CN105986144A - Titanium alloy TA18 seamless pipe and preparation method thereof - Google Patents

Titanium alloy TA18 seamless pipe and preparation method thereof Download PDF

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Publication number
CN105986144A
CN105986144A CN201510076912.1A CN201510076912A CN105986144A CN 105986144 A CN105986144 A CN 105986144A CN 201510076912 A CN201510076912 A CN 201510076912A CN 105986144 A CN105986144 A CN 105986144A
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hot
pipe
titanium alloy
rolling
piercing
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张忠世
郭淑君
张桂艳
王啸虎
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Abstract

The invention relates to a titanium alloy TA18 seamless pipe and a preparation method thereof. The titanium alloy TA18 seamless pipe comprises, by weight, 2%-3.5% of Al, 1.5%-3% of V, 0.3% or less of Fe, 0.08% or less of C, 0.05% or less of N, 0.015% or less of H, 0.2% or less of O, and the balance Ti. The titanium alloy TA18 seamless pipe can be prepared through nine methods, specifically, according to the first method, the titanium alloy TA18 seamless pipe is formed through hot rolling after hot piercing; according to the second method, the titanium alloy TA18 seamless pipe is formed through cold rolling after hot piercing; according to the third method, the titanium alloy TA18 seamless pipe is formed through hot rolling and cold rolling sequentially after hot piercing; according to the fourth step, the titanium alloy TA18 seamless pipe is formed through hot pipe-jacking rolling after hot piercing; according to the fifth method, the titanium alloy TA18 seamless pipe is formed through machining after hot piercing; according to the sixth method, the titanium alloy TA18 seamless pipe is formed through hot rolling after a pipe blank is prepared through hot extrusion; according to the seventh method, the titanium alloy TA18 seamless pipe is formed through cold rolling after the pipe blank is prepared through hot extrusion; according to the eighth method, the titanium alloy TA18 seamless pipe is formed through pipe-jacking rolling after the pipe blank is prepared through hot extrusion; and according to the ninth method, the titanium alloy TA18 seamless pipe is formed through direct machining after the pipe blank is prepared through hot extrusion. The titanium alloy TA18 seamless pipe and the preparation method thereof have the main characteristics that according to the titanium alloy TA18 seamless pipe obtained based on the nine methods, metal crystals are more refined, the texture is more compact, and accordingly the material performance is greatly improved.

