CN105969272A - Hot melt adhesive composition for cold storage label and preparation method thereof - Google Patents
Hot melt adhesive composition for cold storage label and preparation method thereof Download PDFInfo
- Publication number
- CN105969272A CN105969272A CN201610613117.6A CN201610613117A CN105969272A CN 105969272 A CN105969272 A CN 105969272A CN 201610613117 A CN201610613117 A CN 201610613117A CN 105969272 A CN105969272 A CN 105969272A
- Authority
- CN
- China
- Prior art keywords
- adhesive composition
- melt adhesive
- weight
- cold preservation
- percentage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J109/00—Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09J109/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention provides a hot melt adhesive composition for a cold storage label. When the label is pasted, the unit coating amount is small, production efficiency is high, attachment performance is excellent, colloid cohesive strength is high, oil permeability resistance is excellent, and weather resistance is good. The hot melt adhesive composition is prepared from, by weight percentage, 15-25% of first thermoplastic rubber, 10-15% of second thermoplastic rubber, 15-25% of plasticizer, 20-30% of first viscosity increase resin, 20-30% of second viscosity increase resin and 1.0% of antioxygen. The invention further provides a preparation method of the hot melt adhesive composition for the cold storage label.
Description
Technical field
The present invention relates to the technical field of polyurethane hot melt, particularly to a kind of cold preservation label hot-melt adhesive composition and
Its preparation method.
Background technology
Hot-fusible pressure-sensitive adhesive (be called for short HMPSA) with thermoplastic elastomer as base material, collect PUR and pressure sensitive adhesive feature in one
Class adhesive body, solvent-free, pollution-free and easy to use.This kind of adhesive is coated in the molten state, cooling
The after-applied slight finger pressure that hardens just can quick-binding.At present, hot-fusible pressure-sensitive adhesive is widely used in automobile, hygienic article, adhesive tape, mark
The aspects such as the processing of label, health care, surface protection film, timber and shoemaking.
Cold preservation label PUR typically uses SIS rubber to decide polymers.The shortcoming using traditional SIS rubber is coating
Good label is inadequate with by the laminating base material infiltration when low temperature, thus causes bond effect to decline；Use general oil tree
The label that the shortcoming of fat is coated easily comes off when low temperature, is because the Tg (vitrification point) of the Petropols of this class
Height, causes label to come off with by laminating base material when low temperature.The most domestic usually take two kinds of methods: i.e. take during temperature height
Naphthenic oil is less, the most viscous reduction, cohesion higher formula；Take naphthenic oil more when temperature is low, the most viscous relatively big, cohesion relatively low
Formula.So being easier to occur the problems such as label comes off colding and heat succeed each other when, weatherability is not enough.
Summary of the invention
For not enough present on prior art, the invention provides a kind of cold preservation label hot-melt adhesive composition, at mark
When signing stickup, unit coating weight is few, and production efficiency is high, and coating performance is excellent, and colloid cohesive strength is big, and resistance to permeability is excellent, resistance to
Hou Xingjia, invention also provides the preparation method of a kind of cold preservation label hot-melt adhesive composition.
To achieve these goals, the present invention is to realize by the following technical solutions: a kind of cold preservation label hot melt
Glue composition, it is characterised in that: it includes following component:
First thermoplastic elastomer (polymer SIS) 15-25% (percentage by weight), the second thermoplastic elastomer (polymer
SBR): 10-15% (percentage by weight), plasticizer: 15-25% (percentage by weight), the first tackifying resin: 20-30% (weight
Percentage ratio), the second tackifying resin 20-30% (percentage by weight), antioxidant 1.0% (percentage by weight).
