tank unit that can prevent external surface corrosion of pipe materials when a foam heat insulation material is packed around the pipes. A hot water storage tank unit comprises: a hot water storage tank (2); an outer box (3A) that houses the hot water storage tank (2); a foam heat insulation material (6) made of a foam liquid (6a) injected and foamed between the outer box (3A) and the hot water storage tank (2); and pipes (11, 12, 13, 14, 15) housed in the outer box (3A) and having corrosion resistance to amines or ammonia arising from decomposition of the foam heat insulation material (6).

Description

Heat accumulation water pot unit
Technical field
The present invention relates to heat accumulation water pot unit.
Background technology
As existing heat accumulation water pot unit, motion has use stainless steel formation composition to reheat back Road, fill hot-water return, be typically for the heat accumulation water pot unit of the pipe arrangement of hot-water return (with reference to patent Document 1).
Prior art literature
Patent document
Patent document 1: Japanese Unexamined Patent Publication 2010-210157 publication
Content of the invention
Invent problem to be solved
But, the purpose of patent document 1 is to prevent the inner surface of the piping material of hot-warer supplying machine Corrosion, with regard to piping material in the case of filling-foam heat insulating member around pipe arrangement The corrosion of outer surface prevents, both without record and without hint.
The present invention makes to solve above-mentioned existing problem, its object is to provide energy Enough outer surface corruption preventing piping material around pipe arrangement in the case of filling-foam heat insulating member The heat accumulation water pot unit of erosion.
Technical teaching for solving the problem was
It is a feature of the present invention that and include:
Heat accumulation water pot;
Receive the outer container of above-mentioned heat accumulation water pot;
Between above-mentioned outer container and above-mentioned heat accumulation water pot inject expanding foam solution foam obtained from send out Bubble heat insulating member;With
Pipe arrangement, it is accommodated in the inside of above-mentioned outer container, divides for by above-mentioned foaming heat insulation parts The amine or the ammonia that solve and produce have corrosion resistance.
The effect of invention
In accordance with the invention it is possible to provide around pipe arrangement in the case of filling-foam heat insulating member It is prevented from the heat accumulation water pot unit of the outer surface corrosion of piping material.
Brief description
Fig. 1 is the overall structure of the hot-warer supplying machine of the heat accumulation water pot unit representing and having embodiment Figure.
Fig. 2 is the stereogram of the inside of the heat accumulation water pot unit representing embodiment.
Fig. 3 is the front elevation during heat accumulation water pot unit of embodiment in terms of inlet side.
Fig. 4 is the cross section during heat accumulation water pot unit of embodiment in terms of the upper plate side of heat accumulation water pot Figure.
The figure of the flowing of the foaming heat insulation parts (expanding foam solution) when Fig. 5 (a) is to represent injection, (b) be represent injection complete after the figure of state of foaming heat insulation parts (expanding foam solution), (c) It is the figure of the state of the foaming heat insulation parts representing foaming midway.
Fig. 6 is the cross-sectional view of the heat accumulation water pot unit of embodiment.
Fig. 7 (a) is the preflood vacuum heat-insulation parts of foaming heat insulation parts (expanding foam solution) Covering state, (b) be foaming heat insulation parts (expanding foam solution) injection, foaming after vacuum every The covering state of thermal part.
The explanation of reference
1A heat accumulation water pot unit
2 heat accumulation water pots
2a main board
2b top wallboard
2c bottom wallboard
3A outer container
3a header board (upper surface of the vertical direction of outer container)
3b side plate
3c back plate (lower surface of the vertical direction of outer container)
3c1 internal face
3d upper plate (face relative with another side of heat accumulation water pot)
3e base plate (face relative with the end side of heat accumulation water pot)
4th, leg in 4A, 4B, 4C
4a leg receiving portion
8th, 9 inlet
3s piping cover
5 vacuum heat-insulation parts
5a, 5b non-overlapping portion
6 foaming heat insulation parts
6a expanding foam solution (foaming heat insulation parts)
8th, 8A, 8B, the 9th, 9A, 9B inlet
10 heat pump units
11 feed pipes (pipe arrangement)
12 oral siphons (pipe arrangement)
13 hot-water outlet pipes (pipe arrangement)
14 heat supply water pipes (pipe arrangement)
15 bathtub return pipes (pipe arrangement)
16 water mixing valve
17 heat supply water pipes
18 supplying hot water terminals
20 bases
21 otch
31 nozzles
32 holes
40 supporting parts
S, s1, s2, s3 gap
T1, T2 temperature sensor
BT bolt
HE heat exchanger
G setting place
K hot-warer supplying machine
Pa blow pressure
G vertical direction is down
Detailed description of the invention
Hereinafter, enter referring to figs. 1 through the heat accumulation water pot unit 1A to embodiments of the present invention for the Fig. 7 Row explanation.
(explanation of embodiment)
First, with reference to the hot-warer supplying machine K to the heat accumulation water pot unit 1A with embodiment for the Fig. 1 Illustrate.Fig. 1 is the whole of the hot-warer supplying machine of the heat accumulation water pot unit representing and having embodiment Body structure chart.
As it is shown in figure 1, hot-warer supplying machine K includes heat accumulation water pot unit 1A, heat pump unit 10.
Heat accumulation water pot unit 1A includes that heat accumulation water pot the 2nd, outer container 3A, interior leg (leg) are the 4th, true Empty heat insulating member the 5th, foaming heat insulation parts 6.
It is connected with the feed pipe 11 (pipe arrangement) importing running water in the bottom of heat accumulation water pot 2.Heat accumulation The water of the bottom of water pot 2 is imported into heat pump by pump (not shown) through oral siphon 12 (pipe arrangement) Unit 10.Warm water after heat pump unit 10 is heated is imported into water storage through hot-water outlet pipe 13 The top of tank 2.
