CN105969208A - Methoxy ethyl ester and ethoxy ethyl ester based high-elasticity sealant for storage batteries and manufacturing method of methoxy ethyl ester and ethoxy ethyl ester based high-elasticity sealant - Google Patents
Methoxy ethyl ester and ethoxy ethyl ester based high-elasticity sealant for storage batteries and manufacturing method of methoxy ethyl ester and ethoxy ethyl ester based high-elasticity sealant Download PDFInfo
- Publication number
- CN105969208A CN105969208A CN201610486496.7A CN201610486496A CN105969208A CN 105969208 A CN105969208 A CN 105969208A CN 201610486496 A CN201610486496 A CN 201610486496A CN 105969208 A CN105969208 A CN 105969208A
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- component
- ethyl ester
- ester
- parts
- antioxidant
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-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Sealing Material Composition (AREA)
Abstract
The invention discloses a methoxy ethyl ester and ethoxy ethyl ester based high-elasticity sealant for storage batteries and a manufacturing method of the methoxy ethyl ester and ethoxy ethyl ester based high-elasticity sealant. The methoxy ethyl ester and ethoxy ethyl ester based high-elasticity sealant comprises a component A and a component B; the component A comprises methoxyethyl methacrylate, a solvent, di-iso-decylphthalate, nano silicon carbide, reinforcement filler, an antioxidant and chloroprene rubber; the component B comprises ethoxyethyl methacrylate, ABS (acrylonitrile-butadiene-styrene) resin, organobentonite, triethylamine, BYK-2066N and a tackifier. By means of hermetic stirring, vacuum drying and temperature controlled mixing, the component A and the component B are made. Compared with normal adhesives, the methoxy ethyl ester and ethoxy ethyl ester based high-elasticity sealant has advantages of high elasticity, heat resistance, water resistance, heat conductivity and adhesion, freeness of pollution and the like and is capable of realizing favorable adhesion in use, excellent in sealing effect and low in air entrapment.
Description
Technical field
The present invention relates to chemical technology field, particularly to a kind of based on methoxyethyl ester and ethoxyethyl ester the high resiliency accumulator sealant that accumulator is played sealing function
And manufacture method
。
Background technology
There is easily crystallization and glue the up time time of twice (the glue viscosity at a certain temperature be increased to) short problem in the amine curing agent of existing accumulator sealant water, up time embodies the response speed of glue, determine client join glue after glue can use and the length of operating time, after firming agent is produced, crystallization within the shelf-life causes client can not use this product.To accumulator sealant, in firming agent, each raw-material ratio is improper and under the original production process of firming agent, is easy for producing the problems referred to above.
Rising year by year along with the accumulator market demand, the process of old and useless battery is increasingly come into one's own with the maintenance of accumulator, and storage battery maintenance it is crucial that i.e. to open sealing lid can not damage battery cell case, more existing fluid sealants are if adhesive strength is high, battery cell case can be damaged owing to fluid sealant is difficult to stripping when opening sealing lid, and adhesive strength height all ratios of being easily peeled off are relatively low, how and to ensure that good adhesive strength does not damage battery cell case when opening sealing lid again be an anxious to be resolved difficult problem.
Summary of the invention
It is an object of the invention to provide
A kind of have good
High resiliency
,
Thermostability
,
Resistance to water
,
Heat conductivity
,
Cementability
,
Free of contamination a kind of high resiliency accumulator sealant based on methoxyethyl ester and ethoxyethyl ester
And manufacture method
, solve the use needs of problems of accumulator sealant.
In order to achieve the above object, the present invention provides following technical scheme:
A kind of high resiliency accumulator sealant based on methoxyethyl ester and ethoxyethyl ester, it is characterised in that: include
A
Component and
B
Component；Described
A
Component is made up of methoxyethyl methacrylate, solvent, diisooctyl phthalate, nanometer silicon carbide, reinforcing filler, antioxidant, neoprene；
B
Component by methacrylic acid ethoxyethyl ester,
ABS
Resin, organobentonite, triethylamine,
BYK-066N
, viscosifier form；Wherein said
A
In component, including:
50-70
The methoxyethyl methacrylate of part,
15-35
The solvent of part,
2-15
The diisooctyl phthalate of part,
10-15
The nanometer silicon carbide of part,
5-15
The reinforcing filler of part,
5-20
The antioxidant of part,
25-35
The neoprene composition of part；Described
B
In component, including:
60-80
The methacrylic acid ethoxyethyl ester of part,
30-35
Part
ABS
Resin,
5-15
The organobentonite of part,
3-15
The triethylamine of part,
10-25
Part
BYK-066N
,
10-15
The viscosifier of part.
