CN105972463A - Environment-friendly bulb lamp based on graphene composite - Google Patents

Environment-friendly bulb lamp based on graphene composite Download PDF

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CN105972463A
CN105972463A CN201610583512.4A CN201610583512A CN105972463A CN 105972463 A CN105972463 A CN 105972463A CN 201610583512 A CN201610583512 A CN 201610583512A CN 105972463 A CN105972463 A CN 105972463A
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oil
mixture
herba
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庄可香
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    • C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M13/00—Fumigators; Apparatus for distributing gases
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M29/00—Scaring or repelling devices, e.g. bird-scaring apparatus
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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    • F21V29/87—Organic material, e.g. filled polymer composites; Thermo-conductive additives or coatings therefor
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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Abstract

An environment-friendly bulb lamp based on a graphene composite comprises a lampshade, an LED illumination assembly, a metal sleeve sleeved with the lampshade, a power supply driving module, a base and a silicon carbide thermal-conductive body arranged between the lampshade and the metal sleeve. A plurality of cooling holes are formed in the metal sleeve and penetrate through the metal sleeve. A plurality of cooling grooves are formed in the silicon carbide thermal-conductive body. On the basis of not influencing the cooling effect of an existing lamp, the lamp has functions of repelling mosquitoes and releasing anions, has a certain antibacterial function, meanwhile has certain functions of removing decoration pollutants such as formaldehyde, methylbenzene and TVOC, and enriches the use functions of a traditional lamp.

Description

A kind of environmental protection bulb lamp based on graphene composite material
Technical field
The present invention relates to technical field of lamps, be specifically related to a kind of environmental protection bulb lamp based on graphene composite material.
Background technology
Development and progress along with society, the environmental protection idea of people is more and more stronger, thus the illuminator of environmental protection can more be favored by people, day by day ripe LED technology due to its have efficiently, the advantage such as energy-saving and environmental protection, length in service life, power are low, LED illumination lamp the most gradually starts to replace traditional lighting.
LED electricity-saving lamp is actually a kind of compact, carry the LED of ballast, lamp tube ends voltage is directly over plasma state and turns on and send the ultraviolet of 253.7nm, ultraviolet evokes light-emitting phosphor, due to during fluorescent lamp operation the temperature of filament at about 1160K, more much lower than temperature 2200-2700K of electric filament lamp work, so its life-span is also greatly prolonged, arrive more than 5000 hours, due to the electric ballast that its operation efficiency is higher, there is not heating effect of current as electric filament lamp simultaneously, the energy conversion efficiency of fluorescent material is the highest, arrive more than every watt of 50 lumens, saves energy.
On the one hand, along with the continuous rising of Global Temperature, the population of mosquito and quantity all will be greatly improved, and the most day by day threaten the health of the mankind.Mosquito, in addition to directly stining thorn and sucking blood, harass sleep, more seriously propagates multiple disease.The mosquito of China passes disease malaria, Filariasis, epidemic encephalitis type B and dengue fever (or dengue hemorrhagic fever) four class, and mosquito passes more important virosis and also has yellow fever and various equine encephalitis etc..
On the other hand, by negative aeroion Technology application in electricity-saving lamp product, the electricity-saving lamp after using discharges negative aeroion, especially negative oxygen ion for a long time in indoor.Owing to it is structurally similar to ultra-oxygen anion free radical, therefore there is similar biological activity, it is possible to make the biological cell lived electronegative, so that virus loses the attacking ability to cell；Simultaneously, negative oxygen ion can react with finishing pollution things such as formaldehyde, toluene, TVOC, product is nonpoisonous and tasteless carbon dioxide and water, the generation of non-secondary pollution, there is certain effect purified the air of a room, such as, in artificial air's anion environment, in air, mycete, bacterial population can reduce by more than 90% after measured.After negative oxygen ion is inhaled into human body, neural excitatory state can be regulated, improve the ventilatory of lung, improve blood circulation, enhance metabolism, strengthen immune system ability, make in high spirits, the raising work efficiency of people etc., it also has certain therapeutical effect to numerous diseases such as hypertension, asthma, influenza, insomnia, arthritis, so people's anion is called " vitamin in air " " long-lived element ".
So far, the Technology design making conventional lamp product simultaneously have expelling mosquito and anion releasing health care does not also have sees.
Summary of the invention
The deficiency existed for prior art, the technical problem to be solved is to provide a kind of environmental protection bulb lamp based on graphene composite material, on the basis of not affecting original light fixture radiating effect, light fixture is made to have expelling mosquito, the function of anion releasing, simultaneously fragrant odour, character is gentle, also there is certain antibiotic effect, there is certain effect removing the finishing pollution things such as formaldehyde, toluene, TVOC simultaneously, enrich the use function of conventional lamp.
