CN105970679A - Silk fabric dyeing method - Google Patents

Silk fabric dyeing method Download PDF

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Publication number
CN105970679A
CN105970679A CN201610443376.9A CN201610443376A CN105970679A CN 105970679 A CN105970679 A CN 105970679A CN 201610443376 A CN201610443376 A CN 201610443376A CN 105970679 A CN105970679 A CN 105970679A
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CN
China
Prior art keywords
dyeing
chitosan
silk fabric
carminic acid
acid pigment
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Application number
CN201610443376.9A
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Chinese (zh)
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CN105970679B (en
Inventor
白刚
刘艳春
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University of Shaoxing
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University of Shaoxing
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Priority to CN201610443376.9A priority Critical patent/CN105970679B/en
Publication of CN105970679A publication Critical patent/CN105970679A/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48—Derivatives of carbohydrates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Coloring (AREA)

Abstract

The invention discloses a silk fabric dyeing method. The method is characterized in that silk fabric is subjected to pad dyeing with carminic acid pigment; chitosan is added to carminic acid pigment padding liquor, so that viscosity of the padding liquor is increased; dye particles are adsorbed by polar groups in chitosan macromolecules and through intermolecular force, therefore, migration of the dye particles is difficult, and the dye adsorption amount is increased; meanwhile, by means of good affinity of chitosan to the silk, mordanting and color-deepening effects are realized, and deep dyeing performance and color fastness of dyeing are improved. The silk fabric dyeing method adopting the pad dyeing with the carminic acid pigment meets the environmental requirement and has higher color yield rate.