Described
A
In component, the mean molecule quantity of methoxyethyl methacrylate is
8000-10000
, described
B
In component, the mean molecule quantity of methacrylic acid ethoxyethyl ester is
10000-14000
。
Described
A
In component, including:
60
The methoxyethyl methacrylate of part,
25
The solvent of part,
10
The diisooctyl phthalate of part,
12
The nanometer silicon carbide of part,
10
The reinforcing filler of part,
12
The antioxidant of part,
30
The neoprene composition of part；Described
B
In component, including:
70
The methacrylic acid ethoxyethyl ester of part,
32
Part
ABS
Resin,
10
The organobentonite of part,
10
The triethylamine of part,
18
Part
BYK-066N
,
12
The viscosifier of part.
Described solvent is the mixing of one or more in acetone, chloroform, dichloroethanes, nylon acid dimethyl ester, ethyl acetate, toluene or dimethylbenzene；Reinforcing filler is the mixing of one or more that fume colloidal silica, precipitated silica and surface process in white carbon；Antioxidant is
IrgastabPUR68
, antioxidant
1010
With
Irganox5057
In the mixing of one or more；Viscosifier be isopropyl titanate, butyl titanate,
r-
Aminopropyltriethoxywerene werene
,
1
、
2-
Epoxy ethyoxyl trimethoxy silane, carbonic ester ethyl acetoacetate chelate in the mixing of one or more.
Concretely comprise the following steps:
A
Component includes step: in closed reactor, adds the methoxyethyl methacrylate of above-mentioned ratio of weight and number, solvent, diisooctyl phthalate, neoprene, and stirring heats up, and temperature controls
80
℃
~110
℃
, open vacuum pumping negative pressure, Stress control exists
-
0.1MPa
Below；Then cool to
65
℃
Hereinafter, being passed through drying nitrogen and release vacuum, add above-mentioned ratio of weight and number nanometer silicon carbide, reinforcing filler, antioxidant, temperature controls
65
~
75
℃
, mix homogeneously, to obtain final product
A
Component fluid sealant.
B
Component includes step: in closed reactor, adds the methacrylic acid ethoxyethyl ester of above-mentioned ratio of weight and number,
ABS
Resin, organobentonite, stirring heats up, and temperature controls
80
℃
~110
℃
, open vacuum pumping negative pressure, Stress control exists
-
0.1MPa
Below；Then cool to
65
℃
Hereinafter, it is passed through drying nitrogen and releases vacuum, add the triethylamine of above-mentioned ratio of weight and number,
BYK-066N
, viscosifier, temperature controls
65
~
75
DEG C,
Mix homogeneously, to obtain final product
B
Component fluid sealant.
Beneficial effects of the present invention: the present invention is compared to general
Other adhesives have good
High resiliency
,
Thermostability
,
Resistance to water
,
Heat conductivity
,
Cementability
,
Pollution-free
Etc. advantage, it is possible to the best bonding, and good sealing effect, the effects such as inner air is few
。
Detailed description of the invention
Below in conjunction with embodiment, technical scheme is clearly and completely described, it is clear that described embodiment is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, the every other embodiment that those of ordinary skill in the art are obtained under not making creative work premise, broadly fall into the scope of protection of the invention.
Embodiment
1
:
A kind of high resiliency accumulator sealant based on methoxyethyl ester and ethoxyethyl ester, it is characterised in that: include
A
Component and
B
Component；Described
A
Component is made up of methoxyethyl methacrylate, solvent, diisooctyl phthalate, nanometer silicon carbide, reinforcing filler, antioxidant, neoprene；
B
Component by methacrylic acid ethoxyethyl ester,
ABS
Resin, organobentonite, triethylamine,
BYK-066N
, viscosifier form；Wherein said
A
In component, including:
50-70
The methoxyethyl methacrylate of part,
15-35
The solvent of part,
2-15
The diisooctyl phthalate of part,
10-15
The nanometer silicon carbide of part,
5-15
The reinforcing filler of part,
5-20
The antioxidant of part,
25-35
The neoprene composition of part；Described
B
In component, including:
60-80
The methacrylic acid ethoxyethyl ester of part,
30-35
Part
ABS
Resin,
5-15
The organobentonite of part,
3-15
The triethylamine of part,
10-25
Part
BYK-066N
,
10-15
The viscosifier of part.
