CN105968897A - Inorganic mineral environment-friendly fireproof coating - Google Patents
Inorganic mineral environment-friendly fireproof coating Download PDFInfo
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- CN105968897A CN105968897A CN201610388158.XA CN201610388158A CN105968897A CN 105968897 A CN105968897 A CN 105968897A CN 201610388158 A CN201610388158 A CN 201610388158A CN 105968897 A CN105968897 A CN 105968897A
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- inorganic mineral
- sodium
- mineral environment
- fireproof coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
- C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an inorganic mineral environment-friendly fireproof coating. The inorganic mineral environment-friendly fireproof coating is prepared from, by weight, 5-8 parts of potassium silicate, 1-1.5 parts of dispersant, 1-2.5 parts of thickener, 1.5-2.5 parts of dimethicone, 4-8 parts of acrylic emulsion, 2-9 parts of titanium dioxide, 1-10 parts of antimonous oxide, 2-8 parts of opal, 2-5 parts of copper oxide, 2-6 parts of tourmaline, 1-4 parts of calcium carbonate, 1-2 parts of silica sol and 25-70 parts of water. The inorganic mineral environment-friendly fireproof coating is reasonable in compatibility of all matter and wide in application range, and a cured product has excellent chemical corrosion resistance, heat resistance and acid and alkali resistance and good electrical insulativity, has the advantages of durable fireproofness, high flame retardance and the like, and has better environmental suitability.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of inorganic mineral environment-friendlyfireproof fireproof paint.
Background technology
Fireproof coating is also known as anti-flaming dope, and it not only has a dicoration of common coating, and coating itself
Also there is fire protection function.When fire occurs, fireproof coating can stop burning or it is to burning speed
Degree is expanded with retardation, so that people have the sufficient time to carry out fire attack work, reaches protection
The purpose of people's security of the lives and property.
In recent years, along with the continuous enhancing of people's environmental consciousness, inorganic mineral fireproof coating receives and more comes
The most concerns.Inorganic mineral fireproof coating makees solvent with water, and therefore price is low compared with oiliness fireproof coating also
And reduce the pollution to air;Inorganic mineral fireproof coating only with using organic solvent on a small quantity or not,
Effect in terms of reducing pollution, saving resource is notable.
Inorganic coating becomes one of paint development direction with the environmental-protecting performance of its excellence, and it is making and is using
Middle non-volatility Organic substance, environmental sound, with low cost, after normal temperature cure, form a kind
Like inorganic protective film, there is the characteristics such as fire-retardant, weather-proof, anti-corrosion, insulation, thermal insulation, high rigidity, resistance to height
Warm nature can far surpass organic coating.Its high added value and specific function are noticeable.
A kind of inorganic mineral environment-friendlyfireproof fireproof paint of the present invention, each material compatibility is reasonable, applied range,
Product after solidification has excellent chemical resistance, thermostability, resistance to acids and bases and good electric insulation
Property, water proofing property, Scratch Resistance, stain resistance, it is to avoid peeling, fade, have lasting resistance to simultaneously
Fire and flame retarding efficiency advantages of higher, be particularly well-suited to the fields such as civil construction, commercial building, public building
Close, and easy construction, environmental suitability is more preferable, has broad application prospects.
Summary of the invention
For the deficiencies in the prior art, the technical problem to be solved is to provide a kind of nothing
Machine mineral environment-friendlyfireproof fireproof paint.
The present invention seeks to be achieved through the following technical solutions:
A kind of inorganic mineral environment-friendlyfireproof fireproof paint, is prepared from by the raw material of following weight parts:
Potassium silicate 5-8 part, dispersant 1-1.5 part, thickening agent 1-2.5 part, dimethicone 1.5-2.5 part,
Acrylic emulsion 4-8 part, titanium dioxide 2-9 part, antimony oxide 1-10 part, opal 2-8 part,
Copper oxide 2-5 part, tourmaline 2-6 part, calcium carbonate 1-4 part, Ludox 1-2 part, water 25-70 part.
Preferably, described dispersant is by sodium hexameta phosphate, sodium tripolyphosphate, succinic acid di-isooctyl sulfonic acid
Sodium forms, and described sodium hexameta phosphate, sodium tripolyphosphate, the mass ratio of Aerosol OT are
(1-3): (1-3): (1-3).
Preferably, described thickening agent is by hydroxyethyl cellulose, sodium alginate, hydroxypropyl methyl cellulose
Composition, described hydroxyethyl cellulose, sodium alginate, the mass ratio of hydroxypropyl methyl cellulose are (1-3):
(1-3): (1-3).
