CN105968872B - Halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material - Google Patents
Halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material Download PDFInfo
- Publication number
- CN105968872B CN105968872B CN201610380335.XA CN201610380335A CN105968872B CN 105968872 B CN105968872 B CN 105968872B CN 201610380335 A CN201610380335 A CN 201610380335A CN 105968872 B CN105968872 B CN 105968872B
- Authority
- CN
- China
- Prior art keywords
- cable material
- halogen
- free flame
- thermoplastic elastomer
- energy automobile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000463 material Substances 0.000 title claims abstract description 67
- 239000003063 flame retardant Substances 0.000 title claims abstract description 48
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 229920002725 thermoplastic elastomer Polymers 0.000 title claims abstract description 31
- 238000004073 vulcanization Methods 0.000 claims abstract description 64
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000012190 activator Substances 0.000 claims abstract description 30
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 30
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 30
- 239000000203 mixture Substances 0.000 claims abstract description 27
- 150000002978 peroxides Chemical class 0.000 claims abstract description 27
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 19
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 19
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 claims abstract description 16
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 9
- 238000004381 surface treatment Methods 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims description 14
- -1 phenylene maleimides Chemical group 0.000 claims description 10
- 239000008188 pellet Substances 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 3
- 229920000877 Melamine resin Polymers 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 229920000388 Polyphosphate Polymers 0.000 claims description 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 3
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 3
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims description 3
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical class O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims description 3
- 239000001205 polyphosphate Substances 0.000 claims description 3
- 235000011176 polyphosphates Nutrition 0.000 claims description 3
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 2
- 239000004594 Masterbatch (MB) Substances 0.000 claims 1
- 238000001125 extrusion Methods 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 abstract description 27
- 239000000806 elastomer Substances 0.000 abstract description 14
- 239000004793 Polystyrene Substances 0.000 abstract description 12
- 229920002223 polystyrene Polymers 0.000 abstract description 12
- 239000004721 Polyphenylene oxide Substances 0.000 abstract description 11
- 229920006380 polyphenylene oxide Polymers 0.000 abstract description 11
- 239000004727 Noryl Substances 0.000 abstract description 9
- 229920001207 Noryl Polymers 0.000 abstract description 9
- 229920000098 polyolefin Polymers 0.000 abstract description 9
- 239000012752 auxiliary agent Substances 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 239000002253 acid Substances 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- GVYHDVHOWAIYEH-UHFFFAOYSA-N 4-azatricyclo[5.2.2.02,6]undeca-1,6,8,10-tetraene-3,5-dione Chemical group C1=CC2=CC=C1C1=C2C(=O)NC1=O GVYHDVHOWAIYEH-UHFFFAOYSA-N 0.000 description 5
- 230000032683 aging Effects 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- QVTVDJWJGGEOGX-UHFFFAOYSA-N urea;cyanide Chemical compound N#[C-].NC(N)=O QVTVDJWJGGEOGX-UHFFFAOYSA-N 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000005336 cracking Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229920013638 modified polyphenyl ether Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
- C08L101/02—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Insulated Conductors (AREA)
Abstract
The invention belongs to cable material technical field, is related to a kind of halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material, and by mass percentage, the electric wire cable material includes following components：Polystyrene type elastomer 10% 40%；Rubber 5% 25%；Polyolefin 10% 40%；Polyphenylene oxide or Noryl 5% 25%；Halogen-free flame retardants 0.1% 10%；Compatilizer 0.1% 5%；Antioxidant 0.1% 5%；Dynamic vulcanization system 0.1% 10%；Carbon nanotubes 0.1% 2%；It is 100 that the dynamic vulcanization system, which includes mass ratio,：(30‑70)：(5‑20)：The peroxide of (5 30), vulcanization aid, the mixture of activator and white oil；The carbon nanotubes is by carbon nanotubes of the surface treatment with carboxyl.Relative to the prior art, halogen-free flame-retardant thermoplastic elastomer new-energy automobile provided by the invention has oil resistant, antiwear characteristic, high tear resistance and high fire resistance with cable material, can meet the needs of normal use.
