CN105984006A - Waterproof flame-retardant wood hardening agent and preparation method thereof - Google Patents

Waterproof flame-retardant wood hardening agent and preparation method thereof Download PDF

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Publication number
CN105984006A
CN105984006A CN201610057810.XA CN201610057810A CN105984006A CN 105984006 A CN105984006 A CN 105984006A CN 201610057810 A CN201610057810 A CN 201610057810A CN 105984006 A CN105984006 A CN 105984006A
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CN
China
Prior art keywords
parts
water
stirring
component
curing agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610057810.XA
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Chinese (zh)
Inventor
张晓玲
王宁宁
高尚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sky Funan County Hundred Million Arts & Crafts Co Ltd
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Sky Funan County Hundred Million Arts & Crafts Co Ltd
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Publication date
Application filed by Sky Funan County Hundred Million Arts & Crafts Co Ltd filed Critical Sky Funan County Hundred Million Arts & Crafts Co Ltd
Priority to CN201610057810.XA priority Critical patent/CN105984006A/en
Publication of CN105984006A publication Critical patent/CN105984006A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/52Impregnating agents containing mixtures of inorganic and organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/06Softening or hardening of wood
    • B27K5/065Hardening
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00Purpose of the treatment
    • B27K2240/30Fireproofing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00Purpose of the treatment
    • B27K2240/70Hydrophobation treatment

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The invention discloses a waterproof flame-retardant wood hardening agent. The waterproof flame-retardant wood hardening agent is made from the following raw materials comprising, by weight, 5-10 parts of sodium silicate, 5-10 parts of borax, 10-15 parts of magnesium sulfate, 2-3 parts of guar gum, 0.1-0.2 part of ammonium persulfate, 0.1-0.2 part of a titanate coupling agent, 2-4 parts of styrene, 4-6 parts of methyl methacrylate, 0.5-1 part of sodium lignin sulfonate, 1-2 parts of sodium carboxymethylcellulose, 5-10 parts of performance additives and 80-100 parts of water. The waterproof flame-retardant wood hardening agent has the beneficial effects of being good in permeability, not prone to running off and good in durability and having a good capacity to bond with wood. Besides, the waterproof flame-retardant wood hardening agent is good in hardening effect and environmentally friendly, has the waterproof and flame-retardant effects, can improve the use safety and durability of wood and has high practical value.

Description

A kind of water proof fire retardant timber curing agent and preparation method thereof
Technical field
The present invention relates to wood treatment agent technical field, particularly relate to a kind of water proof fire retardant timber curing agent and preparation method thereof.
Background technology
In recent years, with China's rapid development of economy, the field such as furniture, building materials, decoration grows stronger day by day, and steps up timber, the especially demand of high-quality hard wood, even occurs in that under-supply situation.The quick growing species of trees such as masson pine, China fir, poplar have rapid, the cheap advantage of growth, and alternative natural timber uses, not only has good economic benefit, moreover it is possible to reduce the felling of natural forest, conservation of nature environment.But these quick growing species of trees is wooden relatively gently softer, and its serviceability is typically all poor, and range of application is restricted, for meet faster, the needs of high-quality timber are preferably provided, it is necessary to carry out cure process to it, strengthen hardness and improve performance, expand wood usage.Resin type timber curing agent conventional at present is difficult to degrade in the environment, and containing certain free harmful substance, produces potential hazard to health.It is low with timber adhesion to there is poor permeability in non-resinous timber curing agent, is easy to run off, the problem of persistence difference.And, it is contemplated that timber in actual applications, for improving its safety in utilization and durability, often needs have certain water proof fire retardant, and therefore exploitation safety and environmental protection, persistence timber curing agent good, water proof fire retardant have higher practical value.
Content of the invention
The object of the invention is contemplated to make up the defect of prior art, provides a kind of permeability, persistence good and the timber curing agent and preparation method thereof of water proof fire retardant.
The present invention is achieved by the following technical solutions:
A kind of water proof fire retardant timber curing agent, it is to be prepared by the raw material of following weight parts:
Waterglass 5-10, borax 5-10, magnesium sulfate 10-15, guar gum 2-3, ammonium persulfate 0.1-0.2, titanate coupling agent 0.1-0.2, styrene 2-4, methyl methacrylate 4-6, sodium lignin sulfonate 0.5-1, sodium carboxymethylcellulose 1-2, modified additive 5-10, water 80-100;
Wherein modified additive is prepared by the raw materials in: laurate 0.1-0.2, castor oil 3-5, dimethicone 2-4, nano titanium oxide 1-2, aluminium triphosphate 2-4, cocounut oil acyl diethanol amine 0.5-1;The preparation method of modified additive be nano titanium oxide, aluminium triphosphate are mixed with laurate after add in appropriate absolute ethyl alcohol stirring 20-30min, filter, add remaining raw material 800-1000r/min stirring 10-15min after washing, to obtain final product;
The preparation method of a kind of water proof fire retardant timber curing agent, comprises the following steps:
(1) raw material is weighed by weight, 60-80 DEG C of stirring 1-2h in the water first jointly adding 1/2-2/3 to measure waterglass, borax, sodium lignin sulfonate, guar gum and sodium carboxymethylcellulose, it is subsequently adding magnesium sulfate and ammonium persulfate 50-60 DEG C, 1000-1500r/min stir 1-2h, obtain component A;
(2) water first styrene, methyl methacrylate and titanate coupling agent being added surplus mixes, under the conditions of 600-800r/min, is then slowly added to modified additive stirring 10-15min, obtains B component;
(3) component A and B component are mixed latter 60-70 DEG C, 800-1200r/min stir 2-3h, high speed dispersion be ground to≤20 μm after cooling, obtain water proof fire retardant timber curing agent.
The invention have the advantage that
The present invention first passes through guar gum and sodium carboxymethylcellulose and carries out surface modification to the magnesium hydroxide particulate being formed in solution system, then styrene, methyl methacrylate coating modification again are introduced, obtain timber curing agent after compounding with remaining raw material, the product preparing can form stable overcoat at wood surface, there is good penetrability strong with timber adhesion, not easily run off, the good feature of persistence, hardening effect is good, environmental protection, also there is the effect of water proof fire retardant, safety in utilization and the durability of timber can be improved, there is higher practical value.
Detailed description of the invention
A kind of water proof fire retardant timber curing agent, it is to be prepared by the raw material of following weight parts:
Waterglass 5, borax 5, magnesium sulfate 10, guar gum 2, ammonium persulfate 0.1, titanate coupling agent 0.1, styrene 2, methyl methacrylate 4, sodium lignin sulfonate 0.5, sodium carboxymethylcellulose 1, modified additive 5, water 80;
Wherein modified additive is prepared by the raw materials in: laurate 0.1, castor oil 3, dimethicone 2, nano titanium oxide 1, aluminium triphosphate 2, cocounut oil acyl diethanol amine 0.5;The preparation method of modified additive be nano titanium oxide, aluminium triphosphate are mixed with laurate after add in appropriate absolute ethyl alcohol stirring 20min, filter, add remaining raw material 800r/min stirring 10min after washing, to obtain final product;
The preparation method of a kind of water proof fire retardant timber curing agent, comprises the following steps:
(1) weigh raw material by weight, first waterglass, borax, sodium lignin sulfonate, guar gum and sodium carboxymethylcellulose are added jointly 60 DEG C of stirring 1h in the water of 1/2 amount, be subsequently adding magnesium sulfate and ammonium persulfate 50 DEG C, 1000r/min stir 1h, obtain component A;
(2) water first styrene, methyl methacrylate and titanate coupling agent being added surplus mixes, under the conditions of 600r/min, is then slowly added to modified additive stirring 10min, obtains B component;
(3) component A and B component are mixed latter 60 DEG C, 800r/min stir 2h, high speed dispersion be ground to≤20 μm after cooling, obtain water proof fire retardant timber curing agent.
Through inspection, poplar processes rear surface hardness through above-mentioned prepared timber curing agent and improves 180%, and elastic modelling quantity improves 25%, and MOR improves 30%, and combustibility is B1 level.

