CN105969241A - Composite high-temperature-resistant PET Meguiar's paper adhesive tape - Google Patents
Composite high-temperature-resistant PET Meguiar's paper adhesive tape Download PDFInfo
- Publication number
- CN105969241A CN105969241A CN201610366624.4A CN201610366624A CN105969241A CN 105969241 A CN105969241 A CN 105969241A CN 201610366624 A CN201610366624 A CN 201610366624A CN 105969241 A CN105969241 A CN 105969241A
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- parts
- adhesive
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- paper
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
- C09J183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/21—Paper; Textile fabrics
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/20—Presence of organic materials
- C09J2400/28—Presence of paper
- C09J2400/283—Presence of paper in the substrate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2483/00—Presence of polysiloxane
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
Abstract
The invention discloses composite high-temperature-resistant PET Meguiar's paper adhesive tape and mainly solves the problem that compared with general adhesive tape, paper self-adhesive tape is poor in adhesion and poor in high-temperature resistance. The composite high-temperature-resistant PET Meguiar's paper adhesive tape comprises a release agent layer, a paper base material layer, an adhesive layer, a plastic layer and an adhesion layer which are arranged in sequence from top to bottom; the paper base material layer is composed of Meguiar's paper, and the adhesion layer is composed of silicone adhesive; the adhesive layer is composed of, by weight, 1-3 parts of dibenzoyl peroxide, 90-100 parts of organic silicon pressure sensitive glue, 1-4 parts of diisocyanate, 200-210 parts of acrylate pressure-sensitive glue, 50-60 parts of silicone adhesive and 1-3 parts of polymethyl triethoxy silane; the plastic layer is composed of, by weight, 60-70 parts of polyethylene terephthalate, 3-5 parts of silicone and 1-2 parts of di-tert-butyl peroxide. The composite high-temperature-resistant PET Meguiar's paper adhesive tape has the advantages of being high in tension resistance, adhesive force and heat resistance and the like.
Description
Technical field
The present invention relates to a kind of adhesive tape, particularly relate to PET Micron Technology paper complex fire resistant adhesive tape.
Background technology
Adhesive tape is one of instrument fixed and cover conventional in daily life and work, can be divided into high-temp glue by effect
Band, middle temperature adhesive tape, room temperature adhesive tape, two-sided tape, insulating tape, specialty tape, pressure sensitive adhesive tape, cross cutting adhesive tape etc., according to not
Same effect is applicable to different places and field, and wherein high temperature gummed tape is again one of conventional adhesive tape.
Paper self-adhesive tape is mainly used in spraying aspect, in order to protect other surfaces not polluted by coating, needs first to use before construction
Adhesive tape covers the edge of spraying position so that coating will not pollute other surfaces.Surface temperature due to object of constructing
May be higher, and heat up when outdoors sunlight is exposed to the sun and the most easily make U.S. stricture of vagina paper self-adhesive tape lose intrinsic viscosity, affect spraying and execute
The effect of work.
Existing paper self-adhesive tape is compared to general adhesive tape, and surface changes paper into, and usual stickiness is not strong, stretching resistance is the highest, resistant to elevated temperatures
Performance is the best, and the situation also occurring frequently in degumming under hot conditions occurs.
Summary of the invention
It is an object of the invention to solve paper self-adhesive tape not strong compared to general adhesive tape stickiness, resistant to elevated temperatures performance is the best
Problem, it is provided that a kind of PET Micron Technology paper complex fire resistant adhesive tape solving the problems referred to above.
For solving disadvantages mentioned above, technical scheme is as follows:
PET Micron Technology paper complex fire resistant adhesive tape, including the parting agent layer being from top to bottom sequentially arranged, paper substrate sheet material layers, adhesive layer,
Plastic layer and adhesion coating, described paper substrate sheet material layers is made up of Micron Technology's paper, and described adhesion coating is made up of silicone adhesive,
Described adhesive layer is made up of the component of following weight portion:
Dibenzoyl peroxide 1～3 parts, silicone pressure sensitive glue 90～100 parts, diisocyanate 1～4 parts, acrylate pressure
Quick glue 200～210 parts, silicone adhesive 50～60 parts, poly-MTES 1～3 parts；
Described plastic layer is made up of the component of following weight portion:
Polyethylene terephthalate 60～70 parts, silicone 3～5 parts, di-t-butyl peroxide 1～2 parts.
Further, described adhesive layer is made up of the component of following weight portion:
Dibenzoyl peroxide 1～2 parts, silicone pressure sensitive glue 95～100 parts, diisocyanate 2～4 parts, acrylate pressure
Quick glue 200～205 parts, silicone adhesive 55～60 parts, poly-MTES 2～3 parts；
Described plastic layer is made up of the component of following weight portion:
Polyethylene terephthalate 65～70 parts, silicone 3～5 parts, di-t-butyl peroxide 1～2 parts.