Description

A kind of titanium alloy T A18 seamless pipe and preparation method thereof
Technical field
The present invention relates to titanium alloy tube and preparation thereof, specifically a kind of TA18 seamless pipe and preparation side thereof Method.
Background technology
With the development of titanium alloy, increasingly demand high intensity, high tenacity, high temperature resistant and corrosion resistant Titanium alloy, especially titanium alloy pipe demand get more and more, and the difficulty of processing of titanium alloy pipe is increasing, Titanium alloy T A18 tubing major applications is in industries such as oil field, nuclear power station, chemical industry, and present titanium alloy T A18 Tubing is generally all that sheet material volume welds, hole drawn by bar.
Content of the invention
It is an object of the invention to provide a kind of titanium alloy T A18 pipe being suitable for modern market demand, this side TA18 tubing intensity prepared by method is higher, good toughness and corrosion-resistant, the titanium alloy T A18 processing in aforementioned manners Manage the tensile strength in its performance (Rm) and reach 500~1000MPa, elongation percentage 6~25%.
For achieving the above object, the technical solution used in the present invention is:
A kind of titanium alloy T A18 pipe, alloy by weight percentage consists of: Al (2~3.5) %, V (1.5~3) %, Fe≤0.3%, C≤0.08%, N≤0.05%, H≤0.015%, O≤0.2%;Ti surplus;A kind of The preparation method of titanium alloy T A18 hot-rolled pipe, alloy raw material by weight percentage consists of: Al (2~3.5) %, V (1.5~3) %, Fe≤0.3%, C≤0.08%, N≤0.05%, H≤0.015%, O≤0.2%;Ti surplus;Press After above-mentioned raw materials is processed into rod base carries out hot piercing hot rolling or hot piercing cold rolling or hot piercing by conventional method Processing or hot extrusion cold rolling or extruding hot rolling or heat extruder processing, or cold rolling after hot piercing hot rolling, Or the rolling of hot piercing hot push pipe, or the rolling of hot extrusion hot push pipe, and control Fe≤0.3% in titanium alloy T A18, C ≤ 0.08%, N≤0.05%, H≤0.015%, O≤0.2%;Its TA18 seamless pipe specification: pipe external diameterWall thickness 0.9~400mm (but external diameter have to be larger than 2 with the ratio of wall thickness) × length 100~24000mm, square tube 10~1500mm × 10~1500mm × wall thickness 0.9~400mm (but each length of side must Adjacent 2 wall thickness sums must be more than) × length 100~24000mm, special pipe large head external diameterWall thickness 0.9~400mm (but external diameter have to be larger than 2 with the ratio of wall thickness) × small head external diameterWall thickness 0.9~400mm (but external diameter have to be larger than 2 with the ratio of wall thickness) × length 100~24000mm, special pipe large head external diameter have to be larger than small head external diameter;
When preparing TA18 titanium alloy tube, first flawless optical wand blank is placed on heating furnace (gas furnace Or chamber type electric resistance furnace or induction heater) in carry out the heating that heats up;Heating-up temperature 600 DEG C~1100 DEG C, insulation Time=(heating ingot blank diameter/2) mm+ (20~90) minute.Carry out cold rolling after hot piercing or hot extrusion again Carry out again after system, hot piercing or hot extrusion hot rolling finished product, cold rolling finished product after hot piercing hot rolling, Carry out being machined to product after hot piercing or hot extrusion after heat push pipe mill product, hot piercing or hot extrusion, cold rolling When heating rolling deflection for (20%~90%)/time, the temperature after hot piercing, after hot extrusion, after hot rolling 300 DEG C~900 DEG C.
Finished product after rolling completes uses oxidizing annealing or vacuum annealing, and the annealing temperature of oxidizing annealing is 400~1000 DEG C are incubated 0.5~8 hour;The annealing temperature of vacuum annealing is that 400~1000 DEG C of insulations 0.5~8 are little When, the finished product after heat treatment then to carry out washing after pickling or alkali cleaning, pickling or alkali cleaning again, it is thus achieved that finished product, Or once machine acquisition finished product again.
Tensile strength (Rm) in this product titanium alloy T A18 hot-rolled pipe performance is after heat treatment and solid solution aging Up to (500~1000) MPa, elongation percentage is (6~25) %, two annealing in stress relief annealing and perfect recrystallization In the state of kind, its metallographic structure is uniform.
The present invention compared with prior art, has a following beneficial effect:
1. corrosion-resistant: titanium alloy T A18 seamless pipe intensity (Rm) (500~1000MPa) of the present invention is more resistance to than steel pipe Corrosivity is good.