It is an object of the invention to be achieved through the following technical solutions:
nullA kind of environmental protection bulb lamp based on graphene composite material，Including lampshade、LED illumination assembly、The metallic sheath being mutually socketed with lampshade、Electric power driving module、Base and the carborundum heat carrier between lampshade and metallic sheath，Described metallic sheath has some louvres，Described louvre runs through described metallic sheath，Described carborundum heat carrier has some radiating grooves，Surfaces externally and internally even spread at described carborundum heat carrier has heat radiation coating，It is coated with heat radiation coating between described LED illumination assembly and described carborundum heat carrier，Inner surface even spread at described metallic sheath has heat radiation coating，Described heat radiation coating is prepared from according to parts by weight by following component: hybrid resin 60-75 weight portion，Graphene 5-6.5 weight portion，Sodium-based montmorillonite 3-4.5 weight portion，Carboxylic styrene butadiene latex 4-6.5 weight portion，Silicones metlyl branching silicone oil 1.5-2 weight portion，Polyethylene Glycol 0.7-1.2 weight portion，Pentane 0.7-1.8 weight portion，Nano silicon 1-2.5 weight portion，Polyacrylonitrile-based carbon fibre 7-9 weight portion，Aerosil 1-2 weight portion，Fire retardant 5.5-7 weight portion，Curing agent 4-6 weight portion，Solvent 15-20 weight portion，Ceria 0.1-0.15 weight portion，Active mineral matter powder 1.5-2 weight portion，Essential oil of traditional Chinese medicine 1.5-2.5 weight portion；Wherein, described hybrid resin be the mass ratio of the mixture of phenolic resin and epoxy resin, phenolic resin and epoxy resin be 2:1-3:1；The a length of 0.01mm of described polyacrylonitrile-based carbon fibre；Described fire retardant is the mixture of APP, tripolycyanamide and expanded graphites, the mass ratio 2:1.5:1.3 of described APP, tripolycyanamide and expanded graphites；Described solvent is the mixture of DAA and butyl ester, and the mass ratio of described DAA and butyl ester is 3:1-3:2；Described active mineral matter powder is the mixture of germanite, fluorite, tourmaline, gahnite 2.5:3:3.5:1.7 by weight, wherein tourmaline is dravite and the mixture of elbaite 4:3 by weight, particle diameter≤15 μm of described active mineral matter powder, described heat radiation coating is made by the steps and forms:
S1, weigh hybrid resin, sodium-based montmorillonite, carboxylic styrene butadiene latex by weight, silicones metlyl branching silicone oil, Polyethylene Glycol, pentane, nano silicon, polyacrylonitrile-based carbon fibre, Graphene, aerosil, fire retardant and solvent are placed in blender, mix well 80 DEG C of next part high speed stirrings, mixing time is 40 minutes, to be mixed uniformly after take out from blender, i.e. prepare mixture A, standby；
S2, by material Herba Agrimoniae 70-80, Cortex Moutan 15-18 weight portion, Semen Torreyae 20-25 weight portion, lavandula angustifolia 15-20 weight portion, Herba Anemones Hupehensis 3-5 weight portion, Rhizoma Acori Graminei 3-5 weight portion, Radix Salviae Miltiorrhizae 3-4 weight portion, Herba polygoni hydropiperis 3-4 weight portion, Radix Stemonae 5-8 weight portion decontamination, is placed in vacuum still 2-3 hour of-20 DEG C together, is placed in microwave dryer the most again and carries out pretreatment, wherein drying time is 30-40 minute, and microwave power is 17kw；
S3, step S2 is processed after material put into together in super micron mill and be crushed to 60 mesh, prepare crude drug powder, standby；
S4, by step S3 prepare crude drug powder put into supercritical carbon dioxide extraction apparatus extraction kettle in, regulate extracting pressure 28MPa, extraction temperature 45 DEG C, carbon dioxide flow is 1100L/h, dynamic extraction 2 hours, directly collects crude oil at separating still outlet triangular flask, standby；
S5, the crude oil prepared in step S4 is placed in 5 DEG C of environment freezing 70 minutes, the crude oil after freezing is placed in the High speed refrigerated centrifuge that rotating speed is 17000r/min centrifugal 25 minutes again, go the removal of impurity to be placed on 85 DEG C of vacuum tank evacuation 3 hours, i.e. prepare volatile oil B, standby；
S6, by rhododendron molle (bl.) g.don 1-3 weight portion, Rhizoma Atractylodis Macrocephalae 1-3 weight portion, Origanum majorana 1.5-2.5 weight portion, Herba Portulacae 3-4 weight portion, Herba Pogostemonis 3-4 weight portion, Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae) 3-4 weight portion, Artemisia argyi Levl. et Van. var. argyi cv. Qiai 3-4 weight portion is cleaned and is dried, put in super micron mill together and be crushed to 30 mesh, then add deionized water to soak 5 hours, amount of water by 7 times of immersion crude drug quality, dispersed with stirring is mixed well, prepare Traditional Chinese drug mixture, standby；
S7, Traditional Chinese drug mixture step S6 prepared decoct 2 hours in 80 DEG C, collect distillate, and add ether extraction, distillate is 2.5:1 with the volume ratio of ether, takes upper oil phase, then adds anhydrous sodium sulfate 0.13-0.2 weight portion and be dried process, i.e. prepare volatile oil C, standby；
S8, made to step S5 and S7 volatile oil B and volatile oil C are mixed and mixes well prepared miscella, it is sequentially added into Fructus Tritici aestivi quintessence oil, Geranium Essential, Herba Saussureae Involueratae quintessence oil, Fructus Citri Limoniae quintessence oil and grapefruit essential oil the most while stirring, it is sufficiently stirred for 45 minutes, stand 30 minutes, filtering and impurity removing, obtaining essential oil of traditional Chinese medicine, wherein, described miscella is 2:0.5:0.5:0.6:0.4:0.5 with the mass ratio of Fructus Tritici aestivi quintessence oil, Geranium Essential, Herba Saussureae Involueratae quintessence oil, Fructus Citri Limoniae quintessence oil and grapefruit essential oil；
The mixture A that S9, essential oil of traditional Chinese medicine step S8 prepared prepare with step S1, at 70-80 DEG C, in blender, concentrated compactness mixes 15 minutes, obtains premix material, standby；
S10, premix material step S9 prepared put into ball mill, then add ceria, active mineral matter powder and curing agent, at 70-80 DEG C, concentrate and grind 4.5 hours, filter decontamination, i.e. obtain heat radiation coating.
In a preferred embodiment, essential oil of traditional Chinese medicine in step s 8 also includes the component of following weight portion: surfactant 3-5 weight portion, diethyltoluamide 0.1-0.2, butyl butyrate 9-15 weight portion, Eucalyptus oil 10-13 weight portion, isopropyl myristate 1-2 weight portion, polyoxyethylenated alcohol sodium sulfate 10-15 weight portion and sodium benzoate 0.1-0.3 weight portion.
It should be noted that the experiment proved that, active mineral matter powder adds appropriate ceria (CeO2), the emittance utilizing this rare earth element is high, and the feature of half degradation period limit for length can be significantly increased the anion productivity of active mineral matter powder, and its principle is as follows: the Ce in ceria4+Ce is changed under photoenvironment3+, in conversion process, the recombination probability of electron-hole reduces, then in active mineral matter powder under the effect of the material electric field such as tourmaline, part electronics is passively with direction of an electric field displacement, and electron-hole recombination probability reduces, thus at tourmaline/CeO2The energy of substantial amounts of electrolysis air molecule has been gathered on composite powder surface, and then creates the negative aeroion of high concentration, Ce simultaneously3+It is oxidized into again Ce4+, then repeat aforesaid conversion process；Meanwhile, through practice detection, adding appropriate ceria component being combined through the present invention in the active mineral matter powder of proportioning, higher more than 10 times than the concentration without the active mineral matter powder anion adding ceria, r ray is identical with natural environment.