Preferably, described potassium silicate modulus is 2.3-3.3.
Preferably, described Ludox particle diameter is 5.0-22.5nm.
A kind of inorganic mineral environment-friendlyfireproof fireproof paint of the present invention, each material compatibility is reasonable, applied range,
Product after solidification has excellent chemical resistance, thermostability, resistance to acids and bases and good electric insulation
Property, there is lasting fire resistance and flame retarding efficiency advantages of higher simultaneously, environmental suitability is more preferable.
Detailed description of the invention
Each raw material introduction in embodiment:
Antimony oxide, No. CAS: 1309-64-4.
Hydroxyethyl cellulose, No. CAS: 9004-62-0, Zhengzhou Ya Shen chemical products company limited provides.
Sodium alginate, No. CAS: 9005-38-3, Qingdao Jin Hai iodine Chemical Co., Ltd. provides, particle diameter
200 mesh.
Hydroxypropyl methyl cellulose, No. CAS: 9004-65-3, Jinan Yuan Tong Chemical Co., Ltd. provides.
Sodium hexameta phosphate, No. CAS: 10124-56-8.
Aerosol OT, No. CAS: 577-11-7.
Sodium tripolyphosphate, No. CAS: 7758-29-4.
Dimethicone, No. CAS: 63148-62-9.
Acrylic emulsion, No. CAS: 79-10-7, Shandong Kaitai Petrochemical Co., Ltd. provide.
Titanium dioxide, No. CAS: 1317-80-2, particle diameter 20-40nm.
Opal, uses trend branch cutting shale, 325 mesh.
Copper oxide, No. CAS: 1317-38-0, particle diameter 20-40nm.
Tourmaline, uses the crystal tourmaline that Lingshou County rock forming mineral powder body factory produces, specification 80 mesh.
Calcium carbonate, No. CAS: 471-34-1, Jingxian County Hua Hui mining industry company limited provide, specification 3000
Mesh.
Ludox, uses number of patent application: in 201210235302.8 prepared by the method for embodiment 2, grain
Footpath 8nm.
Potassium silicate, No. CAS: 1312-76-1, modulus is 2.55.
Embodiment 1
Weigh each raw material (weight portion): potassium silicate 900g, dispersant 150g, thickening agent 150g, two
Methyl-silicone oil 200g, acrylic emulsion 600g, titanium dioxide 800g, antimony oxide 800g, albumen
Stone 600g, copper oxide 400g, tourmaline 400g, calcium carbonate 400g, Ludox 200g, water 4500g.
Described dispersant is by 50g sodium hexameta phosphate, 50g sodium tripolyphosphate, 50g succinic acid di-isooctyl
Sodium sulfonate mixes.
Described thickening agent is by 50g hydroxyethyl cellulose, 50g sodium alginate, 50g hydroxypropyl methyl fiber
Element mixes.
Prepared by inorganic mineral environment-friendlyfireproof fireproof paint, comprise the following steps:
(1) by potassium silicate, dispersant, thickening agent, dimethicone, acrylic emulsion, titanium dioxide,
Antimony oxide, opal, copper oxide, tourmaline, calcium carbonate, Ludox, water add in Scattered Kettle,
Stir 0.5 hour under rotating speed 800 revs/min, obtain serosity;
(2) serosity injects disc grinder, and (employing Fang Bang bio tech ltd, Shandong model is
The disc grinder of 001), grind 0.5h, to obtain final product.
Embodiment 2
Proportioning raw materials and method by embodiment 1 prepare inorganic mineral environment-friendlyfireproof fireproof paint, differ only in:
Described dispersant is mixed by 75g sodium hexameta phosphate, 75g Aerosol OT.?
Inorganic mineral environment-friendlyfireproof fireproof paint to embodiment 2.
Embodiment 3
Proportioning raw materials and method by embodiment 1 prepare inorganic mineral environment-friendlyfireproof fireproof paint, differ only in:
Described dispersant is mixed by 75g sodium hexameta phosphate, 75g sodium tripolyphosphate.Obtain embodiment 3
Inorganic mineral environment-friendlyfireproof fireproof paint.
Embodiment 4
Proportioning raw materials and method by embodiment 1 prepare inorganic mineral environment-friendlyfireproof fireproof paint, differ only in:
Described dispersant is mixed by 75g Aerosol OT, 75g sodium tripolyphosphate.?