2. reduce cost, shorten the production cycle: will carry out after the rolling of existing titanium alloy pipe production process per pass Vacuum annealing, and after the titanium alloy T A18 seamless tubular goods production technology of the present invention is hot piercing or hot extrusion pipe Carry out mill product or machining finished product, so both reduce power consumption cost and shorten the production cycle.
3. yield rate is high, and quality is good, and performance is excellent: it is high that TA18 seamless pipe of the present invention draws hole pipe yield rate than bar, TA18 seamless pipe utilizes hot piercing or hot extrusion pipe to carry out mill product or machining finished product, is lost little, Yield rate is high, and hole pipe drawn by bar then needs to draw out a lot of bits waste product, and loss is big, and yield rate is low, and bar is drawn Hole pipe is quality and the performance of bar, and the quality of hole pipe drawn by bar, performance prepares TA18 far away from by top method The quality of seamless pipe, performance.
4. service life is long: the congenital dense structure of TA18 seamless pipe of the present invention, and sheet material welded pipe is then in weldering At seam, structural state is inconsistent with matrix, easily causes fatigability corrosion cracking, so there being TA18 seamless pipe ratio Sheet material welded pipe is long for service life.
Detailed description of the invention
The present invention is to be obtained with new titanium alloy by unique method of operating and preparation processing technology TA18 seamless pipe, describes the present invention in detail below by embodiment.
Using oxidation or vacuum annealing, cold rolling or hot rolling preparation method: step is carried out routinely, first with raw material sea Continuous titanium, vananum carry out dispensing (Al by weight percentage (2~3.5) %, V (1.5~3) %, Fe≤0.3%, C≤0.08%, N≤0.05%, H≤0.015%, O≤0.2%;Ti surplus;Raw material is mixed), extrude electrode, Welding electrode, shove charge melting ingot casting, strip off the skin sample analysis, forges bar (rod base), bar car light with ingot casting Blanking, after optical wand hot piercing or being hot extruded into pipe, carries out cold rolling finished product or hot rolling finished product or heat top Pipe mill product or machining finished product, alkali cleaning, pickling, washing, tack, annealing, sample analysis, fixed Chi blanking.
Alkali cleaning proportioning in following embodiment, pickling proportioning are:
Alkali wash water: [85~95%NaOH+15~5%NaNO3(or KNO3)]
Pickle: [30~40%HNO3+ 2~10%HF+ surplus H2O]
Embodiment 1.
Concrete preparation process is as follows:
By TA18 rod baseLoad chamber type electric resistance furnace intensification heating 900 DEG C, be incubated 60 Minute, hot piercing of coming out of the stove, the pipe after hot piercing carries out hot rolling by transmission to Rolling Production equipment, Hot rolling deflection is 50%, finishing temperature 500 DEG C, and hot rolling trimmed size is Oxidizing annealing 600 DEG C be incubated 1 hour, alkali cleaning, pickling, washing, scale blanking, The actual measurement of its performance of sample analysis is Rm 860MPa, Rp0.2760MPa, A 14%;
Titanium alloy T A18 manages, and alloy by weight percentage consists of: more than Al 2.1%, V 2.5%, Ti Amount.
Embodiment 2.
Concrete preparation process is as follows:
By TA18 rod baseLoad gas furnace intensification heating 1100 DEG C, be incubated 11 Hour, hot piercing of coming out of the stove, the pipe after hot piercing carries out cold rolling by transmission to hot rolling production equipment, Cold rolling deflection is 40%, and cold rolling trimmed size isOxidizing annealing 800 DEG C are incubated 8 hours, and alkali cleaning, pickling, washing, scale blanking, the actual measurement of its performance of sample analysis are Rm950 MPa, Rp0.2820MPa, A 11%.
Titanium alloy T A18 manages, and alloy by weight percentage consists of: Al3.2%, V 2.7%, Ti surplus.
Embodiment 3.
Concrete preparation process is as follows:
By TA18 rod baseLoad chamber type electric resistance furnace intensification heating 820 DEG C, be incubated 60 Minute, hot extrusion of coming out of the stove, the pipe after hot extrusion carries out surface treatment, disposes surface defect, then enters Row cold rolling, rolling reduction is 30%, and mill product specification isOxidation Annealing 700 DEG C and being incubated 1 hour, alkali cleaning, pickling, washing, scale blanking, the actual measurement of its performance of sample analysis are Rm 680MPa, Rp0.2535MPa, A 15%;
Titanium alloy T A18 manages, and alloy by weight percentage consists of: Al 2.1%, V 1.6%, Ti surplus.