Description
Technical field
The invention belongs to cable material technical field, is related to a kind of halogen-free flame-retardant thermoplastic elastomer new-energy automobile line
Cable material.
Background technology
In today that environment and energy problem are increasingly serious, electric vehicle engineering as environmental-friendly new energy science and technology
Through having attracted the research and development enthusiasm of numerous domestic and international manufacturers, and the supporting basic electrically-charging equipment of electric automobile is built also into hair
Open up emphasis.One of key technology of automobile cable material is exactly the Improvement of wear-resisting property, this is because, automotive line is made due to it
Special with position, automobile can not avoid the rubs mutually between line and line in the process of running, can be straight once plastic sheath is worn out
Connecing causes short circuit to cause hidden peril of accident, so electric wire for automobile requirement has enough wear-resisting properties.
In addition, during the use of cable for car, long-term shearing, tension load and bending deformation can make cable protection
Fatigue aging is covered, cable cover(ing) is shown cracking phenomena, can not meet normal use.
In view of this, it is necessory to provide a kind of halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material, its
With oil resistant, antiwear characteristic and high tear resistance, can meet the needs of normal use.
The content of the invention
It is an object of the invention to：In view of the deficiencies of the prior art, it is new to provide a kind of halogen-free flame-retardant thermoplastic elastomer
Energy automobile cable material, it can meet the need of normal use with oil resistant, antiwear characteristic and high tear resistance
Ask.
In order to achieve the above object, the present invention adopts the following technical scheme that：
Halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material, by mass percentage, the electric wire cable
Material includes following components：
Polystyrene type elastomer 10%-40%；
Rubber 5%-25%；
Polyolefin 10%-40%；
Polyphenylene oxide or Noryl 5%-25%；
Halogen-free flame retardants 0.1%-10%；
Compatilizer 0.1%-5%；
Antioxidant 0.1%-5%；
Dynamic vulcanization system 0.1%-10%；
Carbon nanotubes 0.1%-2%；
It is 100 that the dynamic vulcanization system, which includes mass ratio,：(30-70)：(5-20)：The peroxide of (5-30), vulcanization
The mixture of auxiliary agent, activator and white oil；
The carbon nanotubes is by carbon nanotubes of the surface treatment with carboxyl.
Wherein, polyphenylene oxide or Noryl electrical insulation capability are good, and water imbibition is small, there is preferable wearability, dimensionally stable
Property is good, has higher heat resistance, anti-flammability is also preferable, but has stress cracking tendency, can evade polyphenyl by compatible technique
The cracking of ether material.Material is set to possess oil resistant, antiwear characteristic in addition, the present invention provides dynamic vulcanization technology.So-called dynamic vulcanization
Technology, refers to that elastomer " is crosslinked " on the spot during two-phase mixtures, crosslinked elastomer phase is dispersed in thermoplastic, is adopted
The rubber made from dynamic vulcanization technology, polystyrene type elastomer, polyethylene, the blend of polyphenylene oxide (or Noryl)
With excellent intensity, heat resistance and medium-resistance, wherein the terrible rubber that cures is moulded as dispersed phase distribution in thermoplasticity
Expect in continuous phase.
During using peroxide as vulcanizing agent, the network structure of gained elastomer is the carbon-carbon bond with very high bond energy,
It is and highly stable so that material has good ageing-resistant performance, and the use of vulcanization aid, activator can improve peroxidating
The curing efficiency of thing, activator can increase cross-linking efficiency, and white oil can then be such that vulcanizing agent etc. is uniformly wrapped on pellet, from
And may insure the full cure of rubber, and be evenly dispersed in thermoplastic continuous phase.
