CN1059724C - High effect mildew-resistant glass ine bedding paper - Google Patents
High effect mildew-resistant glass ine bedding paper Download PDFInfo
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- CN1059724C CN1059724C CN96119637A CN96119637A CN1059724C CN 1059724 C CN1059724 C CN 1059724C CN 96119637 A CN96119637 A CN 96119637A CN 96119637 A CN96119637 A CN 96119637A CN 1059724 C CN1059724 C CN 1059724C
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- mildew
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Abstract
The present invention relates to package pad paper for improving the fungus resistance of plate glass in the process of storage and transportation. The pad paper adopts a mildew inhibitor which is prepared from organic acid and dissolved salt containing divalent metal ions. The mildew inhibitor is directly added to pulp, or is sprayed and coated on immediately formed paper to manufacture high-efficiency glass mildew-resistant pad paper. The pad paper has the advantages of obviously improved fungus resistance of the glass in the process of storage and transportation, simple preparation process, no pollution, no stimulating smell, no poison, low cost, etc.
Description
The invention relates to the packing paper of packing that improves plate glass fungus resistance is used in transporting procedures.
Plate glass is very easily mouldy in transporting procedures, mouldy mechanism can letter chat into the monovalence sodium ion in the glass structure network gap can be spontaneously from the glass internal migration to the surface, after surface absorption low amounts of water, can form the spot or the rainbow of white, i.e. weathering of glass.In order to improve the fungus resistance of glass, method commonly used both at home and abroad has gas treating process, salt facture, acids facture, amine and amide-type facture, organic mould inhibitor facture, electrochemical treatments method, spills mildew-resistant powder method and holding paper method etc.At present the more holding paper method of usefulness is to handle with mould inhibitor being clipped in the transporting procedures packing paper between glass plate.Japan Patent (special permission 31-3684) etc. is introduced with things such as amines and is being packed on the packing paper as mould inhibitor, dipping, spraying, coating or infiltration.China patent of invention 89105376.X introduces the mixture of powders of forming with hexanedioic acid and polymethyl methacrylate and is sprinkled upon on the glass pane surface.And another patent 92105098.4 is introduced anti-mildew agent and is added in the entry by acidic materials alpha-hydroxybutyric dehydrogenase, acetate, ethanedioic acid, phosphoric acid and add sulfuric acid after the dissolving again and form by, ethanol, spices.
The mildew-resistant mechanism of the mould inhibitor that above-mentioned domestic and international disclosed plate glass mildew-resistant packing paper is used, mainly be by isolated water and glass surface contact or by in the acidity and the alkalescence of glass surface monovalence sodium ion improve the fungus resistance of glass.
The purpose of this invention is to provide that a kind of preparation method is simple, the mildew-resistant packing paper with efficient anti-mold effect of low price, nontoxic, harmless, non-environmental-pollution.The mildew-resistant mechanism of high effect mildew-resistant glass ine bedding paper is attached on the mildew-resistant packing paper that presss from both sides between plate glass with bivalent metal ion, when being diffused on the glass surface attached to the bivalent metal ion on the mildew-resistant packing paper, the monovalence sodium ion of energy " compacting " glass inside is spontaneously to the glass surface migration, and this has just fundamentally controlled the mouldy of transporting procedures middle plateform glass.Organic acid of the present invention also be in and the alkalescence of glass surface monovalence sodium ion, but have nontoxic, have no irritating odor and wherein citric acid and malic acid edible.
The mould inhibitor prescription that high effect mildew-resistant glass ine bedding paper provided by the invention adopted is simple, need only a kind of organic acid and after a kind of inorganic dissolved salt that contains bivalent metal ion mixes by finite concentration, and directly join in the paper pulp or spray on the molded good paper.The organic acid and the concentration thereof that adopt are as follows: citric acid:
Concentration: 0.07～0.15mol/L malic acid:
Concentration: 0.07～0.15mol/L tartaric acid:
Concentration: 0.07～0.15mol/L
The inorganic dissolved salt and the concentration thereof that contain bivalent metal ion that adopt are as follows:
Copper sulphate: CuSO
4Concentration: 0.08～0.18mol/L
Caddy: CdCl
22.5H
2O concentration: 0.08～0.18mol/L
Cadmium nitrate: Cd (NO
3)
2Concentration: 0.08～0.18mol/L
Nickel chloride: NiCl
26H
2O concentration: the L among 0.08～0.18mol/L concentration unit mol/L represents: the volume of pulp liquor.
Embodiment 1:
0.07mol/L after citric acid and 0.18mol/L copper sulphate mix, directly add in the paper pulp or spray on the molded good paper.
Embodiment 2:
0.15mol/L after citric acid and 0.08mol/L copper sulphate mix, directly add in the paper pulp or spray on the in type paper.
Embodiment 3:
0.1mol/L after citric acid and 0.11mol/l copper sulphate mix, directly add in the paper pulp or spray on the in type paper.
Embodiment 4:
0.1mol/L after malic acid and 0.11mol/L copper sulphate mix, directly add in the paper pulp or spray on the in type paper.