Embodiment 4.
Concrete preparation process is as follows:
By TA18 rod baseLoad gas furnace intensification heating 1100 DEG C, be incubated 12 Hour, hot extrusion of coming out of the stove, the pipe after hot extrusion carries out hot rolling by transmission to hot rolling production equipment, Hot rolling deflection is 60%, and mill product specification isOxidizing annealing 900 DEG C are incubated 8 hours, and alkali cleaning, pickling, washing, scale blanking, the actual measurement of its performance of sample analysis are Rm980 MPa, Rp0.2890MPa, A 11%.
Titanium alloy T A18 manages, and alloy by weight percentage consists of: Al 3.3%, V 2.9%, Ti surplus.
Embodiment 5.
Concrete preparation process is as follows:
By TA18 rod baseLoad chamber type electric resistance furnace intensification heating 960 DEG C, be incubated 60 Minute, hot piercing of coming out of the stove, after the pipe cooling after hot piercing, machining trimmed size is Oxidizing annealing 600 DEG C be incubated 1 hour, alkali cleaning, pickling, washing, scale blanking, The actual measurement of its performance of sample analysis is Rm 920MPa, Rp0.2750MPa, A 11%;
Titanium alloy T A18 manages, and alloy by weight percentage consists of: Al 3.5%, V 2.9%, Ti surplus.
Embodiment 6.
Concrete preparation process is as follows:
By TA18 rod baseLoad chamber type electric resistance furnace intensification heating 970 DEG C, be incubated 60 Minute, hot piercing of coming out of the stove, carrying out mill product specification after the pipe cooling after hot piercing hot rolling is Oxidizing annealing 600 DEG C be incubated 1 hour, alkali cleaning, pickling, washing, scale blanking, The actual measurement of its performance of sample analysis is Rm 910MPa, Rp0.2830MPa, A 12%;
Titanium alloy T A18 manages, and alloy by weight percentage consists of: Al 3%, V 2.7%, Ti surplus.
Embodiment 7.
Concrete preparation process is as follows:
By TA18 rod baseLoad chamber type electric resistance furnace intensification heating 1020 DEG C, insulation 60 minutes, hot piercing of coming out of the stove, hot piercing after heat top tube rolling to trimmed size was Oxidizing annealing 600 DEG C be incubated 1 hour, alkali cleaning, pickling, washing, scale blanking, The actual measurement of its performance of sample analysis is Rm 930MPa, Rp0.2840MPa, A 13%;
Titanium alloy T A18 manages, and alloy by weight percentage consists of: Al 3.1%, V 2.9%, Ti surplus.
Embodiment 8.
Concrete preparation process is as follows:
By TA18 rod baseLoad chamber type electric resistance furnace intensification heating 980 DEG C, be incubated 60 Minute, hot extrusion of coming out of the stove, hot extrusion after heat top tube rolling to trimmed size is Oxidizing annealing 600 DEG C is incubated 1 hour, and alkali cleaning, pickling, washing, scale blanking, its performance of sample analysis are real Survey is Rm 900MPa, Rp0.2830MPa, A 15%;
Titanium alloy T A18 manages, and alloy by weight percentage consists of: Al 3.1%, V 2.5%, Ti surplus.
Embodiment 9.
Concrete preparation process is as follows:
By TA18 rod baseLoad gas furnace intensification heating 1100 DEG C, be incubated 12 Hour, hot piercing of coming out of the stove, after the pipe cooling after hot piercing, machining trimmed size is Oxidizing annealing 900 DEG C be incubated 8 hours, alkali cleaning, pickling, washing, scale blanking, The actual measurement of its performance of sample analysis is Rm1000MPa, Rp0.2910MPa, A 11%.
Titanium alloy T A18 manages, and alloy by weight percentage consists of: Al 3.5%, V 3%, Ti surplus.
Embodiment 10.
Concrete preparation process is as follows:
By TA18 rod baseLoad chamber type electric resistance furnace intensification heating 960 DEG C, be incubated 60 Minute, hot extrusion of coming out of the stove, after the pipe cooling after hot extrusion, machining trimmed size is Oxidizing annealing 600 DEG C be incubated 1 hour, alkali cleaning, pickling, washing, scale blanking, The actual measurement of its performance of sample analysis is Rm 860MPa, Rp0.2780MPa, A 16%;
Titanium alloy T A18 manages, and alloy by weight percentage consists of: Al 3.1%, V 2.6%, Ti surplus.
Embodiment 11.
Concrete preparation process is as follows:
By TA18 rod baseLoad gas furnace intensification heating 1100 DEG C, be incubated 13 Hour, hot extrusion of coming out of the stove, after the pipe cooling after hot extrusion, machining trimmed size is Oxidizing annealing 900 DEG C be incubated 8 hours, alkali cleaning, pickling, washing, scale blanking, The actual measurement of its performance of sample analysis is Rm950MPa, Rp0.2860MPa, A 11%.
Titanium alloy T A18 manages, and alloy by weight percentage consists of: Al 3.2%, V2.8%, Ti surplus.