Further, described adhesive layer is made up of the component of following weight portion:
Dibenzoyl peroxide 2 parts, 95 parts of silicone pressure sensitive glue, diisocyanate 3 parts, 205 parts of acrylate pressure-sensitive adhesive water,
Silicone adhesive 60 parts, poly-MTES 2 parts；
Described plastic layer is made up of the component of following weight portion:
Polyethylene terephthalate 70 parts, silicone 4 parts, di-t-butyl peroxide 2 parts.
The present invention compared with prior art, has the following advantages and beneficial effect:
Stretching resistance that the present invention prepares, adhesion strength, thermostability are the highest, and under this proportioning, the present invention for a long time
Under hot conditions, adhesion strength is the most splendid, does not haves the situation of degumming, after long-time adhesion the most under the high temperature conditions the most not
There will be the situation of cull, effect is the most notable.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited to this.
Embodiment 1
PET Micron Technology paper complex fire resistant adhesive tape, including the parting agent layer being from top to bottom sequentially arranged, paper substrate sheet material layers, adhesive layer,
Plastic layer and adhesion coating, described paper substrate sheet material layers is made up of Micron Technology's paper, and described adhesion coating is made up of silicone adhesive,
Adhesive layer described in the present embodiment is preferably made up of the component of following weight portion:
Dibenzoyl peroxide 2 parts, 95 parts of silicone pressure sensitive glue, diisocyanate 3 parts, 205 parts of acrylate pressure-sensitive adhesive water,
Silicone adhesive 60 parts, poly-MTES 2 parts；
Described plastic layer is preferably made up of the component of following weight portion:
Polyethylene terephthalate 70 parts, silicone 4 parts, di-t-butyl peroxide 2 parts.
The preparation method of above-mentioned PET Micron Technology paper complex fire resistant adhesive tape, comprises the steps of:
(1) parting agent layer is compound in paper substrate sheet material layers；
(2) plastic layer is prepared: by polyethylene terephthalate and silicone mix homogeneously post-heating to molten condition, then molten
Melt and make plastic layer after adding di-t-butyl peroxide mix homogeneously under state；
(3) prepare adhesive layer: be dissolved in solvent by dibenzoyl peroxide, then it is mixed all with silicone pressure sensitive glue
Even make epoxy glue one；It is dissolved into crossing diisocyanate in solvent, then it is mixed homogeneously with acrylate pressure-sensitive adhesive water system
Become epoxy glue two；Poly-MTES is dissolved in solvent, then it is mixed homogeneously with silicone adhesive makes epoxy glue
Three；Sequentially epoxy glue two and epoxy glue one are added in epoxy glue three, after mix homogeneously, make adhesive layer；
(4) adhesive layer is utilized to be sticked in paper substrate sheet material layers by plastic layer；
(5) finally it is attached to adhesion coating on plastic layer i.e. make finished product.
Embodiment 2
The present embodiment is in plastic layer and adhesive layer that from the difference of embodiment 1 content of each component is different.
Described adhesive layer is made up of the component of following weight portion:
Dibenzoyl peroxide 1 part, 95 parts of silicone pressure sensitive glue, diisocyanate 4 parts, 200 parts of acrylate pressure-sensitive adhesive water,
Silicone adhesive 60 parts, poly-MTES 2 parts.
Described plastic layer is made up of the component of following weight portion:
Polyethylene terephthalate 65 parts, silicone 3 parts, di-t-butyl peroxide 2 parts.
Embodiment 3
The present embodiment is in plastic layer and adhesive layer that from the difference of embodiment 1 content of each component is different.
Described adhesive layer is made up of the component of following weight portion:
Dibenzoyl peroxide 2 parts, 98 parts of silicone pressure sensitive glue, diisocyanate 3 parts, 205 parts of acrylate pressure-sensitive adhesive water,
Silicone adhesive 55 parts, poly-MTES 2 parts.
Described plastic layer is made up of the component of following weight portion:
Polyethylene terephthalate 70 parts, silicone 3 parts, di-t-butyl peroxide 1 part.
Embodiment 4
The present embodiment is the comparative example of embodiment 1-3, and the present embodiment is plastic layer and adhesive with the difference of embodiment 1
In Ceng, the content of each component is different.
Described adhesive layer is made up of the component of following weight portion:
Dibenzoyl peroxide 3 parts, 90 parts of silicone pressure sensitive glue, diisocyanate 3 parts, 210 parts of acrylate pressure-sensitive adhesive water；
Described plastic layer is made up of the component of following weight portion:
Polyethylene terephthalate 80 parts, silicone 1 part, di-t-butyl peroxide 2 parts.
Embodiment 5
The present embodiment is the comparative example of embodiment 1-3, and the present embodiment is plastic layer and adhesive with the difference of embodiment 1
In Ceng, the content of each component is different.
Described adhesive layer is made up of the component of following weight portion:
Dibenzoyl peroxide 2 parts, 90 parts of silicone pressure sensitive glue, diisocyanate 4 parts, 210 parts of acrylate pressure-sensitive adhesive water,
Silicone adhesive 50 parts, poly-MTES 3 parts；
Described plastic layer is made up of polyethylene terephthalate.