Described
A
In component, the mean molecule quantity of methoxyethyl methacrylate is
8000-10000
, described
B
In component, the mean molecule quantity of methacrylic acid ethoxyethyl ester is
10000-14000
。
Described
A
In component, including:
60
The methoxyethyl methacrylate of part,
25
The solvent of part,
10
The diisooctyl phthalate of part,
12
The nanometer silicon carbide of part,
10
The reinforcing filler of part,
12
The antioxidant of part,
30
The neoprene composition of part；Described
B
In component, including:
70
The methacrylic acid ethoxyethyl ester of part,
32
Part
ABS
Resin,
10
The organobentonite of part,
10
The triethylamine of part,
18
Part
BYK-066N
,
12
The viscosifier of part.
Described solvent is the mixing of one or more in acetone, chloroform, dichloroethanes, nylon acid dimethyl ester, ethyl acetate, toluene or dimethylbenzene；Reinforcing filler is the mixing of one or more that fume colloidal silica, precipitated silica and surface process in white carbon；Antioxidant is
IrgastabPUR68
, antioxidant
1010
With
Irganox5057
In the mixing of one or more；Viscosifier be isopropyl titanate, butyl titanate,
r-
Aminopropyltriethoxywerene werene
,
1
、
2-
Epoxy ethyoxyl trimethoxy silane, carbonic ester ethyl acetoacetate chelate in the mixing of one or more.
Concretely comprise the following steps:
A
Component includes step: in closed reactor, adds the methoxyethyl methacrylate of above-mentioned ratio of weight and number, solvent, diisooctyl phthalate, neoprene, and stirring heats up, and temperature controls
80
℃
~110
℃
, open vacuum pumping negative pressure, Stress control exists
-
0.1MPa
Below；Then cool to
65
℃
Hereinafter, being passed through drying nitrogen and release vacuum, add above-mentioned ratio of weight and number nanometer silicon carbide, reinforcing filler, antioxidant, temperature controls
65
~
75
℃
, mix homogeneously, to obtain final product
A
Component fluid sealant.
B
Component includes step: in closed reactor, adds the methacrylic acid ethoxyethyl ester of above-mentioned ratio of weight and number,
ABS
Resin, organobentonite, stirring heats up, and temperature controls
80
℃
~110
℃
, open vacuum pumping negative pressure, Stress control exists
-
0.1MPa
Below；Then cool to
65
℃
Hereinafter, it is passed through drying nitrogen and releases vacuum, add the triethylamine of above-mentioned ratio of weight and number,
BYK-066N
, viscosifier, temperature controls
65
~
75
DEG C,
Mix homogeneously, to obtain final product
B
Component fluid sealant.
Embodiment
2
:
A kind of high resiliency accumulator sealant based on methoxyethyl ester and ethoxyethyl ester, it is characterised in that: include
A
Component and
B
Component；Described
A
Component is made up of methoxyethyl methacrylate, solvent, diisooctyl phthalate, nanometer silicon carbide, reinforcing filler, antioxidant, neoprene；
B
Component by methacrylic acid ethoxyethyl ester,
ABS
Resin, organobentonite, triethylamine,
BYK-066N
, viscosifier form；Wherein said
A
In component, including:
50-70
The methoxyethyl methacrylate of part,
15-35
The solvent of part,
2-15
The diisooctyl phthalate of part,
10-15
The nanometer silicon carbide of part,
5-15
The reinforcing filler of part,
5-20
The antioxidant of part,
25-35
The neoprene composition of part；Described
B
In component, including:
60-80
The methacrylic acid ethoxyethyl ester of part,
30-35
Part
ABS
Resin,
5-15
The organobentonite of part,
3-15
The triethylamine of part,
10-25
Part
BYK-066N
,
10-15
The viscosifier of part.
Specifically
Production and processing
Step is:
A
Component includes step: in closed reactor, adds the methoxyethyl methacrylate of above-mentioned ratio of weight and number, solvent, diisooctyl phthalate, neoprene, and stirring heats up, and temperature controls
80
℃
~110
℃
, open vacuum pumping negative pressure, Stress control exists
-
0.1MPa
Below；Then cool to
65
℃
Hereinafter, being passed through drying nitrogen and release vacuum, add above-mentioned ratio of weight and number nanometer silicon carbide, reinforcing filler, antioxidant, temperature controls
65
~
75
℃
, mix homogeneously, to obtain final product
A
Component fluid sealant.
B
Component includes step: in closed reactor, adds the methacrylic acid ethoxyethyl ester of above-mentioned ratio of weight and number,
ABS
Resin, organobentonite, stirring heats up, and temperature controls
80
℃
~110
℃
, open vacuum pumping negative pressure, Stress control exists
-
0.1MPa
Below；Then cool to
65
℃
Hereinafter, it is passed through drying nitrogen and releases vacuum, add the triethylamine of above-mentioned ratio of weight and number,
BYK-066N
, viscosifier, temperature controls
65
~
75
DEG C,
Mix homogeneously, to obtain final product
B
Component fluid sealant.