The temperature of the warm water in such heat accumulation water pot 2 for example with below vertical direction upwards Side goes and uprises.That is, the bottom in heat accumulation water pot 2 is to top, relatively become low temperature, Middle temperature, the Temperature Distribution of high temperature.For example, the top in heat accumulation water pot 2 be about 90 DEG C, in Between portion be about 50 DEG C.
Heat pump unit 10 is by unit boiled for the water that takes out from heat accumulation water pot 2, for example, include: Compressor, cold-producing medium (such as carbon dioxide) is compressed and makes this cold-producing medium become high by it Temperature high pressure;Condenser, it is by by the cold-producing medium discharged from compressor with from heat accumulation water pot 2 Water carry out heat exchange and to the water heating from heat accumulation water pot 2;Pressure-reducing valve, it is self cooling to coming The cold-producing medium of condenser reduces pressure;And evaporimeter, it makes the heat in absorption air and post-decompression Cold-producing medium evaporates.In addition, in embodiments, as heating arrangements, heat pump unit 10 is enumerated Example illustrate, also can add for utilizing electric heater or coal gas as heating arrangements The mechanism of heat.
The hot water taking out from the top of heat accumulation water pot 2 passes through heat supply water pipe 14, by water mixing valve 16 Mix with the water carrying out branch's feed pipe (not shown) that comfortable feed pipe 11 branch is connected, afterwards It is discharged from supplying hot water terminal 18 through heat supply water pipe 17.In addition, in embodiments, enumerate It is illustrated in case of the hot water that supplying hot water terminal 18 uses within heat accumulation water pot 2, Also can apply to the hot water using heat accumulation water pot 2 be not used as supplying hot water terminal hot water and as use Heat accumulation water pot list in the type that the heating agent carrying out heat exchange (heating) to the water being supplied to uses Unit's (vertical compression heat supply ability of swimming).
Outer container 3A has the space of storage heat accumulation water pot 2, is provided with in front (face side) and joins Shroud 3s.Piping cover 3s has storage and goes out hot water from heat pump unit 10 to what heat accumulation water pot 2 went The space of pipe the 13rd, branch's feed pipe (not shown), water mixing valve the 16th, heat supply water pipe 17 etc..
Fig. 2 is the stereogram of the inside of the heat accumulation water pot unit 1A representing embodiment.And, Fig. 2 represents the state of the header board 3a side excision of outer container 3A, and omits the figure of various pipe arrangement Show.
As in figure 2 it is shown, heat accumulation water pot 2 is for example to utilize stainless steel etc. to have the material of corrosion resistance Material, by the substantially bowl to the main board 2a of drum, the upper opening covering main board 2a The top wallboard 2b of shape (hemispherical, vessel-shaped), lower openings big covering main board 2a The bottom wallboard 2c these three parts causing bowl-shape (hemispherical, vessel-shaped) weld and constitute 's.
Additionally, heat accumulation water pot 2 is propped up by three interior legs 4 (4A), 4 (4B), 4 (4C) Hold the base plate 3e in outer container 3A.Additionally, the lower end of each interior leg 4 utilizes bolt fixing etc. method It is fixed on the base plate 3e of outer container 3A.In addition, the number of interior leg 4 is not limited to 3, Also can be more than 4.
Additionally, at the outer surface (front surface) of heat accumulation water pot 2, at above-below direction at spaced intervals It is provided with temperature sensor T1, T2 (thermistor).The temperature sensor T1 detection of upside is made The boiling temperature of temperature for the top of heat accumulation water pot 2.The temperature sensor T2 detection storage of downside The temperature of the middle warm water of the pars intermedia of hot-water cylinder 2.In addition, the number of temperature sensor T1, T2 It is not limited to embodiment, it is also possible to be not only provided at the top of heat accumulation water pot 2 but from storage The top of hot-water cylinder 2 to bottom arranges the temperature sensor of more than 3.
Outer container 3A is the parts of steel plate of storage heat accumulation water pot 2, such as by being positioned at heat accumulation water pot The header board 3a (with reference to Fig. 1) in the front of 2, the side plate 3b being positioned at the side of heat accumulation water pot 2,3b, It is positioned at back plate (backboard) 3c (in the lump with reference to Fig. 1) at the rear of heat accumulation water pot 2, be positioned at heat accumulation Upper plate (top board) 3d of the top of water pot 2 and the lower section (bottom side) being positioned at heat accumulation water pot 2 Base plate 3e is configured to four square box shapes of lengthwise.But, the shape of outer container 3A is not particularly limited In this, can be for example also polygonal shape for viewgraph of cross-section.
Piping cover 3s is arranged on the front of outer container 3A, has the header board 3a covering from outer container 3A The overall shape of upper end to the lower end of (with reference to Fig. 1).Additionally, the height of piping cover 3s and Width (left and right directions) is identical with the height of outer container 3A and width.Thus, at piping cover 3s In the state of being installed in outer container 3A, the square shape in lengthwise in external view.
It additionally, the bottom of the header board 3a at outer container 3A, is used for injecting polyurethane foam liquid etc. and sends out The expanding foam solution 6a (with reference to Fig. 1 and Fig. 4, Fig. 5 (a)~(c) described later) of bubble heat insulating member 6 Inlet the 8th, 8 formed in the way of the inside with outer container 3A connects through header board 3a.This Outward, the top of header board 3a at outer container 3A, also in the way of the inside with outer container 3A connects It is formed with the inlet of expanding foam solution 6a for injecting foaming heat insulation parts 6 the 9th, through header board 3a 9.In addition, inlet the 8th, the 8th, the 9th, 9 be inject foaming heat insulation parts 6 expanding foam solution 6a when The hole needing, after the injection foaming of the expanding foam solution 6a of foaming heat insulation parts 6 covered (cover) Deng closedown.