The adhesive tape making above-described embodiment detects, and testing result is as shown in table 1.
Table 1
Above-mentioned thermostability refers to that this adhesive tape sticks on steel plate, it is possible to do not remain the temperature of colloid on steel plate when 1h detects, logical
Crossing above-mentioned data to understand, the substrate layer of the present invention has higher stretching resistance, and the adhesion strength persistent period is longer, the present embodiment
In adhesive tape more than 200 DEG C at a temperature of continue after 1h still can not cull, adhesiving effect is the most notable.
Above-described embodiment is only the preferred embodiments of the present invention, not limiting the scope of the invention, as long as using
The design principle of the present invention, and carry out non-creativeness work on this basis and the change made, all should belong to the present invention's
Within protection domain.
Claims (3)
1. PET Micron Technology paper complex fire resistant adhesive tape, including the parting agent layer being from top to bottom sequentially arranged, paper substrate sheet material layers, adhesive
Layer, plastic layer and adhesion coating, described paper substrate sheet material layers is made up of Micron Technology's paper, and described adhesion coating is made up of silicone adhesive, its feature
It is,
Described adhesive layer is made up of the component of following weight portion:
Dibenzoyl peroxide 1～3 parts, silicone pressure sensitive glue 90～100 parts, diisocyanate 1～4 parts, acrylate pressure
Quick glue 200～210 parts, silicone adhesive 50～60 parts, poly-MTES 1～3 parts；
Described plastic layer is made up of the component of following weight portion:
Polyethylene terephthalate 60～70 parts, silicone 3～5 parts, di-t-butyl peroxide 1～2 parts.
PET Micron Technology the most according to claim 1 paper complex fire resistant adhesive tape, it is characterised in that
Described adhesive layer is made up of the component of following weight portion:
Dibenzoyl peroxide 1～2 parts, silicone pressure sensitive glue 95～100 parts, diisocyanate 2～4 parts, acrylate pressure
Quick glue 200～205 parts, silicone adhesive 55～60 parts, poly-MTES 2～3 parts；
Described plastic layer is made up of the component of following weight portion:
Polyethylene terephthalate 65～70 parts, silicone 3～5 parts, di-t-butyl peroxide 1～2 parts.
PET Micron Technology the most according to claim 1 paper complex fire resistant adhesive tape, it is characterised in that
Described adhesive layer is made up of the component of following weight portion:
Dibenzoyl peroxide 2 parts, 95 parts of silicone pressure sensitive glue, diisocyanate 3 parts, 205 parts of acrylate pressure-sensitive adhesive water,
Silicone adhesive 60 parts, poly-MTES 2 parts；
Described plastic layer is made up of the component of following weight portion:
Polyethylene terephthalate 70 parts, silicone 4 parts, di-t-butyl peroxide 2 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610366624.4A CN105969241A (en) | 2016-05-30 | 2016-05-30 | Composite high-temperature-resistant PET Meguiar's paper adhesive tape |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610366624.4A CN105969241A (en) | 2016-05-30 | 2016-05-30 | Composite high-temperature-resistant PET Meguiar's paper adhesive tape |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105969241A true CN105969241A (en) | 2016-09-28 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610366624.4A Pending CN105969241A (en) | 2016-05-30 | 2016-05-30 | Composite high-temperature-resistant PET Meguiar's paper adhesive tape |
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| Country | Link |
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| CN (1) | CN105969241A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108753194A (en) * | 2018-07-16 | 2018-11-06 | 上海晶华胶粘新材料股份有限公司 | Impermeable paper self-adhesive tape |
| CN110003627A (en) * | 2019-04-04 | 2019-07-12 | 苏州思达奇环保新材料有限公司 | Degradable solid electrolyte membrane and preparation method thereof and the lithium battery being made from it |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101457128A (en) * | 2007-12-14 | 2009-06-17 | 3M创新有限公司 | Composite high temperature gummed tape and method for producing the same |
| CN105331301A (en) * | 2015-10-16 | 2016-02-17 | 上海晶华胶粘新材料股份有限公司 | High temperature resistant crepe paper adhesive tape used for shoes |
-
2016
- 2016-05-30 CN CN201610366624.4A patent/CN105969241A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101457128A (en) * | 2007-12-14 | 2009-06-17 | 3M创新有限公司 | Composite high temperature gummed tape and method for producing the same |
| CN105331301A (en) * | 2015-10-16 | 2016-02-17 | 上海晶华胶粘新材料股份有限公司 | High temperature resistant crepe paper adhesive tape used for shoes |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108753194A (en) * | 2018-07-16 | 2018-11-06 | 上海晶华胶粘新材料股份有限公司 | Impermeable paper self-adhesive tape |
| CN110003627A (en) * | 2019-04-04 | 2019-07-12 | 苏州思达奇环保新材料有限公司 | Degradable solid electrolyte membrane and preparation method thereof and the lithium battery being made from it |
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Application publication date: 20160928 |
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| RJ01 | Rejection of invention patent application after publication |