Carbon nanotubes has high intensity, high tenacity and an excellent electro-chemical properties, and the carbon nanotubes in the present invention is by table
Surface treatment carries the carbon nanotubes of carboxyl, shows faintly acid, when its dosage is smaller, weakly acidic carbon nanotubes adds carbon nanometer
The combination of pipe and matrix so that it is scattered more uniform in system, so as to be unlikely to produce local reunion, and then improves
The crosslink density of system, on the other hand since carbon nanotubes has good surface property so that elastomer can be in its week
Enclose to form physical crosslinking, this is conducive to the crosslink density of increase system, but the additive amount of carbon nanotubes cannot be too big, otherwise can
There is serious reunion situation, curing efficiency can not be promoted.Simultaneously as carbon nanotubes has good surface property so that
Rubber matrix can be good in its apparent motion, and appropriate carbon nanotubes act as the effect of lubricant in system, reduce
Flow resistance, makes the increase of system mobility, but when carbon nanotubes exceedes a certain amount of, it tends to form larger particle,
Mutual collision friction produces flow resistance between particle, causes system mobility to decline.In addition, suitable carbon nanotubes can also carry
The tensile property of high material.
Antioxidant can improve the ageing-resistant performance of material.Halogen-free flame retardants can improve the fire resistance of material.
Relative to the prior art, halogen-free flame-retardant thermoplastic elastomer new-energy automobile provided by the invention has with cable material
There are oil resistant, antiwear characteristic, high tear resistance and high fire resistance, can meet the needs of normal use.
One kind as halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material of the present invention is improved, by quality hundred
Divide includes following components than meter, the electric wire cable material：
Polystyrene type elastomer 15%-35%；
Rubber 7%-20%；
Polyolefin 15%-35%；
Polyphenylene oxide or Noryl 7%-20%；
Halogen-free flame retardants 1%-7%；
Compatilizer 1%-3%；
Antioxidant 0.5%-4%；
Dynamic vulcanization system 1%-7%；
Carbon nanotubes 0.5%-1.5%.
One kind as halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material of the present invention is improved, by quality hundred
Divide includes following components than meter, the electric wire cable material：
Polystyrene type elastomer 31%；
Rubber 15%；
Polyolefin 25%；
Polyphenylene oxide or Noryl 15%；
Halogen-free flame retardants 5%；
Compatilizer 2%；
Antioxidant 2%；
Dynamic vulcanization system 4%；
Carbon nanotubes 1%.
One kind as halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material of the present invention is improved, the peroxide
Compound is 2,5- dimethyl -2,5- di-t-butyl peroxyhexanes.
One kind as halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material of the present invention is improved, the activation
Agent is N, N- adjacent phenylene maleimides.
One kind as halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material of the present invention is improved, the vulcanization
Auxiliary agent is Triallyl isocyanurate.
One kind as halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material of the present invention is improved, described compatible
Agent is grafted PE for maleic anhydride-g-SBS and/or maleic anhydride.
One kind as halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material of the present invention is improved, the Halogen
Fire retardant is at least one in melamine cyanurate, melamine polyphosphate, phosphate, phosphinate and hypophosphites
Kind.
One kind as halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material of the present invention is improved, the antioxygen
Agent is at least one of antioxidant 1010, antioxidant 1076, antioxidant 164 and antioxidant 264.
One kind as halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material of the present invention is improved, its preparation side
Method comprises the following steps：
The first step, sets dynamic vulcanization temperature, preheats double screw extruder；
Second step, the component in addition to dynamic vulcanization system is mixed, obtains mixture, then by peroxide, vulcanization
Auxiliary agent, activator are added in mixture, and when mixing adds white oil, peroxide, vulcanization aid, activator is adhered to mother
Expect the surface of particle；
3rd step, the mixing pellet that second step is obtained are added in double screw extruder, are melted and are squeezed at 175 DEG C -210 DEG C
Go out, tie rod, cooling, be granulated, obtain cable material.
Embodiment
Embodiment 1
A kind of halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material is present embodiments provided, its feature exists
In by mass percentage, the electric wire cable material includes following components：
Polystyrene type elastomer 31%；
Rubber 15%；
Polyolefin 25%；
Polyphenylene oxide 15%；
Halogen-free flame retardants 5%；
Compatilizer 2%；
Antioxidant 2%；
Dynamic vulcanization system 4%；
Carbon nanotubes 1%.