The heat insulating member that foaming heat insulation parts 6 are not preshaped as foam styrene (becomes Shape heat insulating member), but by the expanding foam solution 6a of foaming heat insulation parts is injected heat accumulation water pot 2 And the foaming heat insulation space between outer container 3A, and this expanding foam solution 6a is made to foam and structure after the implantation The parts becoming.As this foaming heat insulation parts 6, for example, can use RPUF. This RPUF is to be gathered by making two kinds of polyol component and isocyanates composition Obtained from urethane expanding foam solution reacts in the presence of foaming agent, catalyst, surfactant. Additionally, as foaming agent, pentamethylene, water, carbonic acid gas etc. can be used.In addition, foaming Heat insulating member 6 is not limited to RPUF.
Interior leg 4 is the leg (so-called L-type angle) that cross sectional view is bent into L-shaped, with from bottom The top of wallboard 2c configures along the axial mode extending to base plate 3e of heat accumulation water pot 2.Additionally, Interior leg 4 has leg receiving portion 4a, and this leg receiving portion 4a is fixed on heat accumulation water pot 2 by welding Outer surface.This leg receiving portion 4a is also the parts that cross sectional view is bent into L-shaped, is configured to The top of interior leg 4 is inserted into wherein.Interior leg 4 is fixed on leg receiving portion by multiple bolt B T 4a。
Additionally, each interior leg 4 configures around heat accumulation water pot 2 with 120 degree of intervals, in one Leg 4 (4A) configures in the leading section (being positioned at the part of forefront) of heat accumulation water pot 2, in other Leg 4 (4B, 4C) configures in the way of the left and right rear ramp towards heat accumulation water pot 2.
It at the lower surface of base plate 3e, is fixed with outer leg 7 in position corresponding with each interior leg 4.Should Outer leg 7 is fixed on G at setting by foundation bolt (not shown) etc..
Vacuum heat-insulation parts 5 are the parts of sheet, are centered around the main board 2a's of heat accumulation water pot 2 Around.Additionally, vacuum heat-insulation parts 5 are e.g. by by mineral wool (glass wool) etc. The core components that glass fibre is constituted is covered by the outer cladding parts being coated with this core, then outer cladding portion The inside of part is evacuated and constitutes.Outer cladding parts are by the aluminum with barrier properties for gases Laminated film is constituted.
Additionally, vacuum heat-insulation parts 5, the length of such as its axial and circumferential is formed as comparing water storage The axial length of tank 2 and all-round length are short, so that leg receiving portion 4a and temperature sensor T1, T2 is positioned at not overlapping with heat accumulation water pot 2 non-overlapping portion 5b, the mode of 5a is centered around heat accumulation water pot On 2.This is to be reliably achieved the fixing of leg receiving portion 4a and heat accumulation water pot 2.Additionally, It is for temperature sensor T1, T2 readily replaceable when temperature sensor T1, T2 come into question. But, the installation site with regard to vacuum heat-insulation parts 5 is not particularly limited to this.For example also may be used So that vacuum heat-insulation parts 5 to be arranged on the inner peripheral surface of outer container 3A.
Fig. 3 is front elevation during heat accumulation water pot unit in terms of inlet side, and Fig. 4 is from water storage Sectional view (below, the suitably phase during heat accumulation water pot unit of embodiment is seen in the upper plate side of tank Mutual reference).In addition, Fig. 3 and Fig. 4 represent inject foaming heat insulation parts 6 expanding foam solution 6a it Front state.
As it is shown on figure 3, in the bottom of heat accumulation water pot 2, see outer container 3A by inlet the 8th, 8 sides Back plate 3c when, interior leg 4 (4A) is positioned at the central portion of width, leg the 4th, 4 in other (4B, 4C) is positioned at the substantially two ends of width.Additionally, feed pipe 11 and oral siphon 12 Pass through base plate from the central side of heat accumulation water pot 2 (the front side of diagram vertical direction) to outer peripheral side The vicinity of 3e, configure upward along interior leg 4 (4A).
Additionally, be formed with gap s1, s1 between the side plate 3b and heat accumulation water pot 2 of outer container 3A. In this gap, s1, s1 are also filled with foaming heat insulation parts 6.But, when heat accumulation water pot 2 and side When plate 3b directly contacts, it is possible to the heat in heat accumulation water pot 2 is shed to heat accumulation by outer container 3A The outside of water pot unit 1A.But, by side plate 3b and heat accumulation water pot 2 at outer container 3A Between guarantee gap s1, can suppress heat leakage, therefore, it is possible to suppression as hot-warer supplying machine K Efficiency reduce.In addition, by the degree of the leakage that gap s1 is set as can suppress heat Minimal distance, can constitute heat accumulation water pot unit 1A compactly.
On the other hand, the inlet 8A (8) (on the left of diagram) is formed at and leaves heat accumulation water pot the 2nd, The position of all parts of interior leg 4B, oral siphon 12 and interior leg 4A, and be formed at and can lead to Cross the position that inlet 8A sees back plate 3c (depths) of outer container 3A.In other words, from note In plan view when entrance 8A sees, inlet 8A be formed at heat accumulation water pot the 2nd, interior leg 4B, Oral siphon 12 and the nonoverlapping position of interior leg 4A.
The inlet 8B (8) of other (on the right side of diagrams) too, is formed at and leaves water storage The position of all parts of tank the 2nd, interior leg 4C, feed pipe 11 and interior leg 4A, and be formed at The position of back plate 3c (depths) of outer container 3A can be seen by inlet 8B.In other words, In plan view when in terms of inlet 8B, inlet 8B is formed at and interior leg 4C, heat accumulation Water pot the 2nd, feed pipe 11 and the nonoverlapping position of interior leg 4A.