Description

A kind of colouring method of silk fabric
Technical field:
The present invention relates to the colouring method of a kind of silk fabric, specifically refer to that one utilizes carminic acid pigment to silkworm silk The method that fabric carries out dyeing.
Background technology:
Carminic acid pigment is a kind of Anthraquinones natural pigment, and its outward appearance is red-brown powder, stable in physicochemical property, with environment The compatibility is good, biodegradable, and raw material is renewable, has vast potential for future development.
At present, the domestic and international research about natural dye dying is concentrated mainly on fabric exhaust process aspect.For natural Dyestuff dye-uptake is low, the problem of color fastness difference, and main employing metal salt mordant improves tinctorial yield and color fastness.But, dip method Production efficiency is low, and metal salt mordant also has certain pollution to environment, has run counter to the original intention of natural dye ecological, environmental protective.
Carminic acid pigment is little to the affinity of fiber, and tinctorial yield is low, dyefastness is poor, causes it to process at fabrics printing and dyeing In application be restricted.Need in a hurry at present to develop and a kind of improve carminic acid pigment dyeing deep-cutting gorge and the side of color fastness Method.
Summary of the invention:
The technical problem to be solved is to provide one to utilize carminic acid pigment that silk fabric is carried out pad dyeing The method of dyeing, the method can be effectively improved dyeing deep-cutting gorge and color fastness.
The technical scheme that the present invention takes is as follows:
A kind of colouring method of silk fabric, it is characterised in that: use carminic acid pigment that silk fabric is carried out pad dyeing dye Color, adds chitosan in carminic acid pigment padding liquid.
Use following preferably scheme, it is possible to obtain preferably dye-uptake and dyefastness:
Described chitosan dosage is preferably 10-30g/L, and chitosan is preferably the chitosan of deacetylation 80-90%.
Further, the colouring method of described a kind of silk fabric, it is characterised in that comprise the following steps:
(1) configuration carminic acid pigment padding liquid: carminic acid pigment 10-40g/L, chitosan 10-30g/L, adds water to pad Liquid total amount；
(2) using above-mentioned padding liquid that silk fabric carries out pad dyeing dyeing, pad dyeing dyeing is: use two leachings two to roll, Pad temperature 50-80 DEG C, pick-up 60-80% preliminary drying, temperature 70-80 DEG C, time 5-10min decatize, temperature 80- 100 DEG C, time 10-25min soaps to wash and dries.
Further, the colouring method of described a kind of silk fabric, it is characterised in that comprise the following steps:
(1) configuration carminic acid pigment padding liquid: carminic acid pigment 10-40g/L, chitosan 20g/L, adds water to padding liquid total Amount；
(2) using above-mentioned padding liquid that silk fabric carries out pad dyeing dyeing, pad dyeing dyeing is: two leachings two are rolled, and pad Temperature 70 C, pick-up 65% preliminary drying, temperature 80 DEG C, time 8min decatize, temperature 100 DEG C, time 20min Washing of soaping is dried.
The operation principle of the present invention and having the beneficial effect that:
(1) present invention adds chitosan in carminic acid pigment padding liquid, mainly has two effects: on the one hand chitosan exists Pad dyeing dyeing can be played the effect of migration inhibitor, make the viscosity of dye liquor increase, and by the polarity in chitosan macromole Group and molecular separating force carry out absorbing dye granule, make fine particle loosely be gathered into bulky grain, stick to chitosan macromole On, make dye granule be difficult to migration, and improve dye adsorption amount, increase uniform dyeing property and deep-cutting gorge；On the other hand chitosan The effect of mordant can be played in carminic acid pigment dyeing, improve tinctorial yield and color fastness.Chitosan be a kind of poly-sun from Subtype compound, has hydrophilic amino and hydroxyl, more than silkworm silk isoelectric point, IP (3.5-5.2), has silkworm silk the most affine Power (because silkworm silk is more than isoelectric point, IP, surface is negative charge)；Amino cation on chitosan can also be made by Electrostatic Absorption Combine with anion carminic acid pigment, thus play mordant dyeing and increase deep effect, improve dyeing deep-cutting gorge and color fastness.
(2) by control chitosan dosage, pad, the technological parameter such as preliminary drying, decatize, can be effectively improved carminic acid Colo(u)r specification and color fastness.According to experiment statistics, compared with not using chitosan dyeing, K/S value significantly increases, and dyefastness improves 1 About Ji.
(3) whole dyeing course has abandoned metal salt mordant, has the most significant in terms of dyeing quality and the feature of environmental protection Effect.
