CN105986281A - Descaling agent for industrial boiler - Google Patents

Descaling agent for industrial boiler Download PDF

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Publication number
CN105986281A
CN105986281A CN201510084214.6A CN201510084214A CN105986281A CN 105986281 A CN105986281 A CN 105986281A CN 201510084214 A CN201510084214 A CN 201510084214A CN 105986281 A CN105986281 A CN 105986281A
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China
Prior art keywords
methenamine
mother liquor
mass percent
boiler
raw material
Prior art date
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Pending
Application number
CN201510084214.6A
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Chinese (zh)
Inventor
张舜贤
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Fujian Golden Dongyang Chemical Industry And Trade Co Ltd
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Fujian Golden Dongyang Chemical Industry And Trade Co Ltd
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Priority to CN201510084214.6A priority Critical patent/CN105986281A/en
Publication of CN105986281A publication Critical patent/CN105986281A/en
Pending legal-status Critical Current

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  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
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Abstract

The invention discloses a descaling agent for an industrial boiler. The descaling agent comprises mother liquor and a corrosion inhibitor; the mother liquor comprises the following raw materials in percentage by mass: 20-40% of acetic acid, 15-25% of phosphoric acid, 1-3% of penetrating agent, 5-10% of sodium dodecyl benzene sulfonate, 3-5% of ethanol with a volume concentration of 70-75%, 3-5% of urea, 2-5% of orange peel oil, 3-7% of glycerinum, 0.1-0.5% of urotropin, 2-15% of carbon fibers, and 20-45% of water; and the corrosion inhibitor comprises the raw materials in percentage by mass: 20-45% of sodium dodecyl sulfate, 10-25% of vicinal and contrapuntal methylbenzene, 25-35% of octadecylamine, 15-30% of urotropin, and 5-18% of glyceryl tristearate. The descaling agent is scientific in matching, is free of corrosion and poison on metal, can quickly dissolve such scale components as calcium carbonate, magnesium carbonate, calcium sulfate, calcium silicate and iron oxide attached in the boiler, and achieves the purpose of thoroughly removing the scales of the boiler.