On the top of heat accumulation water pot 2, from the inlet of the expanding foam solution 6a of foaming heat insulation parts 6 the 9th, When 9 sides are seen in outer container 3A, hot-water outlet pipe 13 and heat supply water pipe 14 are from the center of heat accumulation water pot 2 Lateral outer circumferential side (also in the lump with reference to aftermentioned Fig. 4) goes, then along top wallboard 2b to face side (piping cover 3s side) extends.Additionally, when hot-warer supplying machine K has bathtub (not shown), It is provided with the heat exchanger HE reheating in heat accumulation water pot 2, with this heat exchanger HE even The bathtub return pipe 15 connecing is connected with the top of heat accumulation water pot 2.This bathtub return pipe 15 also with Above-mentioned hot-water outlet pipe 13 is the same with heat supply water pipe 14, from lateral front, the center of heat accumulation water pot 2 Side (piping cover 3s side) extends.In addition, in the following description, heat exchanger HE and bath The structure that cylinder return pipe 15 is not necessarily required to.That is, not there is heat exchanger HE and bath The heat accumulation water pot unit of cylinder return pipe 15 also can apply embodiments of the present invention certainly.
Inlet the 9th, 9 (9A, 9B) are formed at and leave heat accumulation water pot the 2nd, hot-water outlet pipe and the 13rd, supply Hot-water line 14 and the position of bathtub return pipe 15, and be formed at can by inlet 9A, 9B sees the position of back plate 3c of outer container 3A.In other words, when in terms of inlet 9A, 9B Plan view in, with heat accumulation water pot the 2nd, hot-water outlet pipe the 13rd, inlet 9A, 9B are formed at Heat supply water pipe 14 and the nonoverlapping position of bathtub return pipe 15.
The heat supply water pipe 14 on heat accumulation water pot 2 top is configured top wallboard 2b's by base 20 Substantially near top.In addition, in figure 3, the base of hot-water outlet pipe's the 13rd, bathtub return pipe 15 20 omit.Base 20 for example includes hollow cylindrical portion and tool for inserting heat supply water pipe 14 Having from hollow cylindrical portion is the flange part of the prominent shape of overshooting shape.
On base 20, engage supporting at above-mentioned flange part with the step difference part of hollow cylindrical portion Parts 40.This supporting parts 40 such as substantially cylindrical shape with the end in hollow, is to have bottom The securing member of the roughly equal shape of the external diameter of hollow cylindrical portion of hollow footpath and base 20.And And, it is provided with the otch 21 inserted for heat supply water pipe 14.This supporting parts 40 are by welding Or the upper plate 3d of the method such as bolt is fixing and outer container 3A fixes.In other words, supporting parts 40 is The securing member engaging with the base 20 for heat supply water pipe 14 is fixed on heat accumulation water pot 2, should Securing member is fixed in outer container 3A the interior leg 4 one becoming with the end side as heat accumulation water pot 2 The inner surface in relative face, another side of the opposition side of side.
Therefore, in existing heat accumulation water pot unit, it is known that as supply to heat accumulation water pot In the case that water uses the high hardness waters such as well water, when pipe arrangement uses the copper alloys such as brass, because of timeliness Deterioration and pipe arrangement inner surface corrodes, cause stress-corrosion cracking (referring for example to bibliography 1: " big Tianjin military logical " stress-corrosion cracking of copper alloy ", anticorrosion technique, Vol.12 (1963), No.9, P412-423, or, Https: //www.jstage.jst.go.jp/article/jcorr1954/12/9/12_9_413/_pd f is international mutual Networking, Heisei retrieval on August 1st, 26 ").Therefore, for the purpose of tackling this problem, design Make all stainless products of pipe arrangement class (for example, referring to patent document 1).
But, the situation of the high hardness waters such as well water is not used at the water as supply to heat accumulation water pot Under, it is not required to consider the problem of the corrosion of pipe arrangement inner surface, therefore due to cost-benefit pass System, pipe arrangement uses the example of copper alloy common.
On the other hand, in the heat accumulation water pot unit 1A of embodiments of the present invention, no matter supply Being which species to the water of heat accumulation water pot 2, it is right that the pipe arrangement of the inside being accommodated in outer container 3A all uses Amine or ammonia have the pipe arrangement of corrosion resistance.Specifically, at least bag being accommodated in outer container 3A Include feed pipe the 11st, oral siphon the 12nd, hot-water outlet pipe the 13rd, heat supply water pipe the 14th, bathtub return pipe 15 All pipe arrangements by amine or ammonia are had corrosion resistance pipe arrangement constitute.In addition, this place Meaning pipe arrangement refer to either bobbin (pipe), flexible pipe (tube), coiled pipe (hose) etc. which kind of The concept that all of which is included by pattern.
The reason using the pipe arrangement being formed by the material to amine or ammonia with corrosion resistance is as follows. As described above, in the heat accumulation water pot unit 1A of embodiments of the present invention, outer container 3A with The expanding foam solution 6a of foaming heat insulation parts 6 is injected in gap between heat accumulation water pot 2.This expanding foam solution 6a In the contained hydroxyl of polyalcohol and the NCO of isocyanates composition react and formed Polyurethane.When forming polyurethane, by making foaming agent foam, become polyurathamc, by The foaming heat insulation parts 6 that polyurathamc is constituted are not filled in outer container 3A and water storage with having space Between tank 2.The foaming heat insulation parts 6 being made up of this polyurathamc from once synthesize because of attachment Hydrolyzable that moisture (such as dew) around heat accumulation water pot 2 and pipe arrangement is caused or The decomposition that caused because of the heat of surrounding and persistently deteriorate.The hydrolyzable of following presentation polyurethane is anti- The example answered or the example of the thermal decomposition of polyurethane.
[chemical formula 1]
[chemical formula 2]
Herein, chemical formula 1 is the adding water of polyurathamc representing and forming foaming heat insulation parts 6 The chemical equation of the example decomposing, chemical formula 2 is to represent to form sending out of foaming heat insulation parts 6 The chemical equation of the example of the thermal decomposition of bubble polyurethane.R, R in formula ' for example represent alkyl. In addition, R, R ' both can be identical, it is also possible to different from each other.It is attached to heat accumulation water pot 2 and pipe arrangement The moisture of surrounding for example can enumerate dew.Additionally, the surrounding of heat accumulation water pot 2 and pipe arrangement The situation of the heat such as heat directly heat transfer of the hot water of the inside of consideration heat accumulation water pot 2 and pipe arrangement, Or consider to be passed by indirect underground heat such as its gaps in the case of being surrounded with vacuum heat-insulation parts 5 Situation about leading.