Below in conjunction with embodiment, the present invention is described in further detail:
Detailed description of the invention:
Embodiment 1: the chitosan dosage impact on pad dyeing dyeability.
The colouring method of a kind of silk fabric, uses carminic acid pigment that silk fabric is carried out pad dyeing dyeing, and step is as follows:
Step a. configures pads dye liquor: carminic acid pigment 15g/L, chitosan 10-30g/L, adds water to padding liquid total amount.
Step b. pad dyeing dyeing: (padding temperature 70 C, pick-up 65%) is rolled in two leachings two--preliminary drying (80 DEG C, 8min)--decatize (100 DEG C, 20min) washing is dried.
Use above-mentioned technique, adjust chitosan dosage, test its impact on dyeability, as shown in table 1.
The impact on dyeability of table 1, chitosan dosage.
As can be seen from Table 1: along with the increase of chitosan dosage, K/S value increases, and tinctorial yield increases, and works as chitosan dosage During for 20g/L, K/S value is maximum.Continuing to increase chitosan dosage, K/S value is declined slightly on the contrary.
Embodiment 2: the carminic acid pigment consumption impact on dyeability.
The colouring method of a kind of silk fabric, uses carminic acid pigment that silk fabric is carried out pad dyeing dyeing, and step is as follows:
Step a. configures pads dye liquor: carminic acid pigment 5-25g/L, chitosan 20g/L, adds water to padding liquid total amount.
Step b. pad dyeing dyeing: (padding temperature 70 C, pick-up 65%) is rolled in two leachings two--preliminary drying (80 DEG C, 8min)--decatize (100 DEG C, 20min) washing is dried.
Use above-mentioned technique, adjust carminic acid pigment consumption, test its impact on dyeability, as shown in table 2.
Table 2, the impact on dyeability of the carminic acid pigment consumption.
As can be seen from Table 2: along with the increase of carminic acid pigment consumption, K/S value increases, and tinctorial yield increases.
Embodiment 3: the different steam temperature impacts on dyeability.
The colouring method of a kind of silk fabric, uses carminic acid pigment that silk fabric is carried out pad dyeing dyeing, and step is as follows:
Step a. configures pads dye liquor: carminic acid pigment 15g/L, chitosan 20g/L, adds water to padding liquid total amount.
Step b. pad dyeing dyeing: (padding temperature 70 C, pick-up 65%) is rolled in two leachings two--preliminary drying (80 DEG C, 8min)--decatize (70-100 DEG C, 20min) washing is dried.
Use above-mentioned technique, adjust different steam temperature, test its impact on dyeability, as shown in table 3.
The impact on dyeability of table 3, steam temperature.
As can be seen from Table 3: K/S value raises along with the rising of steam temperature.Consider energy consumption and to fabric damage aspect, Steam temperature is 100 DEG C and is advisable.
Embodiment 4: dyefastness contrasts.
The colouring method of a kind of silk fabric, uses carminic acid pigment that silk fabric is carried out pad dyeing dyeing, and step is as follows:
Step a. configures pads dye liquor: carminic acid pigment 15g/L, chitosan 20g/L, adds water to padding liquid total amount.
Step b. pad dyeing dyeing: (padding temperature 70 C, pick-up 65%) is rolled in two leachings two--preliminary drying (80 DEG C, 8min)--decatize (100 DEG C, 20min) washing is dried.
Above-described embodiment and the dyefastness being provided without chitosan and carrying out pad dyeing stained specimens are contrasted, the results are shown in Table 4。
Table 4, soaping fastness contrast
From table 4, it can be seen that use chitosan that silk fabric is carried out pad dyeing dyeing, stained specimens soaping fastness can be carried High about 1 grade.
Analysis and summary:
1. the present invention adds chitosan in carminic acid pigment pad dyeing dye liquor, makes padding liquid viscosity increase, and improves dyestuff and inhales Attached amount, and make dye granule be difficult to migration, increase level-dyeing property and deep-cutting gorge；Chitosan is in carminic acid pigment pad dyeing is dyeed simultaneously Mordant dyeing can be played and increase deep effect, improving dyeing deep-cutting gorge and color fastness.
2. by control chitosan dosage, pad, the technological parameter such as preliminary drying, decatize, carminic acid pigment can be effectively improved The tinctorial yield of dyeing and color fastness.
The most whole dyeing course has abandoned metal salt mordant, and the heavy metal ion overcoming the dyeing of conventional metals mordant is dirty Dye problem, has the most significant effect in terms of dyeing quality and the feature of environmental protection.
4, comprehensive optimum embodiment is:
(1) pad dye liquor prescription: carminic acid pigment 10-40g/L, chitosan 20g/L, add water to padding liquid total amount.
(2) pad dyeing dyeing is: (padding temperature 70 C, pick-up 65%) is rolled in two leachings two--preliminary drying (80 DEG C, 8min)--decatize (100 DEG C, 20min)--is soaped to wash and is dried.