Wherein, it is 100 that dynamic vulcanization system, which includes mass ratio,：50：10：6 peroxide, vulcanization aid, activator and
The mixture of white oil；Peroxide is 2,5- dimethyl -2,5- di-t-butyl peroxyhexanes, and vulcanization aid is triallyl isocyanide
Urea acid esters, activator N, N- adjacent phenylene maleimide, carbon nanotubes are by carbon nanometer of the surface treatment with carboxyl
Pipe, halogen-free flame retardants is melamine cyanurate, and compatilizer is maleic anhydride-g-SBS, and antioxidant is antioxidant 1010.
Its preparation method comprises the following steps：
The first step, sets dynamic vulcanization temperature, preheats double screw extruder；
Second step, the component in addition to dynamic vulcanization system is mixed, obtains mixture, then by peroxide, vulcanization
Auxiliary agent, activator are added in mixture, and when mixing adds white oil, peroxide, vulcanization aid, activator is adhered to mother
Expect the surface of particle；
3rd step, the mixing pellet that second step is obtained are added in double screw extruder, are melted and are squeezed at 180 DEG C -190 DEG C
Go out, tie rod, cooling, be granulated, obtain cable material.
Embodiment 2
A kind of halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material is present embodiments provided, by quality percentage
Than meter, the electric wire cable material includes following components：
Polystyrene type elastomer 36.8%；
Rubber 10%；
Polyolefin 20%；
Polyphenylene oxide 22%；
Halogen-free flame retardants 3%；
Compatilizer 2%；
Antioxidant 2%；
Dynamic vulcanization system 3%；
Carbon nanotubes 1.2%；
It is 100 that the dynamic vulcanization system, which includes mass ratio,：40：15：15 peroxide, vulcanization aid, activator and
The mixture of white oil；Peroxide is 2,5- dimethyl -2,5- di-t-butyl peroxyhexanes, and vulcanization aid is triallyl isocyanide
Urea acid esters, activator N, N- adjacent phenylene maleimide, carbon nanotubes are by carbon nanometer of the surface treatment with carboxyl
Pipe.Halogen-free flame retardants is melamine polyphosphate, and compatilizer is grafted PE for maleic anhydride, and antioxidant is antioxidant 1076.
Its preparation method comprises the following steps：
The first step, sets dynamic vulcanization temperature, preheats double screw extruder；
Second step, the component in addition to dynamic vulcanization system is mixed, obtains mixture, then by peroxide, vulcanization
Auxiliary agent, activator are added in mixture, and when mixing adds white oil, peroxide, vulcanization aid, activator is adhered to mother
Expect the surface of particle；
3rd step, the mixing pellet that second step is obtained are added in double screw extruder, are melted and are squeezed at 185 DEG C -200 DEG C
Go out, tie rod, cooling, be granulated, obtain cable material.
Embodiment 3
A kind of halogen-free flameproof new energy charging pile electric wire cable material is present embodiments provided, by mass percentage,
The electric wire cable material includes following components：
Polystyrene type elastomer 30%；
Rubber 19%；
Polyolefin 18%；
Noryl 18%；
Halogen-free flame retardants 4%；
Compatilizer 1.3%；
Antioxidant 3%；
Dynamic vulcanization system 6%；
Carbon nanotubes 0.7%.
Wherein, it is 100 that dynamic vulcanization system, which includes mass ratio,：35：8：8 peroxide, vulcanization aid, activator and white
The mixture of oil；Peroxide is 2,5- dimethyl -2,5- di-t-butyl peroxyhexanes, and vulcanization aid is triallyl isocyanide urea
Acid esters, activator N, N- adjacent phenylene maleimide, the carbon nanotubes are to be received by carbon of the surface treatment with carboxyl
Mitron.Halogen-free flame retardants is phosphate, and compatilizer is grafted PE for maleic anhydride, and antioxidant is antioxidant 164, and Noryl is
Obtained by polyphenylene oxide and polystyrene blend.