Claims (7)

1. a titanium alloy T A18 seamless pipe, it is characterised in that:
Alloy by weight percentage consists of: Al (2~3.5) %, V (1.5~3) %, balance of titanium.
2. according to the titanium alloy seamless pipe described in claim 1, it is characterised in that:
Alloy by weight percentage consists of: Al (2~3.5) %, V (1.5~3) %, Fe≤0.3%, C≤0.08%, N≤0.05%, H≤0.015%, O≤0.2%;Balance of titanium.
3. according to the titanium alloy seamless pipe described in claim 1 or 2, it is characterised in that: titanium alloy T A18 The specification limit of seamless pipe:
Pipe:
Or, square tube:
Or, special pipe: Special pipe large head external diameter have to be larger than small head external diameter.
4. a preparation method for claim the 1st, titanium alloy T A18 seamless pipe described in 2 or 3, its feature exists In:
Alloy raw material by weight percentage consists of: Al (2~3.5) %, V (1.5~3) %, Ti surplus;
According to a conventional method above-mentioned raw materials is processed into rod blank;
Preparing pipe by way of hot extrusion or hot piercing, production tube preparation method is one of following 9 kinds,
The first is to carry out hot rolling finished product after hot piercing;
The second is to carry out cold rolling finished product after hot piercing;
The third is that the laggard row of hot piercing carries out hot rolling cold rolling finished product again;
4th kind is to carry out hot push pipe mill product after hot piercing;
5th kind is production tube obtained by being machined out after hot piercing;
6th kind is to carry out hot rolling production tube after pipe is prepared in hot extrusion;
7th kind is to carry out cold rolling production tube after pipe is prepared in hot extrusion;
8th kind is to carry out push pipe mill product after pipe is prepared in hot extrusion;
9th kind is directly to be machined to QC after pipe is prepared in hot extrusion;
Obtain metal grain by the TA18 seamless pipe of the arbitrary production of above-mentioned 9 kinds of methods more to refine, organize more Add densification, so that the performance of its material has greatly improvement.
5. according to the preparation method described in claim 4, it is characterised in that: titanium alloy T A18 seamless pipe Specification limit:
Pipe: external diameter
Or, square tube: the length of side 10~1500mm × length of side 10~1500mm × wall thickness 0.9~400mm (but each limit Length all have to be larger than adjacent 2 wall thickness sums) × length 100~24000mm;
Or, special pipe: Special pipe large head external diameter have to be larger than small head external diameter.
6. according to the preparation method described in claim 5, it is characterised in that:
When preparing TA18 titanium alloy tube, first flawless optical wand blank is placed on heating furnace (gas furnace Or chamber type electric resistance furnace or induction heater or gas generator) in carry out the heating that heats up;It is heated to temperature 600 DEG C~1100 DEG C, temperature retention time=(heating ingot blank diameter mm/2) minute+(20~90) minute;Come out of the stove Carry out cold rolling or hot rolling, hot piercing or hot extrusion again after hot piercing or hot extrusion, hot piercing or hot extrusion Rear machining, hot piercing or the rolling of hot extrusion after heat push pipe, when cold rolling or hot rolling, deflection is (20%~90%)/time, the temperature after hot piercing, after hot extrusion, after hot rolling is 300 DEG C~900 DEG C.
7. according to claim the 4th, the preparation method described in 5 or 6, it is characterised in that: titanium alloy T A18 The heat treatment of seamless pipe and surface treatment: hot piercing, hot extrusion, cold rolling, hot rolling, hot push pipe rolling, And the finished product after pipe machining uses oxidizing annealing or vacuum annealing, the annealing temperature of oxidizing annealing is 400~1000 DEG C are incubated 0.5~8 hour;The annealing temperature of vacuum annealing is that 400~1000 DEG C of insulations 0.5~8 are little When, the finished product after heat treatment then to carry out washing after pickling or alkali cleaning, pickling or alkali cleaning again, it is thus achieved that finished product, Or once machine acquisition finished product again.
CN201510076912.1A 2015-02-12 2015-02-12 Titanium alloy TA18 seamless pipe and preparation method thereof Pending CN105986144A (en)