Inorganic mineral environment-friendlyfireproof fireproof paint to embodiment 4.
Embodiment 5
Proportioning raw materials and method by embodiment 1 prepare inorganic mineral environment-friendlyfireproof fireproof paint, differ only in:
Described thickening agent is mixed by 75g hydroxyethyl cellulose, 75g sodium alginate.Obtain embodiment 5
Inorganic mineral environment-friendlyfireproof fireproof paint.
Embodiment 6
Proportioning raw materials and method by embodiment 1 prepare inorganic mineral environment-friendlyfireproof fireproof paint, differ only in:
Described thickening agent is by 75g sodium alginate, 75g hydroxypropyl methyl cellulose.Obtain the nothing of embodiment 6
Machine mineral environment-friendlyfireproof fireproof paint.
Embodiment 7
Proportioning raw materials and method by embodiment 1 prepare inorganic mineral environment-friendlyfireproof fireproof paint, differ only in:
Described described thickening agent is mixed by 75g hydroxyethyl cellulose, 75g hydroxypropyl methyl cellulose.
Obtain the inorganic mineral environment-friendlyfireproof fireproof paint of embodiment 7.
Test case 1
The anti-microbial property of the inorganic mineral environment-friendlyfireproof fireproof paint preparing embodiment 1-7 is tested,
Anti-microbial property presses GB/T21866-2008 antibiotic paint anti-microbial property assay method and antibacterial effect, HG/T
3980-2007 antibiotic paint measures, and detection project is antibacterial test and fungus-proof test.
Antibacterial test: escherichia coli ATYCC 25922, staphylococcus aureus ATCC 6538.
Concrete test result is shown in Table 1.
Table 1: inorganic mineral environment-friendlyfireproof fireproof paint anti-microbial property test data
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (sodium hexameta phosphate, sodium tripolyphosphate, succinum
Acid di-isooctyl sodium sulfonate compounds) anti-microbial property is substantially better than embodiment 2-4 (sodium hexameta phosphate, trimerization
In sodium phosphate, Aerosol OT, arbitrarily the two is compounding).Comparing embodiment 1 and embodiment
5-7, embodiment 1 (hydroxyethyl cellulose, sodium alginate, hydroxypropyl methyl cellulose are compounding) antibiotic property
Embodiment 5-7 can be substantially better than (hydroxyethyl cellulose, sodium alginate, hydroxypropyl methyl cellulose are appointed
The two is compounding for meaning).
Test case 2
" the HG/T 4109-2009 anion function coating " standard of employing, nothing prepared by embodiment 1-7
Machine mineral environment-friendlyfireproof fireproof paint carries out negative aeroion and induces measurement examination, and concrete test data are shown in Table 2.
Table 2: negative aeroion induces measurement examination tables of data
Sample name | The negative aeroion amount of inducing, individual/s cm2 |
Embodiment 1 | 1710 |
Embodiment 2 | 1520 |
Embodiment 3 | 1530 |
Embodiment 4 | 1500 |
Embodiment 5 | 1540 |
Embodiment 6 | 1500 |
Embodiment 7 | 1530 |
Comparing embodiment 1-4, comparing embodiment 1 and embodiment 2-4, embodiment 1 (sodium hexameta phosphate,
Sodium tripolyphosphate, Aerosol OT are compounding) the negative aeroion amount of inducing is apparently higher than enforcement
Example 2-4 (in sodium hexameta phosphate, sodium tripolyphosphate, Aerosol OT, arbitrarily the two is compounding).
Comparing embodiment 1 and embodiment 5-7, embodiment 1 (hydroxyethyl cellulose, sodium alginate, hydroxypropyl first
Base cellulose compounds) the negative aeroion amount of inducing is substantially better than embodiment 5-7 (hydroxyethyl cellulose, sea
In sodium alginate, hydroxypropyl methyl cellulose, arbitrarily the two is compounding).
Test case 3
" the HG/T 4109-2009 anion function coating " standard of employing, nothing prepared by embodiment 1-7
Machine mineral environment-friendlyfireproof fireproof paint carries out Fire retardance and the time test of resistance to combustion, Fire retardance: by GB/T15442.4
Regulation test, the resistance to combustion time: test by the regulation of GB/T15442.2.Specifically test number
According to being shown in Table 3.