It is further characterized by described first thermoplastic elastomer, the second thermoplastic elastomer is styrene-butadiene-benzene
One in ethylene copolymer, styrene-ethylene-butylene-styrene copolymer, styrene-isoprene-styrene copolymer
Or it is multiple；
Described first tackifying resin is C5 Petropols, the second tackifying resin terpene phenolic resin；
Described antioxidant is antioxidant 1010 and the irgasfos 168 of equal proportion mixing；
Described cold preservation label hot-melt adhesive composition also includes heat stabilizer, described antioxidant and described heat stabilizer ratio
It is 11；
A kind of preparation method of cold preservation label hot-melt adhesive composition, step is as follows:
(1) fusing: by 15～25 parts of (weight calculating number) first thermoplastic elastomers, 15～20 parts (weight calculating number)
Second part of thermoplastic elastomer, 0.3～1 part of (weight calculating number) antioxidant and 15～25 parts of (weight calculating number) plasticizers are thrown
Entering conduction oil reactor, begin to warm up, be warming up to 140～150 DEG C, heating 30～40min is all melted to raw material；
(2) reaction: put into first, second tackifying resin 40～50 parts, confined reaction in step (1) gained mixture
Still, evacuation stirs, and keeps pressure less than-0.09Mpa, and mixing speed is 60～100r/min, mixing time be 40～
50min, until the tackifying resin fusing put into and mixture mix homogeneously, extracts out without obvious bubble in mixture, stops heating,
Put vacuum；
(3) discharging packaging: by the double-level-metal net filtration discharging of step (2) gained mixture, and use high temperature resistant silicone oil
Release paper packed products, packs after cooling, obtains hot-melt adhesive composition.
Described double-level-metal net is 120-180 mesh.
In the above-mentioned component of the present invention, it includes following component: the first thermoplastic elastomer (polymer SIS) 15-25% is (heavy
Amount percentage ratio), the second thermoplastic elastomer (polymer SBR): 10-15% (percentage by weight), plasticizer: 15-25% (weight hundred
Proportion by subtraction), tackifying resin: 20-30% (percentage by weight), tackifying resin 20-30% (percentage by weight), antioxidant 1.0% (weight
Amount percentage ratio) so that unit coating weight is few, and production efficiency is high, and coating performance is excellent, and colloid cohesive strength is big, and resistance to permeability is excellent
Different, weatherability is good.
Detailed description of the invention
A kind of cold preservation label hot-melt adhesive composition, it is characterised in that: it includes following component:
First thermoplastic elastomer (polymer SIS) 15-25% (percentage by weight), the second thermoplastic elastomer (polymer
SBR): 10-15% (percentage by weight), plasticizer: 15-25% (percentage by weight), tackifying resin: 20-30% (weight percent
Than), tackifying resin 20-30% (percentage by weight), antioxidant 1.0% (percentage by weight).
First thermoplastic elastomer, the second thermoplastic elastomer are styrene-butadiene-styrene, styrene-second
One or more in alkene-butylene-styrene copolymers, styrene-isoprene-styrene copolymer.
Tackifying resin is C5 Petropols and/or terpene phenolic resin, for improving PUR adhesion strength when high temperature, improves
The adhesive wettability to base material, adds terpene phenolic resin and can improve the adhesive adhesion strength when low temperature, for reducing
Colloid viscosity, increases wettability, improves elasticity and the pliability of PUR, adds naphthenic oil.Antioxidant is equal proportion mixing
Antioxidant 1010 and irgasfos 168.
For reduce produce, the aging tendency of product during coating and follow-up use, use compound antioxidant and thermally-stabilised
Agent.Body series is through experimental verification, and when compound antioxidant is 11, ageing resistance and weatherability are optimal.
In following embodiment: tackifying resin KF-146 can be reached by Guangdong Ke Mao, and tackifying resin TP-2040 can be by Ya Lisang
That is buied, and thermoplastic elastomer S-1205 can be buied by Spain's Dai Nasuo synthetic rubber, and thermoplastic elastomer 1250 can be gathered by Shandong
Sage buys, and antioxidant 1010 and 168 can be buied by BASF, and naphthenic oil KN4010 can be buied by Kelamayi.