Claims (2)

1. a water proof fire retardant timber curing agent, it is characterised in that it is to be prepared by the raw material of following weight parts:
Waterglass 5-10, borax 5-10, magnesium sulfate 10-15, guar gum 2-3, ammonium persulfate 0.1-0.2, titanate coupling agent 0.1-0.2, styrene 2-4, methyl methacrylate 4-6, sodium lignin sulfonate 0.5-1, sodium carboxymethylcellulose 1-2, modified additive 5-10, water 80-100;
Described modified additive is prepared by the raw materials in: laurate 0.1-0.2, castor oil 3-5, dimethicone 2-4, nano titanium oxide 1-2, aluminium triphosphate 2-4, cocounut oil acyl diethanol amine 0.5-1;The preparation method of modified additive be nano titanium oxide, aluminium triphosphate are mixed with laurate after add in appropriate absolute ethyl alcohol stirring 20-30min, filter, add remaining raw material 800-1000r/min stirring 10-15min after washing, to obtain final product.
2. the preparation method of a kind of water proof fire retardant timber curing agent according to claim 1, it is characterised in that comprise the following steps:
(1) raw material is weighed by weight, 60-80 DEG C of stirring 1-2h in the water first jointly adding 1/2-2/3 to measure waterglass, borax, sodium lignin sulfonate, guar gum and sodium carboxymethylcellulose, it is subsequently adding magnesium sulfate and ammonium persulfate 50-60 DEG C, 1000-1500r/min stir 1-2h, obtain component A;
(2) water first styrene, methyl methacrylate and titanate coupling agent being added surplus mixes, under the conditions of 600-800r/min, is then slowly added to modified additive stirring 10-15min, obtains B component;
(3) component A and B component are mixed latter 60-70 DEG C, 800-1200r/min stir 2-3h, high speed dispersion be ground to≤20 μm after cooling, obtain water proof fire retardant timber curing agent.
CN201610057810.XA 2016-01-28 2016-01-28 Waterproof flame-retardant wood hardening agent and preparation method thereof Pending CN105984006A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610057810.XA CN105984006A (en) 2016-01-28 2016-01-28 Waterproof flame-retardant wood hardening agent and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201610057810.XA CN105984006A (en) 2016-01-28 2016-01-28 Waterproof flame-retardant wood hardening agent and preparation method thereof

Publications (1)

Publication Number Publication Date
CN105984006A true CN105984006A (en) 2016-10-05

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113305959A (en) * 2021-06-24 2021-08-27 东北林业大学 Method for improving size stability of fast-growing wood by using lignin-based modified liquid medicine

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1457353A (en) * 2001-02-26 2003-11-19 戴尼尔木材及特殊材料粘合剂公司 Process of gluing

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1457353A (en) * 2001-02-26 2003-11-19 戴尼尔木材及特殊材料粘合剂公司 Process of gluing

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113305959A (en) * 2021-06-24 2021-08-27 东北林业大学 Method for improving size stability of fast-growing wood by using lignin-based modified liquid medicine
CN113305959B (en) * 2021-06-24 2022-02-25 东北林业大学 Method for improving size stability of fast-growing wood by using lignin-based modified liquid medicine

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Application publication date: 20161005