Carbonyl in the structural formula of general polyurethane is easily subject to water (H2O) oxygen (O) causes Necleophilic reaction.Accordingly, because the ammonia ester bond in polyurethane reacts with the moisture of surrounding, Polyurethane be decomposed (hydrolyzable) be isocyanates composition and polyol component.Additionally, it is poly- Ammonia ester bond in urethane key between C-O is more weak, and polyurethane is divided owing to being exposed to hanker Solving (thermal decomposition) is isocyanates composition and polyol component.
And, the NCO of the isocyanates composition being generated by the decomposition of polyurethane and water Reaction, thus isocyanates composition is broken down into amine component and the carbon dioxide (CO with amino2) (hydrolyzable).
[chemical formula 3]
As shown in chemical formula 3, when isocyanates composition is by hydrolyzable, generate one-level amine and Carbon dioxide.In the case that in chemical formula, the alkyl (R) of amine is hydrogen atom (H), should Amine becomes ammonia (NH3), generate ammonia.To this in other words, as shown in chemical formula 1~3, pass through The decomposition of above-mentioned foaming heat insulation parts 6, generates amine or ammonia.
But, the ammonia so producing for example as the corrosive medium of the copper alloys such as brass by extensive Solve, and be known as ammonia and be very easy to be dissolved in water so because humidity is affected.I.e., Know in the atmosphere of ammonia, the stress-corrosion cracking (example of the copper alloys such as brass occurs very significantly P418 " 32 ammonia " joint as with reference to above-mentioned bibliography 1).
Therefore, in the case that pipe arrangement is made up of Cu alloy materials such as brass as prior art, Unrelated with the water quality such as hardness of water of supply, due to the foaming being made up of polyurathamc every The ammonia that the deterioration that the decomposition of thermal part 6 is caused carries out and produces, and there is the external table of pipe arrangement The corrosion in face.And, when deterioration is gone down further, there are the feelings causing stress-corrosion cracking Condition.
It in order to tackle this problem, is accommodated in the heat accumulation water pot unit 1A's of embodiments of the present invention The pipe arrangement of the inside of outer container 3A is all made up of the pipe arrangement to amine or ammonia with corrosion resistance.
In addition, as such concrete candidate couple to amine or ammonia with corrosion resistance pipe arrangement As being for example both stainless pipe arrangement or resinous pipe arrangement.Additionally, also The pipe arrangement of the material beyond them can be.Further, for example when parts such as the joints at pipe arrangement Be simultaneously used as combining polymer obtained from sulphur (condensate) in phenyl ring, heat-resisting resistance to During the parts of Compressive Strength aspect of performance excellent PPS (polyphenylene sulfide) resin, not only corrosion-resistant Property is excellent and deflection is also suppressed, it may be said that more preferably.Additionally, for example make corrosion-resistant In the case that property pipe arrangement is stainless pipe arrangement, as the advantage beyond corrosion resistance, additionally it is possible to Enjoy and be difficult to attachment dirt at outer surface, be difficult to attachment incrustation scale at inner surface, be difficult to equivalence of getting rusty With, thus preferably.
In this condition, as shown in Figure 4, make inlet 9A, 9B in vertical direction upwards, The expanding foam solution 6a of foaming heat insulation parts 6 from inlet 9A, 9B towards vertical direction below inject. That is, inlet 9A, 9B becomes the upside of vertical direction, and back plate 3c of outer container 3 becomes vertical (end) side under direction.
But, if the foaming heat insulation parts 6 before injecting foaming from inlet 9A, 9B During expanding foam solution 6a, the expanding foam solution 6a of foaming heat insulation parts 6 reaches back plate 3c of outer container 3A Midway the 20th, support with hot-water outlet pipe's the 13rd, heat supply water pipe the 14th, bathtub return pipe the 15th, base Parts 40 other component contact of grade, then at hot-water outlet pipe's the 13rd, heat supply water pipe the 14th, bathtub backwater The 20th, pipe the 15th, base supports other parts such as parts 40 and starts foaming, there is foaming heat insulation portion The problem that part 6 does not diffuses into the rear side of other parts.Therefore, in embodiments, from note When entrance 9A, 9B inject the expanding foam solution 6a of foaming heat insulation parts 6 below vertical direction, make The expanding foam solution 6a of foaming heat insulation parts 6 not with heat accumulation water pot the 2nd, hot-water outlet pipe the 13rd, heat supply water pipe 14th, the 20th, bathtub return pipe the 15th, base supports the back plate that parts 40 reach outer container 3A contiguously The internal face 3c1 of 3c.Thereby, it is possible to make foaming heat insulation parts 6 foam upward from bottom side, Whole gaps that foaming heat insulation parts 6 are diffused between heat accumulation water pot 2 and outer container 3A can be made.
In addition, in the feelings of the expanding foam solution 6a injecting foaming heat insulation parts 6 from inlet 8A, 8B Under condition, also make from inlet 8A, 8B inject foaming heat insulation parts 6 expanding foam solution 6a not with Heat accumulation water pot is outside the 2nd, interior leg 4A, 4B, 4C, feed pipe the 11st, oral siphon 12 reaches contiguously The internal face 3c1 of back plate 3c of case 3A.Thereby, it is possible to make foaming heat insulation parts 6 from bottom side to Top foaming, can make foaming heat insulation parts 6 be diffused between heat accumulation water pot 2 and outer container 3A Whole gaps.