Its preparation method comprises the following steps：
The first step, sets dynamic vulcanization temperature, preheats double screw extruder；
Second step, the component in addition to dynamic vulcanization system is mixed, obtains mixture, then by peroxide, vulcanization
Auxiliary agent, activator are added in mixture, and when mixing adds white oil, peroxide, vulcanization aid, activator is adhered to mother
Expect the surface of particle；
3rd step, the mixing pellet that second step is obtained are added in double screw extruder, are melted and are squeezed at 190 DEG C -210 DEG C
Go out, tie rod, cooling, be granulated, obtain cable material.
Embodiment 4
A kind of halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material is present embodiments provided, by quality percentage
Than meter, the electric wire cable material includes following components：
Polystyrene type elastomer 18%；
Rubber 20%；
Polyolefin 32%；
Noryl 14%；
Halogen-free flame retardants 8.5%；
Compatilizer 1.5%；
Antioxidant 1.5%；
Dynamic vulcanization system 4%；
Carbon nanotubes 0.5%；
It is 100 that the dynamic vulcanization system, which includes mass ratio,：35：12：22 peroxide, vulcanization aid, activator and
The mixture of white oil；Oxide is 2,5- dimethyl -2,5- di-t-butyl peroxyhexanes, and vulcanization aid is triallyl isocyanide urea
Acid esters, activator N, N- adjacent phenylene maleimide, the carbon nanotubes are to be received by carbon of the surface treatment with carboxyl
Mitron.Halogen-free flame retardants is phosphinate, and compatilizer is maleic anhydride-g-SBS, and antioxidant is antioxidant 264, modified polyphenyl
Ether is obtained by polyphenylene oxide and polystyrene blend.
Its preparation method comprises the following steps：
The first step, sets dynamic vulcanization temperature, preheats double screw extruder；
Second step, the component in addition to dynamic vulcanization system is mixed, obtains mixture, then by peroxide, vulcanization
Auxiliary agent, activator are added in mixture, and when mixing adds white oil, peroxide, vulcanization aid, activator is adhered to mother
Expect the surface of particle；
3rd step, the mixing pellet that second step is obtained are added in double screw extruder, are melted and are squeezed at 180 DEG C -200 DEG C
Go out, tie rod, cooling, be granulated, obtain cable material.
Embodiment 5
A kind of halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material is present embodiments provided, by quality percentage
Than meter, the electric wire cable material includes following components：
Polystyrene type elastomer 24%；
Rubber 21%；
Polyolefin 23%；
Polyphenylene oxide 13.5%；
Halogen-free flame retardants 5.5%；
Compatilizer 3.5%；
Antioxidant 3.5%；
Dynamic vulcanization system 5.2%；
Carbon nanotubes 0.8%；
It is 100 that the dynamic vulcanization system, which includes mass ratio,：45：13：13 peroxide, vulcanization aid, activator and
The mixture of white oil；Oxide is 2,5- dimethyl -2,5- di-t-butyl peroxyhexanes, and vulcanization aid is triallyl isocyanide urea
Acid esters, activator N, N- adjacent phenylene maleimide, the carbon nanotubes are to be received by carbon of the surface treatment with carboxyl
Mitron.Halogen-free flame retardants is hypophosphites, and compatilizer is maleic anhydride-g-SBS, and antioxidant is antioxidant 1010.
Its preparation method comprises the following steps：
The first step, sets dynamic vulcanization temperature, preheats double screw extruder；
Second step, the component in addition to dynamic vulcanization system is mixed, obtains mixture, then by peroxide, vulcanization
Auxiliary agent, activator are added in mixture, and when mixing adds white oil, peroxide, vulcanization aid, activator is adhered to mother
Expect the surface of particle；
3rd step, the mixing pellet that second step is obtained are added in double screw extruder, are melted and are squeezed at 185 DEG C -205 DEG C
Go out, tie rod, cooling, be granulated, obtain cable material.
