CN105969273A - Environment-friendly hot-melt pressure-sensitive adhesive - Google Patents
Environment-friendly hot-melt pressure-sensitive adhesive Download PDFInfo
- Publication number
- CN105969273A CN105969273A CN201610549598.9A CN201610549598A CN105969273A CN 105969273 A CN105969273 A CN 105969273A CN 201610549598 A CN201610549598 A CN 201610549598A CN 105969273 A CN105969273 A CN 105969273A
- Authority
- CN
- China
- Prior art keywords
- sensitive adhesive
- environment
- melt pressure
- pressure sensitive
- hot melt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J157/00—Adhesives based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09J157/02—Copolymers of mineral oil hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Materials For Medical Uses (AREA)
Abstract
The invention discloses an environment-friendly hot-melt pressure-sensitive adhesive which is prepared by mixing the components such as C5 petroleum resin, a plasticizer, a styrene-butadiene-styrene block copolymer and aids. In the environment-friendly hot-melt pressure-sensitive adhesive disclosed by the invention, by adopting the safe and environment-friendly C5 petroleum resin with good performance as a tackifier and adding the plasticizer, aids and the like, the oxidation resistance and thermal stability of the pressure-sensitive adhesive are improved. The peel strength of the pressure-sensitive adhesive reaches 8.2N.cm<-1>, and the melt viscosity is 1.2Pa.S. The comprehensive performance reaches the required industry level, and the environment-friendly hot-melt pressure-sensitive adhesive can be perfectly applied to the industries of labels and hygienic products.
Description
Technical field
The present invention relates to field of fine chemical, be specifically related to a kind of environment-friendly type hot melt pressure sensitive adhesive.
Background technology
Along with modern economy develops rapidly, people improve constantly quality of life, to the demand of the articles for daily use also not
Disconnected lifting, except the theory of the requirement for properties of product, safety and environmental protection is also own through being rooted in the hearts of the people.Hot-fusible pressure-sensitive adhesive has less
Hot melt and pressure-sensitive dual property are coated with in the molten state, cool down after-applied light pressure and get final product quick-binding.Due to hot-fusible pressure-sensitive adhesive
Without organic solvent, free from environmental pollution, and be simple to manufacture, easy to use, of many uses, therefore it is the development of pressure sensitive adhesive from now on
Direction.
Summary of the invention
Present invention aim at, it is provided that a kind of environment-friendly type hot melt pressure sensitive adhesive, the technical solution adopted in the present invention is:
A kind of environment-friendly type hot melt pressure sensitive adhesive, it is characterised in that be mixed with by weight percentage by following components and form:
C5Petropols 25-50 part
Plasticizer 20-35 part
Styrene butadiene styrene block copolymer (SBS) 10-25 part
Auxiliary agent 2-10 part.
One of preferably, described plasticizer is naphthenic oil.
One of preferably, described auxiliary agent includes antioxidant and age resistor.
One of preferably, described age resistor includes N-N-dibutyl sulfuration aminobenzoic acid zinc or ethylphenyl two
Zinc thiocarbamate.
The present invention provides the benefit that relative to prior art: the environment-friendly type hot melt pressure sensitive adhesive of the present invention, selects performance excellent
Good, safety, the C of environmental protection5Petropols are as viscosifier, and add plasticizer auxiliary agent etc., improve the non-oxidizability of pressure sensitive adhesive
And heat stability.The peel strength of pressure sensitive adhesive reaches 8.2N.cm-1, melt viscosity 1.2Pa.S.Combination property reaches industry requirement water
Standard, can be applied in label and sanitary goods industry very well.
Detailed description of the invention
Below with reference to embodiment, the design of the present invention and the technique effect of generation are clearly and completely described, with
It is completely understood by the purpose of the present invention, feature and effect.Obviously, described embodiment is the part enforcement of the present invention
Example rather than all embodiment, based on embodiments of the invention, those skilled in the art is not before paying creative work
Put other embodiments obtained, belong to the scope of protection of the invention.
Embodiment 1: a kind of environment-friendly type hot melt pressure sensitive adhesive, it is characterised in that mixed system by following components by weight percentage
For forming:
C5Petropols 38 parts
Plasticizer 32 parts
Styrene butadiene styrene block copolymer (SBS) 23 parts
Auxiliary agent 7 parts.