A
Component
With
B
Component
Respectively
Stand subpackage, directly will during use
A
Component,
B
Component is according to carrying out potting operation after weight ratio mix homogeneously.
Following table is the Data Comparison of the present invention and other series products:
Upper table shows that the properties of the present invention is better than like product, can meet the process requirements that accumulator seals.
Embodiment
3
:
In the present invention, optimum ratio is:
A
In component:
60
The methoxyethyl methacrylate of part,
25
The solvent of part,
10
The diisooctyl phthalate of part,
12
The nanometer silicon carbide of part,
10
The reinforcing filler of part,
12
The antioxidant of part,
30
The neoprene composition of part；
B
In component
:
70
The methacrylic acid ethoxyethyl ester of part,
32
Part
ABS
Resin,
10
The organobentonite of part,
10
The triethylamine of part,
18
Part
BYK-066N
,
12
The viscosifier of part.
Preferably production and processing
Step is:
A
Component includes step: in closed reactor, adds the methoxyethyl methacrylate of above-mentioned ratio of weight and number, solvent, diisooctyl phthalate, neoprene, and stirring heats up, and temperature controls
90
℃
, open vacuum pumping negative pressure, Stress control exists
-
0.1MPa
Below；Then cool to
65
℃
Hereinafter, being passed through drying nitrogen and release vacuum, add above-mentioned ratio of weight and number nanometer silicon carbide, reinforcing filler, antioxidant, temperature controls
70
℃
, mix homogeneously, to obtain final product
A
Component fluid sealant.
B
Component includes step: in closed reactor, adds the methacrylic acid ethoxyethyl ester of above-mentioned ratio of weight and number,
ABS
Resin, organobentonite, stirring heats up, and temperature controls
90
℃
, open vacuum pumping negative pressure, Stress control exists
-
0.1MPa
Below；Then cool to
65
℃
Hereinafter, it is passed through drying nitrogen and releases vacuum, add the triethylamine of above-mentioned ratio of weight and number,
BYK-066N
, viscosifier, temperature controls
70
DEG C,
Mix homogeneously, to obtain final product
B
Component fluid sealant.
A
Component
With
B
Component
Respectively
Stand subpackage, directly will during use
A
Component,
B
Component is according to carrying out potting operation after weight ratio mix homogeneously.
The above; being only the detailed description of the invention of the present invention, but protection scope of the present invention is not limited thereto, any those familiar with the art is in the technical scope that the invention discloses; change can be readily occurred in or replace, all should contain within protection scope of the present invention.Therefore, protection scope of the present invention should described be as the criterion with scope of the claims.
Claims (5)
1. a high resiliency accumulator sealant based on methoxyethyl ester and ethoxyethyl ester, it is characterised in that: include component A and B component；Described component A is made up of methoxyethyl methacrylate, solvent, diisooctyl phthalate, nanometer silicon carbide, reinforcing filler, antioxidant, neoprene；B component is made up of methacrylic acid ethoxyethyl ester, ABS resin, organobentonite, triethylamine, BYK-066N, viscosifier；In wherein said component A, including: the methoxyethyl methacrylate of 50-70 part, the solvent of 15-35 part, the diisooctyl phthalate of 2-15 part, the nanometer silicon carbide of 10-15 part, the reinforcing filler of 5-15 part, the antioxidant of 5-20 part, the neoprene composition of 25-35 part；In described B component, including: the methacrylic acid ethoxyethyl ester of 60-80 part, the ABS resin of 30-35 part, the organobentonite of 5-15 part, the triethylamine of 3-15 part, the viscosifier of the BYK-066N of 10-25 part, 10-15 part.
A kind of high resiliency accumulator sealant based on methoxyethyl ester and ethoxyethyl ester the most according to claim 1, it is characterized in that: in described component A, the mean molecule quantity of methoxyethyl methacrylate is 8000-10000, in described B component, the mean molecule quantity of methacrylic acid ethoxyethyl ester is 10000-14000.