Embodiment 1
Preparation method is as follows:
(1) fusing: main polymer SIS, SBR, antioxidant and naphthenic oil are put into conduction oil reactor, begins to warm up,
Material temperature controls at 140～150 DEG C, heats 35 minutes, until rubber fusing；
(2) reaction: put into tackifying resin, closed reactor, evacuation stirs, and pressure ＜-0.09Mpa, after 50 minutes, stirs
Mixing speed is 60r/min, confirms that the tackifying resin put into melts and stirs, and material is extracted out without obvious bubble, and heating is closed；
(3) discharging is packed: by the 150 mesh double-level-metal net filtration dischargings of step (2) gained mixture, and use high temperature resistant
Silicon oil release paper packed products, packs after cooling, obtains product cold preservation label hot-melt adhesive composition.
The glue of the present embodiment, the most composed of the following components:
Embodiment 2
Preparation method is as follows:
(1) fusing: main polymer SIS, SBR, antioxidant and naphthenic oil are put into conduction oil reactor, begins to warm up,
Material temperature controls at 140～150 DEG C, heats 35 minutes, until rubber fusing；
(2) reaction: put into tackifying resin, closed reactor, evacuation stirs, and pressure ＜-0.09Mpa, after 50 minutes, stirs
Mixing speed is 60r/min, confirms that the tackifying resin put into melts and stirs, and material is extracted out without obvious bubble, and heating is closed；
(3) discharging is packed: by the 150 mesh double-level-metal net filtration dischargings of step (2) gained mixture, and use high temperature resistant
Silicon oil release paper packed products, packs after cooling, obtains product cold preservation label hot-melt adhesive composition.
The glue of the present embodiment, the most composed of the following components:
Embodiment 3
Preparation method is as follows:
(1) fusing: main polymer SIS, SBR, antioxidant and naphthenic oil are put into conduction oil reactor, begins to warm up,
Material temperature controls at 140～150 DEG C, heats 35 minutes, until rubber fusing；
(2) reaction: put into tackifying resin, closed reactor, evacuation stirs, and pressure ＜-0.09Mpa, after 50 minutes, stirs
Mixing speed is 60r/min, confirms that the tackifying resin put into melts and stirs, and material is extracted out without obvious bubble, and heating is closed；
(3) discharging is packed: by the 150 mesh double-level-metal net filtration dischargings of step (2) gained mixture, and use high temperature resistant
Silicon oil release paper packed products, packs after cooling, obtains product cold preservation label hot-melt adhesive composition.
The glue of the present embodiment, the most composed of the following components:
Embodiment 4
Preparation method is as follows:
(1) fusing: main polymer SIS, SBR, antioxidant and naphthenic oil are put into conduction oil reactor, begins to warm up,
Material temperature controls at 140～150 DEG C, heats 35 minutes, until rubber fusing；
(2) reaction: put into tackifying resin, closed reactor, evacuation stirs, and pressure ＜-0.09Mpa, after 50 minutes, stirs
Mixing speed is 60r/min, confirms that the tackifying resin put into melts and stirs, and material is extracted out without obvious bubble, and heating is closed；
(3) discharging is packed: by the 150 mesh double-level-metal net filtration dischargings of step (2) gained mixture, and use high temperature resistant
Silicon oil release paper packed products, packs after cooling, obtains product cold preservation label hot-melt adhesive composition.
The glue of the present embodiment, the most composed of the following components:
Embodiment 5
Preparation method is as follows:
(1) fusing: main polymer SIS, SBR, antioxidant and naphthenic oil are put into conduction oil reactor, begins to warm up,
Material temperature controls at 140～150 DEG C, heats 35 minutes, until rubber fusing；
(2) reaction: put into tackifying resin, closed reactor, evacuation stirs, and pressure ＜-0.09Mpa, after 50 minutes, stirs
Mixing speed is 60r/min, confirms that the tackifying resin put into melts and stirs, and material is extracted out without obvious bubble, and heating is closed；
(3) discharging is packed: by the 150 mesh double-level-metal net filtration dischargings of step (2) gained mixture, and use high temperature resistant
Silicon oil release paper packed products, packs after cooling, obtains product cold preservation label hot-melt adhesive composition.