Additionally, be formed with gap s2 between back plate 3c and heat accumulation water pot 2 of outer container 3A.? This gap s2 also filling-foam heat insulating member 6.Additionally, at the header board 3a of outer container 3A and heat accumulation It is also formed with gap s3 between water pot 2.So, by assuring that gap s2, s3, can suppress The leakage of heat, therefore, it is possible to suppression reduces as the efficiency of hot-warer supplying machine K.In addition, by inciting somebody to action Gap s2, s3 are set as suppressing the minimal distance of the degree of the leakage of heat, can Constitute heat accumulation water pot unit 1A compactly.
The figure of the flowing of the foaming heat insulation parts (expanding foam solution) when Fig. 5 (a) is to represent injection, Fig. 5 (b) be represent injection complete after the figure of state of foaming heat insulation parts (expanding foam solution), Fig. 5 (c) is the figure of the state representing foaming midway.Wherein, hot-water outlet pipe 13 and bathtub are omitted The record of return pipe 15.
As shown in Fig. 5 (a), before piping cover 3s (with reference to Fig. 1) is installed, in making utilization The structure that leg 4A, 4B, 4C and supporting parts 40 are fixed on heat accumulation water pot 2 in outer container 3A Body becomes following state: by outer container 3A traverse, becomes water up and down during the use of outer container 3A Square to and make header board 3a upward, inlet is the 8th, 9 upward.So by outer container 3A traverse Under state, utilize the week of foaming management tool (also referred to as work piece holder) 30 covering outer container 3A Enclose (with reference to the double dot dash line of Fig. 5) so that outer container 3A will not be due to foaming heat insulation parts 6 Expanding foam solution 6a foaming when pressing force and deform.Foaming management fixture 30 surrounds the whole of outer container 3A Around individual, including press all header board 3a, side plate 3b, 3b, back plate 3c, upper plate 3d, the end The fixture of the tabular of plate 3e.Afterwards, the outside from foaming management fixture 30 will be with inlet the 8th, The 9 preformed nozzles 31 in corresponding position insert inlet the 8th, in 9, from inlet the 8th, 9 Inject the expanding foam solution 6a of foaming heat insulation parts 6.
Thus, from inlet 9A, 8B inject foaming heat insulation parts 6 expanding foam solution 6a not by The 20th, heat accumulation water pot the 2nd, hot-water outlet pipe the 13rd, heat supply water pipe the 14th, bathtub return pipe the 15th, base props up Bearing portion part 40 hinders ground to reach the internal face 3c1 of bottom side (back plate 3c).Afterwards, foaming heat insulation The expanding foam solution 6a of parts 6 along back plate 3c internal face 3c1 extension, as shown in Fig. 5 (b) that Sample Depth Expansion to specify in a face of internal face 3c1.In addition, inject foaming heat insulation portion The degree of depth of the expanding foam solution 6a of part 6 suitably can change according to the expansion ratio of foaming heat insulation parts 6.
Afterwards, foaming heat insulation parts 6 start foaming, from outer container 3A as shown in Fig. 5 (c) Back plate 3c side (on the downside of diagram, bottom side) gradually foam to header board 3a side (on the upside of diagram). Afterwards, foaming heat insulation parts 6 foam to the internal face 3a1 of header board 3a, outer container 3A and water storage Whole gaps between tank 2 are full of by foaming heat insulation parts 6.
Now, outside the downside (on the left of the paper of Fig. 5 (a)) of heat accumulation water pot 2 is by being fixed on Interior leg 4A, 4B, 4C of case 3A, even if by the blow pressure Pa of foaming heat insulation parts 6 (with reference to the hollow arrow of Fig. 5 (b), Fig. 5 (c)) is also prevented from position skews such as floating. Additionally, the upside of heat accumulation water pot 2 (on the right side of the paper of Fig. 5 (a)) is also by being fixed on outer container The supporting parts 40 of 3A, even if by blow pressure Pa (reference Fig. 5 of foaming heat insulation parts 6 The hollow arrow of (b), Fig. 5 (c)) it is also prevented from position skews such as floating.
Additionally, utilize foaming management tool 30, the outer surface of outer container 3A is overall to be pinned, by Blow pressure Pa when this is foamed by foaming heat insulation parts 6 is prevented from outer container 3A and expands (change Shape).Then, foaming heat insulation parts 6 solidify after foaming terminates.
Fig. 6 is the cross-sectional view of heat accumulation water pot unit.
As in Fig. 6 to represent, foaming heat insulation parts 6 are disposed around water storage Between the vacuum heat-insulation parts 5 of tank 2 and outer container 3A.
Additionally, in the front portion of heat accumulation water pot unit 1A, outer container 3A with closest to this outer container 3A Heat accumulation water pot 2 between be formed with gap s3, in the s3 of this gap, be filled with foaming heat insulation parts 6.Additionally, heat accumulation water pot 2 vacuum heat-insulation parts 5 not around non-overlapping portion 5a also It is filled with foaming heat insulation parts 6.
Additionally, in heat accumulation water pot unit 1A both sides, outer container 3A with closest to this outer container 3A Vacuum heat-insulation parts 5 between be formed with gap s1, s1, each gap s1 be filled with foaming every Thermal part 6.Equally, the rear portion at heat accumulation water pot unit 1A, is somebody's turn to do with closest at outer container 3A It is formed with gap s2 between the vacuum heat-insulation parts 5 of outer container 3A, be filled with at this gap s2 and send out Bubble heat insulating member 6.
By so forming gap s3 and at vacuum heat-insulation between heat accumulation water pot 2 and outer container 3A Form gap s1, s1, s2 between parts 5 and outer container 3A, and arrange in these positions foaming every Thermal part 6, can suppress the heat in heat accumulation water pot 2 to leak to outer container by vacuum heat-insulation parts 5 The outside of 3A.
Fig. 7 (a) is the preflood vacuum heat-insulation parts of foaming heat insulation parts (expanding foam solution) Covering state, Fig. 7 (b) be foaming heat insulation parts (expanding foam solution) injection, foaming after true The covering state of empty heat insulating member.