A kind of high resiliency accumulator sealant based on methoxyethyl ester and ethoxyethyl ester the most according to claim 1, it is characterized in that: in described component A, including: the methoxyethyl methacrylate of 60 parts, the solvent of 25 parts, the diisooctyl phthalate of 10 parts, the nanometer silicon carbide of 12 parts, the reinforcing filler of 10 parts, the antioxidant of 12 parts, the neoprene composition of 30 parts；In described B component, including: the methacrylic acid ethoxyethyl ester of 70 parts, the ABS resin of 32 parts, the organobentonite of 10 parts, the triethylamine of 10 parts, the BYK-066N of 18 parts, the viscosifier of 12 parts.
A kind of high resiliency accumulator sealant based on methoxyethyl ester and ethoxyethyl ester the most according to claim 1, it is characterised in that: described solvent is the mixing of one or more in acetone, chloroform, dichloroethanes, nylon acid dimethyl ester, ethyl acetate, toluene or dimethylbenzene；Reinforcing filler is the mixing of one or more that fume colloidal silica, precipitated silica and surface process in white carbon；Antioxidant is the mixing of one or more in IrgastabPUR68, antioxidant 1010 and Irganox5057；Viscosifier are isopropyl titanate, butyl titanate, r-aminopropyltriethoxywerene werene, 1,2-epoxy ethyoxyl trimethoxy silane, carbonic ester ethyl acetoacetate chelate in the mixing of one or more.
5. according to the manufacture method of a kind of based on methoxyethyl ester and ethoxyethyl ester the high resiliency accumulator sealant according to any one of claim 1-4, it is characterised in that: concretely comprise the following steps:
Component A includes step: in closed reactor, adds the methoxyethyl methacrylate of above-mentioned ratio of weight and number, solvent, diisooctyl phthalate, neoprene, stirring heats up, temperature controls at 80 DEG C ~ 110 DEG C, opens vacuum pumping negative pressure, and Stress control is at below-0.1MPa；Then cooling to less than 65 DEG C, be passed through drying nitrogen and release vacuum, add above-mentioned ratio of weight and number nanometer silicon carbide, reinforcing filler, antioxidant, temperature controls at 65～75 DEG C, and mix homogeneously obtains component A fluid sealant；
B component includes step: in closed reactor, adds the methacrylic acid ethoxyethyl ester of above-mentioned ratio of weight and number, ABS resin, organobentonite, and stirring heats up, and temperature controls at 80 DEG C ~ 110 DEG C, opens vacuum pumping negative pressure, and Stress control is at below-0.1MPa；Then cooling to less than 65 DEG C, be passed through drying nitrogen and release vacuum, add the triethylamine of above-mentioned ratio of weight and number, BYK-066N, viscosifier, temperature controls at 65～75 DEG C, and mix homogeneously obtains B component fluid sealant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610486496.7A CN105969208A (en) | 2016-06-29 | 2016-06-29 | Methoxy ethyl ester and ethoxy ethyl ester based high-elasticity sealant for storage batteries and manufacturing method of methoxy ethyl ester and ethoxy ethyl ester based high-elasticity sealant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610486496.7A CN105969208A (en) | 2016-06-29 | 2016-06-29 | Methoxy ethyl ester and ethoxy ethyl ester based high-elasticity sealant for storage batteries and manufacturing method of methoxy ethyl ester and ethoxy ethyl ester based high-elasticity sealant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105969208A true CN105969208A (en) | 2016-09-28 |
Family
ID=57019695
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610486496.7A Pending CN105969208A (en) | 2016-06-29 | 2016-06-29 | Methoxy ethyl ester and ethoxy ethyl ester based high-elasticity sealant for storage batteries and manufacturing method of methoxy ethyl ester and ethoxy ethyl ester based high-elasticity sealant |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105969208A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115197263A (en) * | 2022-05-17 | 2022-10-18 | 广州市白云化工实业有限公司 | Modified silane coupling agent, waterproof silicone structural sealant and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103834308A (en) * | 2012-11-23 | 2014-06-04 | 湖北回天胶业股份有限公司 | New low-odor two-component acrylate adhesive |
| CN104804702A (en) * | 2014-01-28 | 2015-07-29 | 上海铂优新材料有限公司 | Silane modified two-component acrylate structure adhesive |
-
2016
- 2016-06-29 CN CN201610486496.7A patent/CN105969208A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103834308A (en) * | 2012-11-23 | 2014-06-04 | 湖北回天胶业股份有限公司 | New low-odor two-component acrylate adhesive |
| CN104804702A (en) * | 2014-01-28 | 2015-07-29 | 上海铂优新材料有限公司 | Silane modified two-component acrylate structure adhesive |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115197263A (en) * | 2022-05-17 | 2022-10-18 | 广州市白云化工实业有限公司 | Modified silane coupling agent, waterproof silicone structural sealant and preparation method thereof |
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Application publication date: 20160928 |