The present invention is based on motherland's traditional medicine, with reference to modern Chinese medicine pharmacological research, from the drug screening of existing Chinese medicine and repeatedly verifies, giving full play to each group of weight portion synergism, the effect brief introduction of the most each raw material is as follows.
Herba Agrimoniae: dicotyledon Rosaceae, perennial herb, feeble QI, mildly bitter flavor, the bud therapeutic method to keep the adverse QI flowing downwards, effect of anthelmintic.
Cortex Moutan: bacillus subtilis, escherichia coli, Bacillus typhi, Salmonella paratyphi, Bacillus proteus, bacillus pyocyaneus, staphylococcus, Hemolytic streptococcus, streptococcus pneumoniae, vibrio cholera etc. are all had stronger antibacterial action.
Semen Torreyae " herbal classic ": pathogen in main abdomen, goes three worms, and Serpentis stings.
Lavandula angustifolia can remove ant, except roach, acaricide, the when of being placed under wardrobe, medicated pillow, not only can replace camphor ball, the fragrance of one people that oozes can also be left, research finds, lavandula angustifolia has obvious antibacterial action, and the linalool contained in lavandula angustifolia is the main component that lavandula angustifolia is antibacterial, and it can suppress 17 kinds of antibacterials (including gram-negative bacteria and gram-positive bacteria), the growth of 10 kinds of funguses.
Herba Anemones Hupehensis: 1. " Shaanxi Chinese herbal medicine ": " bitter, cool, slightly poisonous." 2. " Chinese herbal medicine is commonly used in Sichuan ": " and toil, temperature, slightly poisonous." removing toxic substances, evacuation of pus granulation promoting, dissipating blood stasis of subsiding a swelling, have and kill maggot, wriggler, change long-pending, detumescence, dissipating blood stasis, control stubborn dermatitis, tinea alba, malaria, infantile malnutrition, dysentery, carbuncle furuncle swells, scrofula, traumatic injury.
Rhizoma Acori Graminei: its flower, stem aromatic flavor, has the effect had one's ideas straightened out, eliminate the phlegm, dissipate wind, epidemic disease of can dispelling Fructus Alpiniae Oxyphyllae, building body, can make spice or mosquito dispersing.
Radix Salviae Miltiorrhizae: nature and flavor are bitter, are slightly cold.GUIXIN, Liver Channel." the southern regions of the Yunnan Province book on Chinese herbal medicine " is recorded: reinforcing the heart sedate, calming heart and tranquilizing mind.Controlling forgetful punching seized with terror, palpitation with fear is insomnia, and has stasis-dispelling and pain-killing, promoting blood circulation to restore menstrual flow, the effect of the relieving restlessness that clears away heart-fire, for menoxenia, amenorrhea dysmenorrhea, lump in the abdomen, chest and abdomen twinge, pyretic arthralgia pain, skin infection.
Herba polygoni hydropiperis: all have inhibitory action, current clinical medicine research to show in test tube to various dysentery bacteriums, Herba polygoni hydropiperis has the effects such as antibacterial, antiviral, antiinflammatory, antioxidation.
The Radix Stemonae: can driving away mosquito, resisting pathogenic microbes effect, the multiple pathomycetes such as beta hemolytic streptococcus, meningococcus, staphylococcus aureus, Staphylococcus albus, Bacillus typhi, pneumobacillus, bacillus pestis, anthrax bacillus are had certain inhibitory action, and its infusion all has killing action to mosquitos and flies larva, head louse, clothing louse and Cimex bedbug etc..
Rhododendron molle (bl.) g.don: have another name called Flos Rhododendri Mollis, Azalea pontica, yellow Rhododendron simsii Planch., there is expelling wind and removing dampness；Analgesic therapy；Effect of parasite killing.
The Rhizoma Atractylodis Macrocephalae: belong to Compositae, [WTBX herbaceos perennial has inhibitory action to acrothesium floccosum, star nocardia.Decoct also has inhibitory action to meningococcus.Nearly report Rhizoma Atractylodis Macrocephalae decoct and decoction of four noble drugs all have bacteriostasis in various degree to Bacillus typhi, paratyphoid bacillus A, shigella flexneri, escherichia coli, bacillus pyocyaneus etc..
Origanum majorana: can improve that mood is depressed and addictive disease, especially effective to liberal-mindedness and vigorous endurance stress symptom, blood vessel, blood pressure lowering can be expanded, alleviate and burden, help to eliminate cardiopalmus, have the nerve of excellence to pacify and calm function.
Herba Portulacae: Portulacaceae annual herb plant.Plump succulence, without hair, high 10-30cm, is born in the area without shade such as roadside, field and ruins, flower garden.All there is distribution domestic various places.This kind is medicine food dual purpose plant.Herb hyoscine, have clearing away heat-damp and promoting diuresis, removing toxic substances and promoting subsidence of swelling, antiinflammatory, quench the thirst, diuresis.
Herba Pogostemonis: acrid in the mouth, slightly warm in nature.Effect: removing dampness for regulating stomach, the effect of administration of inducing sweat, solve, cure mainly dampness taste, breast gastral cavity is vexed swollen, and appetite is the most fragrant, Nausea and vomiting；Summer, heat-damp in summer was sleepy, uncomfortable in chest did not relaxed, and affection of exogenous wind-cold. the diseases such as aversion to cold is uncomfortable in chest, and have and have stronger Fungistasis and antibacterial action.
The Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae): the another name river Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae), continuous poison, Radix Stellerae, chervil, vexed fresh idea, Re Jiaba, Herba Senecionis Dianthui, Radix scopoliae sinensis, one fragrant, the fore-telling of medicine sieve, life pull, flourishing bavin headdress flower, monkey root, Gelsemium elegans Benth., in Chinese medicine with its root eliminate the phlegm, pain relieving, removing food stagnancy, parasite killing.