But, vacuum heat-insulation parts 5 heat-proof quality compared with foaming heat insulation parts 6 etc. is excellent, Solidified by compression by vacuumizing etc..Vacuum heat-insulation parts 5 after so solidifying are any Ground is deposited when bending or configure in the way of being close to be fixed on the cylinder of outer surface of heat accumulation water pot 2 In difficulty.
Therefore, in embodiments, use vacuum heat-insulation parts 5 and foaming heat insulation parts 6 simultaneously, It is possible to make vacuum heat-insulation parts 5 by utilizing the pressure during foaming of foaming heat insulation parts 6 It is close to the outer peripheral face of heat accumulation water pot 2.Additionally, in embodiments, by not using shaping Foaming heat insulation parts and use the expanding foam solution making its foaming heat insulation parts 6 foaming after the implantation 6a, can utilize the gap that foaming heat insulation parts 6 landfill can not be filled by vacuum heat-insulation parts 5 S1, s2, s3, top wallboard 2b, the gap of surrounding of bottom wallboard 2c.It is possible to realize The raising of heat-proof quality.
That is, as shown in Fig. 7 (a), if the expanding foam solution 6a of filling-foam heat insulating member 6 it The front outer surface that vacuum heat-insulation parts 5 are centered around heat accumulation water pot 2, then at heat accumulation water pot 2 Form gap S between outer surface and vacuum heat-insulation parts 5.But, as shown in Fig. 7 (b), The expanding foam solution 6a of foaming heat insulation parts 6 is injected between outer container 3A and vacuum heat-insulation parts 5, It is possible to blow pressure Pa when being foamed by foaming heat insulation parts 6 by vacuum heat-insulation parts 5 directions being pressed against on heat accumulation water pot 2 play a role, and make vacuum heat-insulation parts 5 be close to storage The outer surface of hot-water cylinder 2.
In such manner, it is possible to make vacuum heat-insulation parts 5 be close to heat accumulation water pot 2, therefore heat accumulation water pot unit 1A can improve heat-proof quality.Thereby, it is possible to obtain the heat accumulation water pot with high energy-efficient performance Unit 1A.
(action effect)
Again the action effect of embodiments of the present invention is summarized, as described below.
In the heat accumulation water pot unit 1A of embodiment, inlet 9A, 9B are configured at from this When inlet 9 (9A, 9B) is seen in outer container 3A, (can not be gone out by heat accumulation water pot the 2nd, pipe arrangement Hot-water line the 13rd, heat supply water pipe the 14th, bathtub return pipe 15), base 20 and support parts 40 hamper See the position of the depths (back plate 3c) of outer container 3A with hindering.According to this structure, from injection When mouth 9A, 9B are filled with the expanding foam solution 6a of foaming heat insulation parts 6, can be by foaming heat insulation portion The expanding foam solution 6a of part 6 is directly fed to the internal face 3c1 of back plate 3c from inlet 9A, 9B, Therefore, it is possible to foaming heat insulation parts 6 are filled in outer container 3A and heat accumulation above heat accumulation water pot 2 Whole gaps between water pot 2.Thereby, it is possible to obtain the water storage with high heat-proof quality Tank unit 1A.
Additionally, in the heat accumulation water pot unit 1A of embodiment, inlet 8A, 8B are configured at When seeing in outer container 3A from this inlet 8 (8A, 8B), the 2nd, can not be joined by heat accumulation water pot Pipe (feed pipe the 11st, oral siphon 12) and interior leg 4 (4A, 4B, 4C) hinder ground to see outer container The position of the depths (back plate 3c) of 3A.According to this structure, injecting from inlet 8A, 8B During the expanding foam solution 6a of foaming heat insulation parts 6, can by the expanding foam solution 6a of foaming heat insulation parts 6 It is directly fed to the internal face 3c1 of back plate 3c from inlet 8A, 8B, therefore, it is possible at heat accumulation It is complete that foaming heat insulation parts 6 are filled between outer container 3A and heat accumulation water pot 2 by the lower section of water pot 2 Gap, portion.Thereby, it is possible to obtain the heat accumulation water pot unit 1A with high heat-proof quality.
Additionally, general heat accumulation water pot 2 is outside being injected into the expanding foam solution 6a of foaming heat insulation parts 6 When case 3A is internal, because centre is empty, thus the buoyancy being caused by blow pressure Pa and It is susceptible to position skew.But, the heat accumulation water pot 2 of embodiment has following structure: under Side (on the left of the paper of Fig. 5 (a)) by interior leg receiving portion 4a by solid to interior leg 4A, 4B, 4C It is scheduled on outer container 3A, and upside (on the right side of the paper of Fig. 5 (a)) will also by base 20 Supporting parts 40 are fixed on outer container 3A.Thus, though by foaming heat insulation parts 6 send out Bubble pressure while Pa (with reference to Fig. 5 (b), the hollow arrow of Fig. 5 (c)), also because of heat accumulation water pot 2 Action limited, it is possible to be reliably prevented heat accumulation water pot 2 the position skew such as floats.
Additionally, according to embodiment, be surrounded with the vacuum heat-insulation parts 5 of sheet at heat accumulation water pot 2, Therefore, it is possible to improve thermal insulation further, and the foaming pressure of foaming heat insulation parts 6 can be utilized Power Pa and make vacuum heat-insulation parts 5 be close to the outer surface of heat accumulation water pot 2, therefore, it is possible to obtain There is the heat accumulation water pot unit 1A of higher heat-proof quality.
Additionally, according to embodiment, interior leg 4 (4A, 4B, 4C) is constituted by three, therefore Easily can stably be bearing in heat accumulation water pot 2 in outer container 3A, furthermore it is possible to will inject The 8th, 8 be formed at can not be by heat accumulation water pot the 2nd, pipe arrangement (feed pipe the 11st, oral siphon 12) for mouth See the position of back plate 3c with the ground that hinders of interior leg 4 (4A, 4B, 4C).