Embodiment 2: a kind of environment-friendly type hot melt pressure sensitive adhesive, it is characterised in that be mixed with by weight percentage by following components and
Become:
C5Petropols 45 parts
Naphthenic oil 29 parts
Styrene butadiene styrene block copolymer (SBS) 18 parts
Antioxidant 5 parts
N-N-dibutyl 2 parts of aminobenzoic acid zinc of sulfuration
Zinc-ethylphenyl dithiocarbamate 1 part.
Above the better embodiment of the present invention is illustrated, but the invention is not limited to described embodiment,
Those of ordinary skill in the art also can make all equivalent modifications or replacement on the premise of spirit of the present invention, this
Modification or the replacement of a little equivalents are all contained in the application claim limited range.
Claims (4)
1. an environment-friendly type hot melt pressure sensitive adhesive, it is characterised in that be mixed with by weight percentage by following components and form:
C5Petropols 25-50 part
Plasticizer 20-35 part
Styrene butadiene styrene block copolymer (SBS) 10-25 part
Auxiliary agent 2-10 part.
Environment-friendly type hot melt pressure sensitive adhesive the most according to claim 1, it is characterised in that described plasticizer is naphthenic oil.
Environment-friendly type hot melt pressure sensitive adhesive the most according to claim 1, it is characterised in that described auxiliary agent include antioxidant and
Age resistor.
Environment-friendly type hot melt pressure sensitive adhesive the most according to claim 1, it is characterised in that described age resistor includes N-N-bis-fourth
Base sulfuration aminobenzoic acid zinc or zinc-ethylphenyl dithiocarbamate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610549598.9A CN105969273A (en) | 2016-07-13 | 2016-07-13 | Environment-friendly hot-melt pressure-sensitive adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610549598.9A CN105969273A (en) | 2016-07-13 | 2016-07-13 | Environment-friendly hot-melt pressure-sensitive adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105969273A true CN105969273A (en) | 2016-09-28 |
Family
ID=56951788
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610549598.9A Pending CN105969273A (en) | 2016-07-13 | 2016-07-13 | Environment-friendly hot-melt pressure-sensitive adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105969273A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108611034A (en) * | 2018-04-21 | 2018-10-02 | 浙江精华科技有限公司 | Environmentally protective trademark adhesive and preparation method thereof |
| CN108676529A (en) * | 2018-06-05 | 2018-10-19 | 嘉好(太仓)新材料股份有限公司 | A kind of structure elastic is multi-purpose to defend material glue and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102559112A (en) * | 2011-12-27 | 2012-07-11 | 上海康达化工新材料股份有限公司 | Thermoplastic elastomer styrene-butadiene-styrene (SBS) adhesive and preparation method thereof |
| CN102559111A (en) * | 2012-02-02 | 2012-07-11 | 大连理工大学 | Styrene-series hot-melt pressure-sensitive adhesive and preparation method |
| CN104830257A (en) * | 2015-04-16 | 2015-08-12 | 衢州市富星和宝黏胶工业有限公司 | Hot melt adhesive for production of paper diapers and preparation method thereof |
-
2016
- 2016-07-13 CN CN201610549598.9A patent/CN105969273A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102559112A (en) * | 2011-12-27 | 2012-07-11 | 上海康达化工新材料股份有限公司 | Thermoplastic elastomer styrene-butadiene-styrene (SBS) adhesive and preparation method thereof |
| CN102559111A (en) * | 2012-02-02 | 2012-07-11 | 大连理工大学 | Styrene-series hot-melt pressure-sensitive adhesive and preparation method |
| CN104830257A (en) * | 2015-04-16 | 2015-08-12 | 衢州市富星和宝黏胶工业有限公司 | Hot melt adhesive for production of paper diapers and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108611034A (en) * | 2018-04-21 | 2018-10-02 | 浙江精华科技有限公司 | Environmentally protective trademark adhesive and preparation method thereof |
| CN108676529A (en) * | 2018-06-05 | 2018-10-19 | 嘉好(太仓)新材料股份有限公司 | A kind of structure elastic is multi-purpose to defend material glue and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160928 |