Claims (5)

1. the colouring method of a silk fabric, it is characterised in that: use carminic acid pigment that silk fabric is carried out pad dyeing dyeing, Chitosan is added in carminic acid pigment padding liquid.
The colouring method of a kind of silk fabric the most according to claim 1, it is characterised in that: described chitosan dosage is 10-30 g/L。
The colouring method of a kind of silk fabric the most according to claim 2, it is characterised in that: described chitosan is deacetylated The chitosan of degree 80-90%.
The colouring method of a kind of silk fabric the most according to claim 1, it is characterised in that comprise the following steps:
(1) configuration carminic acid pigment padding liquid: carminic acid pigment 10-40 g/L, chitosan 10-30 g/L, adds water to padding liquid Total amount；
(2) using above-mentioned padding liquid that silk fabric carries out pad dyeing dyeing, pad dyeing dyeing is: uses two leachings two to roll, pads Temperature 50-80 DEG C, pick-up 60-80% preliminary drying, temperature 70-80 DEG C, time 5-10min decatize, temperature 80-100 DEG C, time 10-25min soaps to wash and dries.
The colouring method of a kind of silk fabric the most according to claim 1, it is characterised in that:
(1) configuration carminic acid pigment padding liquid: carminic acid pigment 10-40 g/L, chitosan 20g/L, adds water to padding liquid total amount；
(2) using above-mentioned padding liquid that silk fabric carries out pad dyeing dyeing, pad dyeing dyeing is: two leachings two are rolled, and pad temperature 70 DEG C, pick-up 65% preliminary drying, temperature 80 DEG C, time 8min decatize, temperature 100 DEG C, time 20min soap Wash water washes drying.
CN201610443376.9A 2016-06-17 2016-06-17 A kind of colouring method of silk fabric Expired - Fee Related CN105970679B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107059288A (en) * 2017-04-26 2017-08-18 上海亿朋服饰有限公司 A kind of fabric shrinks in advance, fade washing formula and washing methods
CN108642912A (en) * 2018-03-28 2018-10-12 宜州市壮之都丝绸家纺有限公司 A kind of colouring method of silk

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101851868A (en) * 2010-03-09 2010-10-06 常州耀春格瑞纺织品有限公司 Ecological dyeing method for dyeing cotton fabric with mulberry red natural dye
CN103255645A (en) * 2013-06-04 2013-08-21 浙江纺织服装职业技术学院 Reactive dye-bath dyeing auxiliary for cashmere/viscose blended fabric and dyeing process thereof
CN103451963A (en) * 2013-08-09 2013-12-18 常州纺织服装职业技术学院 Method for dyeing cotton fabric with tea dye and finishing liquor used by method
CN104233884A (en) * 2014-09-11 2014-12-24 苏州印丝特纺织数码科技有限公司 Chitosan modified silk fabric staining method
CN104727165A (en) * 2015-04-02 2015-06-24 太仓市诚乐化纤有限公司 Process of dyeing silk fabric

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101851868A (en) * 2010-03-09 2010-10-06 常州耀春格瑞纺织品有限公司 Ecological dyeing method for dyeing cotton fabric with mulberry red natural dye
CN103255645A (en) * 2013-06-04 2013-08-21 浙江纺织服装职业技术学院 Reactive dye-bath dyeing auxiliary for cashmere/viscose blended fabric and dyeing process thereof
CN103451963A (en) * 2013-08-09 2013-12-18 常州纺织服装职业技术学院 Method for dyeing cotton fabric with tea dye and finishing liquor used by method
CN104233884A (en) * 2014-09-11 2014-12-24 苏州印丝特纺织数码科技有限公司 Chitosan modified silk fabric staining method
CN104727165A (en) * 2015-04-02 2015-06-24 太仓市诚乐化纤有限公司 Process of dyeing silk fabric

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
张艳等: "甜菜红色素对蚕丝织物染色工艺研究", 《丝绸》 *
陈莉等: "壳聚糖在艾蒿植物染料对丝织物染色中的作用", 《丝绸》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107059288A (en) * 2017-04-26 2017-08-18 上海亿朋服饰有限公司 A kind of fabric shrinks in advance, fade washing formula and washing methods
CN107059288B (en) * 2017-04-26 2019-05-10 上海亿朋服饰有限公司 A kind of fabric shrinks in advance, fade washing formula and washing methods
CN108642912A (en) * 2018-03-28 2018-10-12 宜州市壮之都丝绸家纺有限公司 A kind of colouring method of silk
CN108642912B (en) * 2018-03-28 2020-11-13 宜州市壮之都丝绸家纺有限公司 Silk dyeing method

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