The glue of the present embodiment, the most composed of the following components:
Cold preservation label hot-melt adhesive composition Performance comparision prepared by table 1 embodiment 1-5
Above test condition brief description:
1. 180 DEG C of peel strength assay methods press GB/T 2792-1998 mensuration.
Adhesive (spread: 20g/m will be evenly coated with2) PET film (10.0cm × 2.5cm) be affixed on test board, use
The pressing roller that manually turns of 2kg weight rolls three times back and forth, is sandwiched on device by adhesive tape after placing 30min, carries out pulling force and peels off test,
Becoming 180 ° to strip down from test plate surface thin film, test speed is 300mm/min, reading record, parallel testing four times,
Calculate meansigma methods.
2. at the beginning of rolling ball method, viscous assay method presses GB/4852-84 mensuration.
Adhesive (spread: 20g/m will be evenly coated with2) PET film (10.0cm × 2.5cm) be positioned on hang plate,
One steel ball is rolled across the adhesive tape adhesiveness face lain on hang plate.The maximum steel that the adhesive faces of length can be clung according to the rules
Ball size.
3. lower temperature resistance assay method presses GB 11793.3-1989 mensuration
Adhesive (spread: 20g/m will be evenly coated with2) PET film (10.0cm × 2.5cm) be positioned over-30 DEG C low
Temperature test box took out after 24 hours, rolled over whether it ruptures.
Claims (7)
1. a cold preservation label hot-melt adhesive composition, it is characterised in that: it includes following component:
First thermoplastic elastomer 15-25%(percentage by weight), the second thermoplastic elastomer: 10-15%(percentage by weight), plasticising
Agent: 15-25%(percentage by weight), the first tackifying resin: 20-30%(percentage by weight), the second tackifying resin 20-30%(weight
Percentage ratio), antioxidant 1.0%(percentage by weight).
A kind of cold preservation label hot-melt adhesive composition the most according to claim 1, it is characterised in that: it is characterized in that: institute
State the first thermoplastic elastomer, the second thermoplastic elastomer is styrene-butadiene-styrene, styrene-ethylene-butadiene-
One or more in styrol copolymer, styrene-isoprene-styrene copolymer.
A kind of cold preservation label hot-melt adhesive composition the most according to claim 1, it is characterised in that: described first thickening tree
Fat is C5 Petropols, and described second tackifying resin is terpene phenolic resin.
A kind of cold preservation label hot-melt adhesive composition the most according to claim 1, it is characterised in that: described antioxidant is
The antioxidant 1010 of ratio mixing and irgasfos 168.
A kind of cold preservation label hot-melt adhesive composition the most according to claim 1, it is characterised in that: described cold preservation label is used
Hot-melt adhesive composition also includes heat stabilizer, and described antioxidant and described heat stabilizer ratio are 11.
6. the preparation method of a cold preservation label hot-melt adhesive composition, it is characterised in that: it comprises the steps:
(1) fusing: by 15 ~ 25 parts of (weight calculating number) main polymer SIS, 15 ~ 20 parts of (weight calculating number) SBR, 0.3
~ 1 part of (weight calculating number) antioxidant and 15 ~ 25(weight calculate number) part naphthenic oil input conduction oil reactor, start to add
Heat, is warming up to 140 ~ 150 DEG C, and heating 30 ~ 40min all melts to raw material；
(2) reaction: putting into tackifying resin 40 ~ 50 parts, closed reactor in step (1) gained mixture, evacuation stirs, and protects
Holding pressure and be less than-0.09Mpa, mixing speed is 60 ~ 100r/min, and mixing time is 40 ~ 50min, until the thickening tree put into
Fat fusing and mixture mix homogeneously, extract out without obvious bubble in mixture, stops heating, puts vacuum；
(3) discharging packaging: by the double-level-metal net filtration discharging of step (2) gained mixture, and use high temperature resistant silicone oil release
Paper wrapper finished product, packs after cooling, obtains hot-melt adhesive composition.