Additionally, according to embodiment, be accommodated in all pipe arrangements of inside of outer container 3A by amine Or ammonia has the pipe arrangement composition of corrosion resistance.Specifically, at least bag being accommodated in outer container 3A Include feed pipe the 11st, oral siphon the 12nd, hot-water outlet pipe the 13rd, heat supply water pipe the 14th, bathtub return pipe 15 All pipe arrangements by amine or ammonia are had corrosion resistance pipe arrangement constitute.Thus, even if sending out Bubble heat insulating member 6 due to moisture and/or heat and there is chemical reaction, such as ammonia ester bond be decomposed and Producing ammonia, this ammonia for example also will not become corrosive medium and cause stress-corrosion cracking.By This, air-tightness is improved, so will not occur what stress-corrosion cracking caused to leak.That is, It is capable of the heat accumulation water pot unit 1A with high water storage performance.
Therefore, outside heat accumulation water pot unit 1A is generally located on outside room in home-use grade etc. and to be exposed to The place of gas (rain).Additionally, foaming heat insulation parts 6 are because having the property of the impact of Yi Shoushui Matter, it is advantageous to be the structure not contacted with water.Therefore, in embodiments, inlet is the 8th, 8 configurations are at piping cover 3s side (header board 3a side), the thus expanding foam solution at foaming heat insulation parts 6 After the injection of 6a, foaming terminate, the 8th, inlet 8 is covered by piping cover 3s (with reference to Fig. 1). The inlet of the immersion mouth therefore becoming water (rainwater) the 8th, 8 is covered by piping cover 3s, even if Inlet the 8th, 8 measures using reply water to immerse (for example, the 8th, 8 are not added at inlet Lid the measure gap landfill of lid got up further with seal member), it is also possible to only pass through With simple lid blocking inlet the 8th, 8 prevent from inlet the 8th, 8 the immersion of water.By This, can simplify the structure of heat accumulation water pot unit 1A.
Above-mentioned embodiment has been carried out detailed to illustrate to be readily apparent that the present invention Illustrate, but be not necessarily limited to include illustrated all structures.Furthermore it is possible to by one A part for the structure of individual embodiment replaces with the structure of another embodiment, additionally it is possible to Part or all of structure of another embodiment is added in the structure of an embodiment. Furthermore it is possible to the part of the structure of each embodiment is carried out the adding of other structures, remove, Replace.
For example, in embodiments, enumerate by vacuum heat-insulation parts 5 with heat accumulation water pot 2 Outer peripheral face contact mode around structure as a example by be illustrated, but be not limited to this, Also can for case 3 outside internal face (header board 3a, side plate 3b, back plate 3c, upper plate 3d, Each inwall of base plate 3e) configuration vacuum heat-insulation parts 5 structure.Thereby, it is possible to not only cover The side (side face side) of heat accumulation water pot 2, but also with including above and below heat accumulation water pot 2 Cover the whole surrounding of heat accumulation water pot 2.
Additionally, as the variation of embodiment, outer container 3A also can be formed as viewgraph of cross-section In be octagon.Even so, because the distance of heat accumulation water pot 2 and outer container in the circumferential substantially Identical, so being filled in the loading of the foaming heat insulation parts 6 of the surrounding of heat accumulation water pot 2 front Rear left and right is also roughly the same.Thereby, it is possible to make to act on the foaming heat insulation parts 6 of heat accumulation water pot 2 Blow pressure Pa uniform, be prevented from occurring the generation of the unfavorable conditions such as heat accumulation water pot 2 deformation.
Additionally, in embodiments, the base making supporting parts 40 and heat supply water pipe 14 is used The structure of 20 engagings, but it is not limited to this.Supporting parts 40 with arrange the species of pipe arrangement without Close.The base 20 with hot-water outlet pipe's the 13rd, bathtub return pipe 15 for example also can be used to block respectively The structure closed.
Additionally, no matter the species of hot-water supply why, the present invention can be applied to water The hot-water supply etc. of road direct press type, the hot-water supply of this water channel direct press type be to tap or Shower first-class supplying hot water terminal 18 supplies the hot water that takes out from the top of heat accumulation water pot 2 with from the beginning The running water that water carries out heat exchange and becomes warm water.
Furthermore it is possible to be applied to that there is the confession reheating heat exchanger HE in the outside of heat accumulation water pot Hot water apparatus.

Claims (4)

1. a heat accumulation water pot unit, it is characterised in that include:
Heat accumulation water pot;
Receive the outer container of described heat accumulation water pot;
Between described outer container and described heat accumulation water pot inject expanding foam solution carry out foaming and formed send out Bubble heat insulating member;With
Pipe arrangement, it is accommodated in the inside of described outer container, divides for by described foaming heat insulation parts The amine or the ammonia that solve and produce have corrosion resistance.
2. heat accumulation water pot unit as claimed in claim 1, it is characterised in that:
Described pipe arrangement at least includes: import the feed pipe of running water to described heat accumulation water pot;From institute State heat accumulation water pot to the oral siphon of heat pump;From described heat pump to the hot-water outlet pipe of described heat accumulation water pot; With the heat supply water pipe from described heat accumulation water pot to supplying hot water terminal.
3. heat accumulation water pot unit as claimed in claim 1, it is characterised in that:
Described pipe arrangement is formed by stainless steel or resin.
4. heat accumulation water pot unit as claimed in claim 1, it is characterised in that:
Described foaming heat insulation parts are hard polyurethane foams.
CN201510082229.9A 2014-08-22 2015-02-15 Heat accumulation water pot unit Expired - Fee Related CN105987509B (en)

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JP2007292435A (en) * 2006-03-31 2007-11-08 Osaka Gas Co Ltd Atmosphere open type heat storage tank
JP2010096364A (en) * 2008-10-14 2010-04-30 Ecotec Co Ltd Electric water heater
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