Embodiment 5:
0.1mol/L after tartaric acid and 0.11mol/L copper sulphate mix, directly add in the paper pulp or spray on the in type paper.
Embodiment 6:
0.1mol/L after citric acid and 0.11mol/L caddy mix, directly add in the paper pulp or spray on the in type paper.
Embodiment 7:
0.1mol/L after citric acid and 0.11mol/L cadmium nitrate mix, directly add in the paper pulp or spray on the in type paper.
Embodiment 8:
0.1mol/L after citric acid and 0.11mol/L nickel chloride mix, directly add in the paper pulp or spray on the in type paper.
Claims (1)
1, a kind of high effect mildew-resistant glass ine bedding paper, mould inhibitor is made up of a kind of organic acid and a kind of dissolved salt that contains bivalent metal ion, it is characterized in that described organic acid can use: citric acid:
Malic acid:
Or tartaric acid:
The bivalent metal ion dissolved salt can be used copper sulphate: CuSO
4, caddy: CdCl
22.5H
2O, cadmium nitrate: Cd (NO
3)
2Or nickel chloride: NiCl
26H
2O is mixed with composite type mouldproof agent, and its concentration range is:
Citric acid concentration scope: 0.07～0.15mol/L
Malic acid concentration scope: 0.07～0.15mol/L
Tartaric acid concentration scope: 0.07～0.15mol/L
Concentration of copper sulfate scope: 0.08～0.18mol/L
Caddy concentration range: 0.08～0.18mol/L
Cadmium nitrate concentration range: 0.08～0.18mol/L
The nickel chloride concentration range: the L among 0.08～0.18mol/L concentration unit mol/L represents: the volume of pulp liquor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96119637A CN1059724C (en) | 1996-09-18 | 1996-09-18 | High effect mildew-resistant glass ine bedding paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96119637A CN1059724C (en) | 1996-09-18 | 1996-09-18 | High effect mildew-resistant glass ine bedding paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1177033A CN1177033A (en) | 1998-03-25 |
| CN1059724C true CN1059724C (en) | 2000-12-20 |
Family
ID=5125876
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96119637A Expired - Fee Related CN1059724C (en) | 1996-09-18 | 1996-09-18 | High effect mildew-resistant glass ine bedding paper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1059724C (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101113078B (en) * | 2007-07-10 | 2011-02-02 | 程道远 | Novel glass fungus-proof insulating powder |
| CN102092956A (en) * | 2010-12-01 | 2011-06-15 | 秦皇岛玻璃工业研究设计院 | Mildew-proof treatment method for flat glass |
| CN102432194B (en) * | 2011-09-23 | 2017-04-12 | 泰州远创新材料科技有限公司 | Glass mildew remover |
| CN102732127B (en) * | 2012-06-20 | 2014-08-06 | 常州天合光能有限公司 | Paint used for preparing glass mildew-resisting high-molecular transparent protection film |
| JP6171327B2 (en) * | 2012-12-19 | 2017-08-02 | 旭硝子株式会社 | Glass interleaving paper and glass plate packaging |
| CN103603232A (en) * | 2013-11-14 | 2014-02-26 | 苏州惠通新型材料科技有限公司 | Glass backing paper production process |
| US10753044B2 (en) * | 2016-04-22 | 2020-08-25 | Enerpaper S.r.l. | Process for producing a flaked thermal-insulating and/or acoustic-insulating material |
| CN105926367B (en) * | 2016-05-16 | 2018-05-01 | 河南银鸽实业投资股份有限公司 | A kind of fungus-resistant liquid crystal electron glass interval paper and its production technology |
| CN106087526B (en) * | 2016-06-03 | 2018-02-02 | 沈阳思特雷斯纸业有限责任公司 | Mould proof glass plate packing paper and manufacture method |
| CN106087591A (en) * | 2016-06-29 | 2016-11-09 | 福建希源纸业有限公司 | A kind of glass lining paper |
| CN110306378A (en) * | 2018-03-27 | 2019-10-08 | 迁安市恒茂纸业有限公司 | A kind of formula and its preparation method of new anti-fungicide paper |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1044027A (en) * | 1989-01-12 | 1990-07-25 | 徐国起 | Mould-proof agent for glass |
| CN1067937A (en) * | 1992-06-26 | 1993-01-13 | 国家建筑材料工业局管理干部学院秦皇岛分院 | Anti-mouldy anti-scratch wrapping paper of plate glass and manufacture method thereof |
-
1996
- 1996-09-18 CN CN96119637A patent/CN1059724C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1044027A (en) * | 1989-01-12 | 1990-07-25 | 徐国起 | Mould-proof agent for glass |
| CN1067937A (en) * | 1992-06-26 | 1993-01-13 | 国家建筑材料工业局管理干部学院秦皇岛分院 | Anti-mouldy anti-scratch wrapping paper of plate glass and manufacture method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1177033A (en) | 1998-03-25 |
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| CF01 | Termination of patent right due to non-payment of annual fee |