Description

A kind of Industrial Boiler scale remover
Technical field
The present invention relates to a kind of scale remover, specifically a kind of Industrial Boiler scale remover.
Background technology
Most equipment after used a period of time, all can produce dirt more or less, and these dirts will affect the normal use of equipment, it is therefore desirable to dirt is cleared up by timing.Typically being bonded on equipment due to dirt, cleaning up is relatively difficult, especially some small-sized, special-shaped equipment.Scale remover is a kind of chemicals going multiple dirt stain such as scale removal, dirt, is typically formed by various ingredients is compounding.According to the difference of application, scale remover is roughly divided into industrial scale remover and household descaling agent, and industrial scale remover is mainly used in removing the dirt in heat transmission equipment, boiler etc., and household descaling agent is mainly used in removing the dirt in water dispenser, kettle etc..
Industrial Boiler generally refers to the boiler for the heating in industrial production, boiling, drying, factory building or the aspect such as people's heating for residential area and hot water supply.When in boiler, water temperature raises, the salt in water concentrates, and will produce deposition when its concentration exceedes the solubility at a temperature of this, and some salts, as calcium sulfate, magnesium sulfate, calcium phosphate etc. then decline as temperature rises high-dissolvability and separate out;In the boiler, also can separate out when basicity is come higher by the concentration of silica;And solubility heavy carbonate, as carbonic acid calcium dihydrogen, carbonic acid dihydro magnesium are then thermally decomposed, produce indissoluble salt and also result in deposition.These deposits are generally fixedly arranged at boiler or pipe surface, bring serious harm to normal use of boiler: first, and dirt thermal conductivity extreme difference can cause uneven situation of conducting heat because being heated, thus waste fuel or electric power;Secondly, if dirt is consolidated in boiler inner wall, also can greatly increase boiler and burst, owing to expanding with heat and contract with cold and unbalance stress, the danger even exploded;Again, during dirt consolidation, also usually can adhere to plurality of heavy metal ion, if this boiler is used for containing drinking water, have heavy metal ion and be too much dissolved in the risk of drinking water.It accordingly, it would be desirable to a kind of efficient boiler scale remover of research, is attached to the dirt of boiler inner wall with removing quick, thorough.
Content of the invention
It is an object of the invention to provide a kind of Industrial Boiler scale remover, can quickly, thoroughly remove the dirt being attached to boiler inner wall.
For achieving the above object, the present invention provides following technical scheme:
A kind of Industrial Boiler scale remover, including mother liquor and corrosion inhibiter, according to the raw material of mass percent, described mother liquor includes that acetic acid 20-40%, phosphatase 11 5-25%, bleeding agent 1-3%, neopelex 5-10%, volumetric concentration are the ethanol 3-5% of 70-75%, urea 3-5%, tangerine peel oil 2-5%, glycerine 3-7%, methenamine 0.1-0.5%, carbon fiber 2-15%, water 20-45%;Described corrosion inhibiter includes the toluene thiocarbamide 10-25% of dodecyl sodium sulfate 20-45%, ortho position and contraposition, octadecylamine 25-35%, methenamine 15-30%, glyceryl tristearate 5-18% according to the raw material of mass percent.
As the further scheme of the present invention: according to the raw material of mass percent, described mother liquor includes that acetic acid 20-30%, phosphoric acid 20-25%, bleeding agent 1-2%, neopelex 5-8%, volumetric concentration are the ethanol 3-5% of 70-75%, urea 3-5%, tangerine peel oil 2-3%, glycerine 5-7%, methenamine 0.1-0.3%, carbon fiber 2-8%, water 20-32%;Described corrosion inhibiter includes the toluene thiocarbamide 10-15% of dodecyl sodium sulfate 20-35%, ortho position and contraposition, octadecylamine 25-32%, methenamine 20-30%, glyceryl tristearate 5-12% according to the raw material of mass percent.
As the further scheme of the present invention: described mother liquor includes, according to the raw material of mass percent, ethanol the 3%th, urea the 5%th, tangerine peel oil the 2%th, glycerine the 5%th, methenamine the 0.3%th, carbon fiber the 3%th, water 24.7% that acetic acid the 25%th, phosphoric acid the 25%th, bleeding agent the 2%th, neopelex the 5%th, volumetric concentration is 70-75%;Described corrosion inhibiter includes toluene thiocarbamide the 15%th, octadecylamine the 25%th, methenamine the 25%th, glyceryl tristearate 8% of dodecyl sodium sulfate the 27%th, ortho position and contraposition according to the raw material of mass percent.
Compared with prior art, the invention has the beneficial effects as follows: proportioning science of the present invention, corrosion-free, nontoxic to metal, can reach thoroughly to remove the purpose of boiler scale with composition of scales such as the calcium carbonate of rapid solution boiler internal attachment, magnesium carbonate, calcium sulfate, calcium silicates and iron oxide.The raw materials used source of the present invention is wide and biodegradable, environmentally safe, easy to use, economic security.
Detailed description of the invention
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is only a part of embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, every other embodiment that those of ordinary skill in the art are obtained under the premise of not making creative work, broadly fall into the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of Industrial Boiler scale remover, including mother liquor and corrosion inhibiter, described mother liquor includes, according to the raw material of mass percent, ethanol the 3%th, urea the 5%th, tangerine peel oil the 5%th, glycerine the 3%th, methenamine the 0.5%th, carbon fiber the 5.5%th, water 20% that acetic acid the 20%th, phosphoric acid the 25%th, bleeding agent the 3%th, neopelex the 10%th, volumetric concentration is 70-75%;Described corrosion inhibiter includes toluene thiocarbamide the 25%th, octadecylamine the 25%th, methenamine the 20%th, glyceryl tristearate 10% of dodecyl sodium sulfate the 20%th, ortho position and contraposition according to the raw material of mass percent.
Embodiment 2
In the embodiment of the present invention, a kind of Industrial Boiler scale remover, including mother liquor and corrosion inhibiter, described mother liquor includes, according to the raw material of mass percent, ethanol the 3%th, urea the 5%th, tangerine peel oil the 2%th, glycerine the 5%th, methenamine the 0.3%th, carbon fiber the 3%th, water 24.7% that acetic acid the 25%th, phosphoric acid the 25%th, bleeding agent the 2%th, neopelex the 5%th, volumetric concentration is 70-75%;Described corrosion inhibiter includes toluene thiocarbamide the 15%th, octadecylamine the 25%th, methenamine the 25%th, glyceryl tristearate 8% of dodecyl sodium sulfate the 27%th, ortho position and contraposition according to the raw material of mass percent.
Embodiment 3
In the embodiment of the present invention, a kind of Industrial Boiler scale remover, including mother liquor and corrosion inhibiter, described mother liquor includes, according to the raw material of mass percent, ethanol the 4%th, urea the 3%th, tangerine peel oil the 3%th, glycerine the 6%th, methenamine the 0.1%th, carbon fiber the 6.9%th, water 28% that acetic acid the 28%th, phosphatase 11 the 5%th, bleeding agent the 1%th, neopelex the 5%th, volumetric concentration is 70-75%;Described corrosion inhibiter includes toluene thiocarbamide the 10%th, octadecylamine the 35%th, methenamine the 15%th, glyceryl tristearate 5% of dodecyl sodium sulfate the 35%th, ortho position and contraposition according to the raw material of mass percent.
In foregoing invention embodiment, the preparation technology of described Industrial Boiler scale remover is:
(1) preparation of mother liquor: according to mass percent, water is poured in resistance to acid tank, then acetic acid and phosphoric acid are poured into water, add bleeding agent, neopelex, volumetric concentration are the ethanol of 70-75%, urea, tangerine peel oil, glycerine, methenamine, carbon fiber, stirring and dissolving, after placing 8-12 hour, can load in vial or plastic bottle;
(2) preparation of corrosion inhibiter: according to mass percent, pour the toluene thiocarbamide of dodecyl sodium sulfate, ortho position and contraposition, octadecylamine, methenamine and glyceryl tristearate in stirring pool respectively into, after stirring, with plastic bag packaging.
In actual use, first respectively mother liquor and corrosion inhibiter are added after the water of its quality 10-20 times dilutes, then two kinds of dilutions are mixed, i.e. can be widely used for the descaling rinsing of the various metals equipment being made up of iron and steel, aluminium, copper, soldering etc..
Proportioning science of the present invention, corrosion-free, nontoxic to metal, can reach thoroughly to remove the purpose of boiler scale with composition of scales such as the calcium carbonate of rapid solution boiler internal attachment, magnesium carbonate, calcium sulfate, calcium silicates and iron oxide.The raw materials used source of the present invention is wide and biodegradable, environmentally safe, easy to use, economic security.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and without departing from the spirit or essential characteristics of the present invention, the present invention can be realized in other specific forms.Therefore, no matter from the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is limited by claims rather than described above, it is intended that include all changes falling in the implication of equivalency and scope of claim in the present invention.
In addition, should be understood, although this specification is been described by according to embodiment, but not each embodiment only comprises an independent technical scheme, this narrating mode of specification is only for clarity sake, those skilled in the art should be using specification as an entirety, and the technical scheme in each embodiment also can form, through appropriately combined, other embodiments that it will be appreciated by those skilled in the art that.