Quantitative measurement is carried out to the material of embodiment 1 to 5, acquired results are shown in Table 1, as a comparison, are filled commercially available
Electric stake does same test (comparative example) with electric wire cable material：
Table 1：The quantitative measurement result of the material of embodiment 1 to 5：
Material and commercially available material to embodiment 1 to 5 carry out burn-in test, specifically, these materials are placed in air
Aging is carried out in baking oven, aging temperature is 135 DEG C, and the presbyopic time is 168h, then tests its mechanical performance：Low-temperature bending performance
(temperature is -40 DEG C, time 16h), thermal shock resistance (temperature is 150 DEG C, time 1h) and thermal deformation behavior (150
DEG C), acquired results are shown in Table 2:
Table 2：The ageing properties test result of the material of embodiment 1 to 5：
It follows that the present invention has high-tear strength, environmental protection, halogen-free flameproof, and crackle is less prone to, service life
It is long,.
According to the disclosure and teachings of the above specification, those skilled in the art in the invention can also be to above-mentioned embodiment party
Formula carries out appropriate change and modification.Therefore, the invention is not limited in embodiment disclosed and described above, to this
Some modifications and changes of invention should also be as falling into the scope of the claims of the present invention.In addition, although this specification
In used some specific terms, but these terms are merely for convenience of description, do not limit the present invention in any way.
Claims (9)
1. halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material, it is characterised in that by mass percentage, described
Electric wire cable material includes following components：
It is 100 that the dynamic vulcanization system, which includes mass ratio,：(30-70)：(5-20)：The peroxide of (5-30), vulcanization aid,
The mixture of activator and white oil；
The carbon nanotubes is by carbon nanotubes of the surface treatment with carboxyl；
The activator is N, N- adjacent phenylene maleimides.
2. halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material according to claim 1, it is characterised in that
By mass percentage, the electric wire cable material includes following components：
3. halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material according to claim 2, it is characterised in that
By mass percentage, the electric wire cable material includes following components：
4. halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material according to any one of claims 1 to 3, its
It is characterized in that：The peroxide is 2,5- dimethyl -2,5- di-t-butyl peroxyhexanes.
5. halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material according to any one of claims 1 to 3, its
It is characterized in that：The vulcanization aid is Triallyl isocyanurate.
6. halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material according to any one of claims 1 to 3, its
It is characterized in that：The compatilizer is grafted PE for maleic anhydride-g-SBS and/or maleic anhydride.
7. halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material according to any one of claims 1 to 3, its
It is characterized in that：The halogen-free flame retardants for melamine cyanurate, melamine polyphosphate, phosphate, phosphinate and
At least one of hypophosphites.
8. halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material according to any one of claims 1 to 3, its
It is characterized in that：The antioxidant is at least one of antioxidant 1010, antioxidant 1076, antioxidant 164 and antioxidant 264.
9. halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material according to any one of claims 1 to 3, its
It is characterized in that, its preparation method comprises the following steps：
The first step, sets dynamic vulcanization temperature, preheats double screw extruder；
Second step, by addition to dynamic vulcanization system component mix, obtain mixture, then by peroxide, vulcanization aid,
Activator is added in mixture, and when mixing adds white oil, peroxide, vulcanization aid, activator is adhered to masterbatch
The surface of grain；
3rd step, the mixing pellet that second step is obtained are added in double screw extruder, at 175 DEG C -210 DEG C melting extrusion,