The preparation method of a kind of cold preservation label hot-melt adhesive composition the most according to claim 6, it is characterised in that: described
Double-level-metal net is 120-180 mesh.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610613117.6A CN105969272A (en) | 2016-07-29 | 2016-07-29 | Hot melt adhesive composition for cold storage label and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610613117.6A CN105969272A (en) | 2016-07-29 | 2016-07-29 | Hot melt adhesive composition for cold storage label and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105969272A true CN105969272A (en) | 2016-09-28 |
Family
ID=56951255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610613117.6A Pending CN105969272A (en) | 2016-07-29 | 2016-07-29 | Hot melt adhesive composition for cold storage label and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105969272A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107722890A (en) * | 2017-11-29 | 2018-02-23 | 毕同召 | Nigh velocity bedy PUR and preparation method thereof |
| CN109679545A (en) * | 2018-12-24 | 2019-04-26 | 嘉兴正野新材料有限公司 | A kind of bottle sticker adhesive sticker and preparation method thereof |
| CN110938398A (en) * | 2019-11-20 | 2020-03-31 | 广州市豪特粘接材料有限公司 | Label adhesive and preparation method thereof |
| CN111205795A (en) * | 2020-03-03 | 2020-05-29 | 广东荣嘉新材料科技有限公司 | Environment-friendly hot melt adhesive for magic buckle compounding and preparation method thereof |
| CN112694857A (en) * | 2020-12-24 | 2021-04-23 | 松川工业材料(无锡)有限公司 | Modified polymerized terpene resin and preparation method thereof |
| CN113355037A (en) * | 2021-06-30 | 2021-09-07 | 佛山南宝高盛高新材料有限公司 | High-wet-strength hot melt adhesive for glass containers and preparation method thereof |
| CN114381226A (en) * | 2021-12-28 | 2022-04-22 | 佛山南宝高盛高新材料有限公司 | Hot melt adhesive for decoration and pasting and preparation method thereof |
| TWI775847B (en) * | 2017-05-08 | 2022-09-01 | 美商艾維利 丹尼森公司 | High performance reactive pressure sensitive adhesive composition, and method for making the same and uses thereof |
| CN115141580A (en) * | 2021-08-10 | 2022-10-04 | 西诺瑞特新材料(上海)有限公司 | Hot melt adhesive composition and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103045139A (en) * | 2013-01-21 | 2013-04-17 | 无锡市万力粘合材料有限公司 | Hot melt adhesive composition for back voucher of express mail service and method for preparing same |
-
2016
- 2016-07-29 CN CN201610613117.6A patent/CN105969272A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103045139A (en) * | 2013-01-21 | 2013-04-17 | 无锡市万力粘合材料有限公司 | Hot melt adhesive composition for back voucher of express mail service and method for preparing same |
Non-Patent Citations (1)
| Title |
|---|
| 李子东 等: "《胶黏剂助剂》", 30 June 2009, 化学工业出版社 * |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI775847B (en) * | 2017-05-08 | 2022-09-01 | 美商艾維利 丹尼森公司 | High performance reactive pressure sensitive adhesive composition, and method for making the same and uses thereof |
| CN107722890A (en) * | 2017-11-29 | 2018-02-23 | 毕同召 | Nigh velocity bedy PUR and preparation method thereof |
| CN107722890B (en) * | 2017-11-29 | 2019-09-06 | 新乡市华洋粘合剂有限公司 | Nigh velocity bedy hot melt adhesive and preparation method thereof |
| CN109679545A (en) * | 2018-12-24 | 2019-04-26 | 嘉兴正野新材料有限公司 | A kind of bottle sticker adhesive sticker and preparation method thereof |