Artemisia argyi Levl. et Van. var. argyi cv. Qiai: have another name called: containing 17 kinds of known compounds, has and relievings asthma, antitussive, eliminates the phlegm and clear scorching effect, the effect such as reasonable QI and blood, warming the meridian for stopping bleeding antiabortive by cold-damp, regulating menstruation, clearing and antitussive expectorant.Cure mainly the diseases such as cold type of pain in menoxenia, abdomen, vaginal bleeding during pregnancy hematochezia, frequent fetal movement, infertility.
It should be noted that be proven, after carrying out the Radix Salviae Miltiorrhizae of certain part by weight, Herba polygoni hydropiperis and the Radix Stemonae compounding, not only it be remarkably improved degerming antibacterial ability, also can produce a kind of delicate fragrance taste having no side effect, refreshing, there is certain effect of refreshing oneself；, it is proven meanwhile, after carrying out the Herba Agrimoniae of certain part by weight, Semen Torreyae, Rhizoma Acori Graminei, rhododendron molle (bl.) g.don, the Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae) and Herba Anemones Hupehensis compounding, makes the mosquito dispersing ability of said composition be significantly improved；Additionally, after the components such as Cortex Moutan, the Rhizoma Atractylodis Macrocephalae, Herba Portulacae and Artemisia argyi Levl. et Van. var. argyi cv. Qiai carry out compatibility, substantially increase the antibacterial degerming ability of compositions, through practice detection, staphylococcus aureus, anthrax bacillus, hemophilus influenza, micrococcus catarrhalis, streptococcus pneumoniae, escherichia coli, group B streptococcus, diphtheria corynebacterium, Bacillus typhi, green pus liver bacterium, dysentery bacterium etc. more than 30 are planted pathogenic bacteria and have certain suppression and killing action by the compositions after compounding.
The effect of the present invention:
The present invention uses Chinese medicine to compound with active mineral matter, makes the present invention not only have preferable radiating effect, it is also possible to expelling mosquito, anion releasing, fresh air, simultaneously fragrant odour, and character is gentle, has anophelifuge, antibacterial and effect of health care.
Accompanying drawing explanation
Fig. 1 is radiator structure perspective exploded view of the present invention.
Fig. 2 is overall schematic of the present invention.
Fig. 3 is metallic sheath schematic diagram of the present invention.
Detailed description of the invention
Embodiment 1:
Refer to shown in Fig. 1 to Fig. 3, a kind of environmental protection bulb lamp based on graphene composite material, metallic sheath 4, electric power driving module 5, base 6 and the carborundum heat carrier 3 between lampshade (1) and metallic sheath 4 being mutually socketed including lampshade 1, LED illumination assembly 2 and lampshade 1, described metallic sheath 4 has some louvres 40, described louvre (40) runs through described metallic sheath 4, and described carborundum heat carrier 3 has some radiating grooves 31.
Preferably, described carborundum heat carrier 3 has a hollow cavity, described carborundum heat carrier 3 surface has some radiating grooves 31, described radiating groove 31 is axially arranged, this radiating groove 31 runs through the sidewall of described carborundum heat carrier 3, extraneous air can carry out air exchange by this this radiating groove 31 with the air within the hollow cavity of described carborundum heat carrier 3, certainly, for improving radiating effect, the radiating groove 31 of described carborundum heat carrier 3 is corresponding with the louvre 40 of described metallic sheath 4, extraneous air can carry out air exchange by radiating groove 31 and louvre 40 with the air within the hollow cavity of described carborundum heat carrier 3.
nullSurfaces externally and internally even spread at described carborundum heat carrier 3 has heat radiation coating 30，It is coated with heat radiation coating 30 between described LED illumination assembly 2 and described carborundum heat carrier 3，Inner surface even spread at described metallic sheath 4 has heat radiation coating 30，Described heat radiation coating is prepared from according to parts by weight by following component: hybrid resin 60 weight portion，Sodium-based montmorillonite 4.5 weight portion，Carboxylic styrene butadiene latex 4 weight portion，Silicones metlyl branching silicone oil 2 weight portion，Polyethylene Glycol 0.7 weight portion，Pentane 1.8 weight portion，Nano silicon 1 weight portion，Polyacrylonitrile-based carbon fibre 9 weight portion，Graphene 5 weight portion，Aerosil 2 weight portion，Fire retardant 5.5 weight portion，Curing agent 6 weight portion，Solvent 15 weight portion，Ceria 0.1 weight portion，Active mineral matter powder 2 weight portion，Essential oil of traditional Chinese medicine 1.5 weight portion；Wherein, described hybrid resin be the mass ratio of the mixture of phenolic resin and epoxy resin, phenolic resin and epoxy resin be 3:1；The a length of 0.01mm of described polyacrylonitrile-based carbon fibre；Described fire retardant is the mixture of APP, tripolycyanamide and expanded graphites, the mass ratio 2:1.5:1.3 of described APP, tripolycyanamide and expanded graphites；Described solvent is the mixture of DAA and butyl ester, and the mass ratio of described DAA and butyl ester is 3:1；Described active mineral matter powder is the mixture of germanite, fluorite, tourmaline, gahnite 2.5:3:3.5:1.7 by weight, wherein tourmaline is dravite and the mixture of elbaite 4:3 by weight, particle diameter≤15 μm of described active mineral matter powder, described heat radiation coating is made by the steps and forms:
S1, weigh hybrid resin, sodium-based montmorillonite, carboxylic styrene butadiene latex by weight, silicones metlyl branching silicone oil, Polyethylene Glycol, pentane, nano silicon, polyacrylonitrile-based carbon fibre, Graphene, aerosil, fire retardant and solvent are placed in blender, mix well 80 DEG C of next part high speed stirrings, mixing time is 40 minutes, to be mixed uniformly after take out from blender, i.e. prepare mixture A, standby；
S2, by material Herba Agrimoniae 80, Cortex Moutan 15 weight portion, Semen Torreyae 25 weight portion, lavandula angustifolia 15 weight portion, Herba Anemones Hupehensis 5 weight portion, Rhizoma Acori Graminei 3 weight portion, Radix Salviae Miltiorrhizae 4 weight portion, Herba polygoni hydropiperis 3 weight portion, the Radix Stemonae 8 weight portion decontamination, is placed in the vacuum still 2 hours of-20 DEG C together, is placed in microwave dryer the most again and carries out pretreatment, wherein drying time is 30 minutes, and microwave power is 17kw；
S3, step S2 is processed after material put into together in super micron mill and be crushed to 60 mesh, prepare crude drug powder, standby；
S4, by step S3 prepare crude drug powder put into supercritical carbon dioxide extraction apparatus extraction kettle in, regulate extracting pressure 28MPa, extraction temperature 45 DEG C, carbon dioxide flow is 1100L/h, dynamic extraction 2 hours, directly collects crude oil at separating still outlet triangular flask, standby；
S5, the crude oil prepared in step S4 is placed in 5 DEG C of environment freezing 70 minutes, the crude oil after freezing is placed in the High speed refrigerated centrifuge that rotating speed is 17000r/min centrifugal 25 minutes again, go the removal of impurity to be placed on 85 DEG C of vacuum tank evacuation 3 hours, i.e. prepare volatile oil B, standby；
S6, by rhododendron molle (bl.) g.don 1 weight portion, the Rhizoma Atractylodis Macrocephalae 3 weight portion, Origanum majorana 1.5 weight portion, Herba Portulacae 4 weight portion, Herba Pogostemonis 3 weight portion, the Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae) 4 weight portion, Artemisia argyi Levl. et Van. var. argyi cv. Qiai 3 weight portion is cleaned and is dried, put in super micron mill together and be crushed to 30 mesh, then add deionized water to soak 5 hours, amount of water by 7 times of immersion crude drug quality, dispersed with stirring is mixed well, prepare Traditional Chinese drug mixture, standby；
S7, Traditional Chinese drug mixture step S6 prepared decoct 2 hours in 80 DEG C, collect distillate, and add ether extraction, distillate is 2.5:1 with the volume ratio of ether, takes upper oil phase, then adds anhydrous sodium sulfate 0.13 weight portion and be dried process, i.e. prepare volatile oil C, standby；
S8, made to step S5 and S7 volatile oil B and volatile oil C are mixed and mixes well prepared miscella, it is sequentially added into Fructus Tritici aestivi quintessence oil, Geranium Essential, Herba Saussureae Involueratae quintessence oil, Fructus Citri Limoniae quintessence oil and grapefruit essential oil the most while stirring, it is sufficiently stirred for 45 minutes, stand 30 minutes, filtering and impurity removing, obtaining essential oil of traditional Chinese medicine, wherein, described miscella is 2:0.5:0.5:0.6:0.4:0.5 with the mass ratio of Fructus Tritici aestivi quintessence oil, Geranium Essential, Herba Saussureae Involueratae quintessence oil, Fructus Citri Limoniae quintessence oil and grapefruit essential oil；
The mixture A that S9, essential oil of traditional Chinese medicine step S8 prepared prepare with step S1, at 70 DEG C, in blender, concentrated compactness mixes 15 minutes, obtains premix material, standby；
S10, premix material step S9 prepared put into ball mill, then add ceria, active mineral matter powder and curing agent, at 73 DEG C, concentrate and grind 4.5 hours, filter decontamination, i.e. obtain heat radiation coating.
In a preferred embodiment, essential oil of traditional Chinese medicine in step s 8 also includes the component of following weight portion: surfactant 3 weight portion, diethyltoluamide 0. 2 weight portion, butyl butyrate 9 weight portion, Eucalyptus oil 4 weight portion, isopropyl myristate 1 weight portion, polyoxyethylenated alcohol sodium sulfate 15 weight portion and sodium benzoate 0.1 weight portion.
Embodiment 2:
nullA kind of environmental protection bulb lamp based on graphene composite material，Including lampshade 1、LED illumination assembly 2、The metallic sheath 4 being mutually socketed with lampshade 1、Electric power driving module 5、Base 6 and the carborundum heat carrier 3 between lampshade (1) and metallic sheath 4，Described metallic sheath 4 has some louvres 40，Described louvre (40) runs through described metallic sheath 4，Described carborundum heat carrier 3 has some radiating grooves 31，Surfaces externally and internally even spread at described carborundum heat carrier 3 has heat radiation coating 30，It is coated with heat radiation coating 30 between described LED illumination assembly 2 and described carborundum heat carrier 3，Inner surface even spread at described metallic sheath 4 has heat radiation coating 30，Described heat radiation coating is prepared from according to parts by weight by following component: hybrid resin 75 weight portion，Sodium-based montmorillonite 3 weight portion，Carboxylic styrene butadiene latex 6.5 weight portion，Silicones metlyl branching silicone oil 1.5 weight portion，Polyethylene Glycol 