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Cited By (8)

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CN106493187A (en) * 2016-10-27 2017-03-15 南京宝泰特种材料股份有限公司 A kind of heavy caliber thick wall titanium and its low-cost manufacture method of alloy seamless tubing
CN108213865A (en) * 2017-12-26 2018-06-29 张家港华裕有色金属材料有限公司 A kind of tensile strength>The manufacturing method of the titanium alloy seamless tube blank of 400MPa
CN108246829A (en) * 2017-12-26 2018-07-06 张家港华裕有色金属材料有限公司 A kind of manufacturing method of TA18 titanium alloys seamless tube blank
CN109234555A (en) * 2018-10-24 2019-01-18 成都先进金属材料产业技术研究院有限公司 The preparation method of small-bore TA18 titanium alloy seamless pipe
CN114101372A (en) * 2021-11-23 2022-03-01 西北有色金属研究院 High-strength TC18 titanium alloy seamless pipe efficient low-cost preparation method
CN114632837A (en) * 2022-03-07 2022-06-17 江苏银环精密钢管有限公司 Preparation method of spiral heat exchange tube of high-temperature gas cooled reactor steam generator
CN116656994A (en) * 2023-07-25 2023-08-29 成都先进金属材料产业技术研究院股份有限公司 Method for improving shrinkage strain ratio of TA18 titanium alloy seamless tube and TA18 titanium alloy seamless tube
CN117102273A (en) * 2023-10-24 2023-11-24 成都先进金属材料产业技术研究院股份有限公司 Titanium alloy seamless pipe and method for improving rotation bending fatigue performance thereof

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CN106493187A (en) * 2016-10-27 2017-03-15 南京宝泰特种材料股份有限公司 A kind of heavy caliber thick wall titanium and its low-cost manufacture method of alloy seamless tubing
CN108213865A (en) * 2017-12-26 2018-06-29 张家港华裕有色金属材料有限公司 A kind of tensile strength>The manufacturing method of the titanium alloy seamless tube blank of 400MPa
CN108246829A (en) * 2017-12-26 2018-07-06 张家港华裕有色金属材料有限公司 A kind of manufacturing method of TA18 titanium alloys seamless tube blank
CN109234555A (en) * 2018-10-24 2019-01-18 成都先进金属材料产业技术研究院有限公司 The preparation method of small-bore TA18 titanium alloy seamless pipe
CN109234555B (en) * 2018-10-24 2020-08-18 成都先进金属材料产业技术研究院有限公司 Preparation method of small-caliber TA18 titanium alloy seamless tube
CN114101372B (en) * 2021-11-23 2022-07-22 西北有色金属研究院 High-strength TC18 titanium alloy seamless pipe efficient low-cost preparation method
CN114101372A (en) * 2021-11-23 2022-03-01 西北有色金属研究院 High-strength TC18 titanium alloy seamless pipe efficient low-cost preparation method
CN114632837A (en) * 2022-03-07 2022-06-17 江苏银环精密钢管有限公司 Preparation method of spiral heat exchange tube of high-temperature gas cooled reactor steam generator
CN114632837B (en) * 2022-03-07 2022-10-11 江苏银环精密钢管有限公司 Preparation method of spiral heat exchange tube of high-temperature gas cooled reactor steam generator
CN116656994A (en) * 2023-07-25 2023-08-29 成都先进金属材料产业技术研究院股份有限公司 Method for improving shrinkage strain ratio of TA18 titanium alloy seamless tube and TA18 titanium alloy seamless tube
CN116656994B (en) * 2023-07-25 2023-10-13 成都先进金属材料产业技术研究院股份有限公司 Method for improving shrinkage strain ratio of TA18 titanium alloy seamless tube and TA18 titanium alloy seamless tube
CN117102273A (en) * 2023-10-24 2023-11-24 成都先进金属材料产业技术研究院股份有限公司 Titanium alloy seamless pipe and method for improving rotation bending fatigue performance thereof
CN117102273B (en) * 2023-10-24 2024-02-02 成都先进金属材料产业技术研究院股份有限公司 Titanium alloy seamless pipe and method for improving rotation bending fatigue performance thereof

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