Claims (3)

1. an Industrial Boiler scale remover, it is characterized in that, including mother liquor and corrosion inhibiter, according to the raw material of mass percent, described mother liquor includes that acetic acid 20-40%, phosphatase 11 5-25%, bleeding agent 1-3%, neopelex 5-10%, volumetric concentration are the ethanol 3-5% of 70-75%, urea 3-5%, tangerine peel oil 2-5%, glycerine 3-7%, methenamine 0.1-0.5%, carbon fiber 2-15%, water 20-45%;Described corrosion inhibiter includes the toluene thiocarbamide 10-25% of dodecyl sodium sulfate 20-45%, ortho position and contraposition, octadecylamine 25-35%, methenamine 15-30%, glyceryl tristearate 5-18% according to the raw material of mass percent.
2. Industrial Boiler scale remover according to claim 1, it is characterized in that, according to the raw material of mass percent, described mother liquor includes that acetic acid 20-30%, phosphoric acid 20-25%, bleeding agent 1-2%, neopelex 5-8%, volumetric concentration are the ethanol 3-5% of 70-75%, urea 3-5%, tangerine peel oil 2-3%, glycerine 5-7%, methenamine 0.1-0.3%, carbon fiber 2-8%, water 20-32%;Described corrosion inhibiter includes the toluene thiocarbamide 10-15% of dodecyl sodium sulfate 20-35%, ortho position and contraposition, octadecylamine 25-32%, methenamine 20-30%, glyceryl tristearate 5-12% according to the raw material of mass percent.
3. Industrial Boiler scale remover according to claim 1, it is characterized in that, described mother liquor includes, according to the raw material of mass percent, ethanol the 3%th, urea the 5%th, tangerine peel oil the 2%th, glycerine the 5%th, methenamine the 0.3%th, carbon fiber the 3%th, water 24.7% that acetic acid the 25%th, phosphoric acid the 25%th, bleeding agent the 2%th, neopelex the 5%th, volumetric concentration is 70-75%;Described corrosion inhibiter includes toluene thiocarbamide the 15%th, octadecylamine the 25%th, methenamine the 25%th, glyceryl tristearate 8% of dodecyl sodium sulfate the 27%th, ortho position and contraposition according to the raw material of mass percent.
CN201510084214.6A 2015-02-16 2015-02-16 Descaling agent for industrial boiler Pending CN105986281A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510084214.6A CN105986281A (en) 2015-02-16 2015-02-16 Descaling agent for industrial boiler

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510084214.6A CN105986281A (en) 2015-02-16 2015-02-16 Descaling agent for industrial boiler

Publications (1)

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CN105986281A true CN105986281A (en) 2016-10-05

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106430656A (en) * 2016-10-09 2017-02-22 广西大学 Corrosion and scale inhibitor for treating high-concentration circulating water
CN111040887A (en) * 2019-12-24 2020-04-21 广州市粤新工程技术有限公司 Environment-friendly composite cleaning agent for cooling system
RU2738662C1 (en) * 2020-03-25 2020-12-15 Общество с ограниченной ответственностью Preparation for scaling and cleaning of internal surfaces of heat power and process equipment from scaling deposits

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106430656A (en) * 2016-10-09 2017-02-22 广西大学 Corrosion and scale inhibitor for treating high-concentration circulating water
CN111040887A (en) * 2019-12-24 2020-04-21 广州市粤新工程技术有限公司 Environment-friendly composite cleaning agent for cooling system
CN111040887B (en) * 2019-12-24 2021-02-12 广州市粤新工程技术有限公司 Environment-friendly composite cleaning agent for cooling system
RU2738662C1 (en) * 2020-03-25 2020-12-15 Общество с ограниченной ответственностью Preparation for scaling and cleaning of internal surfaces of heat power and process equipment from scaling deposits

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Application publication date: 20161005