Tie rod, cooling, are granulated, obtain cable material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610380335.XA CN105968872B (en) | 2016-05-31 | 2016-05-31 | Halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610380335.XA CN105968872B (en) | 2016-05-31 | 2016-05-31 | Halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105968872A CN105968872A (en) | 2016-09-28 |
| CN105968872B true CN105968872B (en) | 2018-04-24 |
Family
ID=57010031
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610380335.XA Active CN105968872B (en) | 2016-05-31 | 2016-05-31 | Halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105968872B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107141761B (en) * | 2017-06-23 | 2019-05-31 | 广东奥美格传导科技股份有限公司 | A kind of cold resistant cable insulating materials and preparation method thereof |
| CN107602947A (en) * | 2017-09-15 | 2018-01-19 | 安徽伙伴电气有限公司 | A kind of electric wire with excellent cracking resistance oil resistivity |
| CN109825075B (en) * | 2019-01-28 | 2021-04-27 | 凯尔科美(广州)高新材料科技有限公司 | Halogen-free flame-retardant thermoplastic elastomer cable material for new energy automobile |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103613862A (en) * | 2013-11-21 | 2014-03-05 | 宁波市青湖弹性体科技有限公司 | Nano modified high-performance dynamic vulcanization thermoplastic elastomer and preparation method thereof |
| CN103965575A (en) * | 2014-05-15 | 2014-08-06 | 南通普力马弹性体技术有限公司 | Charging wire material for electric vehicles and preparation method thereof |
| CN105038087A (en) * | 2015-08-19 | 2015-11-11 | 深圳市沃尔核材股份有限公司 | Halogen-free flame retardant high-tear-resistance wire and cable compound for electric vehicles and wire and cable production method |
| CN105111556A (en) * | 2015-09-14 | 2015-12-02 | 宁波聚泰新材料科技有限公司 | Thermoplastic elastomer used for electric car charging pile cable and preparing method of thermoplastic elastomer |
| CN105348716A (en) * | 2015-10-29 | 2016-02-24 | 浙江万马高分子材料有限公司 | Halogen-free flame retardant thermoplastic elastomer EV cable material resistant to 125 DEG C and preparation method thereof |
-
2016
- 2016-05-31 CN CN201610380335.XA patent/CN105968872B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103613862A (en) * | 2013-11-21 | 2014-03-05 | 宁波市青湖弹性体科技有限公司 | Nano modified high-performance dynamic vulcanization thermoplastic elastomer and preparation method thereof |
| CN103965575A (en) * | 2014-05-15 | 2014-08-06 | 南通普力马弹性体技术有限公司 | Charging wire material for electric vehicles and preparation method thereof |
| CN105038087A (en) * | 2015-08-19 | 2015-11-11 | 深圳市沃尔核材股份有限公司 | Halogen-free flame retardant high-tear-resistance wire and cable compound for electric vehicles and wire and cable production method |
| CN105111556A (en) * | 2015-09-14 | 2015-12-02 | 宁波聚泰新材料科技有限公司 | Thermoplastic elastomer used for electric car charging pile cable and preparing method of thermoplastic elastomer |
| CN105348716A (en) * | 2015-10-29 | 2016-02-24 | 浙江万马高分子材料有限公司 | Halogen-free flame retardant thermoplastic elastomer EV cable material resistant to 125 DEG C and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105968872A (en) | 2016-09-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2641266C (en) | Semiconductive compositions | |
| CN103642114B (en) | 150 DEG C of high strength high electrically oil resistant irradiation crosslinking halogen-free flame-proof environmental protection cable material of polyolefin and production methods thereof | |
| CN105968872B (en) | Halogen-free flame-retardant thermoplastic elastomer new-energy automobile cable material | |
| CN109486473B (en) | Multifunctional phase-change composite material and preparation method thereof | |
| CN105131419B (en) | A kind of high voltage direct current cable semiconductive shieldin material and preparation method thereof | |
| CN104072854B (en) | Halogen rail truck extra-lnigh tension cable | |
| CN109971110B (en) | Silane cross-linked halogen-free flame-retardant TPE cable material and preparation method and application thereof | |
| CN101544790A (en) | 125 DEG C resistance low smoke non-halogen rubber-sheathed cable shielding material | |
| CN110903538A (en) | 90-DEG C cracking-resistant moisture-proof flame-retardant polyethylene cable material and preparation method thereof | |
| CN105131611A (en) | High-strength halogen-free fire resisting cable insulating plastic and preparation method thereof | |