Table 3: Fire retardance and the time test of resistance to combustion tables of data
Comparing embodiment 1-4, embodiment 1 (sodium hexameta phosphate, sodium tripolyphosphate, succinic acid di-isooctyl
Sodium sulfonate compounds) Fire retardance and resistance to combustion time is substantially better than embodiment 2-4 (sodium hexameta phosphate, trimerization phosphorus
In acid sodium, Aerosol OT, arbitrarily the two is compounding).Comparing embodiment 1 and embodiment 5-7,
Embodiment 1 (hydroxyethyl cellulose, sodium alginate, hydroxypropyl methyl cellulose are compounding) Fire retardance and resistance to
The combustion time can be substantially better than embodiment 5-7 (hydroxyethyl cellulose, sodium alginate, hydroxypropyl methyl fiber
In element, arbitrarily the two is compounding).
Claims (1)
1. an inorganic mineral environment-friendlyfireproof fireproof paint, it is characterised in that prepared by the raw material of following weight parts
Form: potassium silicate 5-8 part, dispersant 1-1.5 part, thickening agent 1-2.5 part, dimethicone 1.5-2.5
Part, acrylic emulsion 4-8 part, titanium dioxide 2-9 part, antimony oxide 1-10 part, opal 2-8
Part, copper oxide 2-5 part, tourmaline 2-6 part, calcium carbonate 1-4 part, Ludox 1-2 part, water 25-70
Part;
Described dispersant is made up of sodium hexameta phosphate, sodium tripolyphosphate, Aerosol OT,
Described sodium hexameta phosphate, sodium tripolyphosphate, the mass ratio of Aerosol OT are (1-3):
(1-3): (1-3).
Described thickening agent is made up of hydroxyethyl cellulose, sodium alginate, hydroxypropyl methyl cellulose, institute
State hydroxyethyl cellulose, sodium alginate, hydroxypropyl methyl cellulose mass ratio for (1-3): (1-3):
(1-3)。
Priority Applications (1)
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CN201610388158.XA CN105968897A (en) | 2016-06-02 | 2016-06-02 | Inorganic mineral environment-friendly fireproof coating |
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CN201610388158.XA CN105968897A (en) | 2016-06-02 | 2016-06-02 | Inorganic mineral environment-friendly fireproof coating |
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CN201610388158.XA Withdrawn CN105968897A (en) | 2016-06-02 | 2016-06-02 | Inorganic mineral environment-friendly fireproof coating |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115260812A (en) * | 2022-08-23 | 2022-11-01 | 河北嘉宝莉涂料有限公司 | Inorganic mineral coating and preparation method thereof |
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CN103319144A (en) * | 2013-06-25 | 2013-09-25 | 关锦池 | Mineral coating |
CN103319142A (en) * | 2013-05-15 | 2013-09-25 | 范菊萍 | Mineral paint formula |
CN103694827A (en) * | 2013-12-30 | 2014-04-02 | 河北晨阳工贸集团有限公司 | Fireproof coating and preparation method thereof |
CN103937302A (en) * | 2014-03-28 | 2014-07-23 | 珠海哥拜耳涂料有限公司 | Inorganic mineral coating and manufacturing method thereof |
CN105086840A (en) * | 2015-09-21 | 2015-11-25 | 北京迪百斯特科技发展有限公司 | Inorganic interior wall environment-friendly coating, adhesive agent and preparing method thoseof |
-
2016
- 2016-06-02 CN CN201610388158.XA patent/CN105968897A/en not_active Withdrawn
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103319142A (en) * | 2013-05-15 | 2013-09-25 | 范菊萍 | Mineral paint formula |
CN103319144A (en) * | 2013-06-25 | 2013-09-25 | 关锦池 | Mineral coating |
CN103694827A (en) * | 2013-12-30 | 2014-04-02 | 河北晨阳工贸集团有限公司 | Fireproof coating and preparation method thereof |
CN103937302A (en) * | 2014-03-28 | 2014-07-23 | 珠海哥拜耳涂料有限公司 | Inorganic mineral coating and manufacturing method thereof |
CN105086840A (en) * | 2015-09-21 | 2015-11-25 | 北京迪百斯特科技发展有限公司 | Inorganic interior wall environment-friendly coating, adhesive agent and preparing method thoseof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115260812A (en) * | 2022-08-23 | 2022-11-01 | 河北嘉宝莉涂料有限公司 | Inorganic mineral coating and preparation method thereof |
CN115260812B (en) * | 2022-08-23 | 2023-06-30 | 河北嘉宝莉涂料有限公司 | Inorganic mineral coating and preparation method thereof |
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Application publication date: 20160928 |