1.2 weight portion，Pentane 0.7 weight portion，Nano silicon 2.5 weight portion，Polyacrylonitrile-based carbon fibre 8 weight portion，Graphene 6 weight portion，Aerosil 1.5 weight portion，Fire retardant 6 weight portion，Curing agent 5 weight portion，Solvent 17 weight portion，Ceria 0.15 weight portion，Active mineral matter powder 1.7 weight portion，Essential oil of traditional Chinese medicine 2 weight portion；Wherein, described hybrid resin be the mass ratio of the mixture of phenolic resin and epoxy resin, phenolic resin and epoxy resin be 3:1；The a length of 0.01mm of described polyacrylonitrile-based carbon fibre；Described fire retardant is the mixture of APP, tripolycyanamide and expanded graphites, the mass ratio 2:1.5:1.3 of described APP, tripolycyanamide and expanded graphites；Described solvent is the mixture of DAA and butyl ester, and the mass ratio of described DAA and butyl ester is 3:2；Described active mineral matter powder is the mixture of germanite, fluorite, tourmaline, gahnite 2.5:3:3.5:1.7 by weight, wherein tourmaline is dravite and the mixture of elbaite 4:3 by weight, particle diameter≤15 μm of described active mineral matter powder, described heat radiation coating is made by the steps and forms:
S1, weigh hybrid resin, sodium-based montmorillonite, carboxylic styrene butadiene latex by weight, silicones metlyl branching silicone oil, Polyethylene Glycol, pentane, nano silicon, polyacrylonitrile-based carbon fibre, Graphene, aerosil, fire retardant and solvent are placed in blender, mix well 80 DEG C of next part high speed stirrings, mixing time is 40 minutes, to be mixed uniformly after take out from blender, i.e. prepare mixture A, standby；
S2, by material Herba Agrimoniae 70, Cortex Moutan 18 weight portion, Semen Torreyae 20 weight portion, lavandula angustifolia 20 weight portion, Herba Anemones Hupehensis 3 weight portion, Rhizoma Acori Graminei 5 weight portion, Radix Salviae Miltiorrhizae 3 weight portion, Herba polygoni hydropiperis 4 weight portion, the Radix Stemonae 5 weight portion decontamination, is placed in the vacuum still 3 hours of-20 DEG C together, is placed in microwave dryer the most again and carries out pretreatment, wherein drying time is 40 minutes, and microwave power is 17kw；
S3, step S2 is processed after material put into together in super micron mill and be crushed to 60 mesh, prepare crude drug powder, standby；
S4, by step S3 prepare crude drug powder put into supercritical carbon dioxide extraction apparatus extraction kettle in, regulate extracting pressure 28MPa, extraction temperature 45 DEG C, carbon dioxide flow is 1100L/h, dynamic extraction 2 hours, directly collects crude oil at separating still outlet triangular flask, standby；
S5, the crude oil prepared in step S4 is placed in 5 DEG C of environment freezing 70 minutes, the crude oil after freezing is placed in the High speed refrigerated centrifuge that rotating speed is 17000r/min centrifugal 25 minutes again, go the removal of impurity to be placed on 85 DEG C of vacuum tank evacuation 3 hours, i.e. prepare volatile oil B, standby；
S6, by rhododendron molle (bl.) g.don 3 weight portion, the Rhizoma Atractylodis Macrocephalae 1 weight portion, Origanum majorana 2.5 weight portion, Herba Portulacae 3 weight portion, Herba Pogostemonis 4 weight portion, the Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae) 3 weight portion, Artemisia argyi Levl. et Van. var. argyi cv. Qiai 4 weight portion is cleaned and is dried, put in super micron mill together and be crushed to 30 mesh, then add deionized water to soak 5 hours, amount of water by 7 times of immersion crude drug quality, dispersed with stirring is mixed well, prepare Traditional Chinese drug mixture, standby；
S7, Traditional Chinese drug mixture step S6 prepared decoct 2 hours in 80 DEG C, collect distillate, and add ether extraction, distillate is 2.5:1 with the volume ratio of ether, takes upper oil phase, then adds anhydrous sodium sulfate 0.18 weight portion and be dried process, i.e. prepare volatile oil C, standby；
S8, made to step S5 and S7 volatile oil B and volatile oil C are mixed and mixes well prepared miscella, it is sequentially added into Fructus Tritici aestivi quintessence oil, Geranium Essential, Herba Saussureae Involueratae quintessence oil, Fructus Citri Limoniae quintessence oil and grapefruit essential oil the most while stirring, it is sufficiently stirred for 45 minutes, stand 30 minutes, filtering and impurity removing, obtaining essential oil of traditional Chinese medicine, wherein, described miscella is 2:0.5:0.5:0.6:0.4:0.5 with the mass ratio of Fructus Tritici aestivi quintessence oil, Geranium Essential, Herba Saussureae Involueratae quintessence oil, Fructus Citri Limoniae quintessence oil and grapefruit essential oil；
The mixture A that S9, essential oil of traditional Chinese medicine step S8 prepared prepare with step S1, at 75 DEG C, in blender, concentrated compactness mixes 15 minutes, obtains premix material, standby；
S10, premix material step S9 prepared put into ball mill, then add ceria, active mineral matter powder and curing agent, at 80 DEG C, concentrate and grind 4.5 hours, filter decontamination, i.e. obtain heat radiation coating.
In a preferred embodiment, essential oil of traditional Chinese medicine in step s 8 also includes the component of following weight portion: surfactant 5 weight portion, diethyltoluamide 0.1 weight portion, butyl butyrate 15 weight portion, Eucalyptus oil 7 weight portion, isopropyl myristate 2 weight portion, polyoxyethylenated alcohol sodium sulfate 10 weight portion and sodium benzoate 0.3 weight portion.
Remaining is with embodiment 1.