| CN110938398A (en) * | 2019-11-20 | 2020-03-31 | 广州市豪特粘接材料有限公司 | Label adhesive and preparation method thereof |
| CN110938398B (en) * | 2019-11-20 | 2021-09-10 | 广州市豪特高新材料有限公司 | Label adhesive and preparation method thereof |
| CN111205795A (en) * | 2020-03-03 | 2020-05-29 | 广东荣嘉新材料科技有限公司 | Environment-friendly hot melt adhesive for magic buckle compounding and preparation method thereof |
| CN112694857A (en) * | 2020-12-24 | 2021-04-23 | 松川工业材料(无锡)有限公司 | Modified polymerized terpene resin and preparation method thereof |
| CN113355037A (en) * | 2021-06-30 | 2021-09-07 | 佛山南宝高盛高新材料有限公司 | High-wet-strength hot melt adhesive for glass containers and preparation method thereof |
| CN115141580A (en) * | 2021-08-10 | 2022-10-04 | 西诺瑞特新材料(上海)有限公司 | Hot melt adhesive composition and preparation method thereof |
| CN114381226A (en) * | 2021-12-28 | 2022-04-22 | 佛山南宝高盛高新材料有限公司 | Hot melt adhesive for decoration and pasting and preparation method thereof |
| CN114381226B (en) * | 2021-12-28 | 2023-11-03 | 佛山南宝高盛高新材料有限公司 | Hot melt adhesive for decoration adhesion and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105969272A (en) | Hot melt adhesive composition for cold storage label and preparation method thereof | |
| TWI781102B (en) | Back Grinding Belt | |
| JP6022884B2 (en) | Double-sided adhesive tape | |
| EP3402854B1 (en) | Pressure-sensitive adhesive composition and article thereof | |
| CN106880623A (en) | One kind carries the special hot-fusible pressure-sensitive adhesive of medicine | |
| JP2013540181A5 (en) | ||
| CN110003802A (en) | Bonding sheet | |
| JP4786189B2 (en) | Adhesive composition for skin application and adhesive sheet for skin application | |
| CN111690353A (en) | Low-temperature hot-melt pressure-sensitive adhesive and preparation method thereof | |
| CN108795340B (en) | Solvent type acrylate pressure-sensitive adhesive with high molecular weight and high conversion rate, and preparation method and application thereof | |
| CN105505268B (en) | Tire label adhesive and preparation method thereof | |
| CN105086893B (en) | Medical hot melt adhesive and preparation method thereof | |
| CN108276940A (en) | Hot-melt Pressure-sensitive Adhesive for Sanitary Napkins and its production method | |
| JP2008222814A (en) | Self-adhesion adhesive and self-adhesion adhesive tape using it | |
| CN111876102A (en) | Medical pressure-sensitive adhesive composition, preparation method thereof and adhesive material | |
| CN109852303B (en) | High-temperature-resistant double-sided adhesive tape and preparation method thereof | |
| CN116421770A (en) | Medical adhesive composition and medical adhesive tape | |
| CN103045139A (en) | Hot melt adhesive composition for back voucher of express mail service and method for preparing same | |
| CN114350279B (en) | Three-component composite pressure-sensitive adhesive, preparation method and adhesive tape | |
| WO2020065501A1 (en) | Pressure-sensitive adhesive and pressure-sensitive adhesive tape | |
| TWI731460B (en) | Thermosetting film | |
| JP2000313862A (en) | Adhesive composition and adhesive sheet | |
| CN103254801A (en) | Hot-melt pressure-sensitive adhesive with high durability and preparation method thereof | |
| TWI698334B (en) | Thermosetting film | |
| JP3994510B2 (en) | Adhesive composition for adhesive bonding of rubber and thermoplastic elastomer and adhesive sheet |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160928 |