| CN109251402A (en) | Fire-retardant electromagnetic shielding thermoplastic elastomer (TPE) nanocomposite of one kind and preparation method thereof | |
| CN106243469A (en) | A kind of POE/EPDM component-type environment friendly non-halogen insulation compound and preparation method thereof | |
| CN114031837A (en) | Crosslinkable polyethylene insulating material for high-voltage cable, preparation method and application thereof | |
| DE112019001430T5 (en) | Composition for wire coating material, insulated wire and wire harness | |
| CN104592737A (en) | Dynamic-vulcanization poly(phenylene oxide) elastomer and preparation method thereof | |
| CN107141747A (en) | A kind of breaker modeling formula sheathing material and preparation method thereof | |
| CN110746682A (en) | Oil-resistant irradiation crosslinked wire and cable material for rail transit vehicles and preparation method thereof | |
| CN114149772B (en) | Hot melt adhesive for crosslinked polyethylene cable connector and preparation method thereof | |
| KR102150247B1 (en) | Rubber composition of fuel cell cooling hose and cooling hose using the same | |
| WO2023065430A1 (en) | High-voltage cable semi-conductive shielding material featuring high-efficiency dispersion of conductive carbon black and preparation method therefor | |
| CN103160113B (en) | A kind of antimicrobial halogen-free flame PET/PA6 alloy material and preparation method thereof | |
| CN112521675B (en) | Insulating cold-resistant cable material and preparation method and application thereof | |
| KR20100041478A (en) | Thermoplastic elastomer composite composition with high dimensional stability for noise and emi shielding and use thereof | |
| CN116836482B (en) | Polypropylene composite material with flame retardant and electromagnetic shielding effects, preparation method and application thereof | |
| CN108395633A (en) | A kind of charging pile weather-proof refractory flexible cable material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 523000 Dongcheng District Tongsha Science Park Guanghui Industrial Zone, Dongguan City, Guangdong Province Patentee after: Guangdong Antopu Polymer Technology Co.,Ltd. Address before: 523000 Area B, Building 2, Guanghui Industrial Zone, Tongsha Science Park, Dongcheng District, Dongguan City, Guangdong Province Patentee before: ADVANCED THERMOPLASTIC POLYMER TECHNOLOGY Co.,Ltd. |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Halogen-free flame-retardant thermoplastic elastomer cable material for new energy automobile Effective date of registration: 20181229 Granted publication date: 20180424 Pledgee: China Co. truction Bank Corp Dongguan Dongcheng Branch Pledgor: Guangdong Antopu Polymer Technology Co.,Ltd. Registration number: 2018440000424 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| CP02 | Change in the address of a patent holder | ||
| CP02 | Change in the address of a patent holder |
Address after: 523000 Dongcheng Street Tongsha Science Park Guanghui Industrial Zone, Dongguan City, Guangdong Province Patentee after: Guangdong Antopu Polymer Technology Co.,Ltd. Address before: 523000 Dongcheng District Tongsha Science Park Guanghui Industrial Zone, Dongguan City, Guangdong Province Patentee before: Guangdong Antopu Polymer Technology Co.,Ltd. |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20230208 Granted publication date: 20180424 Pledgee: China Co. truction Bank Corp Dongguan Dongcheng Branch Pledgor: Guangdong Antopu Polymer Technology Co.,Ltd. Registration number: 2018440000424 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Halogen-free flame retardant thermoplastic elastomer cable material for new energy vehicles Effective date of registration: 20230213 Granted publication date: 20180424 Pledgee: China Co. truction Bank Corp Dongguan branch Pledgor: Guangdong Antopu Polymer Technology Co.,Ltd. Registration number: Y2023980032538 |
|
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 523000 area B2, D and E2, building 2, Guanghui Industrial Zone, Tongsha Science Park, Dongcheng Street, Dongguan City, Guangdong Province Patentee after: Guangdong Antop Polymer Technology Co.,Ltd. Address before: 523000 area B2, D and E2, building 2, Guanghui Industrial Zone, Tongsha Science Park, Dongcheng Street, Dongguan City, Guangdong Province Patentee before: Guangdong Antopu Polymer Technology Co.,Ltd. |