In a preferred embodiment, described lampshade 1 is prepared from according to parts by weight by following component:
Resin 50 weight portion；Glass fibre 13 weight portion；Fire retardant 6 weight portion；Graphene 3 weight portion；Curing agent 3 weight portion；Fluorescent material 0.2 weight portion, good solid 754 light trigger 3 weight portions of vapour Ba Yan；Polyetheramine catalyst 0.6 weight portion；Active mineral matter powder 2 weight portion；Essential oil of traditional Chinese medicine 2.5 weight portion；nullWherein，Described resin is epoxy soybean oil acrylate and the mixture of bisphenol A-type E51 epoxy resin，The mass ratio of described epoxy soybean oil acrylate and bisphenol A-type E51 epoxy resin is 2:1，Described fire retardant is APP、Tripolycyanamide and the mixture of expanded graphites，Described APP、The mass ratio 2:1.5:1.3 of tripolycyanamide and expanded graphites，Described fluorescent material is Ce and YAG fluorescent powder mixture，Particle diameter≤15 μm of described fluorescent material，Described active mineral matter powder is germanite、Fluorite、Tourmaline、Gahnite is by weight the mixture of 2.5:3:3.7:2，Wherein tourmaline is dravite and the mixture of elbaite 5:3 by weight，Particle diameter≤15 μm of described active mineral matter powder，Described lampshade shell is made by the steps and forms:
Good solid 754 light triggers of S1, the resin by required parts by weight, fire retardant, Graphene, fluorescent material, vapour Ba Yan and polyetheramine catalyst are placed in blender, mix well 75 DEG C of next part high speed stirrings, mixing time is 15-30 minute, to be mixed uniformly after take out from blender, i.e. prepare resin compound, standby；
S2, by Pu, material mountain race 60 weight portion, Bulbus Lycoridis Radiatae stem 10 weight portion, walk to and for floral leaf 15 weight portion, shaven head grass roots leaf 6 weight portion, Firmiana platanifolia (Linn. f.) Marsili bark 5 weight portion, sheep Cortex Jujubae 3.5 weight portion, Flos lupuli (Flos Humuli Lupuli) 3 weight portion, Herba Violae dissectae 2 weight portion, Radix et Rhizoma Dysosmatis 2.5 weight portion, Fructus Hordei Germinatus 2 weight portion, the Radix Angelicae Dahuricae 1 weight portion, Herba Lysimachiae foenum-graeci 1.5 weight portion and Flos Caryophylli 1.5 weight portion, decontamination, is placed in the vacuum still 2.5 hours of-20 DEG C together, is placed in microwave dryer the most again and carries out pretreatment, wherein drying time is 35 minutes, and microwave power is 17kw；
S3, step S2 is processed after material put into together in super micron mill and be crushed to 80 mesh, prepare crude drug powder, standby；
S4, by step S3 prepare crude drug powder put into supercritical carbon dioxide extraction apparatus extraction kettle in, regulation extracting pressure 31MPa, extraction temperature 40 DEG C, carbon dioxide flow is 1100L/h, dynamic extraction 2.5 hours, directly collect crude oil at separating still outlet triangular flask, then prepared crude oil is placed in 5 DEG C of environment freezing 65 minutes, the crude oil after freezing is placed in the High speed refrigerated centrifuge that rotating speed is 18000r/min centrifugal 30 minutes again, the removal of impurity is gone to be placed on 85 DEG C of vacuum tank evacuation 3.5 hours, i.e. prepare essential oil of traditional Chinese medicine, standby；
The resin compound that S5, essential oil of traditional Chinese medicine step S4 prepared and step S1 prepare, at 75 DEG C, in blender, concentrated compactness mixes 35 minutes, obtain compound, then this compound is put into ball mill, add active mineral matter powder, curing agent and glass fibre, carry out concentrating at 85 DEG C and grind 3 hours, filter decontamination, i.e. prepare premix material；
S6, the premix material of step S5 being put into twin-screw extrusion equipment, wherein, the rotating speed of twin-screw extrusion equipment is 200 revs/min, and extrusion temperature is 200 ° of C, extrusion, cooling, and pelletizing i.e. obtains composite；
S7, the composite that step S6 is prepared through injection machine heating, extruding, molding, cool down, repair, obtain lampshade 1.
The test index of Example 1 and Example 2 of the present invention is as follows:
(1) abnormal smells from the patient inspection: sense organ, nonirritant abnormal flavour.
(2) repelling effect test.
Carrying out contrast test according to the repelling effect of ordinary lamp and lantern of the prior art with above-described embodiment 1 and embodiment 2, test data ask for an interview table 1.
Conclusion: Example 1 and Example 2 of the present invention all can play preferable mosquito-repelling function, with ordinary lamp and lantern on market
Comparing, the present invention has obviously repelling effect.
(3) anionic textiles.
Using anion test instrument, be primarily directed to timber, Ore, ceramic material, negative ion powder are made the anion quantity that commodity (such as anion medicated clothing, necklace, woollen blanket) etc. are discharged make measurement to relevant, test result is shown in Table 2.
Conclusion: the embodiment of the present invention 1, embodiment 2 can be with sustained release negative aeroions, and compared with ordinary lamp and lantern of the prior art, the present invention has obviously advantage.

Claims (2)

  1. null1. an environmental protection bulb lamp based on graphene composite material，It is characterized in that: include lampshade (1)、LED illumination assembly (2)、Metallic sheath (4) with lampshade (1) mutually socket、Electric power driving module (5)、Base (6) and the carborundum heat carrier (3) between lampshade (1) and metallic sheath (4)，Described metallic sheath (4) has some louvres (40)，Described louvre (40) runs through described metallic sheath (4)，Described carborundum heat carrier (3) has some radiating grooves (31)，Surfaces externally and internally even spread described carborundum heat carrier (3) has heat radiation coating (30)，It is coated with heat radiation coating (30) between described LED illumination assembly (2) and described carborundum heat carrier (3)，Inner surface even spread at described metallic sheath (4) has heat radiation coating (30)，Described heat radiation coating is prepared from according to parts by weight by following component: hybrid resin 60-75 weight portion，Graphene 5-6.5 weight portion，Sodium-based montmorillonite 3-4.5 weight portion，Carboxylic styrene butadiene latex 4-6.5 weight portion，Silicones metlyl branching silicone oil 1.5-2 weight portion，Polyethylene Glycol 0.7-1.2 weight portion，Pentane 0.7-1.8 weight portion，Nano silicon 1-2.5 weight portion，Polyacrylonitrile-based carbon fibre 7-9 weight portion，Aerosil 1-2 weight portion，Fire retardant 5.5-7 weight portion，Curing agent 4-6 weight portion，Solvent 15-20 weight portion，Ceria 0.1-0.15 weight portion，Active mineral matter powder 1.5-2 weight portion，Essential oil of traditional Chinese medicine 1.5-2.5 weight portion；Wherein, described hybrid resin be the mass ratio of the mixture of phenolic resin and epoxy resin, phenolic resin and epoxy resin be 2:1-3:1；The a length of 0.01mm of described polyacrylonitrile-based carbon fibre；Described fire retardant is the mixture of APP, tripolycyanamide and expanded graphites, the mass ratio 2:1.5:1.3 of described APP, tripolycyanamide and expanded graphites；Described solvent is the mixture of DAA and butyl ester, and the mass ratio of described DAA and butyl ester is 3:1-3:2；Described active mineral matter powder is the mixture of germanite, fluorite, tourmaline, gahnite 2.5:3:3.5:1.7 by weight, wherein tourmaline is dravite and the mixture of elbaite 4:3 by weight, particle diameter≤15 μm of described active mineral matter powder, described heat radiation coating is made by the steps and forms:
    S1, weigh hybrid resin, sodium-based montmorillonite, carboxylic styrene butadiene latex by weight, silicones metlyl branching silicone oil, Polyethylene Glycol, pentane, nano silicon, polyacrylonitrile-based carbon fibre, Graphene, aerosil, fire retardant and solvent are placed in blender, mix well 80 DEG C of next part high speed stirrings, mixing time is 40 minutes, to be mixed uniformly after take out from blender, i.e. prepare mixture A, standby；
    S2, by material Herba Agrimoniae 70-80, Cortex Moutan 15-18 weight portion, Semen Torreyae 20-25 weight portion, lavandula angustifolia 15-20 weight portion, Herba Anemones Hupehensis 3-5 weight portion, Rhizoma Acori Graminei 3-5 weight portion, Radix Salviae Miltiorrhizae 3-4 weight portion, Herba polygoni hydropiperis 3-4 weight portion, Radix Stemonae 5-8 weight portion decontamination, is placed in vacuum still 2-3 hour of-20 DEG C together, is placed in microwave dryer the most again and carries out pretreatment, wherein drying time is 30-40 minute, and microwave power is 17kw；
    S3, step S2 is processed after material put into together in super micron mill and be crushed to 60 mesh, prepare crude drug powder, standby；
    S4, by step S3 prepare crude drug powder put into supercritical carbon dioxide extraction apparatus extraction kettle in, regulate extracting pressure 28MPa, extraction temperature 45 DEG C, carbon dioxide flow is 1100L/h, dynamic extraction 2 hours, directly collects crude oil at separating still outlet triangular flask, standby；
    S5, the crude oil prepared in step S4 is placed in 5 DEG C of environment freezing 70 minutes, the crude oil after freezing is placed in the High speed refrigerated centrifuge that rotating speed is 17000r/min centrifugal 25 minutes again, go the removal of impurity to be placed on 85 DEG C of vacuum tank evacuation 3 hours, i.e. prepare volatile oil B, standby；
    S6, by rhododendron molle (bl.) g.don 1-3 weight portion, Rhizoma Atractylodis Macrocephalae 1-3 weight portion, Origanum majorana 1.5-2.5 weight portion, Herba Portulacae 3-4 weight portion, Herba Pogostemonis 3-4 weight portion, Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae) 3-4 weight portion, Artemisia argyi Levl. et Van. var. argyi cv. Qiai 3-4 weight portion is cleaned and is dried, put in super micron mill together and be crushed to 30 mesh, then add deionized water to soak 5 hours, amount of water by 7 times of immersion crude drug quality, dispersed with stirring is mixed well, prepare Traditional Chinese drug mixture, standby；
    S7, Traditional Chinese drug mixture step S6 prepared decoct 2 hours in 80 DEG C, collect distillate, and add ether extraction, distillate is 2.5:1 with the volume ratio of ether, takes upper oil phase, then adds anhydrous sodium sulfate 0.13-0.2 weight portion and be dried process, i.e. prepare volatile oil C, standby；
    S8, made to step S5 and S7 volatile oil B and volatile oil C are mixed and mixes well prepared miscella, it is sequentially added into Fructus Tritici aestivi quintessence oil, Geranium Essential, Herba Saussureae Involueratae quintessence oil, Fructus Citri Limoniae quintessence oil and grapefruit essential oil the most while stirring, it is sufficiently stirred for 45 minutes, stand 30 minutes, filtering and impurity removing, obtaining essential oil of traditional Chinese medicine, wherein, described miscella is 2:0.5:0.5:0.6:0.4:0.5 with the mass ratio of Fructus Tritici aestivi quintessence oil, Geranium Essential, Herba Saussureae Involueratae quintessence oil, Fructus Citri Limoniae quintessence oil and grapefruit essential oil；
    The mixture A that S9, essential oil of traditional Chinese medicine step S8 prepared prepare with step S1, at 70-80 DEG C, in blender, concentrated compactness mixes 15 minutes, obtains premix material, standby；
    S10, premix material step S9 prepared put into ball mill, then add ceria, active mineral matter powder and curing agent, at 70-80 DEG C, concentrate and grind 4.5 hours, filter decontamination, i.e. obtain heat radiation coating.
  2. A kind of environmental protection bulb lamp based on graphene composite material the most according to claim 1, it is characterised in that: essential oil of traditional Chinese medicine in step s 8 also includes the component of following weight portion: surfactant 3-5 weight portion, diethyltoluamide 0.1-0.2 weight portion, butyl butyrate 9-15 weight portion, Eucalyptus oil 4-7 weight portion, isopropyl myristate 1-2 weight portion, polyoxyethylenated alcohol sodium sulfate 10-15 weight portion and sodium benzoate 0.1-0.3 weight portion.
CN201610583512.4A 2016-05-23 2016-07-24 Environment-friendly bulb lamp based on graphene composite Pending CN105972463A (en)

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CN106051486A (en) * 2016-08-19 2016-10-26 桂林电子科技大学 High-power LED lamp heat dissipation device based on graphene heat rectification material and lamp
CN106958752A (en) * 2017-05-25 2017-07-18 无锡市翱宇特新科技发展有限公司 A kind of LED fluorescent lamp tube

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Publication number Priority date Publication date Assignee Title
CN203202684U (en) * 2013-02-25 2013-09-18 建准电机工业股份有限公司 Lamp
CN104292985A (en) * 2014-09-18 2015-01-21 中山市品汇创新专利技术开发有限公司 Negative ion lavender-scented crayons
CN104966459A (en) * 2015-06-08 2015-10-07 中山艺展装饰工程有限公司 Crocus sativus anti-microbial tellurion device for geographical teaching observation and demonstration
CN204962681U (en) * 2015-07-22 2016-01-13 周湘峻 Anion lamp of recuperating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN203202684U (en) * 2013-02-25 2013-09-18 建准电机工业股份有限公司 Lamp
CN104292985A (en) * 2014-09-18 2015-01-21 中山市品汇创新专利技术开发有限公司 Negative ion lavender-scented crayons
CN104966459A (en) * 2015-06-08 2015-10-07 中山艺展装饰工程有限公司 Crocus sativus anti-microbial tellurion device for geographical teaching observation and demonstration
CN204962681U (en) * 2015-07-22 2016-01-13 周湘峻 Anion lamp of recuperating

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